Yazarlar

• İpek, Yeliz(2)

• MakaleYalnız künye2022Scopus SJRQ2/r/munzur/3031
  Eco-Friendly, Thermal Resistant Cotton Fabric Enhanced with Nano Zinc Borate Powder

  İpek, Yeliz

  The easy burning of cotton fabrics, which have the widest usage area among natural fibers, is a serious problem. Thus, treatment with an environmental friend flame retardant material is essential for cotton fabrics. Zinc borates are multifunctional fire retardants. They can act as smoke suppressor, flame retardant and spark suppressor. Since they are non-toxic and environmental friend materials, they are ideal flame retardants for fabric treatment. In this study, nano-sized zinc borate (ZnO·3B2O3·7H2O) was synthesized and cotton fabric was treated with zinc borate powder with a novel method. Zinc borates are slightly soluble in water. They were dissolved with aid of ammonia as zinc ammonia borate complexes and were recrystalised on the cotton fabric fibers through the evaporation of ammonia. The burning resistance of treated cotton fabric was investigated. The hardness, hydrophobicity, smoke suppression and burning resistance of untreated and treated cotton fabrics were compared. Since zinc borates have smoke suppression feature, a more slight smoke was observed and a higher rate of carbonization occurred during combustion test of treated cotton fabric compared to the untreated cotton fabric. In addition, the burning rate was reduced from 2.26 cm/s to 1.26 cm/s.

  AtıfScopus4·WoS3·OpenAlex4

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• MakaleAçık Erişim2021/r/munzur/2800
  Influence of particle size, additive ratio and chemical structure of zinc borate on mechanical properties of poly(vinyl chloride)

  İpek, Yeliz

  Zinc borate (ZB) is a flame retardant and smoke supressant compound of boron. It is widely used to achieve flame resistant polymer composites. Poly(Vinyl Chloride) (PVC) is one of the commercially important polymers that is mostly used for cable insulating, windows, doors, pipes, floorings and toys etc.. On the other hand, PVC releases toxic gases during fire as decomposition products. Zinc borate addition is thought to be a solution for this problem. However, this solution leads a new problem. Zinc borate effects the mechanical properties of the PVC. In the present study, to optimize the contribution of zinc borate, with different formulations (2ZnO·3B2 O3·3.5H2 O and 4ZnO·B2 O3·H2 O), with different additive ratios (1% and 5% by weight) and different particle sizes (nano-sized and micro-sized) were added to the PVC structure and the mechanical and thermomechanical properties of each composite were investigated. Mechanical properties of composites were determined by tensile test, impact test, hardness test while thermomechanical behaviours were detected with dynamic mechanical analysis (DMA). In the perspective of mechanical strength of PVC-ZB composite, additive ratio of ZB was more effective than particle size and chemical formulation of ZB. The additive ratio more than 5% by weight can negatively affect the mechanical strength and quality of the PVC-ZB composite.

  AtıfScopus2·OpenAlex2

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