Sürdürülebilir Kalkınma Amaçları
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- MakaleYalnız künye2026Scopus SJRQ2Drying Shrinkage and Microstructural Properties of Geopolymers Including Steel and Iron Particles
Gulmez, Nihan; Kockal, Niyazi Ugur
Geopolymer mortars show significantly higher shrinkage than normal Portland cement mortars. So, one of the most important disadvantages of these promising alternative binding materials for their wider applications is the cracking occurring by shrinkage. Different inserts and fibers are used in fresh mixtures in order to control drying shrinkage cracks and to provide mechanical capacity. The aim of this study is to investigate the effectiveness of using both metal particles (iron particles) and metallic fibers (steel particles) in geopolymer composites to reduce drying shrinkage. In addition, microstructural properties of composites were determined by scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses and causes of shrinkage were investigated in detail. Mixtures containing 20% silica fume have 38.4% lower drying shrinkage than slag-based mixtures. In slag-based composites, decreases in drying shrinkage were found as 18.8% and 49.1% when adding 10% iron particles or 10% steel particles compared to metal-free composites.
- MakaleAçık Erişim2026Scopus SJRQ1Enhancing the mechanical and durability properties of fly ash/GGBS-based geopolymer mortars using dunite and polypropylene fibers
Cemalgil, Selim; Gülmez, Nihan; Yön, Merve Şahin; Karataş, Mehmet
Polypropylene (PP) fiber-reinforced geopolymer mortar reduces the high brittleness of conventional geopolymer made with natural aggregates. However, the effects of different precursor materials on the performance of PP fiber-reinforced self-compacting geopolymer mortar (SCGM) remain unclear. This study investigates the feasibility of using dunite (D), a magnesium-rich ultramafic rock with consistent mineralogy and low processing energy demand that enhances thermal stability and durability, as an alternative precursor for fly ash (FA)/ground granulated blast furnace slag (GGBS)-based geopolymers. The study examined the workability, flexural and compressive strengths, and sorptivity of mortars cured at 20 ± 2°C and 60 ± 5% relative humidity, as well as their durability under freeze–thaw cycles and high-temperature exposure. Interfacial interactions between aggregates and the geopolymer matrix, along with microstructural and morphological changes caused by fire, were analyzed using scanning electron microscopy (SEM). X-ray diffraction (XRD) and thermogravimetric analysis (TGA) were also performed for detailed material characterization. The mix containing 30% dunite exhibited the highest flexural strength, reaching 5.70 MPa at 28 days, the highest among all mixes. Under fire exposure, the mix containing 10% dunite significantly reduced mechanical strength loss and retained about 33.3% higher residual flexural strength than the FA–slag control mix at 600°C.
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İncele - MakaleYalnız künye2023Scopus SJRQ2Engineering Properties of Geopolymer Mortars Containing Industrial Steel Shavings
Gülmez, Nihan; Koçkal, Niyazi Uğur
The purpose of using waste materials is to prevent the unnecessary use of resources and to reduce the amount of waste. Geopolymer, developed as an alternative to cementitious materials, prevents the depletion of natural resources and saves a large amount of energy. This paper presents the effect of waste steel shavings on the improvement of physical and mechanical properties of geopolymer mortars. For this purpose, geopolymer mortars were produced by using two binder types [slag (BFSb) and silica fume] as well as steel shavings in five different replacement percentages (0%, 2.5%, 5%, 7.5% and 10%) by volume instead of aggregate. A series of experiments on geopolymer mortars were carried out to determine properties such as bulk density, water absorption, apparent porosity, sorptivity coefficient, splitting tensile strength, flexural strength and compressive strength. Results showed that steel shavings recovered from metal processing and forming sector were highly effective at improving engineering properties of geopolymer mortars. Furthermore, although replacement of 20% by volume of BFSb with silica fume improved properties of geopolymer mortar, it was observed that the use of silica fume at higher ratios reduced mechanical properties by increasing porosity and sorptivity of BFSb-based geopolymer mortars.
AtıfScopus1OpenAlex1İncele - MakaleYalnız künye2023Scopus SJRQ2Computer-aided Optimization of Geopolymer Mortars
Gülmez, Nihan; Koçkal, Niyazi Uğur
The optimum mix design of geopolymers involves the purpose of determining which mixture will have high engineering properties without compromising the importance of each variable. This experimental study aimed to investigate the effects of some critical geopolymer mixture parameters on engineering properties by using historical data design in response surface methodology (RSM). Statistical models were developed between factors (binder and aggregate content, curing conditions and aggregate type) and their response surfaces (oven dry (OD) bulk density, water absorption, compressive strength and flexural strength). The final mathematical models for the response surfaces were constructed in terms of coded factors defined as dimensionless. In addition, a multipurpose optimization technique was used to achieve the desired design with the desired maximum strength.
- MakaleYalnız künye2021Scopus SJRQ3Effects of iron powder on properties of geopolymers subjected to different curing regimes
Gulmez, Nihan; Kockal, Niyazi Ugur
Silica fume, slag and iron powder are by-products from various industries. In parallel with development of industrial technology, it is also known that these by-products which cause rapid pollution of the environment are also harmful to human health because they are easily respirable. For this reason, a series of experiments were carried out to determine physical and mechanical properties on samples prepared using different blend designs to examine the effect of factors such as curing conditions, binder type and waste iron powder content. Percentages of iron powder added to replace the aggregate are 10%, 20%, 30% and 40% by volume of slag aggregate. It was observed that the substitution of 30% by volume iron powder instead of slag in geopolymer mortars is the most effective in increasing splitting tensile strength. For 40% partial replacement of fine aggregates with iron powder, increases in compressive strength and flexural strength of slag-based mortars were 7.2% and 43.4%, respectively, compared to mortar without iron powder at 60°C curing conditions.
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