Sürdürülebilir Kalkınma Amaçları
Yayınlar
- MakaleYalnız künye2024Scopus SJRQ1Synthesis, characterization and application of cross-linked functional terpolymer through epoxy group as sorbent for extraction of cadmium from waters and foods: Multivariate optimization
Yılmaz, Ersen; Boztuğ, Ali; Ul Haq, Hameed; Boczkaj, Grzegorz; Altunay, Nail
The purpose of this study was to develop a selective sorbent for cadmium ions (Cd(II)) enrichment in orbital shaker assisted solid phase microextraction (OS-SPME) from different aqueous and food samples. A maleic anhydride-styrene-glycidyl methacrylate (MA-St-GMA) terpolymer was synthesized and characterized in detail. Experimental variables of sample preparation step were optimized using a central composite design (CCD). The final determination step was performed using flame atomic absorption spectroscopy (FAAS). The MA-St-GMA sorbent exhibited a high adsorption capacity (195.9 mg g−1) for the Cd(II) ion. The developed method under optimal conditions provides satisfactory performance and a significant improvement compared to other protocols available in the literature. The linear range and detection limit of the method is 0.1–130 ng mL−1 and 0.03 ng mL−1, respectively. The robustness, intraday/interday precision, selectivity, and accuracy of the method were investigated. To further validate the method, a dedicated series of analysis was performed using certified reference materials (CRMs). This part of the study confirmed the applicability of the method for routine analysis. The OS-SPME-FAAS method was validated using water and food samples. Relative standard deviations and recovery for real-world samples were in ranges 1.7–2.2 % and 95.5–98.5 %, respectively. As a result, the MA-St-GMA sorbent showed that it could quantitatively extract Cd(II) ions from aqueous solution.
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İncele - Kitap BölümüYalnız künye2021Challenges, novel applications, and future prospects of chalcogenides and chalcogenide-based nanomaterials for photocatalysis
Ates, Mehmet; Tanaydın, Mehmet Kayra; Yılmaz, Ersen
Nanomaterials are composed of several atoms or molecules, which may be of various sizes and morphologies. Manmade nanomaterials are specially produced to take advantage of the unique properties of nanoscale. There are many metal chalcogenides with different structures and compositions such as CdSe, InAs, CdS, GaN, InGeAs, CdTe, PbS, PbSe, ZnS, Na2S, CaTe, Ti2S, and Cu2Se. The diversity of metal chalcogenides is related to the orbit of transition metals. In this chapter, new studies using chalcogenide compounds as photocatalysts were explained under the subtopics of metal chalcogenides and their properties, semiconductive nanostructures, nanomaterial production technique, chemical synthesis methods, and metal chalcogenides as photocatalysts. Novel applications of metal chalcogenide-based materials like water splitters, organic pollutant degraders, self-cleaning agents chalcogenide glasses and thermoelectric materials are explained in detail under the relevant headings. Future prospects of chalcogenides are also evaluated from a different perspective.
AtıfScopus30OpenAlex26İncele