Sürdürülebilir Kalkınma Amaçları

  • MakaleYalnız künye2027Scopus SJRQ2
    Design, structural characterization, and simulated radiation-transport assessment of high-entropy (GdErSmEuYb)2X2O7 (X = Hf, Zr, Ce, Si) rare-earth oxides

    Güler, Ömer; Güler, Seval Hale; Yayla, Nihal; Baykal, Duygu Sen; Durmus, Hasan; Tekin, Huseyin Ozan; ALMisned, Ghada

    This study investigates the structural, microstructural, surface-chemical, and radiation attenuation behaviour of high-entropy rare-earth oxide (HEO) powder compositions synthesized as TBC-related candidate coating materials, whose radiation attenuation potential was assessed within a computational Inconel-718-based sandwich model. Four compositions, namely (GdErSmEuYb)2Hf2O7, (GdErSmEuYb)2Ce2O7, (GdErSmEuYb)2Zr2O7, and (GdErSmEuYb)2Si2O7, were synthesized via high-energy ball milling followed by calcination at 1200 °C. X-ray diffraction results revealed the formation of distinct crystal structures depending on B-site chemistry, including defective fluorite and silicate-type phases. SEM-EDS mapping confirmed homogeneous elemental distribution, while XPS analysis demonstrated mixed valence states and different oxygen vacancy concentrations across the compositions. To evaluate radiation attenuation performance, a sandwich-type geometry consisting of a 10 mm Inconel-718 core with symmetrically defined simulated HEO layers was modelled using Monte Carlo simulations. Gamma-ray transmission was analyzed over an energy range of 0.276-1.332 MeV, and fast neutron attenuation was assessed at 4.5 MeV. The results showed that transmission factors decreased with increasing coating thickness, with the effect being more pronounced at lower photon energies. Among the investigated compositions, the Hf-based system exhibited the most favorable predicted attenuation response for both gamma rays and fast neutrons under the defined simulation conditions. Theoretical half-value layer calculations also showed good agreement with the simulation results. Overall, the findings indicate that high-entropy rare-earth oxide coatings may provide an additional radiation attenuation contribution when incorporated as layers in Inconel-718-based systems. However, since direct thermal-barrier properties such as thermal conductivity, thermal diffusivity, thermal cycling resistance, and thermal-stress behavior were not evaluated in the present work, the present study should be interpreted as a structural and radiation-transport assessment of TBC-related coating candidates rather than a direct demonstration of thermal-barrier performance.

  • MakaleAçık Erişim2026Scopus SJRQ1
    Comparative effects of La2O3 and Sm2O3 on structural and radiation shielding properties of WO3 enriched borate glassy-ceramics

    Taşgın, Yahya; Yılmaz, Demet; Kanca, M. Sait; Yayla, Nihal; Kök, Mediha; Güler, Ömer

    This research comprehensively investigates the impact of incorporating rare earth oxides ‑samarium oxide (Sm2O3) and lanthanum oxide (La2O3)- into a borate glassy-ceramic system enriched with tungsten oxide (WO3), with a focus on both structural characteristics and radiation shielding performance. SEM-EDS, elemental mapping, and XRD analyses conducted on the synthesized glassy-ceramic samples revealed that the incorporated rare earth oxides, Sm2O3 and La2O3, were uniformly distributed throughout the glassy-ceramic matrix. The results also confirmed that the glassy-ceramic retained its inherently amorphous structure. Moreover, the nominal doping levels of the rare earth elements were found to be in agreement with both the qualitative and quantitative results obtained from EDS measurements. Also, the gamma ray shielding parameters of synthesized glassy-ceramic samples were measured in absorption geometry with Am-241, Ba-133 and Ra-226 radioactive sources. The neutron shielding parameters were theoretically calculated. The 241Am-Be fast neutron source was used to measure the equivalent dose of neutron absorption. At an incident photon energy of 74.8 keV, the mass attenuation coefficient of the tungsten oxide–enriched borate glassy-ceramic exhibited a remarkable improvement—rising by 17.98 % with the addition of 3 wt% Sm2O3 and by 11.58 % with the addition of 3 wt% La2O3. Notably, the N4 sample demonstrated a significant reduction in neutron-equivalent dose rate, reaching 19.80 % (μSv/h). The lead equivalent thicknesses (Pbeq) calculated at 356 keV were 0.02397 cmPb for N0, 0.0391 cmPb for N1, 0.0403 cmPb for N4, and 0.0389 cmPb for N7. When benchmarked against the undoped N0 sample, the N4 and N7 compositions exhibited reductions in Pbeq values by approximately 68 % and 62 %, respectively, indicating a marked improvement in gamma shielding efficiency. Among all tested formulations, the Sm2O3-doped variant demonstrated superior gamma-ray attenuation capability relative to the La2O3-doped glassy-ceramic. Furthermore, the N4 sample achieved an impressive thermal neutron attenuation rate of 96.46 %, underscoring its strong potential as an effective dual-purpose shielding material against both thermal neutrons and ionizing gamma radiation.

