Sürdürülebilir Kalkınma Amaçları
Yayınlar
- MakaleAçık Erişim2026Scopus SJRQ1Integrating experimental and atomistic insights into the rejuvenation of aged binder using bio-based rejuvenators
Kurban, Mustafa; Yalcin, Beyza Furtana; Yilmaz, Mehmet; Akpinar, Sinan; Kök, Baha Vural; Hekim, Seda; Özdemir, Ahmet Münir; Yalcin, Erkut; Göktaş, Fahrettin
This study integrates experimental and computational methods to evaluate the rejuvenation performance of an aged asphalt binder using two novel bio-based additives, 1T and 2T. The aged binder, sourced from reclaimed asphalt pavement (RAP), was modified with 25 wt% of each rejuvenator (denoted as 1T25 and 2T25, respectively). SARA (Saturates, Aromatics, Resins, Asphaltenes) fractionation and colloidal indices were used to assess compositional recovery. Both additives increased aromatic and resin contents while reducing asphaltenes. The 2T-modified binder achieved the highest colloidal stability (Ic = 0.29) and the most pronounced improvement in stability indicators (CI and Ic) among the tested systems. Complementary molecular dynamics (MD) simulations using the COMPASSII force field modeled the structural and thermodynamic behavior of RAP and rejuvenated systems. The 2T25 system exhibited higher density and more compact molecular packing, suggesting stronger cohesive organization and reduced free volume, whereas 1T25 showed greater molecular spacing and flexibility. RDF analysis and converged thermodynamic/structural trajectories (energy, temperature, cell length, and density stabilization) further supported rejuvenator-dependent rearrangement of packing during equilibration. Overall, MD acts as a mechanistic bridge that interprets experimental SARA/CI/Ic trends and supports design-oriented development of sustainable rejuvenators.
AtıfScopus2OpenAlex1
İncele - MakaleAçık Erişim2026Scopus SJRQ1Sustainable material pathways: Utilizing biomass-derived bio-oils from agricultural wastes to restore aged asphalt binder properties
Yalcin, Beyza Furtana; Yilmaz, Mehmet; Yalcin, Erkut; Kok, Baha Vural
This study explores the valorization of agricultural biomass wastes into high-value bio-based materials by evaluating the performance of pyrolysis-derived bio-oils obtained from straw, pine cone, and olive pomace for the rejuvenation of aged asphalt binders. The effectiveness of these biomass-derived bio-oils was comparatively assessed against two commercial rejuvenators to enhance binder reusability using renewable resources. The optimum rejuvenator dosages were determined through penetration, viscosity, and dynamic shear rheometer (DSR) tests, while the associated physical and chemical modifications were investigated using FTIR, SEM-EDS, and elemental analyses. Penetration and viscosity results indicated that all rejuvenators significantly reduced binder stiffness and improved fluidity. DSR analysis indicated that increasing rejuvenator content reduced G∗/sin δ values, reflecting a decrease in binder stiffness and a softening effect of the rejuvenators, which contributes to restoring the viscoelastic balance of the aged binder. FTIR results demonstrated that biomass-derived bio-oils, particularly those from pine cone and straw, effectively reduced carbonyl (C=O) and sulfoxide (S=O) functional groups, indicating strong chemical rejuvenation. SEM-EDS analyses showed that the heterogeneous and porous morphology of bio-oils promoted improved interaction with the asphalt binder. Based on the combined results of the three experimental approaches, the optimum rejuvenator dosages were identified as 25% for commercial products, 35% for pine cone and olive pomace bio-oils, and 45% for straw bio-oil. Overall, the findings highlight that biomass-derived bio-oils produced via pyrolysis offer a sustainable and performance-effective pathway for converting agricultural residues into value-added materials, supporting circular bioenergy and biomass utilization strategies.
AtıfScopus2WoS3OpenAlex3İncele - MakaleAçık Erişim2025Scopus SJRQ1Rejuvenation of Recycled Asphalt Binders with Bio-Oils from Waste Biomass Pyrolysis
Yalcin, Beyza Furtana; Yilmaz, Mehmet; Yalçin, Erkut; Altundogan, Hamdi Soner
This study evaluates the effects of using bio-oil obtained from waste biomass on the physical properties, rheology, fatigue, and rutting of recycled asphalt binder. In addition, the aim of this study is to provide benefits to the environment and the economy by reusing waste materials. The bio-oils produced were produced by the pyrolysis method. B70/100 pure bitumen was chosen as the reference binder for the rejuvenation of the selected RAP binder. To ensure its properties, five different rejuvenators (two commercial + three bio-based rejuvenators) were added to the aged bitumen obtained from recycled asphalt pavement (RAP) at different rates. The produced bio-oils were compared with commercial products. The first goal of the study is to produce rejuvenators from waste materials, and the second is to achieve similar or better results with commercial rejuvenators by producing rejuvenators from waste materials. When the test results are examined, it can be seen that the aged binder was rejuvenated to the desired hardness by adding rejuvenator to it. It is seen that the penetration value of the aged binder increased by the addition of rejuvenator, whereas the softening point and viscosity values decreased.
