Sürdürülebilir Kalkınma Amaçları

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• MakaleYalnız künye2026Scopus SJRQ2/r/munzur/1431
  Phytoremediation of elements in municipal wastewater treatment plant effluent by Lemna gibba L.: a full-scale study

  Topal, Murat; Öbek, Erdal; Çelik, Erdal; Arslan Topal, E. Işıl

  In this study, capacity of naturally growing Lemna gibba L. in removing elements (B, As, Al, Ca, Ba, Co, Fe, Cu, K, Cr, Li, Mo, Ni, Mn, Na, Mg, Sb, P, Si, Pb, Se, Ti, Zn, V, and Sr) from the effluent of secondary clarifier of a municipal wastewater treatment plant (MWWTP) was determined week by week (W1, W2, W3, and W4) and analyzed as a whole using statistical models. To determine the removal contribution of Lemna gibba L. to the MWWTP effluent, secondary clarifier without Lemna gibba L. was used as a control. The aim here is to determine the contribution of Lemna gibba L. to MWWTP’s removal efficiency. Trace elemental quantification was conducted via validated ICP-MS following microwave-assisted acid digestion. In this context, according to the analysis results, the removal efficiency of Lemna gibba L. for Al was highest at 89.66% over the weeks. Furthermore, treatment efficiencies above 50% were achieved for Co (57.86–60.61%), Sb (64.25–67.35%), and Ti (63.27–66.21%). Based on statistical analyses, PCA (principal component analysis)) and HCA (hierarchical cluster analysis) models explained 85% of the total variance. As a result, this study demonstrated that Lemna gibba L. removes elements from MWWTP effluent, contributing to the removal efficiency of the secondary clarifier and clearly showing its potential use in phytoremediation.

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• MakaleYalnız künye2026Scopus SJRQ2/r/munzur/1423
  Optimization of native plant selection for phytomining of strategic/critical raw materials using Artificial Bee Colony algorithm

  Arslan Topal, E. Işıl; Topal, Murat; Çelik, Erdal; Öbek, Erdal

  This study investigates the potential of native plant species (NPs) as secondary sources for strategic/critical raw materials (SCRMs) through phytomining, aiming to identify the most efficient accumulator for sustainable element recovery. To achieve high-precision results, the Artificial Bee Colony (ABC) algorithm, a robust meta-heuristic optimization technique inspired by the foraging behavior of honeybees, was utilized to minimize the error between experimental data and predicted models to optimize the accumulation of key elements including cobalt (Co), strontium (Sr), antimony (Sb), vanadium (V), phosphorus (P), lanthanum (La), magnesium (Mg), titanium (Ti), aluminum (Al), and scandium (Sc). The research focused on three NP species—Musk thistle (MT), curly dock (CD), and Juncus (JS)—collected from a geothermal hot spring area. Methodological validation was performed through comparative statistical analysis and the calculation of bioconcentration factor (BCF) and translocation factor (TF) to assess phytoremediation efficiency. The ABC optimization results revealed that MT exhibited the most significant accumulation capacity, particularly for Mg, reaching a peak concentration of 3,910 mg/kgdw in the leaves. The concentration range (lowest to highest value) was between 0.01 (for La) and 3,910 mg/kgdw for the studied plants. Principal component analysis (PCA) corroborated these findings, explaining cumulative variances of 80.4% (MT), 89.4% (CD), and 76.4% (JS). The innovation of this study lies in the application of the ABC algorithm to the field of phytomining, which offers a more dynamic and flexible alternative to traditional regression-based models. The primary advantage of this proposed method is its superior global search capability and ability to handle multi-elemental interactions with high predictive accuracy. However, a potential disadvantage remains the computational complexity and the requirement for fine-tuning control parameters to ensure consistent convergence. Overall, MT is identified as a highly promising candidate for the phytomining of SCRMs, with Mg emerging as the most effectively accumulated element under the optimized ABC model.