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  • MakaleAçık Erişim2026Scopus SJRQ2
    Enhanced Radiation Shielding and Structural Modifications in Samarium (III) Oxide-Reinforced Type 316L Stainless Steel Composites for Nuclear Applications: A Comprehensive Evaluation of Physical, Structural, Mechanical, Gamma-Ray, and Neutron Attenuation Properties

    Yayla, Nihal; Albayrak, M. Gökhan; Güler, Ömer; Sen Baykal, Duygu; Alkarrani, Hessa; ALMisned, Ghada; Tekin, H.O.

    Type 316L stainless steel (316L-SS) is widely recognized for its exceptional corrosion resistance, making it a preferred material in various industries. However, conventional stainless steel materials are inadequate for radiation shielding applications. While oxide dispersion-strengthened alloy composites with a 316L-SS matrix have been extensively studied in the literature for their mechanical creep properties, their radiation shielding capabilities remain insufficiently explored. This study investigates the potential of samarium oxide (Sm2O3) doped to improve the structural, physical, mechanical, and radiation shielding properties of 316L-SS composites. Samples containing 1%, 5%, 10%, and 20% Sm2O3 by weight were synthesized and extensively characterized using X-ray diffraction and scanning electron microscopy. These analyses revealed enhanced homogeneity and refined grain structure with increasing Sm2O3 content. Gamma-ray and neutron shielding properties demonstrated significant improvements, particularly in composites with 20% Sm2O3 reinforcement, as evidenced by lower half-value layer and mean free path values, along with an increased fast neutron removal cross section. However, a trade-off was observed between radiation shielding performance and mechanical properties: As the Sm2O3 content increased, the elastic modulus decreased, indicating reduced stiffness due to the incorporation of Sm2O3. This trade-off suggests that while Sm2O3 reinforcement effectively enhances radiation shielding, it may not be ideal for structural applications requiring high mechanical strength. Nevertheless, these findings highlight the potential of Sm2O3-doped 316L-SS composites for nonstructural radiation protection systems, particularly in applications where improved shielding performance is prioritized over mechanical stiffness.

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  • MakaleAçık Erişim2026Scopus SJRQ1
    Radiation shielding performance of (SmEuYbLaEr)2TaO4 high-entropy oxide reinforced Cu matrix composites

    Taşgın, Yahya; Yılmaz, Demet; Kanca, M. Sait; Kök, Mediha; Yayla, Nihal; Güler, Ömer

    High-entropy oxides (HEOs) containing rare earth elements are attracting increasing interest due to their thermal stability and potential for use in radiation shielding applications. In this study, the high-entropy oxide (SmEuYbLaEr)2TaO4 was synthesized via mechanical alloying (MA) followed by calcination and incorporated into a Cu matrix at different reinforcement levels to produce volumetric composites. Structural, thermal, and microstructural analyses confirmed the successful formation of a stable HEO phase and its effective dispersion within the Cu matrix. The radiation shielding performance of the composites was experimentally evaluated over a wide range of photon energies using standard gamma-ray sources. The results showed that shielding performance depends largely on both photon energy and HEO content. Increasing the HEO concentration significantly reduced the half-value layer (HVL) while substantially increasing the mass attenuation coefficient (MAC) and radiation protection efficiency (RPE), particularly in the low- and medium-energy regions where the photoelectric effect is dominant. Among the materials studied, the Cu composite containing 20 wt% HEO exhibited the best overall shielding performance. These results demonstrate that (SmEuYbLaEr)2TaO4 is an effective additive for improving the radiation shielding capability of Cu-based composites and highlight its potential for advanced radiation protection applications.

