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• MakaleYalnız künye2021Scopus SJRQ3/r/munzur/2585
  Enhanced Adhesion and Corrosion Properties of Boron Doped Bioceramic Coated 316L Implants

  Aksoy, M.E.; Aksakal, B.; Aslan, N.; Dikici, B.

  Abstract: In order to provide an effective prevention to 316L implants, a synthesized bioceramic was coated by using electrophoretic deposition (EPD). The effect of boron addition into hydroxyapatite (HA) on surface morphology, adhesion and corrosion resistance of the implant has been examined. Boron doped HA (B–HA) was synthesized by a simple chemical acid-base method with 5, 10, and 15 wt % boron additions to coat on 316L implants. The synthesized B-HA was coated on the substrates and the coated surfaces with and without B additions. Sintering took place at different temperatures and sintering rates. The coatings were characterized by X-ray diffractometer (XRD), Fourier transform infrared spectroscopy (FT–IR) and scanning electron microscope (SEM). Furthermore, adhesion and in vitro corrosion tests were conducted. The influence of boron additons on adhesion and corrosion resistance of 316L have been revealed for the coated substrates at different B additions. It was shown that boron addition increased the adhesion and corrosion resistance of the bioceramic coatings. Furthermore, the sintering effect on adhesion was also evaluated and the highest adhesion as 25.8 MPa has been reached at 750°C for 90 s and 5°C min–1 sintering conditions. It was found that using iodine as EPD dispersant has increased the charging ability of the B–HA powders in the suspension and hence eased deposition rate. The study revealed that boron-containing hydroxyapatite coatings can provide crack-free surfaces that providing high adhesion and hence increase the corrosion resistance of metallic implants. Through the results, it was also shown that the network between powders was improved and hence adhesion was increased with increasing B addition.

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  AtıfScopus10·WoS9·OpenAlex12

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• MakaleYalnız künye2018Scopus SJRQ3/r/munzur/3648
  Synthesis and Characterization of Hydroxyapatite/TiO2 Coatings on the β-Type Titanium Alloys with Different Sintering Parameters using Sol-Gel Method

  Dikici, B.; Niinomi, M.; Topuz, M.; Say, Y.; Aksakal, B.; Yilmazer, H.; Nakai, M.

  In this study, hydroxyapatite (HA) based composite films were successfully syntheses on the β-type Ti29Nb13Ta4.6Zr (TNTZ). The solutionized TNTZ substrates coated with HA and HA/Titania (TiO2) bioactive composite coatings by sol-gel method under various sintering parameters related to sintering temperatures and heating ramp rates. Microstructural observations of the coatings revealed that apatite was formed on the substrates. The hardness values of the coatings increase with increasing both the sintering temperature and the TiO2 concentration in the coatings layer. However, it was found that the heating ramp rate of the sintering was not affecting the hardness values so much. Also, the hardness values of the HA/TiO2 composite coatings at all sintering temperatures were higher than only HA coated TNTZ samples due to the existence TiO2 phases in the HA matrix. Results indicating that the doping of HA with TiO2, improve the physical consistency between the coating layer and the substrates and provide a better inter-particle bonding due to the existence TiO2 phases in the HA.

  AtıfScopus42·OpenAlex43

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