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- MakaleAçık Erişim2026Scopus SJRQ2A Strategic Pre-Mechanical Activation Approach for Reducing Acid Consumption and Ion Release on Acid Leaching of Lithium-Bearing Clays
Boylu, Feridun; Obuz Teker, Gülsen; Ersever Angur, Gafure; Özdemir, Orhan; Güven, Onur; Celik, Mehmet S.
The increasing demand for lithium and the limited availability of high-grade resources have accelerated interest in lithium-bearing clays as a promising alternative, despite their relatively lower lithium content. Lithium extraction from such clay minerals typically requires thermal treatment or acid leaching to disrupt the clay crystal lattice and enhance lithium solubility. The enrichment tailings from the Kırka Boron Processing Plant in Türkiye consist predominantly of dolomite-rich clay minerals and contain approximately 900–1200 ppm Li. Considering the substantial quantities of these tailings currently stored on-site, recovering lithium and converting these materials into a valuable resource would be of significant economic importance. However, due to their mineralogical composition, conventional acid leaching of these tailings demands relatively high sulfuric acid consumption (1.5–2.0 M H2SO4). This leads to excessively low solution pH and the generation of highly acidic waste streams, while also promoting the co-dissolution of iron (Fe) and aluminum (Al) ions at pH levels below 2, which negatively affects lithium recovery and downstream processing. In this study, mechanical activation was applied to the tailings prior to acid leaching. As a result, the acid requirement to achieve lithium extraction efficiencies of 90% and above was successfully reduced from 1.5 M to 1.0 M H2SO4. Moreover, solution pH was maintained near neutral (~7), and the undesirable dissolution of Fe and Al ions was effectively suppressed and kept under control.
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İncele - MakaleAçık Erişim2026Scopus SJRQ3Effect of mechanical activation on lithium and alkali cation release from dolomitic clay wastes of boron processing plant
Boylu, Feridun; Teker, Gülsen Obuz; Angur, Gafure Ersever; Ozdemir, Orhan; Çelik, Mehmet Sabri
With the significant increase in lithium demand and production, alternative resources such as lithium-bearing clays have increasingly attracted attention and have been considered as a potential source. In addition to conventional Li recovery methods such as acid treatment and roasting, more economical and environmentally friendly techniques such as mechanical activation followed by water leaching are also being considered. In Türkiye, wastes from boron processing plants, containing approximately 900 ppm of lithium and mainly of dolomitic clays and unrecovered boron minerals (~10-13% of waste), are considered as a potential lithium source. However, due to high dolomite and boron mineral contents, the waste material may release significant amounts of alkaline earth ions such as Na+, K+, Mg2+, Ca2+, and B2O3 during leaching, which may interfere with lithium extraction from the solution. In this study, the leaching behavior of lithium, alkali ions, and other possible elements (e.g., B2O3, Fe3+, and Al3+) from both raw clay waste and mechanically activated forms of this waste material was investigated in detail. The results showed that water leaching without sodium salt of activated waste samples achieves about 44.7–57.7% lithium recovery, yielding high lithium concentrations (80–115 ppm), low levels of alkali ions (4430 ppm Na+, 114 ppm K+, 20 ppm Ca2+, and 7 ppm Mg2+), and almost no detectable Fe3+ (<0.2 ppm) or Al3+ (0.07 ppm) ions. On the other hand, a single problem was encountered where 0.95 % of B2O3 concentrations did not decrease in water leaching at even room temperature.
- MakaleYayıncıda açık erişim2023Scopus SJRQ3Potassium chloride recovery from mechanically activated microcline through the chlorination roasting and leaching route
Alyosif, Bahaa; Uysal, Turan; Erdemoğlu, Murat
In this study, effects of mechanical activation in the chlorination roasting and water leaching route known as CaCl2 process and developed for the production of potassium chloride (KCl) from potassium feldspar ores were studied. A microcline containing K-feldspar ore with 10.89% K2O was first intensively dry milled by a planetary ball mill and mixed with calcium chloride (CaCl2) and then roasted at temperatures up to 1000 °C to obtain KCl that will be finally dissolved by the water leaching. Potassium recovery by water leaching increased rapidly up to 800 °C. At higher temperatures, the recovery decreased fast due to the evaporation of KCl. According to the K recovery values per unit energy consumed, the optimum roasting temperature was determined as 750 °C and the milling time was 15 min. It was concluded that intensive milling causes mechanical activation of the microcline to reduce the chlorination roasting temperature, which triggers a rise in the K recovery by the water leaching.
AtıfScopus9WoS8OpenAlex7İncele - MakaleYalnız künye2023Scopus SJRQ2Aluminum Recovery by Acid Leaching of Variously Enriched Pyrophyllite Ore: Effects of Pre-treatment Methods for Activation
Aydoğmuş, Ramazan; Erdemoğlu, Murat; Uysal, Turan
Effects of pre-treatment methods such as calcination for thermal activation and intensive milling for mechanical activation on the aluminum (Al) recovery by acid leaching of preliminarily enriched pyrophyllite ore via attrition scrubbing and froth flotation were investigated. XRD patterns of the calcined and the intensively milled samples were compared to determine the changes during the pre-treatment processes. Hot HCl solution was used for dissolution of aluminum to determine the Al recoveries from variously enriched and variously pre-treated pyrophyllite ore samples. Specific thermal and milling energies consumed per unit amount of ore were calculated, and the ideal activation method was suggested by comparing the activation methods in terms of energy consumption. Mechanical activation of the pyrophyllite concentrate obtained by attrition scrubbing rather than froth flotation was suggested for higher recoveries of aluminum from by acidic leaching. It was determined that operating cost (in terms of energy) of the mechanical activation is lower and aluminum recovery is higher than thermal activation. It was concluded that mechanical activation instead of thermal activation is more economical and environmentally friendly method.
AtıfScopus5WoS4OpenAlex5İncele - MakaleYalnız künye2023Scopus SJRQ2Contribution of Mechanical Activation for Obtaining Potassium Chloride from Microcline
Alyosif, Bahaa; Uysal, Turan; Aydemir, Muhammet Kürşat; Erdemoğlu, Murat
The effect of intensive milling on the conversion of microcline (KAlSi3O8) to potassium chloride (KCl) occurred during the chlorination roasting process for artificial KCl production was investigated. A feldspar ore with 10.89% K2O grade and containing microcline was dry milled by a planetary ball mill for mechanical activation. Milled ore mixed with calcium chloride was roasted at temperatures between 500 and 1000 °C to get the chlorination roasting process. The product was then leached in water to dissolve KCl occurring during the roasting, which will be precipitated from the pregnant leach solution by evaporation. Results showed that potassium recovery from the unmilled ore increased rapidly up to 800 °C, and dramatically decreased at higher temperatures due to the removal of KCl from the furnace by means of evaporation. A potassium recovery of 31.95% was achieved by the unmilled ore, whereas it was 88.43% when 15 min milled ore was roasted at 750 °C. It was concluded that intensive milling caused mechanical activation of microcline to reduce the roasting temperature of the chlorination roasting process.
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