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Koleksiyondaki öğeler
- MakaleYalnız künye2024Scopus SJRQ1Physical and biological characteristics of eco-friendly films added with Cinnamomum zeylanicum extract for packaging materials
Gürler, Nedim; Ertekin, Özlem
The effects of Cinnamomum zeylanicum extract (CZE) at different rations (0%, 1%, 3% and 5%) on gelatin (GL)–polyvinyl alcohol (PVA) blend films were evaluated in relation to the structural, tensile strength, physical, antimicrobial and antioxidant properties of the films in this study. The results showed that water barriers of the film samples decreased, but the UV-blocking property increased and became opaque at the highest GLPVA5 film. The tensile strengths of GLPVA, GLPVA1, GLPVA3 and GLPVA5 films were 1.21, 1.78, 1.62 and 1.95 MPa, respectively. The antimicrobial effect of these films was determined against Escherichia coli, Enterococcus faecalis, Salmonella typhimurium and Bacillus cereus according to the parallel stick method. Antioxidant properties of cinnamon extract were investigated using 2,2-diphenyl-1-picryl-hydrazil (DPPH) methods. The % inhibition of DPPH was found to be 82.00. No antibacterial effect was detected for B.cereus and E. faecalis at 0%, 1%, 3% and 5%. While no activity was observed in 0%, 1% and 3% cinnamon, 7.5 and 3.0 mm zones were detected in S. typhimirium and E. coli, respectively, in 5% cinnamon. The results suggest that the film samples could be used in a potential packaging with antioxidant and antibacterial properties.
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İncele - MakaleAçık Erişim2024Scopus SJRQ1Development and in-depth experimental characterization of novel TiZrNbHfTaOx reinforced 316L stainless steel for advanced nuclear applications
Güler, Ömer; Albayrak, M. Gökhan; Başgöz, Öyküm; Kavaz, E.; Alkarrani, Hessa; ALMisned, Ghada; Tekin, H.O.
Oxide Dispersion Strengthened (ODS) materials are known for their exceptional performance in high-temperature and radiation environments. This study explores the radiation shielding properties of 316L Stainless Steel reinforced with TiZrNbHfTaOx High-Entropy Oxide (HEO). By integrating HEOs into the 316L stainless steel matrix, we aim to enhance its structural and radiation shielding properties. The HEO was synthesized using high-energy ball milling and oxidation processes, followed by thorough characterization using X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive spectroscopy (EDS). Our results indicate significant improvements in both gamma-ray and neutron shielding properties. The 316L SS samples reinforced with 20 % HEO exhibited the highest mass attenuation coefficients (MAC), lowest half-value layers (HVL), and highest effective atomic numbers (Zeff) across all tested photon energies. These enhancements are attributed to the high atomic number elements and unique synergistic effects of HEOs. Neutron shielding was evaluated through equivalent dose rate measurements, with the 20 % HEO sample demonstrating the highest absorbed dose rate percentage and superior neutron interaction cross-sections. Benchmarking against standard materials confirmed the superior performance of HEO-reinforced 316L SS, making it a promising candidate for advanced radiation shielding in nuclear reactors and other high-radiation environments. Our findings suggest that HEO reinforcement not only improves mechanical properties but also significantly enhances the radiation protection capabilities of 316L stainless steel.
AtıfScopus12OpenAlex13İncele - MakaleYalnız künye2025Scopus SJRQ1New testimony for local elites in Sophene during the Hellenistic period: Rabat Fortress and its Middle Aramaic inscription in a rocky landscape
Danışmaz, Harun; Adalı, Selim Ferruh; Şahin, Özgür
This study is concerned with the evaluation of a recently discovered Aramaic inscription and other archaeological remains found at Rabat Fortress (in Tunceli, Türkiye). The Hellenistic period Aramaic funerary text was composed in memory of a local lord from Sophene’s local political elite, with connections to the Orontid dynasty. This is the first known local Aramaic inscription from Sophene. The Aramaic inscription introduced in this study provides significant new information about the Hellenistic-period context for rock-cut stepped tunnels and single-roomed rock-cut tombs known across eastern Anatolia. The Rabat Fortress site provides corroborating evidence for the dating of the stepped tunnels that exhibit the same rock-cutting techniques in the same region to the Hellenistic and later periods in the rocky landscape. The inscription is rendered in a unique Sophene adaptation of the Middle Aramaic script extant on a corner block inside the Fortress. Its funerary context in rocky landscape and the inscription’s script and content indicate that the local elite at Rabat Fortress used Aramaic, and the notion of Orontid lineage to connect with the kingdom of Sophene’s central authority, which positioned itself between Hellenistic and Iranian traditions.
