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  • MakaleYalnız künye2026Scopus SJRQ2
    Linking microstructural modifications of Ho2O3-doped borotellurite glasses to the enhancement of critical properties: Synthesis, structural, physical, and experimental Gamma-Ray and neutron transmissioncharacteristics

    Kilic, G.; Ilik, E.; Kavaz, E.; Durmus, Hasan; Güler, Ömer; Birdogan, Selcuk; ALMisned, Ghada; Tekin, H.O.

    This study investigates the effects of holmium oxide (Ho2O3) microparticle reinforcement on the structural, physical, and radiation shielding properties of borotellurite glasses with compositions ranging from 0 to 12 mol% Ho2O3. X-ray diffraction and TEM analyses confirmed the retention of amorphous structure across all samples, with localized short-range ordering observed at higher Ho contents. Glass density increased from 4.598 to 5.202 g/cm3 with increasing Ho2O3, while molar volume expanded from 27.94 to 30.61 cm3/mol, and oxygen packing density decreased from 0.605 to 0.551 g/cm3, indicating network expansion due to the substitution of lighter Li + ions by heavier Ho3+. Gamma-ray shielding properties significantly improved with Ho incorporation. At 81 keV, the linear attenuation coefficient increased from 8.33 to 13.70 cm−1, and the mass attenuation coefficient improved from 2.066 to 2.735 cm2/g. Moreover, effective atomic number rose from 44.9 to 52.5 and half-value layer decreased by 20.5% at 383 keV, and buildup factors dropped by up to 34% at 0.5 MeV. Neutron dose absorption improved, and the fast neutron removal cross-section increased from 0.1066 to 0.1113 cm−1. These results confirm that Ho2O3 contributes as a highly effective multifunctional dopant, significantly enhancing both gamma-ray and neutron shielding performance of borotellurite glasses, one of the most promising glass systems for advanced radiation protection applications.

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  • MakaleYalnız künye2026Scopus SJRQ2
    Exploring Nuclear Radiation Shielding Capabilities of High-Entropy Carbides: A Study on Composition and Effectiveness

    Yilmaz Alan, Hatice; Guler, Omer; Yilmaz, Ayberk; Susam, Lidya Amon; Kavaz, Esra; Kilic, Gokhan; Ilik, Erkan; Oktik, Sener; Akkus, Baki; ALMisned, Ghada

    High-entropy carbides (HECs) are emerging as promising materials for shielding against gamma-ray and neutron radiation due to their unique structural and compositional properties. This study systematically evaluates the shielding capabilities of 12 carbide-reinforced high-entropy alloys (HEAs) composed of elements such as hafnium, niobium, titanium, zirconium, tungsten, tantalum, vanadium, and molybdenum. Various gamma-ray and neutron shielding parameters, including attenuation coefficients, shielding thicknesses, and neutron removal cross sections, were calculated using the Phy-X/PSD software. The findings reveal a strong correlation between material density and shielding efficiency, with the highest density samples, particularly (Zr0.2Hf0.2Ta0.2Mo0.2W0.2)C and (Ti0.2Hf0.2Nb0.2Ta0.2W0.2)C, demonstrating superior gamma-ray attenuation. Additionally, neutron shielding performance was maximized in compositions containing high concentrations of heavy elements, with (Ti0.2V0.2Nb0.2Ta0.2W0.2)C exhibiting the most effective neutron absorption properties. The interactions of photons and charged particles with these materials were further examined through mass stopping power and projected range calculations for alpha particles, protons, and electrons. It can be concluded that HEC-based alloys, due to their high density, optimized composition, and superior radiation attenuation properties, could be strong candidates for advanced shielding applications in nuclear and aerospace environments.

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  • MakaleYalnız künye2024Scopus SJRQ2
    On β-titanium alloys: tailoring gamma-ray, and neutron transmission properties for nuclear and biomedical applications

    Almisned, Ghada; Baykal, Duygu Sen; Alkarrani, Hessa; Güler, Ömer; Kilic, Gokhan; Mesbahi, Asghar; Tekin, Huseyin Ozan

