Sürdürülebilir Kalkınma Amaçları
Yazarlar
- Yaman, Mehmet(3)
- Kaya, Gokce(2)
- Akdeniz, Ismail(1)
- Akkus, Sukran(1)
- Altunay, Nail(1)
- Avci, Halim(1)
- Bal, Tulin(1)
- Boczkaj, Grzegorz(1)
- Boztuğ, Ali(1)
- Ince, Muharrem(1)
- Karaaslan, Nagihan M.(1)
- Kilinc, Ersin(1)
- Kutlu, Banu(1)
- Okumus, Nuh(1)
- Ul Haq, Hameed(1)
- Yaman, Emre(1)
- Yılmaz, Ersen(1)
- Özcan, Gülnaz(1)
- Özcan, Tahir(1)
Yayınlar
- MakaleYalnız künye2024Scopus SJRQ1Synthesis, characterization and application of cross-linked functional terpolymer through epoxy group as sorbent for extraction of cadmium from waters and foods: Multivariate optimization
Yılmaz, Ersen; Boztuğ, Ali; Ul Haq, Hameed; Boczkaj, Grzegorz; Altunay, Nail
The purpose of this study was to develop a selective sorbent for cadmium ions (Cd(II)) enrichment in orbital shaker assisted solid phase microextraction (OS-SPME) from different aqueous and food samples. A maleic anhydride-styrene-glycidyl methacrylate (MA-St-GMA) terpolymer was synthesized and characterized in detail. Experimental variables of sample preparation step were optimized using a central composite design (CCD). The final determination step was performed using flame atomic absorption spectroscopy (FAAS). The MA-St-GMA sorbent exhibited a high adsorption capacity (195.9 mg g−1) for the Cd(II) ion. The developed method under optimal conditions provides satisfactory performance and a significant improvement compared to other protocols available in the literature. The linear range and detection limit of the method is 0.1–130 ng mL−1 and 0.03 ng mL−1, respectively. The robustness, intraday/interday precision, selectivity, and accuracy of the method were investigated. To further validate the method, a dedicated series of analysis was performed using certified reference materials (CRMs). This part of the study confirmed the applicability of the method for routine analysis. The OS-SPME-FAAS method was validated using water and food samples. Relative standard deviations and recovery for real-world samples were in ranges 1.7–2.2 % and 95.5–98.5 %, respectively. As a result, the MA-St-GMA sorbent showed that it could quantitatively extract Cd(II) ions from aqueous solution.
AtıfScopus9WoS8OpenAlex9
İncele - MakaleAçık Erişim2021Scopus SJRQ3Analysis of heavy metal contamination in surface sediments of Iskenderun Bay, Turkey
Kutlu, Banu; Özcan, Tahir; Özcan, Gülnaz
The ecological risk resulting from the accumulation of some heavy metals in the sediments of Iskenderun Bay was assessed using the following measures: enrichment and contamination factor, pollution load index (PLI), and potential ecological risk index (RI). The concentrations of the studied heavy metals were in the following order: Fe > Ni > Mn > Cr > Zn > Cu > As > Pb > Cd > Hg. Ni and As had the highest EF values. This situation is most likely due to the presence of iron, pesticide, and fertilizer plants in the region. According to the United States Environmental Protection Agency, Ni, As, Mn, and Cr may have harmful effects on faunal communities in sediments. According to the RI, Site 4 was more contaminated and toxic than the other seven study sites, with "moderate"ecological risk. Pearson's correlation coefficient was determined by multivariate methods - cluster and principal component analysis. As can be inferred from the RI values, the potential toxic effect of As and Ni in the sediments is moderate.