- MakaleYalnız künye2024Scopus SJRQ2An Evaluation of Living Conditions and Dietary Habits of Seasonal Migrant Agricultural Workers: The Example of Turkey
Orhan, İlksen; Koçak, Hatice Serap
Objective: The nutritional status of seasonal migrant agricultural workers is negatively affected by problems with working conditions, wages, accommodations, and living conditions. This study aimed to investigate the living conditions, dietary habits, and food consumption frequency of seasonal migrant agricultural workers in Turkey. Methods: This descriptive, cross-sectional study was conducted in July and August 2022 in the neighborhoods of Akçadağ district in Malatya Province, Turkey. The sample of the study consisted of 262 seasonal migrant agricultural workers aged 15 and over who came to the region for the apricot harvest. The data were obtained using the face-to-face interview technique via a two-part questionnaire including questions on socio-demographic characteristics, living conditions, dietary behaviors and food consumption frequency. Results: The mean age of the seasonal migrant agricultural workers was 24.16 ± 0.75, and they worked 12.01 ± 0.10 hours per day on average. It was determined 74.8% of the workers had access to clean water, and 50.4% did not think they had an adequate and balanced diet. It was found only 57.3% of the workers had a normal body mass index, 80.2% never ate fish, 53.8% never ate red meat, and 67.2% never drank milk, while only 34.4% were able to eat seasonal vegetables. Conclusion: The findings of the study show that seasonal migrant agricultural workers in Turkey do not have suitable conditions in terms of food and accommodations, and their working conditions, wages, and health conditions are inadequate. These deficiencies have a negative effect on workers’ quality of life and health status.
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İncele - MakaleAçık Erişim2024Scopus SJRQ1Design of Ohmic Thawing Cell with Hydrostatic Pressure Units: Application in Minced Beef
Döner, Deniz; Çokgezme, Ömer Faruk; Çevik, Mutlu; İçier, Filiz
The thawing process is a common processing method used in the meat industry. To ensure provide food safety and protect meat quality, the thawing process should be carried out carefully. Ohmic thawing (OT) is one of the novel thawing methods. In this study, a custom-designed ohmic thawing prototype was set up and used to thaw frozen minced beef samples in different shapes (X: 13 × 4 × 3 cm3; Y: 13 × 6 × 2 cm3; Z: 13 cm height × 3.91 cm diameter) at 3 different voltage gradients (10–13-16 V/cm) by using 3 different electrode designs (E1, titanium foil; E2, needle type titanium electrode; E3, titanium embossed). The optimum OT condition resulting in a high-quality product with the highest process efficiency was determined. As an optimization procedure, a three-level general factorial design was performed. Thawing time, drip loss, thawing ratio, maximum temperature, ohmic power consumption, energy efficiency, and exergy efficiency values were used as responses. The cylindrical sample shape resulted in higher changes in quality and decreased performance of the process. The optimum ohmic thawing condition was a 16 V/cm voltage gradient for Y-shaped samples by using an E2 electrode design. The thawing time for the optimum condition was 2074s corresponding ohmic power consumption of 15.84 W. The drip loss during thawing was measured at 1.20%. The maximum temperature reached during the thawing process was recorded as 15.90 °C. Energy efficiency and exergy efficiency values were greater than 35%. Based on these results, the overall desirability of the ohmic thawing method was evaluated as 0.755. The obtained desirability value indicated the ohmic thawing method to be highly efficient and effective in achieving optimal thawing outcomes. The results of this study could give valuable information on the design of industrial-scale ohmic heating units to be used with solid foods, especially for thawing purposes.
AtıfScopus13WoS11İncele - MakaleYayıncıda açık erişim2024Scopus SJRQ1Investigation of in-vitro bioactivity, electrochemical corrosion, wettability and adhesion properties of bioglass-based coatings modified with Y2O3 and Zr on novel β-type Ti-30Zr-5Mo alloys
Dikici, B.; Say, Y.; Zhao, X.; Niinomi, M.; Szechyńska-Hebda, M.
