Sürdürülebilir Kalkınma Amaçları
Yayınlar
- MakaleAçık Erişim2025Scopus SJRQ3Role of tungsten oxide (WO3) on thermal and optical properties of smart polymer composites
Aydın, Handan; Özen Öner, Ecem; Aydın, Cihat
Tungsten oxide, a versatile transition metal with numerous polymorphs and sub-stoichiometric compositions, containing inherent tunnels and oxygen vacancies, has become a current field of study due to its rich crystal structure, high electrochemical stability, easy accessibility, and environmental friendliness. Thus, the versatile structure of WO3-based materials makes them promising candidates for advanced applications. Our study aims to provide valuable insights into the performance of these materials used in various fields. The structural, optical, and thermal characteristics of PVC-PCL composites doped with tungsten oxide (WO3) were examined in this work. According to DSC research, the thermal characteristics of the polymer matrix were significantly impacted by the addition of WO3. The thermal stability was found to have increased based on the TGA measurement findings. XRD analyses revealed that as the doping rate increased, improved crystallinity was seen. According to SEM tests, the grain clusters are uniformly mixed and the tungsten oxide is evenly spread across the surface. The dopant reacted either chemically or physically with the polymer matrix, according to the ATR-FTIR spectra of PVC-PCL matrix nanocomposite films. An improvement in conductivity with an increase in dopant concentration was noted in the optical experiments. Thus, it can be stated that PVC-PCL composites doped with WO3 can be used in optoelectronic, various industrial, and biomedical application areas due to their structural, optical, and thermal properties.
AtıfScopus1WoS1OpenAlex1
İncele - MakaleYalnız künye2024Scopus SJRQ2Synthesis and characterization of MgO-doped PHA bio-composites
Aydın, Handan
In this study, a highly useable MgO doped polymer composite of Polyhydroxyalkanoates (PHA), which is an alternative to conventional plastics and an environmentally friendly plastic material due to its biodegradability, was investigated. PHA-MgO composites were obtained by stirring in a suitable solution for a long time with the help of a homogenizer. Then, MgO was added and the changes in Poly Hydroxy Alkonate (PHA) polymer composites were investigated according to the changing MgO ratio. Composites were prepared by adding MgO at different ratios of 1 %, 5 %, 10 % and 15 % into PHA. The structural results of the prepared samples were investigated by using XRD (X-Ray Diffraction) and SEM (Scanning Electron Microscopy). In addition, the thermal properties of the composites were investigated by DSC (Differential Scanning Calorimetry) and TGA (Thermogravimetric Analysis). Furthermore, the optical properties of PHA-MgO composites were determined by UV-VIS spectrometry. Finally, since PHA polymer exhibits shape memory properties, the shape memory properties of the composites were also investigated.
AtıfScopus2WoS2OpenAlex3İncele - MakaleAçık Erişim2019Scopus SJRQ1Al-doped ZnO as a multifunctional nanomaterial: Structural, morphological, optical and low-temperature gas sensing properties
Aydın, Handan; Yakuphanoglu, Fahrettin; Aydın, Cihat
In this study, zinc oxide thin films doped with Al at different atomic ratios (0.1%, 0.5%, 1%, 2%, 5%) were prepared using sol-gel spin coating method. Crystal structure, surface morphology, optical properties of the films and their response to ammonia gas were examined. XRD results showed that the ZnO thin films had a hexagonal polycrystalline structure. It was concluded from the calculation of the crystal size and lattice constant of the films that the produced samples were a nanomaterial. Scanning electron microscope (SEM) and atomic force microscope (AFM) images of the samples revealed that the morphology was composed of nanostructured particles and a cluster structure made of the combination of these particles. The optical band gap (Eg) of the prepared films were found within the range of 3.251 eV–3.342 eV by using the optical absorption method. Characteristics of susceptibility against ammonia gas were evaluated depending on the Al dopant. The obtained results showed that the gas response along with the structural, morphological, and optical properties of ZnO thin films changed with Al dopant. The produced thin film samples can be used as a sensor for the detection of ammonia gas in various industrial branches.
AtıfScopus66WoS59OpenAlex76İncele