Sürdürülebilir Kalkınma Amaçları
Yayınlar
- MakaleAçık Erişim2026Geological Formation Environments of Rare Earth Elements: Examples from Around the World and Turkiye
Çimen, Okay; Dönmez, Cahit
Rare earth elements (REEs) are critical raw materials used in strategic fields such as defense, energy, electronics, lasers, and sensor technologies, and particularly in the production of permanent magnets including NdFeB and SmCo types. Since the early 2000s, the global supply of rare earth elements has become dominated by China for mining, beneficiation, and separation processes, as non-Chinese producers have lost competitiveness due to high capital requirements and the costs imposed by environmental regulations. This review addresses the geological formation environments, deposit types, and global reserve-resource distributions of REEs within an integrated framework. REE mineralization occurs within primary geological sources such as carbonatites, alkaline magmatic systems, and iron oxide copper-gold (IOCG) deposits, as well as in secondary sources including ion-adsorption clays, placers, and lateritic formations. Primary sources are generally enriched in light REEs and are characterized by high-cost production processes, whereas heavy REEs are predominantly obtained from secondary sources. Globally, REE reserves are estimated to be approximately 90-120 Mt, while potential resources are on the order of similar to 480 Mt, with China occupying a leading position in terms of both reserves and resources. In Europe, Greenland, Sweden, Finland, Norway, Germany, and Turkiye are among the regions with significant REE potential. In Turkiye, the principal REE areas defined at the deposit scale are the Eski & scedil;ehir-K & imath;z & imath;lcaoren (Beylikova) and Malatya-Kuluncak districts. These districts are associated with alkaline magmatism and display enrichment particularly in Nd and Pr (beyond La and Ce), rendering them strategically important for NdFeB permanent magnet production. Recent studies conducted by Eti Maden indicate that the Eski & scedil;ehir-K & imath;z & imath;lcaoren area hosts a large-scale resource of approximately 694 Mt with total REE grades of1.5-1.8%. The Eski & scedil;ehir-K & imath;z & imath;lcaoren area is related to the extensional tectonic regime of Western Anatolia, whereas the Malatya-Kuluncak area is associated with post-collisional alkaline magmatism of Late Cretaceous-Early Paleocene age developed within the Central Anatolian Crystalline Complex. The presence of similar alkaline systems across Turkiye indicates significant potential for REE exploration and critical mineral strategies. This synthesis provides a comprehensive geological reference framework for the development of REE exploration strategies, the diversification of global supply chains, and evaluation of Turkiyes'REE potential.
- MakaleYalnız künye2026Scopus SJRQ1Geochemical signature, detrital zircon U–Pb, and mica Ar–Ar age systematics from the Karadere Basement Unit of the İstanbul-Zonguldak Terrane (NW, Türkiye): evidence for an Avalonian-Cadomian active continental margin
Çimen, Okay; Gücer, Mehmet Ali; Göncüoğlu, Mehmet Cemal; Akal, Cüneyt; Arslan, Mehmet; Simonetti, Antonio; Karaoğlan, Fatih
The İstanbul-Zonguldak Terrane is located in northwest Anatolia and includes several outcrops with pre-Cambrian basement units. The Karadere Basement Unit represents the easternmost basement of this terrane and is composed of paragneiss, quartzite, and orthogneiss. The paragneiss and quartzite are cut by orthogneisses and disconformably overlain by Lower Ordovician to Middle Devonian cover units. Its pre-Cambrian to Palaeozoic tectonic evolution remains poorly understood, and therefore, this study reports whole-rock trace element signatures, detrital zircon U–Pb, and muscovite Ar–Ar age data for samples of paragneiss, quartzite, amphibolite, and orthogneiss. The whole-rock geochemical data indicate that the protoliths of the paragneiss and quartzite samples investigated here could have been derived from arc-related felsic magmatic units located in an active continental margin. The protoliths of amphibolites and orthogneiss samples are gabbro and granite, respectively, and their geochemical signatures are akin to those from continental arc igneous suites. The detrital zircon U–Pb data are characterized by predominantly Mesoproterozoic (84%) and lesser amount of Palaeoproterozoic and Neoproterozoic ages and suggest an early Tonian (youngest peak age of 915 ± 18 Ma) maximum depositional age. Moreover, zircon U–Pb dating analyses from an orthogneiss sample yielded an age of 603 ± 2 Ma, indicating the occurrence of mid-Ediacaran arc magmatism. This represents one of the oldest Ediacaran ages obtained from the metamagmatic basement rocks of the İstanbul-Zonguldak Terrane. Ar–Ar dating of muscovite from ortho- and paragneiss samples yielded ages of 533 ± 25 Ma and 530 ± 9 Ma, respectively, which are interpreted as early Cambrian cooling ages. Overall, the combined results reported here reveal that the Karadere Basement Unit is markedly different from NE African basement units but displays similarities to the basement rocks of both Avalonian and Amazonian terranes. It may have been formed and metamorphosed in an Avalonian–Cadomian active continental margin during the mid- to late Neoproterozoic and early Cambrian.