In this study, the in-vitro bioactivity, electrochemical corrosion resistance, wettability, and adhesion properties of bioglass-based coatings modified with Y2O3 and ZrO2 on Ti-30Zr-5Mo alloy were investigated. The coatings were prepared using the sol-gel method and applied to the alloy substrates through dip-coating. The surface morphology and elemental composition of the coatings were analyzed using SEM/EDS and XRD techniques. Potentiodynamic polarization (PDS) and electrochemical impedance spectroscopy (EIS) were employed to assess the electrochemical behavior of the coatings under in-vitro conditions. Contact angle measurements were conducted to evaluate the wettability of the surfaces. Adhesion strength was measured using tensile testing in accordance with ISO 13779-2 standards. Bioactivity tests were performed by immersing the samples in simulated body fluid (SBF). The results demonstrate that the addition of Y2O3 and ZrO2 improves adhesion strength and corrosion potential, but introducing localized galvanic effects that increase the corrosion current density. Besides, the coatings maintained their structural integrity after the bioactivity tests, and promoted new apatite formation.
AtıfScopus9İncele - MakaleAçık Erişim2023Scopus SJRQ3Two Moss Species New to Turkey and South-West Asia
Batan, Nevzat; Özcan, Osman; Özen-Öztürk, Öznur; Erata, Hüseyin; Alataş, Mevlüt; Ezer, Tülay
Abstrat: —Sphagnum russowii and Leptodontium flexifolium found as new to Turkey following a recent bryofloristic foray in Artvin region (Caucasus), from the East Black Sea region of Turkey and Leptodontium is the first record of the genus from Turkey. Descriptions, illustrations, a distribution map, ecological characteristics, and comparisons with morphologically similar taxa were presented.
AtıfScopus1OpenAlex3İncele - MakaleYalnız künye2024Scopus SJRQ1Effect of Zr content on microstructure and wear behavior of Al-Si-Cu-Ni Mg-Zrx alloy
Taşgın, Yahya; Gök, Mehmet
In this study, the effect of zirconium addition (1, 1.5, 2 wt%) on the microstructural morphology and wear behavior of Al-Si-Cu-Ni-Mg alloys, known as light metals in which intermediate phases solidify rapidly at high temperatures, was investigated. The study aimed to obtain a stronger material by modifying the Al81Si12Cu4Ni2Mg alloy. It was observed that the Zr added to the alloy was homogeneously distributed throughout the samples. Aluminum and silicon formed compounds with zirconium (Al3Zr and ZrSi2), leading to the formation of a thinner and stronger structure. With the heat treatment applied to the aluminum alloys, the structure became more ductile. Additionally, as a result of Zr addition, microhardness increased, and wear values improved. Graphical abstract: (Figure presented.)
AtıfScopus2WoS2OpenAlex5İncele - BildiriAçık Erişim2025Investigation of Fatigue Performance of Hot Mix Asphalt Mixtures Modified with Elvaloy and Phosphoric Acid (PPA) as an Alternative to SBS Polymer
Furtana-Yalcin, Beyza
In this study, the combined use of Elvaloy and phosphoric acid (PPA) was investigated to enhance the performance of asphalt concrete (Hot Mix Asphalt - HMA) layers used in flexible pavement structures under increasing traffic loads and environmental conditions. These additives, considered as alternatives to Styrene-Butadiene-Styrene (SBS) polymer, were evaluated solely for their effects on the mechanical performance of HMA mixtures. Binders modified with Elvaloy/PPA at specified proportions were used to produce HMA specimens, and indirect tensile fatigue tests were conducted on these samples. The experimental results indicated that the addition of Elvaloy and PPA improved the mechanical properties of mixtures prepared with bituminous binders, extended fatigue life, and enhanced the strength and deformation resistance of asphalt mixtures at the selected proportions. The findings suggest that the Elvaloy/PPA additive combination could be a viable alternative to SBS polymer and has the potential to extend the service life of hot mix asphalt. Thus, it was concluded that the use of these additives contributes to improving HMA performance and supports sustainable pavement design.