    This study explores the gamma-ray and neutron transmission properties of β-Titanium alloys pivotal for their performance in nuclear and biomedical applications. Utilizing the Monte Carlo N-Particle (MCNP 6.3) simulations, we analyzed a spectrum of Ti-based alloys modified with elements like molybdenum (Mo), zirconium (Zr), niobium (Nb), and hafnium (Hf) to determine their radiation attenuation properties. Key parameters such as mass and linear attenuation coefficients, half-value layers, exposure buildup factors, and fast neutron effective removal cross-section values were computed, revealing significant enhancements in attenuation with the addition of high-Z elements. Specifically, alloys like Ti50Hf50 and (TiZr)40Cu60 exhibited superior photon and fast neutron attenuation due to their high-Z constituents. For instance, Ti50Hf50 showed a mass attenuation coefficient of 0.217 cm2/g and a half-value layer of 2.97-cm at 0.1 MeV photon energy, while (TiZr)40Cu60 demonstrated similar performance with a mass attenuation coefficient of 0.198 cm2/g and a half-value layer of 3.26-cm. These alloys also exhibited effective neutron removal cross-section values of 0.115 cm-1 and 0.130 cm-1, respectively. Alloys with lower-Z elements showed less attenuation, which may be beneficial in scenarios requiring reduced radiographic contrast in biomedical applications. The MCNP outcomes were in strong agreement with standard data, affirming the accuracy of computational methods in predicting material behavior. In conclusion, tailored alloy development is crucial for improving radiation shielding and diagnostic visualization, with broader implications for patient safety and treatment efficacy.

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  • MakaleAçık Erişim2024Scopus SJRQ1
    Fabrication and structural, physical, and nuclear radiation shielding properties for Oxide Dispersion-Strengthened (ODS) alloys through Erbium (III) oxide, Samarium (III) oxide, and Praseodymium (III) oxide into 316L matrix

    Güler, Seval Hale; Güler, Ömer; Kavaz, E.; ALMisned, Ghada; Albayrak, M. Gökhan; Issa, Bashar; Tekin, H.O.

    We report a comprehensive investigation on customization process of Oxide Dispersion-Strengthened alloys through Sm2O3, Pr2O3, and Er2O3 incorporation into 316L stainless steel matrix in terms of a desired enhancement in structural, physical, and nuclear radiation shielding properties. Oxide powders are incorporated into 316L stainless steel powder all with the same purity of 99.5%. These were Erbium oxide (Er2O3), Praseodymium oxide (Pr2O3), and Samarium oxide (Sm2O3). First, X-Ray diffraction and Scanning Electron Microscope/Energy-dispersive X-ray spectroscopy analyses are conducted in order to investigate their physical and structural properties. Next, two different experimental setups are employed using a133Ba and 241Am/Be sources for the measurements of gamma-ray and neutron transmission properties of Oxide Dispersion-Strengthened alloys. The maximum density increment is achieved through Er2O3 compared to other reinforced oxides. The detector counting value reached its minimum level when a 5% Er2O3 oxide dispersion was introduced into the 316L SS matrix. Similarly, the most significant degree of photon absorption, the highest values of mass attenuation coefficient, lowest half value layer, and most effective atomic number, were all attained by the same sample. Based on the findings derived from the investigation, it can be concluded that incorporating Er2O3 oxide into 316L steel can be considered as a viable option in terms of enhancing the critical properties of Oxide Dispersion-Strengthened alloys for extreme conditions such as nuclear reactors and other similar fields, where the behavioral attributes of the utilized materials are at utmost importance.

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  • MakaleYalnız künye2024Scopus SJRQ2
    Exploring critical behavioral differences in physical, structural, and nuclear radiation attenuation properties of produced High Entropy Alloy (HEA) and Refractory-High Entropy Alloy (RHEA) samples

    Güler, Seval Hale; Güler, Ömer; Kavaz, E.; Almisned, Ghada; Issa, Bashar; Tekin, H.O.