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İncele - MakaleAçık Erişim2026Scopus SJRQ4Petrography, geochemistry and formation of the Sarıçimen (Van, eastern Türkiye) Fe-Ni-Co laterite deposit
Çimen, Okay
The Sarıçimen Fe-Ni laterite deposit is located in eastern Türkiye (Van province) and represents one of the important Ni and Co-enriched lateritic mineralizations formed in the ophiolitic occurences. This study aims to decipher the petrographic and geochemical signatures of the laterite horizon in order to better figure out the processes controlling Fe-Ni-Co mineralization and the genesis of the deposit. In this study, field and petrographic observations, and whole-rock geochemical data have been used to characterize the mineralogical and geochemical evolution of the lateritic horizon. Petrographic studies indicate that the protolith of the laterite zone is mostly composed of serpentinized ultramafic rocks including relics of Cr-spinel and chromite grains. This lateritic zone is characterized by hematite-and magnetite-rich zones formed above saprolitic levels that may have been derived from the weathering of ultramafic parent rocks. Whole rock geochemical analyses indicate that Fe₂O₃ and SiO₂ are the dominant oxides, and Ni concentrations vary between 0.33 and 1.01 wt.%. Also, Co values are ranging between 330 ppm and 600 ppm in the laterite samples investigated here. More importantly, correlation analyses exhibit a positive relationship between Ni and Fe₂O₃ and this may be attributed to a close association with Fe-oxide minerals during the lateritization. In contrast, a negative correlation between Ni and SiO₂ may indicate the presence of silica depletion during chemical weathering. The geochemical trends investigated here reveal that the laterite zone developed through intense lateritic weathering of ultramafic rocks, which is characterized by the removal of relatively mobile elements such as Si and Ca and the residual enrichment of Fe, Ni, and Co. The presence of Cr-spinel relics once again confirms the ultramafic origin of the parental rocks. Overall, the Sarıçimen deposit represents a Fe-Ni-Co laterite derived from nearby ultramafic sources within the ophiolitic sequence. The occurrence of Fe-Ni-Co laterite deposits at both the southwestern and northeastern segments of the Southern Neotethys Suture Zone suggests that this tectonic belt may represent a promising metallogenic area for lateritic Fe-Ni-Co mineralization in the southern Türkiye.
- MakaleYalnız künye2026Scopus SJRQ1Mineralogical and geochemical controls on Co-V-Pt-Ni enrichment in manganese mineralization: evidence from the Dilli deposit, Eastern Türkiye
Gücer, Mehmet Ali; Çimen, Okay; Aktağ, Alican; Keskin, Serdar
The growing demand for critical minerals driven by the global energy transition and advanced technologies highlights the importance of unconventional metal reservoirs. This study investigates the Ni-, Co-, V-, and Pt-enriched Dilli manganese deposit (Kemaliye-Erzincan, Eastern Türkiye) to constrain the mineralogical, geochemical, and genetic controls on critical metal enrichment in Mn oxide mineralization. An integrated approach combining field observations, petrography, X-ray diffraction (XRD), whole-rock geochemistry, mineral chemistry, and stable C-O isotope analysis was applied to better understand the potential origin of critical mineral enrichments. The mineralization is dominated by Mn4+-bearing oxides, principally pyrolusite and hollandite, accompanied by minor rhodochrosite. High MnO (39-64 wt%) and very low Al2O3 and Fe2O3 contents indicate chemical precipitation with negligible detrital input. Discrimination diagrams and trace-element systematics consistently support a structurally controlled hydrothermal origin. Chondrite-normalized REE patterns display low total REE and very low Nd contents comparable to typical hydrothermal deposits, whereas neutral to slightly positive Ce anomalies and non-chondritic Y/Ho ratios suggest limited oxidative interaction with surface-derived fluids rather than primary marine hydrogenetic growth. Stable C–O isotope compositions of co-genetic calcite are inconsistent with a purely marine depositional environment and indicate precipitation from low-to moderate-temperature hydrothermal fluids. Mineral chemistry reveals strong phase-specific partitioning: hollandite preferentially incorporates V and Ba, whereas pyrolusite is enriched in Ni. Cobalt occurs in both phases, whereas Pt may also be present in both Mn oxide phases, suggesting that trace-element distribution is influenced by both crystallochemical and physicochemical controls. The enrichment of Ni, Co, and Pt is most plausibly linked to hydrothermal fluid circulation through ultramafic units, which likely acted as the primary metal source prior to precipitation. The Dilli deposit thus represents a structurally controlled hydrothermal Mn system enriched in critical metals, emphasizing the exploration relevance of Mn oxide mineral chemistry in identifying alternative sources of critical metals in Türkiye.
- MakaleAçık Erişim2025Scopus SJRQ2Geochronological and isotopic data from the adakitic Dodurga Pluton (Central Pontides, N Türkiye): new insights for the geodynamic evolution of the northern Neotethys
Çimen, Okay; Gücer, Mehmet Ali; Simonetti, Antonio; Karaoğlan, Fatih
The Dodurga Pluton is located within the Central Pontides (northern Türkiye), has a SW–NE elongation, and consists of granodiorite and dacite porphyry. Previous studies have suggested that this pluton is Triassic in age, and its whole-rock geochemical systematics is consistent with that from adakitic magmatic occurrences rather than the classic arc granitoid suite. This study reports for the first time in situ/whole-rock radiogenic isotopic (Sr, Nd, and Pb) and mica/amphibole Ar–Ar age data to evaluate better its petrogenetic/geodynamic evolution and the chemical nature of mantle source(s). Unlike previous data, combined new in situ zircon U–Pb yield Late Cretaceous crystallization ages of 84.2 ± 0.9 Ma and 86.9 ± 0.9 Ma, and the Ar–Ar age data along with apatite fission track measurements suggest magma cooling extending to 82.3 ± 0.4 Ma and 85.4 ± 0.4 Ma, respectively. The apatite fission track (AFT) dating results also reveal that this pluton was buried at a depth of 2.5–3 km following a fast-cooling period during the Late Cretaceous and cooled/exhumed over ~2 km during the Middle–Late Miocene (15–10 Ma) in a slow cooling phase. The overall data reported here suggest that the Dodurga Pluton represents melts derived from an enriched/metasomatized mantle source that interacted with lower crustal mafic rocks in an active continental margin as a result of northward subduction of the northern branch of the Neotethys Ocean.
