Güner, Melek; Özkan, Betül Çiçek; Gürgenç, Ezgi; Macit, Cevher Kürşat; Aslan, Naim; Gurgenc, Turan

Rare-earth oxide nanoparticles offer a strategy to tune dielectric films via interfacial polarization while maintaining low-loss insulating behavior. Here, polystyrene/samarium oxide (PS/Sm2O3) nanocomposite films containing 0, 1, 3, 5, and 10 wt.% Sm2O3 were fabricated by solvent casting and evaluated as a low-loss dielectric for frequency-sensitive electronic applications. FTIR, XRD, SEM/EDX, and XPS confirmed successful Sm2O3 incorporation, preservation of the PS structure, formation of PS/Sm2O3 interfacial regions, and Sm3+/Sm–O species. XRD revealed amorphous PS with increasingly intense crystalline Sm2O3 reflections, whereas SEM/EDX showed relatively uniform filler distribution at low and moderate loadings and partial agglomeration at 10 wt.%. Dielectric spectroscopy at room temperature from 1 kHz to 1 MHz showed a frequency-dependent response governed by interfacial polarization and limited charge transport. At 1 kHz, the dielectric constant increased from 8.67241 ± 0.00280 for pure PS to 10.13061 ± 0.00641 for PS-10, while the loss tangent remained low (∼ 0.068). The dielectric loss increased moderately from 0.59535 ± 0.00236–0.69194 ± 0.00710, and AC conductivity rose from (3.31202 ± 0.01314) × 10−10 to (3.84935 ± 0.03948) × 10−10 S cm−1. These results indicate interface-controlled dielectric enhancement without conductive percolation, highlighting PS/Sm2O3 films for capacitor dielectric layers, insulating films, flexible electronics, and frequency-sensitive dielectric technologies.

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