Yüzüak, E.; Durak Yüzüak, G.

This study investigates the Martensite transition in Cu–Mn–Al alloys (CMAs) via the use of many methods, including scanning electron microscopy, temperature-dependent X-ray diffraction, resistivity and thermal measurements. The Martensite transition hysteresis and characteristic temperature are primarily determined by the alloy composition, crystal structure and residual stress. Furthermore, these alloys have been reported to have surface and crystallographic characteristics often associated with twinning structures. Resistivity experiments conducted during heating and cooling cycles demonstrate a 2.57-fold increase inside the phase change zone, emphasizing the influence of the transition on electrical conductivity. The Martensite transition temperature may be altered by 110 K by the manipulation of the electron-to-atom ratio (e/a), indicating the high susceptibility of this temperature to changes in chemical composition. Differential scanning calorimetry shows that the transition is accompanied by a maximum entropy shift of 48 J kg−1. K, which offers valuable information on the thermodynamic driving factors involved. This work successfully attains a cooling power of 1350 W, which is equivalent to the cooling power of NiTi wire (1500 W), by using a theoretical manufacturing method and optimizing the CMAs. Overall, this work clarifies the Martensite transition in CMAs, highlighting its impact on their characteristics and indicating their potential for effective thermal energy storage and release applications. It is advisable to further optimize their performance and economic viability by considering the e/a ratio.

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Aydin, Handan; Torgut, Gülben

In this study, firstly, the copolymer of acrylonitrile (AN) and styrene (St) was synthesized by solution polymerization method using 2,2′-azobisisobutyronitrile (AIBN) as an initiator. The composites of copolymer incorporating lanthanum (III) chloride (3, 6, 9 and 18 wt%), the rare earth element (REE), were prepared and thin films were produced by thermal evaporation method for optical measurement. The samples were characterized by attenuated total reflectance Fourier transform infrared (ATR–FTIR), scanning electron microscopy–energy dispersive spectroscopy (SEM–EDS) and X-ray diffraction (XRD). The glass transition temperature, which is one of the thermal properties of the synthesized copolymers and composites, was examined with a differential thermal analyzer. The changes in the optical properties of the samples produced with LaCl3 dopant were investigated using the UV–VIS spectroscopy. The optical band gaps of the samples were calculated using Tauc equation. As a result of the optical studies, it was observed that there was a change in the conductivity properties of the samples with the addition of LaCl3. The present results showed the advantage of using LaCl3 as a filler to improve the optical properties of poly(AN-co-St) samples.

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