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• MakaleAçık Erişim2026Scopus SJRQ1/r/munzur/1026
  Health risk assessment of heavy metal accumulation in fruits exposed to geothermal waters: a case study and global implications

  Arslan Topal, E Işıl; Topal, Murat; Çelik, Erdal; Öbek, Erdal

  BACKGROUND: The present study investigated the potential health risks of heavy metals (HMs) in the fruits and leaves of mulberry and sour cherry trees exposed to water from Sivas geothermal basin (Turkey). RESULTS: The target HMs were ranked according to their hazard index as: Cd < Pb < Zn < Cu < Ni < Mn < Cr. The total hazard index for mulberry and sour cherry fruits was calculated as 7.87 and 4.57, respectively, and was determined to be well above the safe threshold value of 1.0. At the same time, the calculated cancer risk values exceeded the established maximum limit (1.0 × 10−4) for Ni (6.4 × 10−3) in mulberry fruit and for Cr (1.15 × 10−3) in sour cherry fruit. Ingestion has been identified as the primary route of exposure. The study results showed that Cr and Ni metals were ranked in the order of mulberry fruit > sour cherry fruit > mulberry leaf > sour cherry leaf, and that for mulberry and sour cherry fruit. CONCLUSION: The findings indicate that edible foods exposed to geothermal waters may have adverse effects on human health. Furthermore, the study highlights the necessity of reducing water discharges from geothermal fields and implementing phytoremediation strategies to ensure food safety in geothermally active agricultural basins.

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• MakaleAçık Erişim2026Scopus SJRQ2/r/munzur/843
  Pollution estimation and health risks assessment related to the agricultural application of mussel shell-derived chitosan as organic amendment

  Arslan Topal, E. Işil; Topal, Murat; Çelik, Erdal; Öbek, Erdal

  In this study, estimation of pollution and assessment of health risks related to the agricultural application of mussel shell–derived chitosan as organic amendment were evaluated. Furthermore, considering WHO maximum permissible levels in soil, the application rates of chitosan to agricultural soils were calculated. Geo-accumulation index (Igeo), enrichment factor (EF), contamination factor (CF), pollution load index (PLI), and ecological risk index (ERI) were calculated. Mussel shell-derived chitosan generally did not contribute to soil metal loading when evaluated in terms of those indices. The highest hazard quotient for ingestion (HQing) across male (ML), female (FML), and children (CL) followed the order Cr > Ni > Mn >Pb >Zn >Cu, while maximum HQing among metals was observed in the order CL > FML > ML. For inhalation exposure, highest HQinh for all metals was also found in the order CL > FML > ML, with individual metal contributions following Mn > Ni > Cr >Zn >Pb >Cu. Maximum HQder exhibited the trend ML > FML > CL, and the metal-specific order for HQder was Cr > Pb > Ni >Zn >Mn >Cu. Hazard Index (HI) and Total HI for ingestion, inhalation and dermal exposure were all less than 1. Cancer risk was less than 1 × 10−6. Consequently, there were no pollution and health risks associated with the use of musselshell‑derived chitosan in agriculture as organic amendment.

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• MakaleAçık Erişim2024/r/munzur/6340
  Potential Human Health Risk from Toxic/Carcinogenic Arsenic in Ripe and Unripe Tomatoes Grown in Wastewater Exposed Zone