- MakaleAçık Erişim2024Scopus SJRQ4Erken Eosen yaşlı adakitik andezitler (Gümüşhane, KD Türkiye) içerisindeki mikrogranüler anklavların jeokimyasal karakteristikleri
Çimen, Okay; Gücer, Mehmet Ali; Güner, Abdulkadir Murat
Doğu Sakarya Zonu’ndaki (KD Türkiye) erken Senozoyik magmatizması, bölgesel tektonomagmatik gelişime dair önemli veriler sağlamaktadır. Bölgede, adakit veya adakitik intrüzif/ekstrüzif kayaçlar Geç Paleosen’den Pliyo-Kuvaterner döneme kadar yaygın olarak gözlenmektedir. Çalışma alanında, Erken Eosen adakitik andezitler, genellikle 10 km2’den küçük mostralar halinde gözlenmektedir. Adakitik bileşimli bu andezitler bol miktarda mikrogranüler anklav içermekte olup bu çalışmada petrografik/jeokimyasal özellikleri ve ana kayaç ile olan petrolojik ilişkileri irdelenmiştir. Ana kayaca kıyasla nispeten bazik bileşimli anklavlar, küreselden elipsoidala kadar değişen şekillerde ve birkaç cm ile 20 cm arasında değişen boyutlarda gözlenmektedir. Anklavlar mikrolitik yer yer porfirik dokulu olup başlıca plajiyoklas, hornblend, klinopiroksen, ortoklas ve opak minerallerden meydana gelmektedir. Gerek petrografik gerekse petrokimyasal özellikleri anklavların bazaltik andezit türünde olduğunu ve sub-alkalin bir magmadan türemiş olabileceğini göstermektedir. Ana ve iz element değişimleri, gelişimlerinde fraksiyonel kristallenmenin etkili olduğunu ve plajiyoklas, piroksen, hornblend, magnetit ve apatit ayrımlaşmasının büyük ölçüde rol oynadığını göstermiştir. Anklav ve ana kayaçların benzer iz element davranışları felsik ve mafik magmaların karışması esnasındaki etkileşim süreçlerini işaret edebilir. NTE dağılımları ise gelişimlerinde hornblend fraksiyonlaşmasının önemli rol oynadığını, buna karşılık plajiyoklas ayrımlaşmasının etkili olmadığını işaret etmektedir. Petrokimyasal veriler, anklavların ana magmasının, kuzey Neotetis Okyanusu’nun tamamen kapanmasından hemen sonra; genleşmeli tektonik rejimin başlangıç aşamalarında, amfibol-eklojit fasiyesi koşullarında okyanusal bazaltların kısmi erimesi ile üretildiğini göstermektedir.
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İncele - MakaleAçık Erişim2024Geochemical and petrological features of Carboniferous granites from the Güneydere (Bayburt) area
Gücer, Mehmet Ali; Delimehmet, Zeynep; Çimen, Okay
Middle-Late Carboniferousgranitic rocks are widely observed in larger outcrops in the Eastern Pontide orogenic belt of the Eastern Sakarya Zone. This tectonic belt is an important part of the Anatolian plate in terms of containing igneous rocks with a wide age and composition range. This study presents new petrochemical-petrological data on Carboniferous granites in the G & uuml;neydere and surrounding area of Bayburt (NE Turkey). The granitic rocks, which include an area of approximately 5 km, represent the pre-Jurassic basement in the study area. Besides, they are unconformably overlain by Early- Middle Jurassic volcano-clastics units and Late Jurassic- Early Cretaceous limestones. They mainly consist ofgranite, granite porphyry and aplite, to a lesser extent granodiorite and quartz monzonite. Rocks have high SiO2 contents (60.43-75.51%) and high K calc-alkali to shoshonitic affinities and have been derived from an I-type source. The granitic rocks are metalumine-peralumine in character and are similar to postcollisional volcanic arc granitoids. Whole-rocks major and trace element trends show that plagioclase, hornblende, biotite, apatite, and Fe-Ti oxide mineral fractionations play an important role in the formation of the rocks. It has been revealed that fractional crystallization and assimilation+magma mixing processes play a role in the development of granites. Also, the saturation temperatures calculated from the whole-rock zircon values reflect lower initial magma temperatures. All results obtained indicate that parental magma of studied granitic rocks have evolved from lower/middle crust- derived melts as a result of partial melting and differentiated and emplaced in the continental magma chamber.
