Boonin, K.; Yasaka, P.; Limkitjaroenporn, P.; Rajaramakrishna, R.; Askin, A.; Sayyed, M.I.; Kothan, S.; Kaewkhao, J.

In this study, the zinc barium tellurite glasses (ZBaT) synthesized and inspected their radiation defensive mechanism and structural behavior. Glass composition (90-x) TeO2 - 10 ZnO - xBaO, where 25≤ x ≤ 35 (mol%) was prepared using the melt quenching technique and glass-forming pseudo-ternary diagram was discussed. Addition of BaO enhances the polarization in the present glasses there by it increases the bond length hence glass network expands resulting in volume. The mass attenuation coefficient (μm) of ZBaT glasses have been evaluated at various energies via Compton scattering technique. The results found that the μm, effective atomic number and effective electron density decrease with the increase in γ-ray energies which is in a good agreement with theoretical values attained using Geant4 and WinXCOM. At 25 mol% BaO content the glass samples show less mean free path (MFP) which were compared with other standard shield defensive materials. The obtained results reveal that the formation of non-bridging oxygens increased with higher concentration of BaO. The transmission spectra of the prepared glasses displayed optical light transparency thereby demonstrating their efficient role being transparent window when used as radiation defensive material without Pb component proving them as eco-friendly for environment.

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Al-Hadeethi, Y.; Sayyed, M.I.; Kaewkhao, J.; Askin, A.; Raffah, Bahaaudin M.; Mkawi, E.M.; Rajaramakrishna, R.

In the current paper, glass samples were prepared from the composition xGd2O3–(30-x)Y2O3–70B2O3 (where x = 5, 10, 15, 20 and 25 mol%) via the technique of melt-quenching. Various optical parameters and inter-atomic separation were evaluated for the fabricated samples. The results showed that the inter-substitution of Y2O3 content in replacement with Gd2O3 content in the glass matrix shows structural variation in the glass. The density increases from 3.5521 to 4.1613 g/cm3 with increase in Gd2O3 content that signifies the role of Gd2O3 being a glass modifier. The transmission spectra of the glass sample show more than 85% transmittance suggesting their superior transparency in the visible region. Also, several important shielding parameters of the prepared glass system have been computationally determined via the Geant4 model and the results were compared with Phy-X/PDS database software. The results revealed that the mass attenuation factor (µ/ρ) obtained by utilizing the two different toolkits are in agreement. The transmission fraction and the half value layer parameters of the glass system indicate that the glass sample with higher Gd concentration provides a better gamma blocking ability thanks to the high atomic number of Gd.

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