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  • MakaleYalnız künye2026Scopus SJRQ2
    Manufacturing, Structural Characterization, and Radiation Interaction Evaluation of Lightweight 6061-Al/Ytterbium(III) Oxide Composites with Emphasis on Gamma-Ray Shielding and Fast Neutron Removal Potential

    Guler, Seval Hale; Yayla, Nihal; Guler, Omer; ALMisned, Ghada; Sen Baykal, Duygu; Kilic, Gokhan; Tekin, Huseyin Ozan

    In this study, 6061-aluminum metal matrix composites doped with varying concentrations of ytterbium(III) oxide were synthesized using high-energy mechanical alloying to evaluate their structural, physical, and radiation shielding properties. X-ray diffraction confirmed the retention of the aluminum crystal structure with no secondary phase formation, while scanning electron microscopy and energy-dispersive X-ray spectroscopy revealed homogenous dispersion of Yb2O3 particles within the matrix. With increasing Yb2O3 content, particle densification and structural integrity were significantly enhanced. Gamma-ray and neutron shielding performance was assessed through theoretical modeling and Monte Carlo simulations. At low photon energy, the 20 wt% Yb2O3 composites showed a remarkable increase in linear attenuation coefficients compared to the undoped 6061-aluminum matrix. Neutron removal efficiency also increased by 32% at the highest Yb2O3 content. It can be concluded that Yb2O3 incorporation significantly improves both the photon and neutron shielding performance of the 6061-aluminum metal matrix.

  • MakaleAçık Erişim2025
    Investigation of the Bioactivity Properties of TiZrCrNb0.3Ta0.07 Medium Entropy Alloy Produced from TNTZ Waste

    Say, Yakup; Yayla, Nihal; Güler, Ömer; Güzel, Harun

    High entropy alloys (HEAs) and medium entropy alloys (MEAs) have garnered significant attention as alternative materials in various fields due to their superior physical and chemical properties compared to conventional alloys. One of the most promising applications of this innovative material class is in biomaterials. In this study, a bio-medium entropy alloy (BioMEA), TiZrCrNb0.25Ta0.05, was successfully synthesized using non-toxic elements (Ti, Zr, Cr, Nb and Ta) through arc melting of TNTZ alloy waste. The produced BioMEA was comprehensively characterized using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD) to analyze its structural and chemical properties. Additionally, the in-vitro degradation, ion release, and bioactivity properties of the alloy were evaluated and compared with those of the conventional TNTZ alloy, with a focus on the effects of heat treatment. The results demonstrated that heat treatment did not cause significant changes in the microstructure of the TiZrCrNb0.25Ta0.05 alloy but led to the formation of intermetallic compounds such as Cr2Zr and Cr2Ta on the surface. Degradation tests revealed an unexpected mass gain across all sample groups after a four-week immersion period due to surface precipitation, surpassing the expected mass loss from degradation. Ion release analyses showed similar behavior between the TiZrCrNb0.25Ta0.05 and TNTZ alloys, with ion release levels in the ppb range, confirming that Ti was released at non-toxic levels. Bioactivity tests identified low lesvels of Ca-P-O deposition on all sample surfaces, with the highest bioactivity observed in the heat-treated TiZrCrNb0.25Ta0.05 sample. Overall, the findings suggest that the TiZrCrNb0.25Ta0.05 alloy has the potential to serve as an alternative biomaterial to the TNTZ alloy, with its bioactivity properties being further enhanced through heat treatment. Further studies are recommended to optimize its bioactivity and evaluate its in-vivo performance for biomedical applications.

