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- MakaleAçık Erişim2026Scopus SJRQ1Removal of Reactive Blue 4 Dye from Aqueous Solution with Magnetic Fe3O4@Nd/Alg Beads
Karaaslan Ayhan, Nagihan; Seker, Seda
In this study, magnetic iron oxide@neodymium/alginate (Fe3O4@Nd/Alg) beads were prepared by ionic crosslinking with neodymium (Nd) ions, then subjected to heat treatment, and for the first time, effective removal of Reactive Blue 4 (RB 4) dye from aqueous solution was achieved with these beads. For this purpose, ideal adsorption conditions that significantly affect the removal of this dye were determined. The ideal adsorption conditions were determined as pH:5, contact time (t):60 min, amount of magnetic Fe3O4@Nd/Alg bead (m):10 mg, initial RB 4 dye concentration (C0):25 mg/L, temperature (T): 25 °C. Adsorption isotherm, kinetic and thermodynamic studies were carried out under the ideal adsorption conditions. The adsorption data was found to completely follow Langmuir model for RB 4 dye and the maximum adsorption capacity of RB 4 was found to be 263.16 mg/g. The adsorption kinetic data was found to be compatible with pseudo-second order and adsorption processes were explained by intraparticle diffusion. In adsorption thermodynamics studies, it has been determined that the nature of the adsorption reaction is spontaneous, endothermic and with increasing randomness. Furthermore, reuse studies of magnetic Fe3O4@Nd/Alg beads were carried out and it was determined that these beads could be used successfully up to 10 adsorption/desorption cycles.
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İncele - MakaleAçık Erişim2022Scopus SJRQ2Assessment of heavy metal accumulations and health risk potentials in tomatoes grown in the discharge area of a municipal wastewater treatment plant
Arslan Topal, E. Işıl; Topal, Murat; Öbek, Erdal
Some heavy metals were detected in organs of the tomatoes grown in the discharge area of effluents of a municipal wastewater treatment plant. Also, the health risk potentials of heavy metals in the tomatoes consumed by human were investigated. The highest concentrations for Cu, Ni, Cr, Mn and Pb were followed the order of root>leaf>stem>fruit. When the bioconcentration factors values calculated for bioconcentration of metals from effluent to stem and root were examined, the highest values were determined for Cu. When translocation factors values are examined, the highest translocation from root to leaf was determined for Cd. The highest translocation from stem to leaf was determined for Pb. The estimated total exposure dose for male, female and children was listed as Zn>Mn>Cu>Cr>Ni>Pb>Cd. In terms of dietary, we can list the non-carcinogenic risks of heavy metals as children> female> male. The highest carcinogenic risk was calculated for Cr via dietary intake.
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İncele - Kitap BölümüAçık Erişim2022Fungal Exopolymeric Substances and Their Applications
Topal, Murat; Arslan Topal, E. Işıl
Exopolymeric substances that are also known as extracellular polymeric substances, extracellular polysaccharides, exopolymers, and exopolysaccharides are produced by various microorganisms. They primarily include polysaccharides, lipids, nucleic acids, and proteins. Exopolymeric substances protect microorganisms from various environmental stresses. Exopolymeric substances have unique characteristics. Some of the functional properties of them include adhesion, aggregation, binding activity, energy and nutrient source, water retention, and sorption. One of the exopolymeric substances is fungal exopolymeric substances. The fungal exopolysaccharides are pullulan, scleroglucan, fungal β-glucans, botryosphaeran, and others. The fungal exopolymeric substances are valuable products because of their different application areas such as industries of medical, cosmetic, food, wastewater treatment and agriculture.
- MakaleYalnız künye2021Scopus SJRQ1Investigation of Some Metal Accumulation Ability of Phragmites australis from Poultry Slaughterhouse Wastewaters
Topal, Murat
In this study, the bioaccumulation of some metals by Phragmites australis plants exposed to poultry slaughterhouse wastewater was investigated. For this aim, Mo, As, Cd, Se, Cu, Zn, Cr, Ba, Ti, Fe, Al, and Mn metals were determined in slaughterhouse wastewaters, P. australis plants, and sediment samples. The uptake of metals by P. australis was investigated. Also, BCF and TF values were calculated and compared with reference plant values. The maximum metal accumulation in P. australis plants exposed to poultry slaughterhouse wastewaters was 5900% for Al and 33.5% for Mn when compared with reference plant values. According to the BCF values, P. australis was bioaccumulative for Mo, Se, and Al. As a result, it was determined that P. australis plant can be used in the remediation of metals found in poultry slaughterhouse wastewaters and would be a good accumulator.