AtıfOpenAlex1İncele - MakaleYayıncıda açık erişim2024Scopus SJRQ1Revisiting the depositional age and provenance characteristics of metasedimentary rocks from the basement units in the Central Pontides (N Turkey): New constraints for tectonic evolution of the southern Black Sea region
Çimen, Okay; Ali Gücer, Mehmet; Akal, Cüneyt; Cemal Göncüoğlu, Mehmet; Arslan, Mehmet; Simonetti, Antonio; Karaoğlan, Fatih
The pre-Jurassic tectonic evolution of the Central Pontides in northern Turkey is still poorly understood due to the lack of detailed geochemical and geochronological data from the basement units. Therefore, this study reports for the first time combined whole rock geochemistry, trace element data and U-Pb ages for detrital zircons, and Ar-Ar geochronological data from the metasedimentary rocks of the Devrekani Massif, Geme Complex, and the Serveçay Unit to better understand their provenance, depositional age characteristics, and tectonic evolutions. The detrital zircon U-Pb data of metasedimentary units from the Devrekani Massif, Geme Complex, and the Serveçay Unit yield ca. 191, 185 and 298 Ma maximum depositional ages (youngest age peaks), respectively. The Devrekani Massif is dominated by Permo-Carboniferous-aged detrital zircons (67 %), whereas Neoproterozoic and Devonian-aged detrital zircons are more common in the Geme Complex (47 %) and the Serveçay Unit (53 %). These distinct age distributions clearly indicate that the Devrekani Massif may has been deposited in a dissimilar location compared to the Geme Complex and the Serveçay Unit. Furthermore, in contrast to the Devrekani Massif, the source area of the metasedimentary rocks from the Geme Complex is comparable with that of the Serveçay Unit. Lastly, the obtained detrital zircon U-Pb and mica Ar-Ar ages suggest that the Devrekani Massif and the Geme Complex were deposited and metamorphosed during the Early and Middle Jurassic, respectively. The Serveçay Unit was deposited and metamorphosed in the Permian.
AtıfScopus5İncele - MakaleYayıncıda açık erişim2023Scopus SJRQ1Geochemical and radiometric data for mafic rocks from the Guleman Ophiolite (SE, Turkey): New insights on the geodynamic evolution of the southern Neo-Tethyan ocean
Sapancı, Özgür; Tokat, Gürkan; Eraslan, Nuh Kadri; Karakaya, Abdullah Onur; Gücer, Mehmet Ali; Çimen, Okay
The Guleman Ophiolite is located in the southeast of Turkey and mainly consists of harzburgites and dunites hosting economically viable chromitite bodies, and lesser amounts of cumulate and isotropic gabbro, diabase dykes, pyroxenite and locally plagiogranite. This study reports the combined whole-rock geochemical and radiogenic isotope (Sr and Nd) data for gabbro and diabase dykes, and in-situ zircon U-Pb geochronological data for plagiogranite and gabbro from the Guleman Ophiolite. Two different geochemical groups were determined based on immobile minor and trace elements, and radiogenic isotope characteristics of gabbro and diabase dykes investigated here. The first group is represented by boninites and displays highly depleted elemental patterns compared to NMORB, and spoon-shaped rare earth element profiles. Contrarily, the second group resembles back-arc basin basalts and is characterized by NMORB-like rare earth element patterns associated with negative Nb anomalies. The boninitic samples are characterized by less radiogenic 143Nd/144Nd(i) (0.51229 to 0.51267; ƐNd = −4.8 to +2.7) and more radiogenic 87Sr/86Sr(i) (0.70549 to 0.70758) isotope compositions compared to the back-arc basin basalt-like samples (143Nd/144Nd(i) = 0.51289 to 0.51296; ƐNd = +7.0 to +8.4; 87Sr/86Sr(i) = 0.70496 to 0.70629), indicating derivation from distinct and/or heterogeneous mantle source regions within a supra-subduction zone. The LA–ICP–MS zircon U-Pb analyses yielded concordant late Cretaceous ages for gabbro (82 ± 2.9 Ma) and plagiogranite (79.9 ± 0.8 Ma) samples. The overall geochemical, isotopic and geochronological data presented here suggest that the Guleman Ophiolite consists of forearc and initial back-arc spreading sections of oceanic crust, which may have been formed in an intra-oceanic subduction zone within the Berit Ocean (northern branch of the southern Neo-Tethyan ocean). Moreover, the generation of continental arc magmatism (i.e. Baskil and Esence Granitoids) was well-documented on the active margin of the Malatya-Keban Metamorphics to the north. Therefore the closure of this oceanic basin should have resulted in multiple coeval northward subduction events during the late Cretaceous.
AtıfScopus8WoS7OpenAlex9İncele - MakaleAçık Erişim2022Scopus SJRQ1Geochemical, isotopic and U-Pb geochronological investigation of the late Cretaceous Karaçayır carbonatite (Sivas, Turkey): Insights into mantle sources within a post-collisional tectonic setting
Çimen, Okay; Ağrılı, Haşim; Kuebler, Corinne; Simonetti, Antonio; Corcoran, Loretta; Simonetti, Stefanie; Çolak, Turgut; İnal, Sedat; Dönmez, Cahit
The Karaçayır carbonatite is located within the northeastern edge of the Central Anatolian Crystalline Complex, and represents one of the significant rare earth element (REE) mineralizations in Turkey. The carbonatite intrudes the associated syenite as dikes and veins, and is mainly composed of medium- to coarse-grained calcite, and lesser amounts of apatite, mica, amphibole, pyroxene, and magnetite. This study reports new and combined geochemical, radiogenic (Sr, Pb), stable (O and C), and for the first time B and Nd isotopic ratios and in-situ U-Pb age data from the Karaçayır carbonatite. The carbonate separates from the Karaçayır carbonatite are characterized by high Ba (30 to 484 ppm), Sr (613 to 9106 ppm) and total rare earth element (TREE) concentrations (172 to 2892 ppm), which are consistent with geochemical signatures for mantle-derived carbonate melts. The combined δ18OV-SMOW (+10.7 to +19.0 ‰), δ13CV-PDB (−2.9 to +1.8 ‰) and δ11B (−13.9 to −2.9 ‰) data for a majority of the carbonate separates investigated here in contrast indicate that they are the result of open system behavior involving contamination by the country rock (marble), and/or sub-solidus, low temperature alteration. Based on the combined stable and radiogenic isotopic signatures for the least altered/contaminated samples, the carbonatite magma at Karaçayır most likely represents a low-degree partial melt of an isotopically heterogeneous (metasomatized) mantle source containing EM (enriched mantle)-like components and recycled crustal carbon; the latter finding is consistent with those recorded for young (<300 Ma old) carbonatites worldwide. A weighted mean 206Pb/238U age of 69.3 ± 1.7 Ma is obtained for apatite from the Karaçayır carbonatite, and indicates its emplacement within a post-collisional tectonic setting during the late Cretaceous.
