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- MakaleAçık Erişim2025Scopus SJRQ4Adsorption of RB-5 Dyestuff onto Boric Acid-Zinc Nanoalloys: Isotherm, Kinetic, and Thermodynamic Investigations
İlhan, Hasan; Güler, Ömer; Şi̇mşek, Tuncay; Alkan, Salih
In this study, boric acid-zinc (BA-Zn) nanoalloys were employed as an adsorbent for the removal of RB-5 dyestuff from aqueous solutions. The investigation focused on analyzing the impact of the initial dyestuff concentration, solution pH, temperature, and equilibrium contact time on the adsorption process of RB-5. The adsorption behavior of RB-5 onto the surface of BA-Zn-nanoalloys was explored, with a particular emphasis on the influence of initial dyestuff concentration and solution pH. The adsorption equilibrium data were subjected to analysis using Langmuir, Freundlich, DRK, and Temkin isotherm models. The results revealed a consistent alignment of RB-5 adsorption with both Langmuir and Temkin isotherms. Notably, the Langmuir adsorption capacity of BA-Zn-nanoparticles for RB-5 adsorption was determined to be 11.77mg / g at a temperature of 25°C. In the Temkin isotherm model, an adsorption constant (AT) of 1.003 was obtained. The calculated adsorption energy from the DR adsorption model was 1.09kJ / mol, implying a physical interaction-driven adsorption process. The empirical data further exhibited conformity with the pseudo-second order kinetic model, reflecting the rate-limiting step and overall kinetics of the adsorption process. Complementary to this, thermodynamic parameters such as enthalpy (ΔH0), Gibbs free energy (ΔG0), and entropy (ΔS0) were evaluated to discern the energetics of BA-Zn-nanoparticle RB-5 adsorption. This study not only underscores the effectiveness of BA-Zn nanoalloys as a potential adsorbent for RB-5 dyestuff removal but also contributes to the understanding of the underlying adsorption mechanisms and energetics. The insights gained hold implications for the development of sustainable and efficient strategies for wastewater treatment and environmental protection.
- MakaleYalnız künye2024Scopus SJRQ2Activity of nanosized copper-boron alloys against Phytophthora species
Yiğit, Uğur; Türkkan, Muharrem; İlhan, Hasan; Şimşek, Tuncay; Güler, Ömer; Derviş, Sibel
This study aimed to evaluate the antifungal activity of copper-boron (Cu-B) nanoalloys against a range of Phytophthora species, including P. capsici, P. citrophthora, P. palmivora, P. cinnamomi, P. nicotianae, P. cactorum, P. plurivora, P. inundata, and P. megasperma. The nanoalloys were synthesized via mechanical alloying under an argon atmosphere, resulting in the formation of nanocrystalline Cu-B nanoalloys with irregular morphology and particle sizes ranging from 50 to 240 nm. At a concentration of 250 µg mL−1, the Cu-B nanoalloys demonstrated complete inhibition of mycelial growth, sporangium production, and zoospore germination in all tested Phytophthora species. The EC50 values for mycelial growth ranged from 28.02 to 120.17 µg mL−1, while for sporangium production and zoospore germination, they were below 10 µg mL−1. Furthermore, the nanoalloys exhibited fungicidal activity against specific Phytophthora species, such as P. capsici, P. citrophthora, P. inundata, and P. megasperma, at concentrations of 100, 250, 250, and 250 µg mL−1, respectively. Notably, the Cu-B nanoalloys displayed significant protective and curative effects on tuber rot severity in P. nicotianae-inoculated potatoes, resulting in reductions of 94.13% and 92.61% compared to the control, respectively, at a concentration of 10 µg mL−1 (P < 0.05). These findings highlight the potential of Cu-B nanoalloys as a promising fungicide for the management of plant diseases caused by Phytophthora spp.
AtıfScopus3WoS1OpenAlex2
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