Yazarlar

  • MakaleYalnız künye2026Scopus SJRQ1
    Exploring the photocatalytic potential of NbTiZrW-based high-entropy alloys with Hf/Mo/Ta additions: Influence of alloying elements on their structural and photocatalytic performance

    Zakir, O.; Guler, O.; Idouhli, R.; Aklalouch, M.; Dikici, B.; Khadiri, M.E.; Abouelfida, A.; Selen, V.; Şimşek, T.

    In this study, the photocatalytic performance of NbTiZrW-based high-entropy alloys (HEAs) with Hf, Mo, and Ta additions was investigated. The alloys were synthesized by mechanical alloying for 120 h under a high-purity Ar atmosphere to prevent oxidation. The photocatalytic activity of the samples was evaluated based on the degradation of methylene blue (MB) under UV irradiation. Structural and chemical characterizations were performed using energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The results showed that MB removal by adsorption reached 22.96 % for NbTiZrWHf, 21.90 % for NbTiZrWTa, and 47.01 % for NbTiZrWMo. The incorporation of Mo into the NbTiZrW alloy was found to enhance electrostatic interactions between MB molecules and the alloy surface. Upon UV irradiation, the degradation efficiency increased significantly, reaching 32.84 % for NbTiZrWHf, 82.02 % for NbTiZrWTa, and 46.13 % for NbTiZrWMo within 3 h. The improved performance of the NbTiZrWHf alloy was attributed to its low particle size, which provided a larger number of active sites for photocatalytic activity, as confirmed by SEM analysis.

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  • MakaleYalnız künye2025Scopus SJRQ2
    The effect of WC addition on CrMnFeCoNi high entropy alloys: crystal-micro structure, hardness and wear behavior

    Taşgın, Yahya; Kanca, M Sait; Kök, Mediha; Anik, Kerem

    High entropy alloys are produced by combining four or more elements in close percentage ratios. Recently, these alloys have become the preferred group due to their superior mechanical and thermal properties. In this study, tungsten carbide (WC) was doped into CrMnFeCoNi alloys at different ratios, and the effects of WC and heat treatment on the doped alloys were investigated. XRD, SEM, and EDS analyses, wear tests, and microhardness measurements were performed on the produced samples to examine their microstructural properties. When comparing the heat-treated samples with WC (3%, 5%, and 10% additions) to the untreated samples, it was found that the average hardness values of the heat-treated samples were higher. Although the grain structures of the samples, as observed through XRD, SEM, and EDS, were preserved, their ratios were altered, and the wear tests revealed that the mass losses of the heat-treated samples increased.

  • Derleme MakaleYalnız künye2025Scopus SJRQ1
    A short review of structural, mechanical and magnetic properties of high and medium entropy alloys added rare earth elements

    Yayla, Nihal; Güler, Ömer

    This study presents a comprehensive review of the structural, mechanical and magnetic properties of high and medium entropy alloys (HEA and MEA) with rare earth elements (REE) additions. The addition of REE has been shown to have significant effects on phase transformations, microstructural arrangements and thermodynamic stability. Studies in the literature show that REE addition improves properties such as hardness, strength, deformation resistance and magnetic performance. In particular, changes such as transitions from FCC to HCP, formation of intermetallic phases and grain refinement have been observed in phase types with the addition of elements such as Gd, Y and Nd. REE added HEAs offer great potential for modern engineering and advanced technology applications with their superior magnetic moments, magnetocaloric effects and thermal stability. However, there is limited information in the literature on REE added HEAs. This review aims to provide a comprehensive framework for the development of REE added HEAs and to serve as an important reference point for future research.

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  • MakaleYalnız künye2024Scopus SJRQ1
    Effects of Er2O3 contribution on microstructure and mechanical properties of high entropy and dual phase alloys

    Taşgın, Yahya; Malkoç, Aziz; Kanca, M. Sait

    The study aimed to look at the differences between a high entropy alloy and a dual phase high entropy alloy with high iron and Mn content. It also wanted to find out what happened when a small amount of the rare earth element erbium oxide (Er2O3) was added to these alloys, especially on the mechanical and microstructure of the alloy. The first step in this study was to get 99 % pure metal powders, which were then made by dividing the powders into 30 g of equal weight. The powders were mixed evenly and then pressed into 10-g blocks under 6 tons of pressure. They were then set up to be melted in an arc. Four of the eight samples that were melted in an arc under vacuum were treated with heat. The four different compositions were then turned into small metallographic samples for SEM, EDX, Mapping, XRD, and microhardness tests. The study's imaging and analysis processes were also carried out. After that, SEM images were taken at various magnifications (100X, 500X, 1000X, 2500X, and 5000X), and EDS and XRD analyses were done on different structures found in these images. These analyses were based on literature research about the clarity of the metallographic images in the alloy, which showed the study's metallographic differences. The samples were put through microhardness and wear tests to see which one was stronger and less worn. The dual phase high entropy alloy (A2) was stronger and less worn than the high entropy alloy (A1). Er2O3 had little effect on the alloys' mechanical properties or microstructure. The heat treatment that was done to the samples helped the metallographic structure. In terms of physics, it didn't change the hardness much, but it did make the material wear less quickly.

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  • MakaleYalnız künye2022Scopus SJRQ2
    Microstructure and corrosion investigation of FeCoCrNiMo0,5(MnAl)0,3 high entropy alloy produced by 316 L stainless steel scrap

    Cihangir, Salih; Say, Yakup; Ozkul, İskender; Guler, Omer; Guler, Seval Hale

    FeCrCoNiMo0,5(MnAl)0.3 high-entropy alloy (HEA) was manufactured via arc melting process by adding the related metal powders into scrap of 316 L stainless steel for corrosion resistance tests under salt and acid conditions. Cyclic potentiodynamic polarization experiments performed under acidic conditions revealed pre-passivation due to abundance of network modifying metals in HEA composition which was further analyzed by electrochemical impedance spectroscopy. Elemental resolved analysis of leftover solutions was used to compare metal ions released during corrosion. X-ray diffraction analysis indicated the phase change in heat treated HEA samples. Non-heat treated HEA samples can be compared with stainless steel under moderate corrosion conditions and had better hardness results.

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