AtıfScopus7OpenAlex6İncele - MakaleYalnız künye2013Scopus SJRQ3FLAME ATOMIC ABSORPTION SPECTROMETRIC DETERMINATION OF NICKEL AND CHROMIUM IN VARIOUS PLANT LEAVES USED AS BIOMONITORS IN ENVIRONMENTAL POLLUTION
Avci, Halim; Kaya, Gokce; Akdeniz, Ismail; Ince, Muharrem; Yaman, Mehmet
Levels of nickel and chromium in leaves of 14 plant species grown in industrial sites of Gaziantep and surrounding were examined for biomonitoring of atmospheric pollution using flame atomic absorption spectrophotometry (FAAS). The plant leaf samples were collected from different locations with different degrees of metal pollution. The metal levels in the plants were in the ranges of (with mean values) 0.4-28.0 (3.1) mg kg(-1) for Ni and 0.1-6.6 (1.5) mg kg(-1) for Cr. On the other hand, the Ni and Cr levels in the plant leaf samples collected from control) areas were in the ranges of 0.4-2.1 (1.1) and 0.1-1.4 (0.58) mg kg(-1), respectively. It was concluded that Pinus nigra L., Acacia robinia L., Platanus orientalis L., Nerium oleander L., Pyracantha coccinea M.Roem. and Populus nigra L. for Ni, Pinus nigra L., Acacia robinia L., Olea europaea L. and Nerium oleander L. for Cr could be biomonitors. Therefore, it was demonstrated that the plant leaves could be used for heavy metal air pollution monitoring in urban and industrial regions.
AtıfWoS10İncele - MakaleAçık Erişim2013Scopus SJRQ1Fractionation of Ni, Cr and Cu from Soil by Sequential Extraction Procedure and Determination by Inductively Coupled Plasma Optical Emission Spectrometry
Akkus, Sukran; Bal, Tulin; Karaaslan, Nagihan M.; Yaman, Emre; Kilinc, Ersin; Yaman, Mehmet
Five-step sequential extractions were employed to fractionation of Ni, Cr and Cu in soil polluted by anthropogenic activities and determine the mobility of the metals. Twelve samples were collected on an agricultural area that was located near an airport and intercity roads in Elazig-Turkey. Exchangeable, organically bounded, carbonate bounded, adsorbed species on Fe and Mn oxides and residual species (except silicates) of Ni, Cr and Cu were extracted into solution by using CaCl2, Na4P2O7, Na(2)EDTA, NH2OH-HCl and HNO3-H2O2, respectively. Mobile metal concentrations in fractions and total recoverable in soils were determined by using inductively coupled plasma-optical emission spectrometry (ICP-OES). Total recoverable Ni, Cr and Cu concentrations were in the range of 40-119, 45-126 and 23-72mgkg(-1), respectively. It was observed that total concentrations of metals in some of the samples were higher than the permitted values. The sum of the mobile percentages of metals was found to be lower than 50%. The Ni, Cr and Cu percentages for exchangeable species are in the ranges of 0.18-1.64, 0.03-0.59 and 0.42-2.53%, respectively.
AtıfWoS6OpenAlex5İncele - MakaleYalnız künye2010Scopus SJRQ3LEAD, CADMIUM AND COPPER CONCENTRATIONS IN LEAVES OF Nerium oleander L. AND Robinia pseudoacacia L. AS BIOMONITORS OF ATMOSPHERIC POLLUTION
Kaya, Gokce; Okumus, Nuh; Yaman, Mehmet
Pb, Cd and Cu concentrations in leaves of Nerium oleander L. and Robinia pseudoacacia L. plants collected from industrial areas in Gaziantep-Turkey were examined for biomonitoring of atmospheric pollution using flame atomic absorption spectrophotometry. The Pb levels in the leaves of Nerium oleander L. and Robinia pseudoacacia L. collected at a distance of 50 m from the battery plant were observed to be 2820 and 1860 mg kg(-1), respectively. The Pb, Cd, and Cu concentrations in the soils studied were in the range of 17-602, 0.142-0.656 and 12-38 mg kg(-1), respectively. Lead concentrations described above for plant leaves were found to be about 2000-fold higher than those in the same plants collected from the control area (1.0 mg Pb kg(-1) for both plant species). Similarly, Cd levels in Robinia pseudoacacia L. collected from polluted area were observed to be about 40 times higher than those from control area. Consequently, it is observed that the leaves of Neriurn oleander L. can be used for biomonitoring of Pb, and Robinia pseudoacacia L. for biomonitoring of both Pb and Cd pollution.
AtıfWoS31İncele