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- MakaleYalnız künye2025Scopus SJRQ2Response surface method (RSM) for optimization of electrical properties of polymer/CdS composites for dielectric capacitors
Torğut, Gülben; İncesu, Rabia
This paper aims to present the statistical evaluation of dielectric constant (έ) and conductivity (σ) performance of composites preparing Maleic Anhydride (MA) and Styrene (St) polymer with various amounts of Cadmium Sülfide (CdS) by analysis of variance (ANOVA) model. For this purpose, frequency, applied voltage and CdS amount at different weight percentages were selected as input factors while dielectric constant and conductivity of the composites were selected as the response. Analysis of input factors was performed, RSM method was designed and used for estimation of response factor. From the analysis results, we found that high values of dielectric constant and conductivity were strongly related to frequency and CdS amount. However, we found that applied voltage in the selected ranges did not have a significant effect on both factors. The structural properties of the composites were investigated by Fourier Transform Infrared Spectroscopy (FTIR). The surface morphology was investigated by Scanning Electron Microscopy (SEM). The presence of CdS in polymers has been proven by X-Ray Diffraction (XRD). The thermal properties of polymers were examined by thermogravimetric analysis (TGA).
AtıfScopus1WoS2OpenAlex2
İncele - MakaleAçık Erişim2022Scopus SJRQ4Molecular Structure, Vibrational, Spectral Investigation and Quantum Chemical DFT Calculations of Poly(N-isopropyl acrylamide-co-nbutyl methacrylate)
Pihtili, Güzin; Hekim, Seda; Pekdemir, Mustafa Ersin
A new copolymer poly(N-isopropylacrylamide-co-nbutylmethacrylate) was synthesized by free radical solution polymerization process using 2,2′-Azobis(2-methylpropionitrile) as an initiator in 1,4-dioxane at 70 °C. The structure of the copolymer was characterized by Fourier Transform Infrared Spectrometer (FTIR), the proton nuclear magnetic resonance (1H NMR), and the ultraviolet-visible spectroscopy (UV-vis) method. Theoretically, density functional theory (DFT) (B3LYP) was utilized to identify the molecular geometry and then examine the vibrational frequencies and electrical characteristics of this molecule, with the 6-31G basis set in the ground state. In dichloromethane solution, UV-vis spectra of the molecule were calculated using the Time-Dependent DFT method. 1H NMR chemical shifts have been calculated with GIAO approximation, and the calculated results show good agreement with experimental chemical shifts.
AtıfScopus2WoS2OpenAlex2İncele - DergiPolymer (Korea)
- DergiMacromolecular Research