Sürdürülebilir Kalkınma Amaçları
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- MakaleYalnız künye2024Scopus SJRQ1Synthesis, characterization and application of cross-linked functional terpolymer through epoxy group as sorbent for extraction of cadmium from waters and foods: Multivariate optimization
Yılmaz, Ersen; Boztuğ, Ali; Ul Haq, Hameed; Boczkaj, Grzegorz; Altunay, Nail
The purpose of this study was to develop a selective sorbent for cadmium ions (Cd(II)) enrichment in orbital shaker assisted solid phase microextraction (OS-SPME) from different aqueous and food samples. A maleic anhydride-styrene-glycidyl methacrylate (MA-St-GMA) terpolymer was synthesized and characterized in detail. Experimental variables of sample preparation step were optimized using a central composite design (CCD). The final determination step was performed using flame atomic absorption spectroscopy (FAAS). The MA-St-GMA sorbent exhibited a high adsorption capacity (195.9 mg g−1) for the Cd(II) ion. The developed method under optimal conditions provides satisfactory performance and a significant improvement compared to other protocols available in the literature. The linear range and detection limit of the method is 0.1–130 ng mL−1 and 0.03 ng mL−1, respectively. The robustness, intraday/interday precision, selectivity, and accuracy of the method were investigated. To further validate the method, a dedicated series of analysis was performed using certified reference materials (CRMs). This part of the study confirmed the applicability of the method for routine analysis. The OS-SPME-FAAS method was validated using water and food samples. Relative standard deviations and recovery for real-world samples were in ranges 1.7–2.2 % and 95.5–98.5 %, respectively. As a result, the MA-St-GMA sorbent showed that it could quantitatively extract Cd(II) ions from aqueous solution.
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İncele - MakaleYalnız künye2011Scopus SJRQ3The Adsorption of the 2,2 Dichlorovinylphosfate on Raw and Modified Bentonites
Yonten, Vahap; Kubilay, Senol
This study aimed to investigate the adsorption of the 2,2 Dichlorovinylphosfate (DDVP) on raw and modified bentonite using High Pressure Liquid Chromatography (HPLC) and infrared spectroscopy (FT-IR). The modified bentonite were prepared by adding HNO3 and Na2CO3. The Freundlich adsorption isotherm defines DDVP adsorption in aqueous and ethanol-aqueous solutions by raw and modified bentonite. The variables of temperature, time and pH were observed on adsorption of DDVP. Then maximum adsorption of DDVP capacity was measured on bentonite modified with HNC), in pH 3.0 and 40 degrees C. The MBB clay used in experimental work played a major role on the adsorption of DDVP so MBB has better characteristics than other adsorbents and The Freundlich isotherms of MBB in aqueous ethanol solution was better than isotherms of aqueous solution for much better to adsorb of DDVP.
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