Sürdürülebilir Kalkınma Amaçları

Yazarlar

  • MakaleYayıncıda açık erişim2024Scopus SJRQ2
    Controlling of electro-optical properties of cobalt phthalocyanine formed single chain polymer: Sudan III and nanographene based its composites

    Demirelli, Kadir; Barım, Esra; Tuncer, Hülya; Dere, Ayşegül; Canbay, Canan Aksu; Karaduman, Oktay; Al-Sehemi, Abdullah G.; Al-Ghamdif, Ahmed A.; Yakuphanoğlu, Fahretttin

    The synthesis of poly[4-(4-vinylbenzyl)oxy)phthalonitrile-co-styrene] [P(VBOPN5 %-co-St)] was carried out by free radical polymerisation at 60 °C. The successful formation of a green coloured single-chain polymer molecule with the formation of cobalt phthalocyanine (SCP-CoPc) was performed at 140–150 °C in the presence of dilute cyclohexanol. The characterization of SCP-CoPc was confirmed by FT-IR and UV/vis spectroscopic techniques. The absorption filtration process of the SCP-CoPc polymer/Sudan III composite was investigated. The introduction of Sudan III into the SCP-CoPc polymer matric strongly affected the optical transmission spectrum of the composite films. The optical transmission measurements of the SCP-CoPc/Sudan III thin film show a high absorption in the visible region (400–800 nm). In the SCP-CoPc/Sudan III composites, the optical band gaps (Eg1 and Eg2) of each of its components has changed significantly. The Eg1 and Eg2 were found to be between 1.90 and 2.83 eV, respectively. Depending on the sudan III content, a wide range from 600 nm to 730 nm indicates complete absorption filtration. The dc electrical conductivity and dielectric behavior of the SCP-CoPc/Nanografene (NG) 6 wt% nanocomposite increased with increasing temperature. From the dc conductivity plot, the Ea values of I. and II. regions were found to be 0.75 eV and 0.27 eV, respectively and it was found that the calculated activation energy obeyed the Arrhenius relationship. The refractive index and the optical permittivity of SCP-CoPc/NG 6 wt% have been estimated.

    AtıfScopus2OpenAlex3
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2024Scopus SJRQ1
    An innovative approach in oat milk production: Ohmic heating

    Ak, Ferit; Karakavuk, Emrah; Goksu, Ali; Sabancı, Serdal

    This study aimed to produce oat-milk by using the ohmic heating (OH) system and to compare some quality properties of this milk with the milk produced by conventional methods. The solution containing oats was heated from 20 °C to 75 °C using 3 different voltage-gradients, and then oat-milk was obtained by applying a series of processes. It has been determined that as the voltage gradient increased during heating in oat milk production, the processing time shortens, and this time was 482 seconds in the conventional heating process. The effective electrical conductivity values increased as the temperature increased in the OH process during the production of oat-milk and these values vary between 0.13 and 0.41 S/m. Also, some quality characteristics of oat milk such as color and total phenolic content were better preserved in milk obtained by the OH process than conventional heating process. In addition, oat milk obtained by OH process had higher apparent viscosity at all temperatures.

    • SDG 2 · Açlığa Son
    • SDG 7 · Erişilebilir ve Temiz Enerji
    AtıfScopus8WoS6OpenAlex8
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2021Scopus SJRQ2
    Electrical investigation on Eu+3- doped copolymer composite system and conventional kinetic analysis

    Pıhtılı, Güzin; Biryan, Fatih

    Poly(maleic anhydride-co-benzyl methacrylate) copolymer was prepared by using free radical polymerization (FRP) method at 70 °C. The structural characterization of the polymer was accomplished FT-IR, 1H and 13C NMR spectroscopic techniques. P(MA-co-BMA)/ EuCl3 composites were prepared rate of 2%, 5% and 10% (wt/wt). The thermal behavior of pure copolymer was investigated by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Thermal decomposition kinetics of poly(MA-co-BMA) carried out from Flynn–Wall–Ozawa method via TG curves for calculated apparent activation energies. According to FWO; the activation energy (Ea) was estimated as; 185.61 kJ/mol. Dielectric and electrical properties of copolymer/composite systems were investigated against frequency (range from 100 Hz to 20 kHz) at room temperature by using an impedance analyzer. The effect of EuCl3 concentration on dielectric constant, dielectric loss factors, ac conductivity, susceptance (B) and impedance (Z) was investigated. A remarkable increase was observed in dielectric and AC electrical properties were observed with the addition of Eu+3 to the polymer matrix. The B and Z parameters of poly(MA-co-BMA) and composites were investigated depending on frequency at room temperature based on the alternating current (AC).

    AtıfScopus2WoS2OpenAlex2
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2020Scopus SJRQ2
    Electrical properties of two-armed poly(Ɛ-CL-co-BMA) composites filled with bentonite

    Pihtili, Güzin; Torğut, Gülben; Biryan, Fatih

    The dielectric and electrical conductivity properties of two-armed poly(Ɛ-CL-co-BMA) copolymer and adding bentonite forms were studied. The effect of the bentonite was investigated at different quantities (%3wt, %6wt, %15 wt). The measurements were performed at frequencies between 100 Hz to 10 kHz at room temperature, and the dielectric permittivity (ε′), the dielectric loss factor (ɛ″) and conductivity (σac) were calculated. ε′ and ɛ″ increased with increasing bentonite content. In addition, changes of susceptance (B) and impedance (IZI) were examined at different frequencies ranging from 100 Hz to 10 kHz in order to investigate the effect of bentonite loading. As frequency increases, (B) increases linearly, whereas IZI decreases and remains constant at high frequencies. Two-armed copolymer synthesized using ring-opening polymerization (ROP) and Atom Transfer Radical Polymerization (ATRP) and its composites prepared with bentonite were characterized by FT-IR, 1H-NMR and SEM. Thermal behaviors were examined by TGA and DSC methods and the effect of bentonite was discussed.

    AtıfScopus15WoS14
    ScopusWeb of Scienceİncele