AtıfScopus2WoS1OpenAlex4İncele - MakaleYayıncıda açık erişim2020Scopus SJRQ2Phytoremediaton of priority substances (Pb and Ni) by Phragmites australis exposed to poultry slaughterhouse wastewater
Topal, Murat; Arslan Topal, E. Işıl
The aim of the work was to evaluate the ability of Phragmites australis to uptake lead and nickel from the stream taking the treated poultry slaughterhouse wastewater (PSW). Pb and Ni concentrations, which are the priority substances of the water frame directive, were detected separately at the root, stem and leaf of P. australis at 50 m and 100 m from the downstream of discharge point. The uptake of Pb and Ni by P. australis followed the order of root > leaf > stem. The Ni uptake was higher than Pb uptake in P. australis exposed to poultry wastewater. As a result, P. australis exposed to PSW were found to have the ability to uptake Pb and Ni. It has been determined that P. australis can be used for removal and phytoremediation of Pb and Ni metals from PSWs.
AtıfScopus13WoS12İncele - MakaleYalnız künye2019Uptake of some elements with aquatic plants exposed to the effluent of wastewater treatment plant
Tatar, S.; Öbek, E.; Arslan Topal, E.I.; Topal, M.
In this study, in the removal of macro (P, S, Na, K, Ca, Mg) and micro (Sb, Ba, Co, Cu, Fe, Pb, Mn, Hg, Mo, Se, Ag, Zn) elements in the effluent of Elazig Wastewater Treatment Plant, the efficiency of Lemna minor L. and Lemna gibba L. has been studied comparatively. For this aim, fronds of these plants have been adapted to the effluent of the treatment plant that feeds pilot scale reactors. The concentrations of elements in fronds harvested during the working period were analyzed by ICP/MS. The analytical results show that Lemna minor L. has a high accumulation potential for P, Sb, Ba, Co, Fe, Pb, Mn, Hg, Ag and Zn while Lemna gibba L. has a high accumulation potential for S, Na, Ca, Mg, Cu, Mo and Se. The results show that Lemna minor L. and Lemna gibba L. can be used as phytoremediators of wastewater.
AtıfScopus10OpenAlex6İncele - MakaleYayıncıda açık erişim2018Scopus SJRQ2Determination of pollution and heavy metal fractions in golden horn sediment sludge (Istanbul, Turkey)
Kanat, Gurdal; Ikizoglu, Bahar; Erguven, Gokhan Onder; Akgun, Berivan
In our study we studied pollution and heavy metal fractions in the Golden Horn (Istanbul, Turkey). This area has been exposed to domestic and industrial pollution for many years. Concentrations of Zn, Cr, Cu, Pb, Cd, and Ni heavy metals were determined in the study that was conducted to monitor the current state of pollution and changing conditions in the polluted estuary. Mean heavy metal concentrations were found as: Zn 70-260, Cr 26-110, Cu 70-135, Pb 8-50, Cd 0.1-2, and Ni 10-38 mg/kg. Results of the analysis showed that metal concentrations were usually low, indicating that the sediment was not too polluted in the present case. The range of ratios, different fractions of metal concentrations, and total metal concentrations in the samples were critical for potential toxicity and mobility of metals. Results of the analysis showed that heavy metal fractions in the sediment were usually found in residual forms. The values obtained in the study were also compared with the literature. It was found that surface sediments in the Golden Horn were less polluted than other areas. Establishment of sewer collectors and wastewater treatment plants has improved the heavy metal levels in the sediment.
AtıfScopus22WoS19OpenAlex23İncele - MakaleYalnız künye2018Scopus SJRQ2Microbial Sorption of Uranium Using Amycolatopsis sp. K47 Isolated from Uranium Deposits
Celik, Fatih; Camas, Mustafa; Kyeremeh, Kwaku; Sazak Camas, Anil
The increasing contamination of soils, sediments, and water with heavy metals through natural and industrial processes is a worldwide problem. Mining processes produce tons of material contaminated with radionuclides such as U and different heavy metals such as Cd, Ni, and Pb. U(VI) adsorbs strongly on bacteria, exhibiting pH-dependent adsorption behavior that is caused by a range of uranyl surface complexes on bacteria cell walls. The Amycolatopsis sp. K47 was isolated from Manisa Koprubasi Kasar open-cast uranium mine and identified for the first time. Using the batch adsorption method, the biosorption potential of this microbe was investigated by studying the effects of changes in pH (1–10), biomass dose (0.1–5 g/l), initial uranium metal concentration (5–200 mg/l), contact time (5–180 min), and temperature (20–60 °C). Interpretation of FTIR data obtained for both the uranium loaded and unloaded Amycolatopsis sp. K47 biomass showed the presence of carboxylic acid, hydroxyl, and amide functional groups that could interact with uranium ions. Scanning electron microscopy images demonstrated that uranium was intensely adsorbed on the microbial biomass surface. The sorption isotherms were investigated by analysis of the Langmuir, Freundlich, and Dubinin–Radushkevich (D–R) models. The Langmuir isotherm model was found to show the best fit for the experimental data obtained. Furthermore, thermodynamic parameters, such as ΔH°, ΔS°, and ΔG°, were calculated using adsorption equilibrium constant obtained from the Langmuir isotherm. The optimal experimental conditions were determined to be pH = 4, C0 = 40 ppm, t = 150 min, temp. = 40 °C, and abs. dose = 1 g/l, and the corresponding U(VI) removal efficiency was about 97 ± 2%.
AtıfScopus16WoS14OpenAlex15İncele