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- MakaleAçık Erişim2025EFFECT OF GRAPHITE AND MAX PHASE ON THE THERMAL AND DIELECTRIC PROPERTIES OF N-VINYL CARBAZOLE AND BENZYL METHACRYLATE COPOLYMER
Barim, Esra; Gundogdu, Emrah
In this study, the P(N-vinyl carbazole-co-benzyl methacrylate) copolymer was synthesized, characterized by FT-IR/1H-NMR spectroscopic methods, and its composition was calculated from 1H NMR spectra. Composites of the copolymer with four different ratios of graphite (GR) and MAX phase (Ti3AlC2) by weight were prepared to obtain functional and novel electronic components for energy storage applications. Scanning electron microscopy, X-ray diffraction analyses were performed for some samples. Differential scanning calorimetry, thermogravimetric analysis curves were used to determine the thermal behavior of the materials. It was concluded that the composite with the highest glass transition temperatures and thermal stability was the composite with 10wt%GR/10wt%MAX additive. The thermal degradation kinetics of the copolymer and the composite containing 10wt%GR/10wt%MAX were investigated by applying the Flynn-Wall-Ozawa (FWO), Kissinger-Akahira-Sunose (KAS) methods and it was found that the thermal degradation activation energy of the composite was lower than that of the polymer. The dielectric properties of the materials were investigated at room temperature and between 0.1 kHz and 5 kHz. At 1 kHz the dielectric constants of the copolymer and 10wt%GR-doped composite were found to be 2.22 and 12.31, respectively. The composites doped with 10wt%GR and 10wt%GR/10wt%MAX were confirmed to be semiconductors.
- MakaleAçık Erişim2024ASSESSMENT OF URBAN FLOOD RISKS OF THE CITIES USING ENTROPY-VIKOR METHODS IN TURKIYE
Derse, Onur; Polat, Elifcan Gocmen
In recent years, there is growing interest for evaluation of urban flood risks of cities over the past decade due to rapid urbanization and climate change. The optimal flood risk assessment is strategically achieved not only with classical risk modelling approaches but also with holistic and comprehensive framework. This paper focuses on a detailed flood assessment providing risk database for policymakers and urban planners to decide the flood prone areas in Turkey. In this context, the Entropy based VIKOR (VIseKriterijumska Optimizacija Kompromisno Resenje) was provided to evaluate a range of flood risk criteria named number of floods, population density and number of buildings, flood protection area which are under the concept of risk dimension including hazard, exposure and vulnerability aspects. Computational results demonstrate that the provinces of & Scedil;anl & imath;urfa, Ordu, Zonguldak and Van are assigned with higher urban risk values, respectively and the ranking of the cities was presented with different q values. The findings should support practitioners and researchers for land use planning and risk reduction works as the detailed flood risk evaluation was presented in terms of the flood management.
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İncele - DergiKONYA JOURNAL OF ENGINEERING SCIENCES