Simsek, Selcuk; Yilmaz, Ersen; Boztug, Ali

Maleic anhydride-styrene-methyl methacrylate (MA-S-MM) terpolymer was prepared. It was modified by ethylenediamine (EDA) and diethylenetriamine (DETA) in order to get cross-linked polymers bearing carboxyl and amine groups. Modified polymers used as an adsorbent for the removal of UO2 (2+) from water. The characterizations of structures of all the polymers were performed by Fourier transform infrared. The adsorptive features of adsorbents were then investigated for UO2 (2+) in view of dependency on ion concentration, pH, temperature and kinetics. Experimentally obtained isotherms were evaluated with reference to Langmuir, Freundlich and Dubinin-Radushkevich models. The maximum monolayer adsorption capacity for UO2 (2+) was found to be 1.59 and 2.43 mol kg(-1) for EDA-MA-S-MM and DETA-MA-S-MM, respectively. It can be said that the new modified polymers prepared in our laboratory have been suggested as new adsorbents for uranyl ions.

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Bolayir, Giray; Soygun, Koray; Simsek, Selcuk; Yilmaz, Ersen; Dogan, Arife; Boztug, Ali; Dogan, Orhan Murat

In the present study, tensile bond strength between on acrylic resin and a soft liner, molloplast B, was studied. To enhance the bonding capacity between these materials, acrylic resin surface was modified using ethyl methacrylate, iso-butyl methacrylate or tert-butyl methacrylate monomers. The monomers were applied onto the surfaces of methacrylate components for 60, 120 or 180 s and the bond strength values were obtained. The values were statistically compared. Changes on the modified surfaces were investigated by fourier transform infared spectroscopy with attenuated total reflectance (FTIR-ATR). The highest bond strength value was obtained from 120 s treatments with ethyl methacrylate and the lowest value was obtained from 60 s treatments with iso-butyl methacrylate. These high alkyl monomers also had secondary interactions on the acrylic surfaces, evidenced by FTIR-ATR.

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