Sürdürülebilir Kalkınma Amaçları

Yazarlar

  • MakaleYalnız künye2024Scopus SJRQ1
    Effect of boron on microstructure, thermal, and mechanical properties of Ni–B matrix diamond cutting tools

    Islak, Serkan; Çelik, Ertuğrul; Houssain, Hasaneen; Danacı, Hacer Cemre

    This study examines the impact of adding boron on the microstructural, thermal, and mechanical properties of Ni–B alloy matrix diamond cutting segments, which are created using the hot pressing process. Microstructure was investigated using SEM-EDS and XRD analysis. The high-temperature oxidation behavior of the samples was determined by thermogravimetric analysis. The hardness was quantified employing Vickers hardness testing, as well as, sample densities were derived based on Archimedes' principle. The wear resistance was evaluated using the reciprocating wear test method. A three-point bending test was used to examine how the diamond grains were retained inside the Ni–B matrix. The XRD investigations identified the formation of Ni, Ni3B, and Ni2B phases. The thermogravimetric analysis results showed that Ni–B alloys were exposed to oxidation at elevated temperatures as the B content increased, However, a hardness improvement was observed as the B content increased due to the formation of borides. Furthermore, the tribological investigation reveals that adding the B as reinforcement has a positive effect at a specific amount, where the optimal wear resistance and minimal friction coefficient were evident at 6% B contained sample.

    AtıfScopus10WoS10OpenAlex10
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  • MakaleYalnız künye2023Scopus SJRQ1
    Carbide slag recycling to fabricate shape-stable phase change composites for thermal energy storage

    Xiong, Yaxuan; Wang, Huixiang; Ren, Jing; Nevzat, Akkurt; Xu, Qian; Nie, Binjian; Li, Chuan; Ding, Yulong

    The mining and processing of traditional skeleton materials inevitably generates carbon emissions and pollutes the surrounding environment. To make full use of industrial solid waste, this work innovatively used carbide slag as skeleton material and Na2CO3 as phase change material (PCM) to fabricate shape-stable phase change composites (SSPCCs) via the cold-compression & hot-sintering method. Seven SSPCCs were fabricated with different mass ratios of carbide slag to Na2CO3. Then, the thermal energy storage (TES) performance, mechanical property, micromorphology, chemical compatibility as well as thermal cycling stability were investigated. The results showed that the carbide slag could combine with Na2CO3 to fabricate SSPCCs; Sample CN5 achieved the optimal performance with the mass ratio 52.5:47.5 of carbide slag to Na2CO3; Sample CN5 achieved a TES density of 993 J/g in the range of 100 to 900 °C, a compressive strength of 22.02 MPa and a maximal thermal conductivity of 0.62 W/(m·K); Both carbide slag and Na2CO3 were distributed uniformly in sample CN5, while good thermal stability after the 100 heating/cooling cycles and good chemical compatibility between the carbide slag components and the Na2CO3 were observed.

    • SDG 7 · Erişilebilir ve Temiz Enerji
    • SDG 12 · Sorumlu Üretim ve Tüketim
    • SDG 13 · İklim Eylemi
    AtıfScopus34OpenAlex30
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  • MakaleAçık Erişim2022Scopus SJRQ1
    Novel of (PLA/PCL blend)/Gd2O3 rare earth oxide nanocomposites: Shape memory effect, thermal, magnetic, and mechanical properties

    Özen Öner, Ecem; Pekdemir, Mustafa Ersin; Ercan, Ercan; Say, Yakup; Kök, Mediha; Aydoğdu, Yıldırım

    Poly ɛ-caprolactone (PCL) and poly lactic acid (PLA) stand out as biocompatible polymers. In this study, PCL and PLA were blended in 40:60 ratio, respectively, and then the Gd2O3 compound, which is an important earth element oxide, was mixed in PLA–PCL shape memory polymer (SMP) blend at different rates and polymer blend nanocomposites were obtained. First of all, the effects of Gd2O3 oxide on the thermal properties of the SMP blend were determined with a differential scanning calorimeter (DSC) and thermogravimetric analyzer (TGA), and it was determined that Gd2O3 did not have a significant effect on the melting temperature of the blend, while it significantly increased its thermal stability. As a result of the XRD (X-ray diffraction) analysis of the composites at room temperature, it was determined that the semicrystalline blend, with the addition of Gd2O3, increased its crystalline property. When the shape memory effect was examined, it was understood that the additive did not eliminate the shape memory effect. When the magnetic property of the gadolinium oxide-doped composite, which is magnetocaloric oxide, was examined, the magnetic property of the composite changed from diamagnetic to paramagnetic with increasing additives. Finally, the mechanical properties of the shape memory blend composite were investigated and no regular changes were observed in the mechanical properties with increasing Gd2O3.

    AtıfScopus38OpenAlex42
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  • MakaleYalnız künye2021Scopus SJRQ1
    Silane doped biodegradable starch-PLA bilayer films for food packaging applications: Mechanical, thermal, barrier and biodegradability properties

    Gürler, Nedim; Paşa, Salih; Temel, Hamdi

    In this work, pure potato starch (PPS) purified from waste potato starch, was recovered and used. PPS was modified by 3-APTMS (3-(aminopropyl) trimethoxy silane) to manufacture a crosslinked film. To obtain a bilayer PPS-3APTMS-PLA film, the polylactic acid (PLA) was employed with PPS-3APTMS by casting method. The resulting materials, PPS-3APTMS and PPS-3APTMS-PLA were characterized by attenuated total reflectance fourier transform ınfrared (ATR-FTIR), x-ray Diffraction (XRD), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA). The silane-doped bilayer films have more thermal stability compared to PPS. The mechanical, solubility, swelling, water vapor permeability, optical properties and biodegradability under controlled compost conditions were examined. When the tensile strength of the PPS, PPS-3APTMS and PPS-3APTMS-PLA films were evaluated, the tensile strength (TS) were to 1.017±0.35 MPa, 1.437 ± 0.19 MPa and 10.918 ± 1.30 MPa, respectively. The PPS and PPS-3APTMS films were not elongation at break, while it was found about 21.94 ± 9.48 for the bilayer PPS-3APTMS-PLA film. The solubility, swelling, water vapor permeability, and transparency decreased for bilayer films. The water vapor permeability of PPS, PPS-3APTMS and PPS-3APTMS-PLA films were obtained as 31.69±0.4 × 10−7 g s−1 m−1 Pa−1, 28.96±0.4 × 10−7 g s−1 m−1 Pa−1, and 14.26±0.3 × 10−7 g s−1 m−1 Pa−1, respectively. Then, the biodegradability of films was performed under controlled compost conditions for 46 days according to ISO-14,855 standard. The biodegradation of PPS, PPS-3APTMS and PPS-3APTMS-PLA was also calculated as 9.30%, 5.45% and 5.08%. Biodegradation of PPS-3APTMS film decreases compared to PPS. Furthermore, the biodegradation value of bilayer film, PPS-3APTMS-PLA, was also decreased due to the slower degradation tendency of PLA. The contribution to the reusability of waste starch and the modifying of starch for food packaging and coating applications are the novelty aspects of the current study.

    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus93WoS77OpenAlex90
    ScopusWeb of Scienceİncele