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  • MakaleAçık Erişim2025Scopus SJRQ2
    Dual-effect of Holmium(III) oxide and Boron Carbide reinforcement on physical, microstructural evolution and gamma-ray shielding performance of 316L-SS

    Yayla, Nihal; Albayrak, M. Gökhan; Güler, Ömer; Almisned, Ghada; Sen Baykal, Duygu; Alkarrani, Hessa; Kilic, Gokhan; Tekin, Huseyin Ozan

    This study provides one of the first comprehensive evaluations of 316L stainless steel composites reinforced with 10 wt.% B4C and varying concentrations of Ho2O3, proposing a new compositional design for simultaneous structural enhancement and dual gamma-neutron shielding optimization. XRD analysis confirmed the predominance of the austenitic phase with minor martensitic peaks at higher Ho2O3levels. SEM and EDX results revealed uniform dispersion and improved densification with increasing oxide content. The 316L-B4C-20%Ho2O3composite exhibited the highest mass attenuation coefficient (0.8953 cm2/g) and linear attenuation coefficient (6.73 cm−1) at 0.1 MeV, demonstrating superior gamma-ray shielding capability. The effective electron density increased from 2.86 × 1023to 5.82 × 1023electrons/cm³, while the energy absorption buildup factor (EABF) showed a consistent decrease with higher oxide concentrations. Although a slight reduction in fast neutron removal cross-section was observed, the composite maintained satisfactory neutron attenuation performance. Overall, the findings indicate that the 316L-B4C-20%Ho2O3system offers a promising balance between structural stability and dual radiation protection, making it a strong candidate for next-generation nuclear shielding materials.

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  • MakaleAçık Erişim2025Scopus SJRQ1
    Enhanced radiation shielding via incorporating europium oxide in 316L stainless steel: Synthesis, physical, microstructural, shielding, and mechanical properties

    Tekin, H.O.; Yayla, Nihal; Albayrak, M.Gökhan; Güler, Ömer; Baykal, Duygu Sen; Alkarrani, Hessa; ALMisned, Ghada

    316L stainless steel is widely utilized in various industries due to its excellent corrosion resistance, mechanical strength, and biocompatibility, making it a preferred material for applications in nuclear filed. However, enhancing its radiation shielding and mechanical properties through reinforcement strategies, such as the addition of high-Z materials like Europium(III) oxide, is crucial for extending its functionality in high-radiation environments, where improved performance is essential for safety and durability. In this study, 316L stainless steel composites reinforced with varying amounts of Eu2O3 (1%, 5%, 10%, and 20%) were synthesized and investigated for their structural, mechanical, and radiation shielding properties. X-ray diffraction (XRD) analysis revealed that the face-centered cubic (FCC) structure of the steel matrix was preserved up to 5% Eu2O3 reinforcement, while higher concentrations led to phase formation and crystallographic changes. Scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX) analysis showed uniform element distribution at low reinforcement levels, with particle clustering at 20% Eu2O3. Transmission factors (TFs) were evaluated using PHITS simulations for photon energies of 0.662 MeV, 1.1732 MeV, and 1.3325 MeV. The 20% Eu2O3 composite exhibited the lowest TF and highest attenuation properties, confirmed by mass and linear attenuation coefficients. Elastic modulus values decreased from 224.46 GPa in pure 316L to 189.26 GPa with 20% Eu2O3 reinforcement, reflecting the inverse relationship between mechanical stiffness and radiation shielding performance. Benchmarking against other shielding materials demonstrated superior performance of the Eu2O3-reinforced steel in gamma-ray attenuation. The 20% Eu2O3 composite shows strong potential for applications in nuclear radiation shielding where attenuation efficiency is prioritized over mechanical properties.