AtıfScopus7WoS8OpenAlex7İncele - MakaleYalnız künye2020Scopus SJRQ1Geochemical characteristics of the adakite-like Dodurga Pluton (Central Pontides, N Turkey): implications for Middle Triassic continental arc magmatism in southern Black Sea region
Çimen, Okay
The tracing of Triassic arc magmatism is much-debated for a long time along the Sakarya Composite Terrane in Turkey and the southern Black Sea region. The Dodurga Pluton is located in the Central Pontides (N Turkey), one of the most complicated regions around the Black Sea region, and represents the first documented middle Triassic continental arc in the region. This pluton comprises of dacite porphyry and granodiorite, and displays calc-alkaline signatures, which is in agreement with arc-related and I-type magmas. The PM-normalized multi element and CN-normalized REE patterns are akin to volcanic arc granites, and characterized by LILEs and LREEs enrichments relative to HFSEs and HREEs coupled with negative Nb anomalies, which confirm derivation in a subduction-related tectonic setting. Moreover, the major and trace element systematics of the samples including higher Sr/Y ratios (22.93–101.36) and lower Yb contents (0.31–1.30 ppm) are consistent with those from adakitic melts compared to classical arc magmas. Therefore, this pluton also represents the first middle Triassic adakite-like magmatic occurrence in Turkey. Overall petrographic and geochemical signatures reported here indicate that the Dodurga Pluton might have been derived from a heterogeneous source, mixed by melts from subducted oceanic slab and lower continental crust in an active continental margin. Based on the Tethyan evolution in the Anatolian realm, three geodynamic scenarios are possible for its formation, and it could have been formed as a result of northward or southward-subduction of the Paleotethys Ocean or northward-subduction of the northern branch of Neotethys Ocean during the middle Triassic.
AtıfScopus8WoS8OpenAlex4İncele - MakaleYalnız künye2020Scopus SJRQ1Geochemical characteristics of a pre-Middle Jurassic oceanic crust fragment from the Central Pontides in northern Turkey: Geodynamic implications on intra-oceanic subduction initiation
Çimen, Okay
The Central Pontides (northern Turkey) is one of the key localities to understand the geodynamic evolution of the Palaeo- and Neotethyan oceans. It consists of the pre-Jurassic basement units, the Early Jurassic and the Early Cretaceous accretionary complexes, the widespread Middle Jurassic continental arc magmatics and the Late Jurassic to Tertiary cover units. The Early Cretaceous accretionary complex is represented by the Central Pontide Structural Complex and includes the Middle Jurassic oceanic units, which were metamorphosed during the Early Cretaceous. Apart from these oceanic units, a few metaophiolite and serpentinite fragments have been recognized within the basement units, which may represent the remnants of an older ocean. The pre-Middle Jurassic Devrekani Metaophiolite is the largest oceanic fragment and tectonically intercalated within/between the Devrekani Metamorphics and the Çangaldağ Metamorphic Complex. It is mainly composed of harzburgites, dunites with chromite veins and metagabbros, and cut by metabasaltic andesites and metadacites. Petrographically, the gabbro consists mainly of plagioclase and clinopyroxene, and displays phaneritic/porphyritic texture. In contrast, the metabasaltic andesite includes plagioclase and mica phenocrysts within a fine-grained groundmass. Also, the metadacite is composed predominantly of quartz, plagioclase, and mica minerals. Two different magmatic groups belonging to completely different tectono-magmatic settings have been geochemically determined based on the immobile trace element systematics. The metadacites and metabasaltic andesites are akin to continental arc magmatics and characterized by negative Nb and Ta anomalies and depleted HFSE relative to Th and La contents. However, the metagabbro samples display the geochemical signatures of boninitic rocks and characterized by highly depletion in HFSEs and REEs relative to N-MORB. The Devrekani Metaophiolite in the Central Pontides may represent another remnant of pre-Middle Jurassic oceanic crust generation and can be north-eastward continuation of the Permian-aged Almacık complex and the Boğazköy Metaophiolite fragment in the western Sakarya Composite Terrane. It may have been cut by intrusions of the extensive Middle Jurassic continental arc magmatism after its imbrication within the basement unit. The presence of pre-Middle Jurassic oceanic units may indicate that the Paleozoic ocean may have survived as the Jurassic Intra-Pontide Ocean between the Scythian Platform and Sakarya Composite Terrane during the Mesozoic time. Thus, the Intra-Pontide Suture may normally include the Palaeozoic and Mesozoic remnants of the long-lived northward subducting Tethyan ocean.
