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- MakaleYalnız künye2026Scopus SJRQ2Development and Characterization of Starch/Microcrystalline Cellulose/Bentonite Intelligent Packaging Films Incorporated With Red Beet Peel Extract for Monitoring Chicken Freshness
Gürler, Nedim
This study presents the physical, mechanical, antioxidant, and application properties of films prepared by adding red beet peel extract to the starch/microcrystalline cellulose/bentonite clay polymer composites by casting method to monitor chicken breast freshness. The effects of bentonite in different proportions (0%, 1%, 5%, and 10%) were investigated. The structure of the films was elucidated by XRD, FTIR spectroscopy, and SEM for surface morphology of films. Regarding mechanical testing, the highest tensile strength starch/microcrystalline cellulose-1% bentonite film was 0.88 MPa. It was noticed that water vapor permeability (WVP) improved with the addition of bentonite. Films containing 10% bentonite clay showed a 27% decrease in water vapor permeability compared to films without clay. However, the swelling power of composites increased as the bentonite content increased. Additionally, with the addition of clay the films exhibited more opaque properties. Red beet peel extract was also incorporated to the polymer composite to monitor chicken breast freshness. The antioxidant properties of the films were accomplished using DPPH method. When red beet peel extract was incorporated into the polymer film, the highest DPPH scavenging activity increased by 50%. In summary, starch/microcrystalline cellulose/bentonite films can be used as pH-sensitive intelligent packaging for controlling the freshness of chicken breast.
- MakaleAçık Erişim2020Scopus SJRQ2Electrical properties of two-armed poly(Ɛ-CL-co-BMA) composites filled with bentonite
Pihtili, Güzin; Torğut, Gülben; Biryan, Fatih
The dielectric and electrical conductivity properties of two-armed poly(Ɛ-CL-co-BMA) copolymer and adding bentonite forms were studied. The effect of the bentonite was investigated at different quantities (%3wt, %6wt, %15 wt). The measurements were performed at frequencies between 100 Hz to 10 kHz at room temperature, and the dielectric permittivity (ε′), the dielectric loss factor (ɛ″) and conductivity (σac) were calculated. ε′ and ɛ″ increased with increasing bentonite content. In addition, changes of susceptance (B) and impedance (IZI) were examined at different frequencies ranging from 100 Hz to 10 kHz in order to investigate the effect of bentonite loading. As frequency increases, (B) increases linearly, whereas IZI decreases and remains constant at high frequencies. Two-armed copolymer synthesized using ring-opening polymerization (ROP) and Atom Transfer Radical Polymerization (ATRP) and its composites prepared with bentonite were characterized by FT-IR, 1H-NMR and SEM. Thermal behaviors were examined by TGA and DSC methods and the effect of bentonite was discussed.
AtıfScopus15WoS14
İncele - MakaleAçık Erişim2013Scopus SJRQ4Adsorption of the 2,2-Dichlorovinylphosphate on Raw and Modified Bentonites
Yönten, Vahap; Kubilay, Senol
This study aims to investigate the adsorption of the 2,2-dichlorovinylphosphate (DDVP) on raw and modified bentonite via high pressure liquid chromatography and infrared spectroscopy. The modified bentonites were prepared by adding HNO3 and Na2CO3. The Freundlich adsorption isotherm defines 2,2-dichlorovinylphosphate adsorption in aqueous and aqueous ethanol solutions through raw and modified bentonite. Variables such as temperature, time and pH were observed on 2,2-dichlorovinylphosphate adsorption. Then the capacity for maximum 2,2-dichlorovinylphosphate adsorption was measured on modified bentonite with HNO3 under the conditions of pH 3 and 40 degrees C. The modified bentonite with Na2CO3 clay used in experimental work played a major role on the adsorption of 2,2-dichlorovinylphosphate; thus modified bentonite with Na2CO3 is considered to possess better characteristics than modified bentonite with HNO3 and raw bentonite. The Freundlich isotherms of modified bentonite with Na2CO3 in aqueous-ethanol solution were found to be better than isotherms of aqueous solution for a much better 2,2-dichlorovinylphosphate adsorption.
AtıfOpenAlex1İncele - MakaleYalnız künye2012Scopus SJRQ4Adsorption of the 2,4-Dichlorophenoxyacetic Acid Dimethylamine by Raw and Modified Bentonite
Yonten, Vahap; Kubilay, Senol; Battal, Peyami
The adsorption of the 2,4-dichlorophenoxyacetic acid dimethyl amine on raw bentonite (Tokat, Turkey), modified bentonite with base and modified bentonite with acid has been studied using high pressure liquid chromatography (HPLC) and FT- infrared spectrophotometer. Sorption of 2,4-dichlorophenoxyacetic acid dimethyl amine on raw bentonite, modified bentonite with base and modified bentonite with acid was compared solving in different solutions such as aqueous and aqueous-ethanol solutions based on adsorption isotherms. The effect of temperature, time and pH were observed on adsorption of 2,4-dichlorophenoxyacetic acid dimethyl amine. Sorption mechanisms in soils, the effect of surface functional groups as well as parameters influencing adsorption were discussed. Then maximum adsorption of 2,4-dichlorophenoxyacetic acid dimethyl amine capacity was measured on modified bentonite with base in pH 5 at 40 degrees C for 24 h. The modified bentonite with base used in experimental work played a major role than on the adsorption of 2,4-dichlorophenoxyacetic acid dimethyl amine so, the modified bentonite with base has better characteristics than raw bentonite and modified bentonite with acid adsorbents. The Freundlich isotherms of aqueous-ethanol solution was better than isotherms of aqueous solution for much better to adsorb of 2,4-dichlorophenoxyacetic acid dimethyl amine.
AtıfWoS4İncele - MakaleYalnız künye2011Scopus SJRQ3The Adsorption of the 2,2 Dichlorovinylphosfate on Raw and Modified Bentonites
Yonten, Vahap; Kubilay, Senol
This study aimed to investigate the adsorption of the 2,2 Dichlorovinylphosfate (DDVP) on raw and modified bentonite using High Pressure Liquid Chromatography (HPLC) and infrared spectroscopy (FT-IR). The modified bentonite were prepared by adding HNO3 and Na2CO3. The Freundlich adsorption isotherm defines DDVP adsorption in aqueous and ethanol-aqueous solutions by raw and modified bentonite. The variables of temperature, time and pH were observed on adsorption of DDVP. Then maximum adsorption of DDVP capacity was measured on bentonite modified with HNC), in pH 3.0 and 40 degrees C. The MBB clay used in experimental work played a major role on the adsorption of DDVP so MBB has better characteristics than other adsorbents and The Freundlich isotherms of MBB in aqueous ethanol solution was better than isotherms of aqueous solution for much better to adsorb of DDVP.
AtıfWoS1İncele