Özkul, İskender; Kalay, Ece; Güler, Seval Hale; Karaduman, Oktay; Şimşek, Telem; Bülbül, Zeynel Abidin; Aksu Canbay, Canan; Sen Baykal, Duygu; ALMisned, Ghada; Tekin, H.O.

Rare-earth substitution provides a route for tailoring the structural, magnetic, and gamma-ray attenuation behaviour of Ho-based Co-Mn double perovskites; however, the combined effects of rare-earth ionic size, magnetic character, and substitution level remain insufficiently understood. In this study, Ho1.5La0.5CoMnO6, Ho1.2Er0.8CoMnO6, Ho1.3Sm0.7CoMnO6, and Ho2CoMnO6 were synthesized through a two-step route involving mechanical alloying to obtain precursor powders, followed by annealing at 1000 °C in air to promote oxidation and double-perovskite phase formation. Their structural, thermal, surface-chemical, magnetic, and gamma-ray attenuation properties were examined by X-ray diffraction, thermal analysis, X-ray photoelectron spectroscopy, SEM-EDS, vibrating-sample magnetometry, and theoretical shielding calculations based on half-value layer (HVL) and transmission factor (TF) parameters. The XRD patterns were consistent with predominantly monoclinic P21/n type double-perovskite structures, while weak additional reflections suggested possible minor secondary phases. SEM-EDS showed homogeneous elemental distributions, and XPS analysis indicated Co2+ dominated and mixed Mn-valence characteristics in the spectra where reliable component analysis was possible. All compositions exhibited a low-temperature ferromagnetic-like field response but did not reach magnetic saturation at 3 T. Ho2CoMnO6 and Ho1.3Sm0.7CoMnO6 showed the highest field-dependent magnetization values at 10 K, whereas Ho1.2Er0.8CoMnO6 displayed the lowest response. The theoretical gamma-ray attenuation calculations showed clear composition-dependent differences. At 0.662 MeV, the HVL values were 1.0650, 0.9972, 1.0438, and 0.9967 cm for Ho1.5La0.5CoMnO6, Ho1.2Er0.8CoMnO6, Ho1.3Sm0.7CoMnO6, and Ho2CoMnO6, respectively. At the same photon energy and a thickness of 1.0 cm, the corresponding TF values were 0.0896, 0.0858, 0.0882, and 0.0860. Thus, Ho1.2Er0.8CoMnO6 and Ho2CoMnO6 exhibited the lowest HVL and TF values among the investigated compositions. The shielding calculations identified Ho1.2Er0.8CoMnO6 and Ho2CoMnO6 as the most effective attenuators, with lower HVL and TF values across the investigated energy range. These results show that rare-earth substitution enables compositional tuning of magnetic and theoretical gamma-ray attenuation behaviour, with the observed trends reflecting the combined influence of rare-earth ionic size, magnetic character, substitution level, and valence-state complexity.

İncele

Özkul, İskender; Kalay, Ece; Guler, Omer; Aksu Canbay, Canan

Half-metallic Heusler alloys are promising materials for spintronic and thermoelectric applications. These alloys exhibit metallic conductivity in one spin direction while acting as insulators in the opposite spin direction, enabling nearly 100% spin polarization. This property is crucial for spintronic devices such as magnetic tunnel junctions (MTJs), magnetic random-access memories, and spin-based transistors. This study investigates the electronic, magnetic, and structural properties of Heusler alloys, focusing on their synthesis methods, atomic ordering, and modelling via density functional theory (DFT). DFT-based calculations serve as a key tool for predicting band structures, spin polarization, and magnetic properties. Additionally, the effects of disorder, strain, and compositional changes on material properties are analysed to explore performance optimization strategies. The potential applications of Heusler alloys in spintronic memory devices, thermoelectric energy conversion, and quantum technologies are also discussed. This work is presented as a review article and systematically compiles and interprets findings from the existing literature to provide a broad understanding of the topic. By integrating theoretical and experimental approaches, this study provides a comprehensive overview of the role of these materials in advanced technological applications.

