Sayyed, M.I.; Abdel-Ghany, A.M.; Askin, A.; Sedqy, E.M.; Sadeq, M.S.

In this work, we study the structural, optical and radiation shielding properties of Na2O–CaO-borate glass doped with different amounts of V2O5. A glass system with the composition (10.5CaO+ 16.5Na2O+ (73-x)B2O3+ xV2O5; where x = 0, 2.5, 5 and 10.5 mol%) was produced following the melt quenching technique. The molar volume and density of glasses both increase with the increase in V2O5:B2O3 ratios. Moreover, the average ligand field strength reduced from 2.32 to 2.15 × 1016 cm2 with the increase in V2O5:B2O3 ratios, which correlates with the increased values of molar volume and interatomic separations. Furthermore, the optical basicity of the glass samples increased from 0.601 to 0.666 with increasing V2O5:B2O3 ratios. The optical absorption spectra are studied for further investigation of the optical features. To extract the absorption edge and the absorption bands, a deconvolution process was applied to the absorption spectra. The obtained bands from this deconvolution process confirmed the presence of vanadium in its oxidation states V3+, V4+ and V5+. Furthermore, more additions of V2O5 produced an obvious reduction in Eg values from 3.69 to 3.08 eV along with a redshift in the fundamental absorption edges. These results were attributed to the further creation of nonbridging oxygens within the glass matrix. Furthermore, the addition of V2O5 rather than B2O3 enhances the radiation shielding parameters. Accordingly, the CaNaBV10.5 glass sample is the best attenuator among the fabricated CaO–Na2O–B2O3–V2O5 glasses due to the highest mass attenuation coefficient and lowest half-value layer. Moreover, the half-value layer values of the present glasses were compared to some common materials in the radiation shielding field. From this comparison, we concluded that all glass samples are better than commercial glass windows and ordinary concrete.

AtıfScopus19·OpenAlex21

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Taşgin, Yahya; Kanca, Muhammed Sait; Kök, Mediha

In this study, in order to add different properties and functions to inorganic amorphous glasses, the applicability and effects of the thin film coating produced by thermal evaporation method were examined by metallographically imaging the effects of 3%–5% CeO2 and Tm2O3 rare earth elements (REE) oxide added to selenium to change the morphology of the glass surface. As a result of the study, it has been proved that CeO 2 and Tm2O3 added to selenium can be coated by thermal evaporation method with AFM images taken from the glass surface and metallographic analyses (SEM, EDX, Mapping). The lowest roughness value was observed in 95Se–5CeO2 coating glass substrate. In all coatings, selenium, which is the main sample, was found to be active, and XRD measurements showed that the thin films were formed by agglomeration on the (101) plane. According to UV-VIS measurements, the lowest optical band energy range was observed in the 95Se–5CeO2 coating.

AtıfScopus11·WoS10·OpenAlex12

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Aslan, Naim; Kurt, Mustafa Şükrü; Mehmet Koç, Mümin

Diamond-like carbon films have found various areas of application due to their particularly durable characteristics. To enhance the electrical and optoelectronic characteristics of the material, diamond-like carbon was co-deposited with Ge on p-type Si wafer using the DC magnetron sputtering technique, from which diamond-like carbon-germanium nanocomposites were obtained. The structural properties of the nanocomposites were assessed using electron microscopy techniques. The chemical structure of the nanocomposite films was confirmed using energy dispersive spectroscopy and Raman spectroscopy. The electrical properties of the nanocomposite films were investigated via various electrical parameters as determined through current-voltage, capacitance–voltage, and conductance–voltage graphs. Photoresponsive and photosensitivity properties were also assessed using a solar simulator at various illumination intensities. It was concluded that nanocomposite thin films were responsive to light, where photosensitivity and photoresponsivity increased with increasing illumination intensity. The electrical characteristics of the nanocomposite films were associated with the frequency of the AC voltage applied.

AtıfScopus27·WoS23·OpenAlex27

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Boukhris, Imed; Kebaili, Imen; Sayyed, M.I.; Askin, A.; Rammah, Y.S.

Linear and nonlinear optical features of La3+ doped tellurite glasses in the form 75TeO2–10ZnO –5Li2O –(10-x)Nb2O5 –xLa2O3: x = 0, 0.5, 1.0, 1.5, 2.0, and 2.5 in mol% (abbreviated as La0.0. La0.5, La1.0, La1.5, La2.0, and La2.5) were investigated. Also, the γ-photons attenuation parameters were tested utilizing Geant4 simulation code. Results revealed that the molar polarizability (αmolar) takes values from 8.685 × 10−24 to 7.933 × 10−24 cm3, while the molar refraction (Rmolar) changes from 21.886 to 20.219 (cm3/mol) for La0.0 to La2.5 glasses. The static dielectric constant (εstatic) varies from 6.368 to 5.191, whereas optical electronegativity (χ*) varies from 0.690 to 0.852 for La0.0-La2.5 glasses. Non-linear optical susceptibility (χ3) decreases from 5.675 × 10−12 to 2.109 × 10−12 (esu) with increment La2O3 content in the glasses, while non-linear refractive index (n2optical) decreases from 8.472 × 10−11 to 3.488 × 10−11 (esu). The radiation attenuation characteristics for the tested glasses were investigated with the help of Geant4 code. The mass attenuation coefficient (μm) was simulated between 0.284 and 2.506 MeV. The influnce of La2O3 on the shielding parameters was examined. Among the studied glasses, La2.5 posseses the highest μm values. Also, La2.5 sample has the lowest transmission fraction, which implies that more photons can be attenuated with La2.5 glass using a thin glass layer. From the transmission fraction results, we found that thick glasses are needed to attenuate gamma rays coming at high energies. At 0.511 MeV, the half value layer (HVL) value of the La0.0 glass is 1.49 cm while, at the same energy, the HVL value of the La2.5 glass is 1.44 cm.

AtıfScopus34·OpenAlex35

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