AtıfWoS1OpenAlex1İncele - BildiriAçık Erişim2025Investigation of Mechanical Properties of Hot Mix Asphalt Modified with Elvaloy and Polyphosphoric Acid
Yilmaz, Mehmet; Yalcin, Beyza Furtana; El Naggar, H.; Barros, J.; Cachim, P.
In order for the bituminous hot mix layers to resist the increased traffic load and volume as well as the adverse environmental conditions for a long time without being deformed, the bituminous binder used in the mixture has been commonly modified with the Styrene-Butadiene-Styrene (SBS) polymer. The high demand for SBS makes it difficult to supply and therefore brings on the use of alternative additives. In this study, the combined use of Elvaloy and phosphoric acid (PPA) was investigated. Additionally, the effects on the mechanical properties of bituminous mixtures were examined. Modified binders were prepared using Elvaloy/PPA additives mixed under specified conditions. Hot mix asphalt (HMA) samples prepared with these binders were subjected to Marshall stability and flow, indirect tensile stiffness modulus, and indirect tensile fatigue tests to comprehensively evaluate the effects of modified bi nders on the mechanical properties of bituminous hot mixtures. As a result, the bituminous hot mix tests revealed that asphalt mixtures improved their mechanical properties at the specified ratios.
- BildiriAçık Erişim2024Investigation of the Effects of Different Modified Asphalts on Storage Stability
Yalcin, Beyza Furtana; Yilmaz, Mehmet; Yalcin, Erkut; Ozdemir, Ahmet Münir; El Naggar, H.; Barros, J.; Cachim, P.
In this study, the storage stability of modified bitumen prepared with bitumen additives styrene-butadiene-styrene (SBS) and American Gilsonite (AG) was evaluated. For this purpose, modified bitumen was prepared by using different ratios of each additive type. The prepared modified bitumens were subjected to storage stability test according to EN 13399 standard. Penetration, softening point and rotational viscometry tests were performed on the samples subjected to storage stability test. As a result of the penetration and softening point tests of the samples prepared with SBS after storage stability, it was determined that the penetration and softening point values of the samples obtained from the upper part of the tube were higher. This is thought to be due to the accumulation of SBS, which has a lower specific gravity than bitumen, in the upper part of the tube during the storage stability test. Considering the viscosity test results, it was determined that the viscosity values of the modified bitumen samples obtained from the upper part of the tubes were higher than the samples obtained from the lower part of the tubes.
- BildiriAçık Erişim2024Effect Of The Actıvatıon Force On The Healıng Level Of Asphalt Mıxture Wıth Embedded Capsules
Yalcin, Erkut; Yilmaz, Mehmet; Yalcin, Beyza Furtana; El Naggar, H.; Barros, J.; Cachim, P.
By increasing the asphalt mixtures' inherent capacity for self-healing, encapsulated rejuvenators can extend the service lives of asphalt pavements. The capsules are shattered when crack damage occurs, allowing the rejuvenator ingredient to seep into the cracks. In this work, a brand-new kind of capsule was created. Sunflower oil was a rejuvenator in these capsules. We looked at how well asphalt mixture samples with and without capsules self-healed under static loading. The capacity for self-healing of asphalt mixtures incorporating a novel class of capsules that contain sunflower oil as a rejuvenating agent. For this reason, the ability of the rejuvenating ingredient to diffuse inside of samples of virgin bitumen and the healing potential of combinations of cracked asphalt containing capsules have both been assessed. Due to the mechanical properties of the polymeric capsules examined. Then, using a unique mechanical test, the impact of capsule content on the crack-healing characteristics of asphalt mixtures was assessed at various healing durations (from 5 to 216h) and loads (from 0 to 85kN). As the applied load increases, the healing levels of the asphalt samples with capsules rise; later, the healing levels of the asphalt samples with capsule remain constant. According to the findings, the maximal healing level was typically attained after 96 hours and remained constant until 216 hours.