Sürdürülebilir Kalkınma Amaçları
Yayınlar
- MakaleYalnız künye2023Scopus SJRQ3Green Synthesis and Encapsulation of Superparamagnetic Magnetite for Mercury (II) Removal: Adsorption Isotherms, Adsorption Kinetics, and Thermodynamic Studies
Alp Kavlo, Hevidar; Ince, Muharrem; Kaplan Ince, Olcay; Aydogdu, Burcu; Ozcan, Cemile
Mercury (II) ions have significant ecological impacts. In the current study, magnetized iron oxide (Fe3O4) nanoparticles were green synthesized and encapsulated with alginate (ALG). The nanoparticles were converted into a composite (Fe3O4/ALG). The Fe3O4/ALG beads were used to remove Hg (II) from industrial wastewater. Characterization was performed by X-ray diffraction (XRD), scanning electron microscopy—energy dispersive spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy (FT-IR), and thermogravimetric analysis-differential thermal analysis (TGA-DTA). A central composite design (CCD) approach was performed to define the experimental conditions providing the highest global adsorption efficiency and to optimize the pH, temperature and adsorbent mass. Hg (II) concentrations were determined by flame and electrothermal atomic absorption spectrometry (FAAS and ETAAS). The limits of detection (LOD) and quantification (LOQ) were 1.2 mg L−1 and 3.5 mg L−1 for FAAS and 0.2 µg L−1 and 0.5 µg L−1 for ETAAS, respectively. Additionally, Langmuir, Freundlich, and Temkin isotherm models were employed to determine the adsorption mechanism. The adsorption capacity of Fe3O4/ALG was determined to be 49.18 mg g−1 by the Langmuir model. Kinetic studies revealed that the adsorption of Hg (II) best fitted the pseudo-second order model. The Gibb’s free energy (ΔG°) values showed that the adsorption of Hg (II) on Fe3O4/ALG occurred spontaneously.
AtıfScopus8WoS8OpenAlex10
İncele - MakaleAçık Erişim2011Scopus SJRQ4Determination of Elements in Thermal Springs for Monitoring Pre-Earthquake Activites by ICP-MS
Yaman, Mehmet; Sasmaz, Ahmet; Kaya, Gokce; Ince, Muharrem; Karaaslan, Nagihan M.; Ozcan, Cemile; Akkus, Sukran
AtıfOpenAlex3İncele - MakaleYalnız künye2010Scopus SJRQ3Use of Flame Atomic Absorption Spectrometry in Diagnosis of Cancerous and Non-Cancerous Breast Tissues: Comparison of Metal Concentrations
Kaya, Gokce; Akdeniz, Ismail; Ozcan, Cemile; Kilinc, Ersin; Yaman, Mehmet
- MakaleAçık Erişim2010Scopus SJRQ2Flame Atomic Absorption Spectrometric Determination of Pb, Cd, and Cu in Pinus nigra L. and Eriobotrya japonica Leaves Used as Biomonitors in Environmental Pollution
Kaya, Gokce; Ozcan, Cemile; Yaman, Mehmet
The assessment of trace metal pollution in Gaziantep city-Turkey has been studied using plant leaves of Pinus nigra L. and Eriobotrya japonica as biomonitor. The concentrations up to 3,056 mg Pb kg(-1) in the needles of Pinus nigra L., and 367 ng Cd g(-1) in the leaves of Eriobotrya japonica were determined. The observed Cu concentrations were in range of 1.6-7.1 mg kg(-1). The Pb, Cd, and Cu levels in soils were determined to be in the range of 17-602, 0.142-0.656, and 12-38 mg kg(-1), respectively. It was concluded that Pinus nigra L. can be considered as both biomonitor of atmospheric Pb pollution and hyperaccumulator plant.
AtıfWoS41OpenAlex37
İncele - MakaleYalnız künye2009Scopus SJRQ3Synthesis of New Polymeric Resin and Its Application in Solid Phase Extraction of Copper in Water Samples Using STAT-FAAS
Timur, Irfan; Senkal, B. Filiz; Kaplan, Olcay; Kaya, Gokce; Ozcan, Cemile; Karaaslan, Nagihan M.; Yaman, Mehmet
- MakaleAçık Erişim2009Scopus SJRQ2Acrylamide concentrations in grilled foodstuffs of Turkish kitchen by high performance liquid chromatography-mass spectrometry
Kaplan, Olcay; Kaya, Gokce; Ozcan, Cemile; Ince, Muharrem; Yaman, Mehmet
For over ten years, there has been a considerable interest in determination of acrylamide in foodstuffs. It was known that both protein-rich and carbohydrates-rich foods cooked at high-temperatures can cause acrylamide formation. However, carbohydrates-rich foods such as potato chips and biscuit samples have been the common studied foods compared with protein-rich foods such as meat samples. In this study, determination of acrylamide in these two group foods was examined using HPLC-MS. For this purpose, firstly, the parameters that are thought to affect the response in the HPLC-MS analysis were optimized. The optimized conditions were found to be 0.3 ml min(-1) for flow rate of mobile phase, 40 mu l for injection volume, 5 degrees C for column temperature and 70 V for fragmentor potential. The optimized method was applied for the determination of acrylamide levels in Turkish foodstuffs including grilled meat and chicken samples, potato chips, coffee and biscuit. The obtained concentrations for all studied foods were in the range of 20-250 mu g kg(-1). The results showed that acrylamide concentrations highly varied depending on the kind of food samples. (C) 2009 Elsevier B.V. All rights reserved.
AtıfWoS36OpenAlex45İncele