  Topal, Murat; Topal, E.Işıl Arslan; Öbek, Erdal

  The aim of the present study was to investigate the potential risk to human health from toxic/carcinogenic arsenic in ripe (RiTo) and unripe tomatoes (UnRiTo) grown in the municipal wastewater treatment plant effluents exposure zone. The arsenic concen-trations were determined in each tissue of RiTo and UnRiTo tomatoes. Arsenic values in tomatoes were root>leaf>unripe tomato>ripe tomato>stem. The maximum ED (exposure dose) value in RiTos was 1.21E-02 mg.kg-1.day-1 for child, minimum ED value was 4.80E-03 mg.kg-1.day-1 for male. The ED value was calculated as 5.44E-03 mg.kg-1.day-1 for female. The maximum ED value in UnRiTo was 2.12E-02 mg.kg-1.day-1 for child, min ED value was 8.39-03 mg.kg-1.day-1 for male. ED value was calculated as 9.51E-03 mg.kg-1.day-1 for female. EDs in RiTo and UnRiTo were child>female>male. When the HQs (hazard quotient) in RiTo and UnRiTo compared, HQ values in UnRiTo were higher. All of the HQ values were higher than 1. As a re-sult, results of tomatoes analysis show that there was non-carcinogenic and carcino-genic health risks.

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  AtıfOpenAlex2·TR Dizin1

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• MakaleAçık Erişim2024Scopus SJRQ2/r/munzur/2305
  Is Cladophora fracta an efficient tool of accumulating critical raw materials from wastewater and there a potential health risk of use of algae as organic fertilizer?

  Arslan Topal, E. Işıl; Öbek, Erdal; Topal, Murat

  In this study investigation of accumulations of critical raw materials (cobalt (Co), antimony (Sb), vanadium (V), lanthanum (La) and tungsten (W)) from wastewater by using C. fracta were aimed. Besides, assessment of the potential health risks in terms of the use of organic fertilizer obtained from the macroalga to be harvested from the treatment were also aimed. Highest Co, Sb, V, La and W accumulations by algae in reactor were 125±6.2%, 201.25±10%, 318.18±15%, 357.97±18%, and 500±25%, respectively. When compared with control, Co, Sb, V, La and W in algae increased 2.25, 3.01, 4.18, 4.58, and 6 times, respectively. The algae was very high bioaccumulative for Co and La. Highest MPI was calculated as 3.94. Non-carcinogenic risk of CRMs according to different exposure types (ingestion, inhalation, and dermal) were calculated for man, woman and child. There is not any non-carcinogenic risk from the investigated exposure ways of algae as organic fertilizer.

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  AtıfScopus2·WoS2·OpenAlex2

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• Kitap BölümüAçık Erişim2024Scopus SJRQ4/r/munzur/1844
  Heavy Metals in Cetraria islandica: Health Risk Assessment

  Topal, Murat; Arslan Topal, E. Işıl; Öbek, Erdal; Aslan, Ali

  In this chapter, potential human health risk of the heavy metals associated with usage of Cetraria islandica were evaluated. Heavy metals (lead, cadmium, manganese, chromium, copper, zinc, and nickel) were determined in Cetraria islandica. Highest and lowest heavy metal values were 87 ± 4.3 mg/kg for manganese (Mn) and 0.12 ± 0.01 mg/kg for cadmium (Cd). When potential health risk was assessed, the doses of exposure for man, woman, and child followed the order of bread > tea > dermal. Risk of health for bread and tea were child > woman > man. Also, risk of health for dermal was woman > child > man. Non-carcinogenic risk was woman > child > man for dermal way. Non-carcinogenic risks were child > woman > man for dietary. Highest total hazard index (THI) was 6.33 for chromium (Cr), lowest THI was 0.22 for zinc (Zn). THIs were zinc < copper < cadmium < nickel < lead < manganese < chromium. The THIs were higher than 1 for chromium, manganese and lead. Total highest carcinogenic value was 1.73E−03 for Ni and minimum was 1.19 E−05 for lead. Carcinogenic risks for bread (cadmium, nickel and chromium) were high. As a result, it was determined that Cetraria islandica may cause cancer risk if consumed as additive in bread. It was determined that if Cetraria islandica was consumed as tea and cream, there would be no risk of cancer and could not adversely affect human health.