AtıfScopus7WoS7OpenAlex5İncele - MakaleAçık Erişim2020Scopus SJRQ3Geochemical, stable (O, c, and b) and radiogenic (sr, nd, pb) isotopic data from the eskişehir-kızılcaören (nw-anatolia) and the malatya-kuluncak (e-central anatolia) f-ree-th deposits, Turkey: Implications for nature of carbonate-hosted mineralization
Çimen, Okay; Corcoran, Loretta; Kuebler, Corinne; Simonetti, Stefanie S.; Simonetti, Antonio
In Turkey, the largest fluorine (F)-rare earth element (REE)-thorium (Th) deposits are located within the Eskişehir-Kızılcaören (north-western Anatolia) and the Malatya-Kuluncak (east-central Anatolia) regions, and these are associated with Oligocene extensional alkaline volcanic and Late Cretecaous-Early Paleocene postcollisional intrusive rocks, respectively. In the Kızılcaören region, the basement units include the Triassic Karakaya Complex and the Late Cretaceous oceanic units (Neotethyan suture) that are cut and overlain by phonolite and carbonatite intrusions and lava flows. In the Kuluncak region, the plutonic rocks are mainly composed of syenite, quartz syenite, and rare monzonite, and these cut the late-Cretaceous Karapınar limestone, which hosts the F-REE-Th mineralization in contact zones. A carbonatite sample from the Kızılcaören region displays both a total rare earth element (TREE) concentration (4795 ppm) and δ11B (–6.83‰) isotope composition consistent with mantle-derived carbonatite; whereas it is characterized by heavier δ13C (+1.43‰) and δ18O (+20.23‰) isotope signatures compared to those for carbonatites worldwide. In contrast, the carbonates which host the F-REE-Th mineralization in the Kuluncak region are characterized by lower TREE concentrations (5.13 to 55.88 ppm), and heavier δ13C (–0.14 to –0.75‰), δ18O (+27.36 to +30.61‰), and δ11B (+5.38 to +6.89‰) isotope ratios compared to mantle-derived carbonatites. Moreover, the combined initial87Sr/86Sr (0.70584 to 0.70759) and143Nd/144Nd (0.512238 to 0.512571) isotope ratios for samples investigated here are distinct and much more radiogenic compared to those for carbonatites worldwide, and therefore indicate significant crustal input and/or hydrothermal metasomatic-related alteration. Overall, stable and radiogenic isotope data suggest that the host carbonate rocks for the F-REE-Th mineralization in both the Kızılcaören and the Kuluncak regions consist of hydrothermally metasomatized carbonatite and limestone, respectively. The mineralization in the Kızılcaören region may potentially be related to carbonatite magmatism, whereas the mineralization in the Kuluncak region, which most likely formed through interactions between the plutonic rocks and surrounding limestone at contact metamorphism zone, involved hydrothermal/magmatic fluids associated with extensive postcollisional magmatism.
AtıfScopus15WoS14OpenAlex18İncele - MakaleAçık Erişim2019Scopus SJRQ1Petrology and 40Ar-39Ar dating of paragneisses from the Devrekani Massif (Central Pontides, Northern Turkey): Implications for the Jurassic high-T metamorphism in an extensional tectonic environment
Gücer, Mehmet Ali; Arslan, Mehmet; Çimen, Okay; Sherlock, Sarah C.
The Devrekani Massif in the northern part of the Central Pontides (Northern Turkey) provides important clues to the regional tectonics and geodynamic processes associated with Jurassic high grade metamorphic conditions. This study reports new paragenetic assemblages, mineral compositions, whole-rock geochemistry and 40Ar-39Ar geochronological data from the paragneisses in the massif, and, discusses the P–T conditions and geodynamic implications of the Jurassic metamorphism during continental extension in the Central Pontides. Upper amphibolite to lower granulite facies paragneisses form one of the main lithological units in the massif. Within these, there are five different mineral parageneses with diagnostic mineral assemblages of: quartz, K-feldspar (An0-1Ab4-26Or73-96), plagioclase (An18-35), biotite [XPhl: 0.28–0.57; Mg/(Mg + Fe2+): 0.33–0.61], sillimanite, cordierite [Mg/(Mg + Fe2+): 0.48–0.71] and garnet (Alm43-80Grs0-18Prp5-23And0-4Sps10-33) with minor hercynite. Based on Na-in-Crd thermometry and GASP barometry results, the peak metamorphic conditions are 775 ± 25 °C and 6 ± 1 kbar in the massif. The field relations, petrography and bulk chemical data suggest that the paragneisses, derived from shale-wackestone and pelitic sedimentary protoliths, are typical rock lithologies of an active continental margin. They display enrichments in LILE over HFSE, coupled with negative Nb and Ti anomalies, which are geochemical signatures of subduction-related sources. It is likely that the peak metamorphism took place during the Middle–Upper Jurassic period (ca. 174–156 Ma), suggesting that the metamorphic rocks cooled to 300–350 °C at ca. 156 Ma. The mineral assemblages reveal that the prograde history passed from sillimanite zone conditions up to the cordierite-garnet-K-feldspar zone. The petrological and geochronological data indicate that the protoliths are related to multiple sources such as volcano-sedimentary successions. We conclude that the Devrekani Massif represents the products of pre-Jurassic sedimentation, and Permo-Carboniferous continental arc magmatism, overprinted by Jurassic metamorphism.