    Refractory-High entropy alloys (RHEAs) are known for their exceptional mechanical and radiation-resistant properties, making them promising materials for use in nuclear reactors. Their high entropy composition, which consists of multiple elements in roughly equal proportions, can create a stable microstructure that withstands high levels of radiation damage. The objective of this work is to further our comprehension of the unique behavioral, physical, structural, and nuclear radiation attenuation characteristics shown by High-Entropy Alloys (HEA) and Refractory-High entropy alloy (RHEA) materials. Accordingly, two high entropy alloy (HEA) samples through two different compositions were produced. The first composition under consideration is the typical high-entropy alloy (HEA) defined as MnCrFeNiCoMo0.5. The second composition under consideration is a refractory high entropy alloy (RHEA) characterized by the following elemental composition: TiZrNbHfVTa0.1. SEM and EDX analyses were conducted in terms of determining their physical and structural attributes. Next, a133Ba radioisotope together with a HPGe detector were utilized for gamma-ray transmission experiments. Finally, a241Am/Be source and a gas proportional detector were used for neutron absorption experiments for HEA and RHEA samples. The alloy structures displayed a unique degree of uniformity. Throughout the RHEA phase, the incorporation of refractory elements did not provide any discernible adverse impacts on the physical stability. The counting spectrum provided a clear explanation of the gamma ray absorption features shown by the RHEA (R) sample, highlighting its exceptional absorption properties. Regarding the absorption properties of neutrons, it was observed that RHEA had a comparatively reduced amount of absorption. Therefore, it can be concluded that the basic structure of RHEA grants it superior gamma-ray attenuation qualities compared to HEA. It can be concluded that RHEA demonstrates superior applicability as a material in comparison to HEA, especially in situations involving the use of fuel rods, where maintaining of neutron quantity has paramount importance for achieving optimum neutron activation.

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  • MakaleYalnız künye2024Scopus SJRQ1
    First-ever fusion of high entropy alloy (HEA) with glass: Enhancing of critical properties of zinc-tellurite glass through TiZrNbHfTaOx incorporation

    Güler, Ömer; Kilic, G.; Kavaz, E.; Ilik, E.; Guler, Seval Hale; ALMisned, Ghada; Tekin, H.O.

    Many oxide additives have historically been used to enhance the radiation shielding properties of glasses, yet the potential of high-entropy oxides (HEOs), which have gained popularity in material science for their unique properties, has not been explored in this context. This study is the first to investigate the radiation shielding capabilities of Zinc-Tellurite glass infused with High Entropy Oxide (HEO), specifically utilizing the novel attributes of a synthesized TiZrNbHfTa. In this study, the nuclear shielding properties of newly fabricated Zinc-Tellurite glasses doped with TiZrNbHfTaOx with a composition (25ZnO·75TeO2)100-x. (TiZrNbHfTaOx)x (x = 0, 1, 2, 3, 4 mol%) were studied. Through the synthesis of a TiZrNbHfTa HEA and its integration into glass structure, we have developed a series of novel materials with enhanced protective properties against both gamma-ray and neutron radiation. Experimental results demonstrate that the HEO-infused glass, particularly the HEC1-4 composition, significantly surpasses traditional shielding materials in neutron attenuation, evidenced by its superior effective neutron removal cross-section. Additionally, the HEC1-4 glass demonstrates improved gamma-ray shielding capabilities, with increased mass attenuation coefficients and decreased half-value layers, indicating a higher capacity for photon interaction and absorption. It can be concluded that the incorporation of High Entropy Alloys into glass matrices not only opens a new frontier in radiation shielding materials but also provides a versatile and effective solution with considerable potential for enhancing safety measures in radiation-prone environments.

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  • MakaleYalnız künye2024Scopus SJRQ2
    A first-time fusion of TiNbWMoZrOx high entropy oxide (HEO) with zinc-tellurite glass: Toward superior physical properties

    Kilic, G.; Güler, Ömer; Kavaz, E.; Ilik, E.; Guler, Seval Hale; ALMisned, Ghada; Tekin, H.O.

    While numerous oxide additives have traditionally been employed to enhance the radiation shielding capabilities of glasses, the unique attributes of high-entropy oxides (HEOs), a group of materials acclaimed in contemporary material science for their distinctive properties have remained unexamined in this specific area. This novel study explores the enhancement of radiation shielding properties in zinc-tellurite glasses through the integration of TiNbWMoZrOx High Entropy Oxides (HEO). Utilizing advanced synthesis techniques, including mechanical alloying and oxidation, the research successfully incorporates HEOs into glass matrices, aiming to improve gamma-ray and neutron attenuation. Characterization through X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) confirms the uniform distribution and structural integrity of the HEOs within the glasses. The synthesis of glass samples with a base structure suitable for the molar composition of 25ZnO.75TeO2 (mol%) and glass samples doped with TiNbWMoZrOx (HEO) was carried out using the traditional high-temperature melting and annealing method. The outcomes demonstrate a concentration-dependent increase in shielding efficacy, particularly highlighting the superior performance of glasses doped with 4 mol% of TiNbWMoZrOx (HEC2–4), which exhibit significantly enhanced mass attenuation coefficients, lower half-value layers, and higher effective atomic numbers. This indicates the effective role of HEOs in boosting radiation protection capabilities. Comparative analysis with traditional shielding materials showcases the HEC2–4 glasses' competitive advantage, underlining their potential as a versatile shielding solution. It can be concluded that incorporating TiNbWMoZrOx high entropy oxides into zinc-tellurite glasses significantly augments their radiation shielding properties, offering a novel approach for enhancing protection against gamma-ray and neutron in various applications.

