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- MakaleYalnız künye2024Scopus SJRQ2Production of high entropy (FeNiMnCrV)3O4 oxide by mechanical alloying process and electrochemical performance analysis for Li-ion cells
Dogan, Ebru; Altin, Serdar; Guler, Seval Hale; Guler, Omer; Altin, Emine
In this study, a high entropy oxide material was fabricated from its alloy using mechanical alloying technique in the form of (FeNiMnCrV)3O4 with a symmetry of Fd-3m, and their structural properties were investigated by XRD, SEM-EDS dot mapping, and XPS analyses. The EDS analysis results of oxide and alloy show that Fe, Ni, Mn, Cr, and V have similar ratios for both samples. The elemental ratios were also measured by ICP-MS and the results support the EDS and XPS data. The alloy and oxide powders were used for the production of the anode materials for the half-cell configuration of the battery. The CV analysis of both cells showed that they have similar characteristic redox reactions and the main difference between the two electrodes is the current density values in the peaks. The initial capacity value of the (FeNiMnCrV)3O4 for 10 mA/g was found as 1070 mAh/g for the first cycle which is promising results as an anode material for Li-ion cells.
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İncele - MakaleYalnız künye2022Scopus SJRQ1Cooling of non-sloped, positively sloped, and negatively sloped arrangements of Li-ion batteries with a phase change material connected to a solar system
Akkurt, Nevzat; Aghakhani, S.; Mahmoud, Mustafa Z.; Abdelrahman, Anas
Three cylindrical Li-ion batteries are simulated using COMSOL Multiphysics in this study. A circular PCM layer is used to cover the batteries. A battery pack connected to a solar system is tested to store energy in a residential building. The PCM is 100% melted at the beginning, and the frozen PCM volume fraction (PVOF) is studied over time. In addition, the temperatures of individual batteries in three different configurations are analyzed at air velocities 1 and 3 mm/s. The three battery configurations included a positive slope, a negative slope, and no slope. The finite element method (FEM) is utilized to derive algebraic equations. The test results are given to the network as training data, and different neural network architectures are tested in terms of the number of layers and the number of neurons in each layer, and finally a structure that has a minimum mean squared error as a network. Battery behavior predictor is selected. Finally, this model is given to the optimization algorithm as an optimization function to investigate the point at which the maximum voltage is obtained. The results showed that the positively sloped battery configuration decreased the temperatures of the batteries, while the non-sloped configuration increased the temperatures. In addition, the positively sloped configuration resulted in more frozen PCM than non-sloped and negatively sloped configurations at a given time. The minimum frozen PCM was observed in the non-sloped configuration. A change in the air velocity from 1 to 3 mm/s increased the frozen PCM and improved the cooling of the batteries.
AtıfScopus15OpenAlex13İncele - MakaleYalnız künye2022Scopus SJRQ1The influence of battery distance on a hybrid air-cooled cylindrical lithium-ion battery phase change material thermal management system for storing solar energy
Akkurt, Nevzat; Aghakhani, S.; Mahmoud, Mustafa Z.; Tag El Din, ElSayed M.
The cooling of a lithium-ion battery pack made up of three cylindrical batteries in a channel is studied using the finite element technique in this research. The phase change material (PCM) is surrounded by a laminar flow of air. The solid PCM fraction values and the average temperature of each battery and battery pack at various periods were studied by varying the distance between the batteries from 7 to 10 mm and adjusting the speed from 0.1 to 0.3 cm/s. When compared to other batteries surrounding this battery, the left battery had the lowest temperature and the maximum quantity of solid PCM was generated at various periods, according to the findings of this article. At 0.1 cm/s, the distance 7 mm is the greatest and the distance 8 mm is the lowest in the left battery, the distance 10 mm is the largest in the center battery, the distance 8 mm is the lowest in the right battery, and the distance 8 mm generates the least amount of solid PCM in the battery pack. The second and third batteries, as well as the battery pack, have the lowest average temperature across various distances of the batteries due to a distance of 10 mm between them. Increasing the speed from 0.1 to 0.3 cm/s causes the temperature to decrease in a time-dependent manner.
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