AtıfScopus9OpenAlex6İncele - MakaleYalnız künye2019Scopus SJRQ1Combined boron, radiogenic (Nd, Pb, Sr), stable (C, O) isotopic and geochemical investigations of carbonatites from the Blue River Region, British Columbia (Canada): Implications for mantle sources and recycling of crustal carbon
Çimen, Okay; Kuebler, Corinne; Simonetti, Stefanie S.; Corcoran, Loretta; Mitchell, Roger; Simonetti, Antonio
This study reports the combined major, minor and trace element compositions, and stable (C, O), radiogenic (Nd, Pb, and Sr) isotopic compositions, and first δ11B isotopic data for the Fir, Felix, Gum, and Howard Creek carbonatites from the Blue River Region, British Columbia (Canada). These sill-like occurrences were intruded into Late Proterozoic strata during rifting and extensional episodes during the Late Cambrian and Devonian -Mississippian, and subsequently deformed and metamorphosed to amphibolite grade in relation to a collisional-type tectonic environment. The carbonatites at Fir, Gum, and Felix contain both calcite and dolomite, whereas the carbonatite at Howard Creek contains only calcite. The dolomite compositions reported here are consistent with those experimentally determined by direct partial melting of metasomatized peridotitic mantle. The combined major and trace element compositions and δ13CPDB (−5.37 to −4.85‰) and δ18OSMOW (9.14 to 9.62‰) values for all the samples investigated are consistent with those for primary igneous carbonate and support their mantle origin. However, these signatures cannot be attributed to closed system melt differentiation from a single parental melt. The initial Nd, Pb, and Sr isotopic ratios are highly variable and suggest generation from multiple, small degree parental melts derived from a heterogeneous mantle source. The δ11B values for carbonates from Felix, Gum, and Howard Creek vary between −8.67 and −6.36‰, and overlap the range for asthenospheric mantle (−7.1 ± 0.9‰), whereas two samples from Fir yield heavier values of −3.98 and −2.47‰. The latter indicate the presence of recycled crustal carbon in their mantle source region, which is consistent with those for young (<300 Ma) carbonatites worldwide. The radiogenic and B isotope results for the Blue River carbonatites are compared to those from contrasting, anorogenic tectonic settings at Chipman Lake, Fen, and Jacupiranga, and indicate that similar upper mantle sources are being tapped for carbonatite melt generation. The pristine, mantle-like δ11B values reported here for the Blue River carbonatites clearly demonstrate that this isotope system is robust and was not perturbed by post-solidification tectono-metamorphic events. This observation indicates that B isotope signatures are a valuable tool for deciphering the nature of the upper mantle sources for carbonates of igneous origin.
AtıfScopus28OpenAlex25İncele - MakaleAçık Erişim2018The new findings on the Late Devonian volcanism in the Eastern Taurides (Develi, Kayseri): Preliminary data
Çimen, Okay
The Tauride-Anatolide Platfom includes of widespread Paleozoic (Cambrian to Permian) units, which rarely consist magmatic rocks that were identified in two areas: Eastern Taurides (SW of Tufanbeyli and Yahyali) and Central Taurides (Northern Konya). There are problematic views related to the magmatic evolution of these rocks. The available geochemical database is mostly concentrated on the magmatics from the Central Taurides (Konya Region). In this study, the mafic volcanic rocks were recently found in the Eastern Taurides (Develi-Kayseri). These mafic volcanics are intercalated with the Late Devonian limestones and covered by the Early Carboniferous sandstones. The geochemical charateristics of the volcanic rocks exhibit back arc basin (BAB) features with slightly negative Nb anomalies, normal-MORB (NMORB)-like high field strength element (HFSE) patterns and flat REE profile. The newly found basic volcanic rocks in the Eastern Taurides geochemically resemble the meta-diabase dykes in the Konya and Yahyali regions, which were assigned to a subduction related event. The new data reported in this study will benefit to better understand the mid-Paleozoic evolution of the Taurides.
AtıfWoS9OpenAlex1İncele - MakaleYalnız künye2018Scopus SJRQ2Assessment of pollution potential of the Hasangazi chromite pit (Tunceli, Turkey): implications for the natural environment
Çimen, Okay; Öztüfekçi Önal, Ayten; Akyol, Eylem Akarsu
The Hasangazi chromite pit is an abandoned mine located to the east of the town of Pülümür (Tunceli, Turkey). The surface water that circulates in the pit flows into the Pülümür stream via the Turnadere creek. The quality of the surface water and soil from the region is important regarding the ecosystem in the Tunceli area. The open pit operations in the chromite deposits may be the cause of toxic element enrichments. To understand the effects of such pits, samples from the sediments, soil, waste material, and surface water were collected from the Hasangazi pit and its surrounding area. Samples were mineralogically and geochemically analyzed by XRD, ICP-OES, and ICP-MS methods. Mineralogical analyses showed the presence of chrysotile and plagioclase in the sediment and soil samples. These samples are also enriched in toxic elements, e.g., Cr, Ni, and Co. In particular, the Cr and Ni concentrations exceed the limits of soil pollution regulation of Turkey and the US Environmental Protection Agency. Overall the Cr, Ni, and chrysotile contents demonstrate the impact of the abandoned pit and the ultramafic rocks. Moreover, the surface water samples in the dry season have Zn concentrations above the toxic levels that may have been derived from the volcanic rocks. Environmental remediation precautions should immediately be taken around this inactive pit.