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  • MakaleAçık Erişim2025Scopus SJRQ2
    Effect of neodymium addition on the structural, mechanical, and magnetic properties of FeCoNiCu(MnCr)0.5 high entropy alloys

    Yayla, Nihal; Şimşek, Telem; Boyrazlı, Mustafa; Güler, Ömer

    Neodymium (Nd), a rare earth element, was incorporated into the [FeCoNiCu(MnCr)0.5] high-entropy alloy (HEA) at weight percentages of 0.5%, 1%, 2%, and 5%. The alloys were synthesized successfully using the arc melting method. X-ray diffraction (XRD) analysis confirmed that both the undoped and Nd-doped alloys exhibit a single-phase solid solution with a face-centered cubic (FCC) crystal structure, consistent with thermodynamic predictions derived from the Miedema model. Scanning electron microscopy (SEM) revealed a dendritic structure in the undoped alloy, which was replaced by Cu- and Cr-rich regions in the 5% Nd-doped alloy, as confirmed by energy dispersive spectroscopy (EDS). Differential scanning calorimetry (DSC) indicated an endothermic peak in the undoped alloy and minor thermal responses in Nd-doped samples, without distinct phase transitions within the 0–800 °C range. Mechanical testing demonstrated substantial enhancements in both hardness and tensile strength with increasing Nd content. The 5% Nd-doped alloy exhibited the highest performance, achieving a Vickers hardness of 370 HV and a tensile strength of 1186 MPa. Magnetic testing indicated ferromagnetic behavior in all samples, with Nd additions significantly enhancing magnetic properties. Notably, the 5% Nd-doped alloy achieved a saturation magnetization (Ms) of 41 emu/g and a coercivity (Hc) of 6.3 Oe, highlighting improved magnetic softness and rapid magnetization loss characteristic of soft magnetic materials.

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  • MakaleAçık Erişim2025Scopus SJRQ2
    Synthesis, microstructural refinement, and shielding optimization of Gd2O3-reinforced AISI 316L stainless steel: a multi-dimensional integration assessment for targeted protection applications

    Yayla, Nihal; Albayrak, M Gökhan; Güler, Ömer; Sen Baykal, Duygu; Alkarrani, Hessa; ALMisned, Ghada; Issa, Bashar; Tekin, H.O.

    This study investigates the multi-dimensional effects of increasing Gd2O3 reinforcement on the structural, mechanical, and gamma-ray shielding properties of AISI 316L stainless steel composites. Samples with varying Gd2O3 content (1%, 5%, 10%, and 20% by weight) were synthesized and characterized through x-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) to assess the microstructural changes and homogeneity of Gd2O3 dispersion after mechanical milling. The addition of Gd2O3 significantly enhanced the gamma-ray shielding properties, with the mass attenuation coefficient (MAC), linear attenuation coefficient (LAC), and half-value layer (HVL) improving as the Gd2O3 content increased, particularly in low to moderate photon energy ranges. Simultaneously, the elastic modulus exhibited an inverse relationship, decreasing with higher Gd2O3 content due to the lower stiffness of gadolinium compared to iron. Transmission factor (TF) values also decreased, indicating enhanced photon attenuation with higher Gd2O3 content across various thicknesses. The experimental characterization confirmed improved Gd2O3 dispersion and material uniformity after mechanical milling, contributing to the composites’ superior radiation shielding performance. It can be concluded that Gd2O3-reinforced AISI 316L stainless steel composites offer a promising balance between enhanced radiation shielding properties and reduced mechanical stiffness, making them ideal candidates for applications requiring efficient and adaptable radiation protection especially for portable and non-structural shielding applications.

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  • MakaleAçık Erişim2025Scopus SJRQ1
    Blending effects of boron carbide and lanthanum(III) oxide reinforcements on the structural, physical, mechanical, and radiation shielding properties of 316L-stainless steel composites for nuclear applications

    ALMisned, Ghada; Yayla, Nihal; Albayrak, M.Gökhan; Güler, Ömer; Baykal, Duygu Sen; Alkarrani, Hessa; Tekin, H.O.

