Sürdürülebilir Kalkınma Amaçları
Yayınlar
- MakaleAçık Erişim2026Scopus SJRQ1Integrating experimental and atomistic insights into the rejuvenation of aged binder using bio-based rejuvenators
Kurban, Mustafa; Yalcin, Beyza Furtana; Yilmaz, Mehmet; Akpinar, Sinan; Kök, Baha Vural; Hekim, Seda; Özdemir, Ahmet Münir; Yalcin, Erkut; Göktaş, Fahrettin
This study integrates experimental and computational methods to evaluate the rejuvenation performance of an aged asphalt binder using two novel bio-based additives, 1T and 2T. The aged binder, sourced from reclaimed asphalt pavement (RAP), was modified with 25 wt% of each rejuvenator (denoted as 1T25 and 2T25, respectively). SARA (Saturates, Aromatics, Resins, Asphaltenes) fractionation and colloidal indices were used to assess compositional recovery. Both additives increased aromatic and resin contents while reducing asphaltenes. The 2T-modified binder achieved the highest colloidal stability (Ic = 0.29) and the most pronounced improvement in stability indicators (CI and Ic) among the tested systems. Complementary molecular dynamics (MD) simulations using the COMPASSII force field modeled the structural and thermodynamic behavior of RAP and rejuvenated systems. The 2T25 system exhibited higher density and more compact molecular packing, suggesting stronger cohesive organization and reduced free volume, whereas 1T25 showed greater molecular spacing and flexibility. RDF analysis and converged thermodynamic/structural trajectories (energy, temperature, cell length, and density stabilization) further supported rejuvenator-dependent rearrangement of packing during equilibration. Overall, MD acts as a mechanistic bridge that interprets experimental SARA/CI/Ic trends and supports design-oriented development of sustainable rejuvenators.
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İncele - MakaleAçık Erişim2025Scopus SJRQ3Effect of polymer modification on bitumen rheology: A comparative study of bitumens obtained from different sources
Özdemir, Ahmet Münir; Yalçln, Beyza Furtana; Yllmaz, Mehmet
The rheological and mechanical properties of bituminous binders vary significantly depending on the crude oil source. Consequently, the response of binders from different sources to polymer modification also differs. This study compares the rheological performance of B160/220 penetration-grade binders sourced from the Turkey-Batman and Iraq-Lanaz refineries, modified with styrene-butadiene-styrene (SBS), the most widely used polymer additive. To evaluate high-temperature performance, performance grade and frequency sweep tests were conducted using a dynamic shear rheometer. In addition to experimental assessments, the rheological behavior of the binders was analyzed using the Christensen-Anderson, Cross, and Carreau-Yasuda models. Time-temperature superposition principle master curves were generated to characterize their viscoelastic behavior. Zero shear viscosity (ZSV) values were determined using the Cross and Carreau-Yasuda models to examine the impact of polymer modification on binder viscosity. The findings indicate that the initial rheological properties of bitumen significantly influence its response to SBS modification. For instance, the G∗/sin δvalue increased by up to 199% at 64°C with 4% SBS addition, while the softening point rose by 9.5°C compared to unmodified binders. Modelled ZSV values showed more than a sevenfold increase in some cases, especially in Iraqi binders. On the other hand, at -18°C, the m-value dropped to 0.282 in the B-SBS4 binder, indicating a potential risk of low-temperature cracking. While polymer modification improved the rheological properties of both bitumen types, its effectiveness varied depending on the source.
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