AtıfScopus6WoS6OpenAlex8İncele - MakaleAçık Erişim2018Scopus SJRQ1New zircon U-Pb LA-ICP-MS ages and Hf isotope data from the Central Pontides (Turkey): Geological and geodynamic constraints
Çimen, Okay; Göncüoğlu, M. Cemal; Simonetti, Antonio; Sayit, Kaan
The Central Pontides in northern Anatolia is located on the accretionary complex formed by the closure of Neotethyan Intra-Pontide Ocean between the southern Eurasian margin (Istanbul-Zonguldak Terrane) and the Cimmerian Sakarya Composite Terrane. Among other components of the oceanic lithosphere, it comprises not yet well-dated felsic igneous rocks formed in arc-basin as well as continent margin settings. In-situ U-Pb age results for zircons from the arc-basin system (öangaldağ Metamorphic Complex) and the continental arc (Devrekani Metadiorite and Granitoid) yield ages of 176 ± 6 Ma, 163 ± 9 Ma and 165 ± 3 Ma, respectively. Corresponding in-situ average (initial) 176Hf/177Hf initial ratios are 0.28261 ± 0.00003, 0.28267 ± 0.00002 and 0.28290 ± 0.00004 for these units and indicative of a subduction-modified mantle source. The new U-Pb ages and Hf isotope data from these oceanic and continental arc units together with regional geological constraints support the presence of a multiple subduction system within the Intra-Pontide Ocean during the Middle Jurassic.
AtıfScopus39OpenAlex32İncele - MakaleYalnız künye2018Scopus SJRQ2Preliminary geochemical data of the mafic rocks from the ovacik and Pülümür ophiolite zone (Eastern Anatolia, Turkey): Implications for the geodynamic evolution of the northern neotethyan ocean
Çimen, Okay; Önal, Ayten Öztüfekçi
The İzmir-Ankara-Erzincan-Sevan-Akera Suture Belt (IAESASB) stretches from the Aegean Sea to the Lesser Caucasus and includes the remnants of the Northern Neotethys. The Ovacık and Pülümür Ophiolite Zone (OPOZ) to the north of Tunceli is less-known members of this belt. In this study, preliminary geochemical data from the basaltic and gabbroic rocks from this zone are presented to provide the first insights into their geochemistry. The studied mafic samples exhibit geochemical characteristics of an intra-oceanic subduction system. Three types of samples were differentiated on the basis of their major, trace and rare earth element (REE) geochemistry. The first one is boninitic and displays highly depleted elemental pattern (relative to N-MORB) and concave REE profile. The second type is akin to back-arc basin basalts (BABB) and generally reflects normal-MORB (NMORB)-like high field strength element (HFSE) patterns coupled with negative Nb anomalies. The last type is relatively similar to the BABB-type, but it lacks the marked negative anomaly in Nb and can be ascribed to the mid-ocean ridge basalt (MORB). The overall geochemical features suggest that these mafic rocks were predominantly generated in a supra-subduction setting from a subduction-modified mantle source. It is further suggested that the Ovacık and Pülümür Ophiolite Zone was formed in an oceanic arc-basin system within the northward subducting Northern Neotethys.
AtıfScopus7İncele - MakaleAçık Erişim2017Scopus SJRQ1Whole rock geochemistry, Zircon U–Pb and Hf isotope systematics of the Çangaldağ Pluton: Evidences for Middle Jurassic Continental Arc Magmatism in the Central Pontides, Turkey
Çimen, Okay; Göncüoğlu, M. Cemal; Simonetti, Antonio; Sayit, Kaan
The Central Pontides (Turkey) includes several igneous complexes, which are predominantly Permo-Carboniferous and Middle Jurassic in age. The Çangaldağ Pluton is one of the largest igneous bodies located in the northern Central Pontides, whose age and tectono-magmatic evaluation is important to constrain the geological evolution of the Northern Neotethys. The pluton tectonically overlies the Çangaldağ Metamorphic Complex, which represents an arc–back-arc complex of Middle Jurassic age. The Çangaldağ Pluton consists mainly of non-metamorphic gabbroic diorite, dacite porphyry, and lesser amount of granitic rocks. Geochemically, the various rock types are akin to volcanic arc magmas displaying Th/Nb and light rare earth element/heavy rare earth element enrichments. In-situ U–Pb age results of zircons from dacite porphyry and granite samples yield ages of 161 ± 5 Ma and 170 ± 2 Ma, respectively. Corresponding in-situ average 176Hf/177Hf initial ratios are 0.28287 ± 0.00004 and 0.28213 ± 0.00002 for the dacite porphyry and granite samples, respectively. These results are consistent with derivation from a subduction-modified mantle source. Based on Hf isotope compositions, TDM model ages vary between 624 and 1512 Ma and suggest that the arc magmatism associated with the Çangaldağ Pluton may have involved partial melting of Neoproterozoic/Mesoproterozoic crustal rocks, a common feature in Gondwana-derived terranes. The geochemical, Hf isotope, and geochronological data reported here confirm the presence of a continental arc system during the Middle Jurassic in the Central Pontides, and suggests that the Çangaldağ Pluton formed during northward subduction of the Intra-Pontide branch of the Northern Neotethys.
AtıfScopus35OpenAlex32İncele