    Four composite samples were fabricated, maintaining 10 % B4C and varying La2O3 content from 0 % to 20 %. X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and Energy Dispersive X-ray Spectroscopy (EDX) analyses confirmed the successful incorporation of reinforcements, preserving the austenitic structure of 316L-SS. Elastic modulus calculations revealed a gradual reduction from 225.0 GPa to 215.0 GPa with increasing La2O3 due to clustering and reduced homogeneity. Gamma-ray shielding properties demonstrated significant improvements, particularly at low and intermediate photon energies, with Sample 4 with 20 % La2O3 addition, achieving a 13.6 % higher linear attenuation coefficients (LAC) at 0.015 MeV. Neutron shielding highlighted Sample 4 as one of the most effective materials, outperforming conventional alloys. This study demonstrates the potential of 316L Stainless-Steel (316L-SS) + B4C + La2O3 composites as multifunctional materials for radiation-intensive applications, offering superior attenuation and structural stability. It can be concluded that optimization of reinforcement distribution would play an important role in balancing mechanical and shielding performance in next-generation nuclear materials.

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  • MakaleAçık Erişim2025Scopus SJRQ2
    An investigation on microstructural, physical, and radiation shielding properties Yb2O3 oxide dispersion-strengthened 316L-SS alloys

    ALMisned, Ghada; Yayla, Nihal; Albayrak, M. Gökhan; Güler, Ömer; Sen Baykal, Duygu; Alkarrani, Hessa; Susoy, Gulfem; Tekin, H.O.

    Oxide dispersion-strengthened alloys have emerged as a highly effective solution to address the physical, structural, and shielding challenges faced by traditional alloys in nuclear environments. This study presents a comprehensive evaluation of the microstructural, mechanical, and radiation shielding properties of Yb2O3 oxide dispersion-strengthened 316L stainless steel composites at varying Yb2O3 concentrations such as 1%, 5%, 10%, and 20% by weight. XRD analysis revealed lattice distortions, with crystallite sizes decreasing from 11.2267 nm to 9.3351 nm. SEM/EDX analyses confirmed homogeneous Yb2O3 dispersion at lower concentrations, with agglomeration at 20% Yb2O3. The mass attenuation coefficient increased from 56.103 cm2/g to 65.919 cm2/g at 0.015 MeV, marking a 17.5% enhancement. HVL decreased by 40.68% at 0.2 MeV for the 20% Yb2O3 sample. Additionally, the 20% Yb2O3 composite showed nearly 33% lower transmission factor at 3.0 cm thickness and 0.662 MeV. It can be concluded that Yb2O3 reinforcement significantly enhances the microstructural, and gamma-ray attenuation properties of 316L-SS composites, positioning them as promising materials for advanced nuclear shielding and structural applications.

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  • DüzeltmeYayıncıda açık erişim2025Scopus SJRQ1
    Corrigendum to “A short review of structural, mechanical and magnetic properties of high and medium entropy alloys added rare earth elements” [Mater. Today Commun. 47 (2025) 113264] (Materials Today Communications (2025) 47, (S2352492825017763), (10.1016/j.mtcomm.2025.113264))

    Yayla, Nihal; Güler, Ömer

    The authors regret that in the published version of the article, although the explanations for Figs. 13–16 (Also, Figure numbers and explanations given just below the figures) are correct in the text, the figure numbers in text are mixed up. The incorrect figure title and its correction are as follows: On page 9, throughout the text: - All sentences starting with Fig. 14 (Wrong) has been corrected to Fig. 13.- All sentences starting with Fig. 15 (Wrong) has been corrected to Fig. 14.- All sentences starting with Fig. 16 (Wrong) has been corrected to Fig. 15.On page 10, throughout the text: - All sentences starting with Fig. 13 (Wrong) has been corrected to Fig. 16.The authors would like to apologise for any inconvenience caused.

