Sürdürülebilir Kalkınma Amaçları

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• MakaleAçık Erişim2025Scopus SJRQ1/r/munzur/1296
  Monitoring of organic micropollutant behavior and fate in a full-scale conventional biological urban wastewater treatment plant

  Demirbilek, D.; İpek, U.; Yetis, U.

  Organic micropollutants, found at trace levels in nature, are causing significant concern due to their toxic, carcinogenic, and mutagenic effects. In this study, the fate and removal of organic micropollutants were monitored covering all seasons in an urban wastewater treatment plant in Turkey. The plant influent, effluent, and aeration basin were sampled seven times in the years of 2019–2020; and three surfactants (linear alkylbenzene sulfonate, nonylphenol mono-di-ethoxylate, nonylphenol), polychlorinated biphenyls and polyaromatic hydrocarbons were monitored in this context. The plant was being operated in the endogenous respiration phase during the monitoring period without sludge removal. Results obtained showed that the highest NH3-N removal (41%) of the study period was realized in March when the lowest mixed liquid volatile suspended solids value (380 mg/L) and the lowest sludge age were observed. In this month, the highest organic micropollutants removal efficiency was obtained in relation to the increased metabolic activity. On the other hand, in August, when the highest mixed liquid volatile suspended solids value (1,750 mg/L) was observed, the lowest organic micropollutants removal was recorded, with the lowest NH3-N removal (6%). The removal of linear alkylbenzene sulfonate and nonylphenol mono-di-ethoxylate was high during the period, and microorganisms could metabolize these pollutants efficiently. Polychlorinated biphenyls, polyaromatic hydrocarbons, and nonylphenol were resistant to metabolic degradation, so they were present in high amounts at various stages of the treatment process. Due to the poor plant treatment performance, a high quantity of organic micropollutants was discharged into the receiving environment.

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  AtıfScopus2·WoS2·OpenAlex2

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• MakaleAçık Erişim2023Scopus SJRQ2/r/munzur/1613
  Seasonal monitoring of microbial activity using conventional approaches in a full-scale urban biological wastewater treatment plant

  Demirbilek, Deniz; İpek, Ubeyde; Yetis, Ulku

  Activated sludge processes contain various groups of microorganisms with different metabolic properties, which are responsible for contaminants removal. Therefore, it is important to elucidate the general structure and functional properties of biomass in activated sludge processes. For this purpose, a full-scale domestic biological wastewater treatment plant in Tunceli (Turkey), Tunceli WWTP (wastewater treatment plant), was monitored to observe seasonal variations in process performance and biomass properties for a year. It was observed that nitrifying bacteria developed abundantly in the rainy and cool spring season as they were suppressed in summer because their large losses took place due to an environment containing high alkalinity values. In September, aerobic heterotrophic, nitrify, denitrify, and anaerobic activities increased. It can be said that the biomass contained young and mature microorganism in this environment in which the sludge volume index (SVI) value increased to 196 mL/g. As a result of the improvement in the structural and functional properties of biomass, the nitrogen removal efficiency reached 99%. Throughout the whole study, the structural improvement observed in biomass was reflected in its removal activity. The amount of biomass and removal activity decreased with the abundance of organic matter in the influent at the period in which biomass was closer to being categorized in the aged sludge class. The results showed that as the lowest mixed liquid suspended solids (MLSS) and mixed liquid volatile suspended solids (MLVSS) values of the year were 530 and 400 mg/L, respectively, in November 2017, MLSS and MLVSS values reached the highest amount (1700 and 1400 mg/L, respectively) in December 2017 when aerobic heterotrophic activity accelerated with a decrease in organic matter level.

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  AtıfScopus7·WoS7·OpenAlex7

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• MakaleYalnız künye2018Scopus SJRQ2/r/munzur/3481
  The determination of present and possible environmental risks in solid waste dumping site, Tunceli, Turkey

  Yildirim, Nuran Cikcikoglu; Demirbilek, Deniz; Erguven, Gokhan Onder; Kayar, Rahime; Basaran, Senay; Tulpar, Dilan