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  • MakaleAçık Erişim2023Scopus SJRQ1
    A comprehensive study on structural properties, photon and particle attenuation competence of CoNiFeCr-Ti/Al high entropy alloys (HEAs)

    Sakar, Erdem; Guler, Omer; Alım, Bünyamin; Say, Yakup; Dikici, Burak

    It is well known that high entropy alloys (HEAs) have a wide range of potential applications as radiation shielding due to their superior properties. The CoNiFeCr-Ti/Al compositions were chosen for their low cost as HEA in this study. The HEAs were successfully produced using the mechanical alloying (MA) method with equimolar CoNiFeCr, CoNiFeCrAl, and CoNiFeCrTi compositions. The production and structural properties of the alloys were investigated in detail. Besides, the photon and particle radiation shielding properties of the HEAs were calculated with the help of Phy-X/PSD, SRIM (10 keV-20 MeV), and ESTAR (10 keV-20 MeV) programs. The photon-matter interaction parameters were calculated in both specific photon energies emitted from 241Am, 133Ba, 109Cd, 60Co, 137Cs, 131I, and 22Na nuclides and a continuous energy range of 15 keV-15 MeV. The characterization of the alloys was investigated by using X-ray diffraction (XRD) and scanning electron microscopes (SEM) attached to an energy dispersive spectroscopy (EDX). It was found that the HEAs have a highly amorphous structure due to the selected production method. The crystal size of the alloys was calculated as 70, 35, and 20 nm for CoNiFeCr, CoNiFeCrAl, and CoNiFeCrTi, respectively. In terms of shielding properties, it has been determined that the produced HEAs have better shielding characteristics for photon and particle radiations than standard shielding concretes. In addition, the results demonstrated that CoNiFeCr alloy, which has the best shielding ability among the HEA alloys, can be used as a shielding material application requiring photon, electron, proton, alpha, and neutron radiations.

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  • MakaleAçık Erişim2022Scopus SJRQ1
    Newly synthesized NiCoFeCrW High-Entropy Alloys (HEAs): Multiple impacts of B4C additive on structural, mechanical, and nuclear shielding properties

    Gul, Ali Oktay; Kavaz, Esra; Basgoz, Oykum; Guler, Omer; ALMisned, Ghada; Bahceci, Ersin; Albayrak, M. Gokhan; Tekin, H.O.

    High-Entropy Alloys (HEAs) are regarded as potential structural materials for fusion and next-generation fission reactors, which will be required to fulfil growing nuclear energy demands. In this study, a HEA-composite was synthesized by adding B4C to an HEA containing Ni. The microstructure of the obtained HEA-composite was examined and the changes in its mechanical properties were revealed. Additionally, the nuclear radiation shielding properties of the Ni-containing HEA, and the HEA-composite are investigated using experimental and theoretical methods. Our initial findings showed that with the addition of 2.5% B4C to the alloy, the hardness increased more than two times. The addition of B4C to the HEA matrix resulted in a more than 90% and a nearly twofold increase in compressive strength. The shielding qualities of gamma-ray and neutron radiation were investigated using experimental and theoretical approaches. Our findings demonstrated that increasing the B4C reinforcement considerably enhanced the composite material's neutron attenuation capabilities. On the other hand, no significant change in the gamma-ray shielding characteristics of HEA and HEA-composite samples was observed. The gamma-ray shielding characteristics of HEA and HEA-composite samples were compared to those of other alloy shields and commercial products. Our findings indicate that both HEA and HEA-composite samples exhibit superior gamma-ray shielding characteristics when compared to the control samples. It can be concluded that increasing B4C reinforcement may be a multifunctional tool in terms of improving the mechanical properties as well as neutron attenuation properties for advanced applications in nuclear radiation facilities and next-generation fission reactors. Additionally, due to their promising material features and higher gamma-ray shielding capabilities compared to other kinds of alloys and commercial shields, HEAs may be beneficial materials.

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