Yazarlar
- Alim, B.(1)
- Dikici, B.(1)
- Guler, O.(1)
- Guler, S.H.(1)
- Güler, Ömer(1)
- Kanca, M. Sait(1)
- Lampke, T.(1)
- Pathman, Abdul Fatah(1)
- Sakar, E.(1)
- Taşgın, Yahya(1)
- Yılmaz, Demet(1)
Yayınlar
- MakaleYalnız künye2024Scopus SJRQ1The effect of high entropy oxide on radiation shielding parameters of erbium oxide doped glasses
Kanca, M. Sait; Taşgın, Yahya; Yılmaz, Demet; Pathman, Abdul Fatah; Güler, Ömer
High-entropy materials are one of the most studied topics in recent years due to the extraordinary properties they exhibit. High entropy oxide (HEO) is a group of materials that have been studied for different applications. However, the effects of HEOs on the radiation properties of glasses are not well known. In this study, the structural, radiation and neutron shielding properties of SiO2 glass systems doped erbium oxide reinforced with refractory high entropy oxide (RHEO) with the formula TiMoNbTaWZrO11 were investigated. RHEAs used in the study were produced and characterized in our laboratory. Then, they were added to the glass samples at different rates together with Erbium oxide. As a result of SEM-EDS and XRD analyses, it was determined that the additives were distributed very homogeneously on the glass. The composition of glass systems is [95SiO2+(5-x)Er2O3+x TiMoNbTaWZrO11], where (x = 0, 0.5, 1 and 2 %, mol). The linear and mass attenuation coefficients (LAC and MAC), mean free path (MFP), half-value layer (HVL) and effective atomic numbers (Zeff) and effective electron density (Nel) of the glass structures were experimentally measured at the energy region of 53.16–661.62 keV. Also, the equivalent dose rates due to fast neutrons absorption were measured by using an 241Am–Be fast neutron source. Exposure buildup factor (EBF) and fast neutron removal cross section (ΣR) were theoretically determined. The proton and alpha shielding parameters of glasses were calculated. It is observed that glasses containing higher amounts of refractory high entropy oxide, within the SiO2–Er2O3 composition, demonstrated enhanced capabilities for shielding against radiation and neutrons.
AtıfScopus15WoS15OpenAlex17
İncele - MakaleYalnız künye2024Scopus SJRQ1Effect of oxidation on radiation shielding capacity of ZrNbTaMoW Refractory High Entropy Alloys (RHEA) for nuclear reactor applications: Experimental and theoretical assessment
Sakar, E.; Guler, O.; Alim, B.; Guler, S.H.; Dikici, B.; Lampke, T.
This study presents the production and comprehensive assessment of a Refractory High Entropy Alloy (RHEA) with a ZrNbTaMoW composition for possible usage nuclear reactor applications. The alloy was synthesized using the mechanical alloying (MA) method, and its radiation properties were examined. Elemental powders of Zr, Nb, Ta, Mo, and W were utilized in equimolar quantities during the 120-hour MA process, conducted under a high-purity Ar atmosphere to prevent oxidation. The obtained HEA was then subjected to a mechano-thermal process to transform it into Refractory High-Entropy Oxide (RHEO) for comparing their radiation-shielding performance under oxide conditions. The characterization of the produced alloys through X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron dispersive spectroscopy (EDS). The photon shielding parameters of the alloys were experimentally obtained for various energies emitted from a 133Ba radioactive source, employing a Canberra UltraLEGe semiconductor detector. Furthermore, theoretical calculations were performed to validate the experimental data and to evaluate the alloys' photon shielding capabilities comprehensively. For this purpose, Phy-X/PSD software was employed to determine mass attenuation coefficients, half-value layer, effective atomic number, and effective electron density. Fast neutron absorption capabilities were determined through the calculation of average absorption cross-sections in the 2–12 MeV energy range. The results showed that the oxidation process significantly diminished the photon absorption capacity of RHEA.
AtıfScopus34OpenAlex37İncele