İncele

Karaduman, Oktay; Özkul, İskender; Aksu Canbay, Canan

Cu-based shape memory alloys (SMAs), except for exhibiting shape recovery, superelasticity, and high damping, are desirable because these smart materials have higher electrical and thermal conductivity and much lower prices than NiTi SMAs. However, they also have some downsides in mechanical strength and brittleness (mostly stemming from their coarse grain structure) and thermal instability. Therefore, adding some grain refining elements to these SMAs to improve their shape memory effect (SME), and thermal, structural, and mechanical properties is a widespread and simple way that significantly affects their martensitic phase transitions, structure, and mechanical properties. One of these grain-refining elements is titanium. Its thermal conductivity is lower than those of Cu and Al elements and has a low solubility in Cu-matrix. Besides the effects of small Al variations, the use of minor amounts of titanium in binary CuAl-base alloys can show impressive effects on all characteristics of these shape memory alloys, such as shape memory effect properties, martensitic transformation kinetics parameters, and microstructural features. In this research work, CuAlTi ternary high-temperature shape memory alloys (HTSMAs) with new compositions were produced by the arc melting method without a complicating use of Mn or Ni components in usual ternary CuAlMn and CuAlNi shape memory alloys. Thermal analyses of the prepared samples of the alloys were investigated by using differential scanning calorimetry (DSC) and differential thermal analysis (DTA) measurements. In contrast, x-ray diffraction (XRD) test results and optical micrographs were used for analyzing the structure of the alloy samples. The effect of different amounts of low soluble and grain refining Ti element on the binary CuAl alloy system was investigated.

AtıfScopus2·WoS2·OpenAlex2

İncele

Karaduman, Oktay; Özkul, İskender; Güler, Seval Hale; Aksu Canbay, Canan

In this study, two high-temperature shape memory alloys (HTSMAs) of CuAlV with unprecedented chemical compositions were fabricated using the arc melting technique, followed by traditional ice-brine water quenching after the melting process. To characterize the shape memory properties and structure of the alloys, a series of tests including differential calorimetry (DSC and DTA), EDS, optical microscopy, and XRD were conducted. The DSC tests, performed at different heating and cooling rates, demonstrated highly stable reversible martensitic phase transformation peaks at high temperatures, which were also confirmed by the results of DTA tests. Microstructural XRD and optical microscopy tests were conducted at room temperature, revealing the martensitic structure of the alloys in both cases. Based on all the results, the effects of different minor amounts of vanadium additives directly on the CuAlV alloy were discussed.

AtıfScopus2·WoS2·OpenAlex3

İncele

Özkul, İskender; Boyrazli, Mustafa; Aksu Canbay, Canan; Başbağ, Güneş; Karaduman, Oktay

Shape memory alloys (SMAs) constitute the second largest commercial smart material class after piezoelectric materials. Different SMA alloy systems or SMAs with miscellaneous functionalities and characteristic properties have been designed for using in different applications until today. High temperature shape memory alloys (HTSMAs) are also widely desired to be used in various smart materials applications. HTSMAs with different functional and characteristic properties are muchly demanded for different tasks to be done by these alloys or devices designed by these alloys. A common and practical way to fabricate SMAs or HTSMAs with different shape memory effect (SME) and other properties is to fabricate them with different alloying compositions and add different additive elements. In this work, a quaternary CuAlZnMg HTSMA with an unprecedented composition consisting minor amount of zinc and magnesium additives was produced by arc melting method. As a result of applying post-homogenization in high β–phase temperature region and immediate quenching, the microstructural mechanism of a SME property was formed in the produced alloy. After then, to examine SME characteristics of the CuAlZnMg alloy some differential thermal analysis (DTA), microstructural (XRD) and magnetization (VSM) characterization tests were carried out. The DTA results showed that the alloy is a HTSMA exhibiting reverse martensitic transformations at temperature range between 167 °C and 489 °C. The XRD pattern obtained at room temperature revealed the martensite phases formed in the alloy, which phases are the base mechanism of the reversible martensitic transformation (the SME property) of the alloy. The VSM test showed that the alloy exhibit a diamagnetic property with a weak ferromagnetic coercivity contribution.

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