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  • Derleme MakaleYalnız künye2025Scopus SJRQ1
    A short review of structural, mechanical and magnetic properties of high and medium entropy alloys added rare earth elements

    Yayla, Nihal; Güler, Ömer

    This study presents a comprehensive review of the structural, mechanical and magnetic properties of high and medium entropy alloys (HEA and MEA) with rare earth elements (REE) additions. The addition of REE has been shown to have significant effects on phase transformations, microstructural arrangements and thermodynamic stability. Studies in the literature show that REE addition improves properties such as hardness, strength, deformation resistance and magnetic performance. In particular, changes such as transitions from FCC to HCP, formation of intermetallic phases and grain refinement have been observed in phase types with the addition of elements such as Gd, Y and Nd. REE added HEAs offer great potential for modern engineering and advanced technology applications with their superior magnetic moments, magnetocaloric effects and thermal stability. However, there is limited information in the literature on REE added HEAs. This review aims to provide a comprehensive framework for the development of REE added HEAs and to serve as an important reference point for future research.

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  • MakaleAçık Erişim2025Scopus SJRQ1
    Examining the trade-off between structural, mechanical properties and shielding performance of Pr2O3-enhanced 316L stainless steel

    Yayla, Nihal; Albayrak, M.Gökhan; Güler, Ömer; Baykal, Duygu Sen; Alkarrani, Hessa; ALMisned, Ghada; Zakaly, Hesham M.H.; Tekin, H.O.

    This study explores the structural, mechanical, and radiation shielding properties of 316L stainless steel composites reinforced with varying weight percentages of Pr2O3. The aim is to enhance radiation attenuation capabilities while maintaining structural integrity for nuclear applications. The composites were fabricated using the mechanical alloying method, followed by detailed characterization through X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. Key radiation shielding parameters, including mass attenuation coefficient, linear attenuation coefficient, half-value layer, and effective atomic number, and transmission factor values were analysed using theoretical and computational models. Additionally, elastic modulus calculations were performed to assess mechanical properties. The results indicate that incorporating Pr2O3 significantly enhances shielding performance. The 316L-SS%20Pr2O3 composite exhibited the highest mass and linear attenuation coefficients values, with a notable reduction in half value layer values compared to the unreinforced 316L stainless steel. At lower photon energies, effective atomic number improved by 39.3 % for the 316L-SS%20Pr2O3 sample, while neutron shielding efficiency also increased. However, the elastic modulus decreased with higher Pr2O3 content, reflecting a trade-off between mechanical stiffness and radiation shielding efficiency. The findings demonstrate that 316L-SS%20Pr2O3 is a promising material for applications requiring superior radiation shielding, particularly in environments where mechanical load is secondary.

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  • MakaleAçık Erişim2024Scopus SJRQ2
    Innovative Al6061-gadolinium oxide ods alloys: fabrication and comprehensive characterization of microstructural, physical, mechanical, and radiation shielding properties

    ALMisned, Ghada; Yayla, Nihal; Albayrak, M. Gökhan; Güler, Ömer; Baykal, Duygu Sen; Tekin, H.O.

    This study explores the development and comprehensive characterization of Al6061-Gd₂O₃ composites, designed to enhance radiation shielding and mechanical properties for critical applications in environments exposed to ionizing radiation. The purpose of this research is to assess the effectiveness of Gd2O3 as a reinforcing material for Al6061, with the aim of creating a dual-function composite that combines structural integrity with superior gamma-ray and neutron attenuation capabilities. Using X-ray diffraction (XRD) and scanning electron microscopy (SEM), we analyzed the microstructural effects of varying Gd2O3 content, observing homogeneous dispersion at low concentrations and clustering at higher levels. Mechanical properties demonstrated that increased Gd2O3 content reduces the elastic modulus, indicating a trade-off between stiffness and shielding efficiency. Radiation shielding parameters, including Transmission Factor (TF), mass attenuation coefficient (MAC), and Fast Neutron Removal Cross Section (FNRCS), were evaluated through Phy-X/PSD and PHITS Monte Carlo simulations. Results indicate that Gd2O3 reinforcement significantly improves gamma-ray and neutron shielding, particularly at higher concentrations, making the composite viable for non-structural applications prioritizing radiation protection. The findings from this study highlight the potential of Gd2O3-reinforced Al6061 composites to serve as effective shielding materials in environments where radiation exposure is a primary concern.

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