Sürdürülebilir Kalkınma Amaçları

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• MakaleAçık Erişim2026Scopus SJRQ1/r/munzur/603
  Removal of Reactive Blue 4 Dye from Aqueous Solution with Magnetic Fe3O4@Nd/Alg Beads

  Karaaslan Ayhan, Nagihan; Seker, Seda

  In this study, magnetic iron oxide@neodymium/alginate (Fe3O4@Nd/Alg) beads were prepared by ionic crosslinking with neodymium (Nd) ions, then subjected to heat treatment, and for the first time, effective removal of Reactive Blue 4 (RB 4) dye from aqueous solution was achieved with these beads. For this purpose, ideal adsorption conditions that significantly affect the removal of this dye were determined. The ideal adsorption conditions were determined as pH:5, contact time (t):60 min, amount of magnetic Fe3O4@Nd/Alg bead (m):10 mg, initial RB 4 dye concentration (C0):25 mg/L, temperature (T): 25 °C. Adsorption isotherm, kinetic and thermodynamic studies were carried out under the ideal adsorption conditions. The adsorption data was found to completely follow Langmuir model for RB 4 dye and the maximum adsorption capacity of RB 4 was found to be 263.16 mg/g. The adsorption kinetic data was found to be compatible with pseudo-second order and adsorption processes were explained by intraparticle diffusion. In adsorption thermodynamics studies, it has been determined that the nature of the adsorption reaction is spontaneous, endothermic and with increasing randomness. Furthermore, reuse studies of magnetic Fe3O4@Nd/Alg beads were carried out and it was determined that these beads could be used successfully up to 10 adsorption/desorption cycles.

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  AtıfScopus4·WoS4·OpenAlex4

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• Yüksek Lisans TeziAçık Erişim2023/r/munzur/7301
  Neodimyum/Aljinat boncukların boyar madde giderimde kullanılabilirliğinin araştırılması

  Seda Şeker

  Bu tez çalışmasında, Kongo Kırmızısı (KK) ve Parlak Mavi G (PMG) boyalarının sulu çözeltiden uzaklaştırılması için Neodimyum/Aljinat (Nd/Alg) boncukları hazırlanmış ve bu boyaların adsorpsiyon potansiyelleri incelenmiştir. Bunun için çapraz bağlama kullanılarak hazırlanan Nd/Alg boncukları FTIR, SEM-EDS ve TGA ile karakterize edilmiştir. KK ve PMG boyalarının adsorpsiyonu için adsorban (boncuk) içindeki Nd miktarı, pH, temas süresi, adsorban miktarı, başlangıç boya konsantrasyonu ve sıcaklık gibi çeşitli parametrelerin etkileri incelenmiştir. KK ve PMG boyalarının etkin uzaklaştırılması için optimum koşullar boncuktaki Nd miktarı: %3, pH: 7, temas süresi: 60 dk, boncuk miktarı: 15 mg, başlangıç boya konsantrasyonu: 25 mg/L ve sıcaklık: 298 K olarak belirlenmiştir. Adsorpsiyon izoterm çalışmaları (Langmuir ve Freundlich izotermleri) ve kinetik çalışmalar (sözde birinci mertebe ve sözde ikinci mertebe) optimum koşullar altında gerçekleştirildi. Adsorpsiyon verilerinin, KK ve PMG boyaları için Langmuir modelini takip ettiği bulunmuştur. Optimum koşullar altında maksimum adsorpsiyon kapasiteleri KK için 46.03 mg/g ve PMG için 25.25 mg/g olarak bulunmuştur. Her iki boyanın adsorpsiyon kinetik verileri sözde birinci mertebe ile uyumlu bulunmuş ve adsorpsiyon süreçleri partikül içi difüzyon ile açıklanmıştır. Termodinamik çalışmalara göre, adsorpsiyon reaksiyonunun doğası her iki boya için de spontan, ekzotermik ve artan rastgeleliktedir. Özetle, doğal bir polimer ile elde edilen Nd/Alg boncuklarının düşük maliyetli ve yüksek verimliliğe sahip olduğu ve bu boncukların küçük miktarlarının bile yüksek konsantrasyonlu boya atık sularının arıtımı için yüksek potansiyele sahip olduğu sonucuna varılabilir.

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• MakaleYalnız künye2023Scopus SJRQ1/r/munzur/1811
  Adsorption potential of neodymium/alginate beads for removal of Congo red and Brilliant blue G from aqueous solution

  Seker, S.; Karaaslan Ayhan, N.

  In this study, neodymium/alginate (Nd/Alg) beads were prepared to removal of Congo Red (CR) and Brilliant Blue G (BBG) dyes from aqueous solution and the adsorption potentials of these dyes were investigated. For this, Nd/Alg beads prepared using crosslinking were characterized by FTIR, SEM–EDS and TGA. For the adsorption of CR and BBG dyes, the effects of various parameters including the amount of Nd in adsorbent (bead), pH, contact time, adsorbent amount, initial dye concentration and temperature were investigated. The optimum conditions for the effective removal of CR and BBG dyes were determined as Nd amount in bead: 3%, pH: 7, contact time: 60 min, bead amount: 15 mg, initial dye concentration: 25 mg/L and temperature 298 K. Adsorption isotherm studies (Langmuir and Freundlich isotherms) and kinetic studies (pseudo-first-order and pseudo-second-order) were carried out under optimum conditions. The adsorption data were found to completely follow Langmuir model for CR and BBG dyes. The maximum adsorption capacities were found to be 46.03 mg/g for CR and 25.25 mg/g for BBG under optimum conditions. The adsorption kinetic data of both dyes were found to be compatible with pseudo-first-order and adsorption processes were explained by intraparticle diffusion. According to thermodynamic studies, nature of adsorption reaction was spontaneous, exothermic and increasing randomness for both dyes. As a result, it can be concluded that Nd/Alg beads obtained with a natural polymer have low cost and high efficiency and even small amounts of these beads have high potential for treatment of high concentration dye wastewater.

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  AtıfScopus10·WoS8·OpenAlex10

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