Sürdürülebilir Kalkınma Amaçları

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• MakaleYalnız künye2024Scopus SJRQ2/r/munzur/1709
  Degradation Products of Rhyolitic Rocks, Adsorption Applications, Isotherm Studies

  Fırat, Tülay; Sarıcı-Özdemir, Çiğdem

  Heavy metals and their toxicity are a major global concern. They are one of the major environmental problems causing serious problems for living beings. In this study, the adsorption properties of a clay sample located in nature are improved by treating with different materials, and then adsorption properties are examined. It is observed that clay sample can be used in many adsorption applications, including the adsorption of heavy metals such as copper. The clay mineral used in the study was obtained from a rhyolite type rock. Rhyolite rocks, one of the degradation products of volcanic rocks, are the volcanic counterparts of granite. In this study, rhyolite rock was crushed with suitable crushers and grinders, then sieved under 200 mesh with molecular sieve and clay minerals were obtained. The clay samples (K1,K2. K8) were synthesized by subjecting clay with acid and base. Adsorption properties of clay are due to wide surface area, surface functional groups and microporosity. Adsorption of methylene blue and iodine, adsorption from aqueous solutions of copper are done with clay samples and results were compared with samples of clay have not undergone any pre-treatment. In the study, the highest adsorption capacity was determined by applying the Freundlich isotherm. In the K6 sample treated with a base, the highest adsorption capacity was calculated as 26.98 Lg−1. In contrast, the Langmuir isotherm results were calculated in the range of 10.56 to 11.86 Lg−1. This indicates that the adsorption takes place on a heterogeneous surface. The structure and surface properties of clay were examined.

  AtıfScopus2·WoS2·OpenAlex2

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• MakaleAçık Erişim2011Scopus SJRQ2/r/munzur/4036
  Sequential and Selective Extraction of Copper in Different Soil Phases and Plant Parts from Former Industrialized Area

  Kaplan, Olcay; Kaya, Gokce; Yaman, Mehmet

  Copper (Cu) is an essential trace element for all living organisms; however, excess amounts in soil, plants, and food have negative impacts on the environment and human health. The aim of this study was to determine Cu levels in different chemical phases of soils and the relationship between Cu levels in soil phases and concentrations in plants. Soils and plants grown in these soils from an industrialized area in Turkey were analyzed using a selective and four-stage sequential extraction procedure. Copper levels in exchangeable fractions were found up to 658 mg kg(-1) while total levels were in the range of 133-5609 mg kg(-1). Copper concentrations in plant parts (roots and stem) were in the range of 2.6-240 mg kg(-1). The exchangeable forms of Cu were in the range of 3-22% of total Cu concentrations. The relationships were observed between soil Cu and Rumex plant Cu, and soil Cu and root of Brassicasea plant Cu.

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  AtıfWoS11·OpenAlex10

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