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• MakaleAçık Erişim2023/r/munzur/6483
  Lichens as Biomonitors of Air Pollutants Deposition: Strategically Important Element Pollution

  Topal, Murat; Topal, E.Işıl Arslan; Aslan, Ali; Öbek, Erdal

  Investigation of various species of lichen as biomonitors of air pollutants deposition and evaluation of element pollution were aimed. Maximum accumulation was 43.9±2.1 mg/kg in X. somloensis. Strontium in lichen species was quite high. Percentages of strontium for L.pulmonaria, C.furcata, U.longissima, X.somloensis, and F.caperata were between 58% and 78% indicating the efficient accumulation of strontium. Lichens were also accumulated strategically important elements. Maximum contamination factors in lichens were for strontium and tantalum. Maximum contamination factors of hafnium, niobium, lithium, gallium, and bismuth were for L. pulmonaria while maximum contamination factors of strontium, yttrium, scandium, and cerium were for X.somloensis. Maximum contamination factor of tantalum was for F.caperata. Enrichment factors for L.pulmonaria, C.furcata, and F.caperata were higher than 10, only for bismuth while lower than 10 for U.longissima. Enrichment factors for X.somloensis were higher than 10. Pollution load indexes for L.pulmonaria and U.longissima were higher than 1. Presence of strategically important elements in lichens showed that lichen species can be used as biomonitors of air pollutants.

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  AtıfOpenAlex1

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• MakaleAçık Erişim2023/r/munzur/6477
  Toxic Elements from Critical Raw Materials Group in Ripe and Unripe Tomatoes in A Contaminated Area: Accumulation and Potential Health Risk Assessment

  Topal, Murat; Topal, E.Işıl Arslan; Öbek, Erdal

  Accumulation and health risk assessment of cobalt (Co), antimony (Sb), vanadium (V), and lanthanum (La) in tomatoes growing in an area contaminated with municipal wastewater were investigated. For this aim, tomatoe samples were taken and sepertaed into root, stem and leaf parts. Co, Sb, V and La concentrations were detected in plant organs. The arrangement of the elements in the root, stem, and leaf of ripe and unripe tomatoes was V>Co>La>Sb. According to total element values in the ripe and unripe tomatoes; the highest values were 23±1.1 mg/kg and 35±1.7 mg/kg for V, respectively. Co, Sb, V, and La values accumulated by ripe and unripe tomatoes were determined as 24.65 and 25.6 times for Co, 1.8 and 2.7 times for Sb, 46 and 70 times for V and 4.4 and 6.15 times for La, respectively when compared with control. Total Co, Sb, V, and La were male

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• MakaleAçık Erişim2023/r/munzur/6457
  Determination of some trace elements in various lichens as biomonitors of pollution and assessment of pollution status

  Topal, Murat; Topal, E.Işıl Arslan; Aslan, Ali; Öbek, Erdal

  Some trace elements in various lichens as biomonitors of pollution were investigated. Also, the pollution status was assessed by enrichment factor, contamination factor, and pollution load index. Investigated elements were Ta, Bi, Hf, Nb, Ga, Sc, Li, Y, Ce, and Sr. The lichen species were Rhizoplaca chrysoleuca, Umbilicaria vellea, Aspicilia calcarea, Pseudevernia furfuracea, and Cetraria islandica. According to the results, lichen species accumulate Sr element well. The highest trace element accumulated by Pseudevernia furfuracea (21.7±1.0 mg/kg; 75%), Rhizoplaca chrysoleuca (31.9±1.6 mg/kg; 61%), Umbilicaria vellea (16.3±0.8 mg/kg; 59%), Aspicilia calcarea (77.9±3.8 mg/kg; 88%), and Cetraria islandica (22.7±1.1 mg/kg; 75%) was determined as Sr. The highest CFs in lichens investigated were calculated for Sr, Ta, and Li. PLI values for Cetraria islandica, Aspicilia calcarea, and Umbilicaria vellea were greater than 1. As a result, it has been proven that these lichen species can be used as good biomonitors of pollution.

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  AtıfOpenAlex3·TR Dizin1

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