  Leachate was a major cause of high risk classification. This landfill was set as one with highest possible risk classification due to high vulnerability of private water wells to contamination from leachate flows. The aim of this study is to determine the present and possible environmental risks of the leachate spreading from solid waste dumping site in Tunceli and offer solutions for those determined environmental risks. For this purpose, the characteristics of the leachate were monitored at two station points detected in the solid waste dumping site for 7 months. The characteristics of the leachate were found for pH between 7.9 and 8.7. Oxidation reduction potential (ORP) occurred between − 143 and − 48 mV while conductivity was between 2.8 and 2.6 mS. Total solid matter (TSM) and suspended solid matter (SSM) were between 1000 and 7000 mg/l, 0.2–22.5 mg/l, respectively, while total volatile solids (TVS) occurred between 300 and 1800 mg/l for the two stations. Alkalinity was approximately between 290 and 5210 mg/l, while biological oxygen demand (BOD5) and chemical oxygen demand (COD) results were 15–606 mg/l and 60–1160 mg/l, respectively, for two stations in all sampling time. In both stations, orthophosphate, ammonium nitrogen, nitrate, sulfate, and chloride analyses stayed between 3.04 and 921.1 mg/l; 0.29–619.36 mg/l; 8.94–135.04 mg/l; 125.9–1360.9 mg/l and 99.9–1249.9 mg/l, respectively, in 6 months. As a result of the characterization studies obtained from the leachate, it was found that the amounts of water entering into the waste mass and the retention period of the water in the mass were very effective in the temporal character change of the leachate. According to the Discharge Standards for Solid Waste Assessment and Disposal Facilities and Discharge to Waste Water Infrastructure Facilities of waste management regulation, the results were found to be risky. Consequently, the site in question needs to be urgently rehabilitated when considering the environmental risks of the leachate spreading from the site.

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  AtıfScopus1·WoS1·OpenAlex1

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• MakaleAçık Erişim2013Scopus SJRQ2/r/munzur/4611
  Characterization and pollution potential assessment of Tunceli, Turkey municipal solid waste open dumping site leachates

  Demirbilek, Deniz; Önal, Ayten Oztufekci; Demir, Veysel; Uslu, Gulsad; Arslanoglu-Isik, Hilal

  Environmental monitoring of leachate quality from an open municipal solid waste dumping site in Tunceli, Turkey was studied in this research. The most commonly examined pollution parameters were determined on a seasonal basis. The annual average 5-day biological oxygen demand (BOD5) and chemical oxygen demand (COD) values of station points were measured as 70 and 425 mg/L, respectively, and also the average BOD5/COD ratio (a measure of biodegradability) was calculated as 0.20. The low ratio of biodegradability and slightly alkaline pH values in the leachate samples indicated that the site was characterized by methanogenic conditions. The mean ammonium-nitrogen (NH4 (+)-N) and corresponding phosphate (orthophosphate) values were assayed as 70 and 11 mg/L, respectively. The average solids content in the leachates was measured as 4,681 mg/L (total solids) and 144 mg/L (suspended solids). Very low concentrations of iron, manganese, copper, and zinc in the leachate samples were found and the concentration of cadmium was measured below detection limits. Excessive amount of nutrients and high organic and inorganic pollutant content in the leachates pose serious pollution potential to the environment. Since no drainage system or bio treatment exists in this open dumping site, high permeability of natural soil at the site and in the surrounding area and very fractured and crackled rocks under natural soil are indicators of high groundwater pollution potential in this site.

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  AtıfWoS23·OpenAlex21

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• MakaleYalnız künye2013Scopus SJRQ1/r/munzur/4808
  Geo-environmental site investigation for Tunceli, Turkey municipal solid waste disposal site

  Önal, Ayten Oztufekci; Demirbilek, Deniz; Demir, Veysel

  The environmental and geological condition of a current solid waste disposal site in the city of Tunceli, Turkey was investigated. Improper geological structure and soil properties of this unsanitary solid waste storage site as well as leachate from this site caused significant pollution in air, soil, and surface water. Natural soil characteristics and geology of the site are presented in this paper. Petrographic properties of vulcanized rubber rocks composed of tuff and volcanic sandstone at the bottom of storage sites and the mineralogical composition of the base composed of these rocks were examined. Permeability of the natural soil and index properties were determined using soil mechanics experiments (moisture content, specific gravity, Atterberg limit tests, sieve analysis, hydrometer analysis, falling-head permeability test, and standard proctor test) conducted on disturbed samples collected from excavated sites and the relationship between mineralogical composition and soil hydraulic behavior was investigated. Natural soil samples of six different parts of the site indicated that, the soil class in four samples is silty sands, sand-silt mixtures, one is clayey sands, sand-clay mixtures and one is clayey silts with slight plasticity. The values obtained using permeability tests for subsoil samples vary from 10(-5) to 10(-8) cm/s. Low permeability (10(-7) and 10(-8) cm/s) at the south part of the site increases to 10(-5) cm/s at the natural soil of the North side. Extensively faulted and fissured volcanic sandstone levels at the site give potential to waste leachate to reach deep levels. The soil composition, hydraulic conductivity, topographic conditions, and other location criteria in the current solid waste disposal site showed that the current disposal site is not suitable for this purpose. (C) 2013 Elsevier B.V. All rights reserved.

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  AtıfWoS5·OpenAlex6

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