AtıfOpenAlex1İncele - MakaleYalnız künye2023Scopus SJRQ2Physiological peristaltic flow of Jeffrey fluid inside an elliptic cross section with heat and mass transfer: Exact solutions through Polynomial solution technique
Nadeem, Sohail; Akhtar, Salman; Akkurt, Nevzat; Saleem, Anber; Almutairi, Shahah; Ghazwani, Hassan Ali
An interpretation of heat and mass transfer for the peristaltic flow of a non-Newtonian Jeffrey fluid inside a duct having an elliptic cross-section is mathematically investigated. We have considered constant heat absorption for the present study and a descriptive heat as well as mass transfer analysis is carried out. Exact solutions are computed by utilizing a polynomial solution technique to solve the dimensionless partial differential equations appearing in the problem. A purposeful and detailed graphical assessment is provided for the final mathematical results. Velocity as well as temperature profiles attain highest value at the core region of duct while these profiles gradually decline toward duct boundaries. The incrementing value of λ1 is resulting in an increase of flow and since λ1 is the dimensionless ratio of relaxation to retardation time, it means that the increasing value of λ1 results in an increase of relaxation time but it also results in decline of retardation time.
AtıfScopus11OpenAlex10İncele - MakaleAçık Erişim2024Scopus SJRQ2Innovative Al6061-gadolinium oxide ods alloys: fabrication and comprehensive characterization of microstructural, physical, mechanical, and radiation shielding properties
ALMisned, Ghada; Yayla, Nihal; Albayrak, M. Gökhan; Güler, Ömer; Baykal, Duygu Sen; Tekin, H.O.
This study explores the development and comprehensive characterization of Al6061-Gd₂O₃ composites, designed to enhance radiation shielding and mechanical properties for critical applications in environments exposed to ionizing radiation. The purpose of this research is to assess the effectiveness of Gd2O3 as a reinforcing material for Al6061, with the aim of creating a dual-function composite that combines structural integrity with superior gamma-ray and neutron attenuation capabilities. Using X-ray diffraction (XRD) and scanning electron microscopy (SEM), we analyzed the microstructural effects of varying Gd2O3 content, observing homogeneous dispersion at low concentrations and clustering at higher levels. Mechanical properties demonstrated that increased Gd2O3 content reduces the elastic modulus, indicating a trade-off between stiffness and shielding efficiency. Radiation shielding parameters, including Transmission Factor (TF), mass attenuation coefficient (MAC), and Fast Neutron Removal Cross Section (FNRCS), were evaluated through Phy-X/PSD and PHITS Monte Carlo simulations. Results indicate that Gd2O3 reinforcement significantly improves gamma-ray and neutron shielding, particularly at higher concentrations, making the composite viable for non-structural applications prioritizing radiation protection. The findings from this study highlight the potential of Gd2O3-reinforced Al6061 composites to serve as effective shielding materials in environments where radiation exposure is a primary concern.
AtıfScopus4OpenAlex5İncele - MakaleYayıncıda açık erişim2023Estimation of Contact Lengths Using Deep Neural Network; [Derin Öğrenme Yöntemi ile Temas Uzunlukları Tahmini]
Polat, Alper
One of the most common problems in engineering is contact problems. In recent years, researchers have turned to alternative methods that can offer effective solutions in a shorter time, instead of solutions containing complex and long mathematical expressions. This study focuses on the estimation of the contact lengths in a homogeneous elastic layer suppressed by two elastic punches with two solution methods. Firstly, a new model was designed for estimation using Deep Learning Neural Network (DNN), one of the deep learning structures. Estimation of contact lengths was provided with the output of the DNN model, which was fed with the homogeneous elastic layer, the ratio of shear modules of the punches and the input parameters of punch radii. The finite element method was used as the second solution method. The problem was modelled in the ANSYS programme, and the solution was made with the same parameters used in DNN modelled. The results obtained from both solutions were compared with the solutions obtained by the theory of elasticity and classical NN in the literature. It had been seen that the results obtained with DNN and ANSYS were compatible with the results obtained with analytical and classical NN and the margin of error was smaller.
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İncele - MakaleAçık Erişim2024Scopus SJRQ2Photocatalytic Hydrogen Evolution of TiZrNbHfTaOx High-Entropy Oxide Synthesized by Mechano-Thermal Method
Güler, Ömer; Boyrazlı, Mustafa; Albayrak, Muhammet Gökhan; Güler, Seval Hale; Ishihara, Tatsumi; Edalati, Kaveh
One of the most promising solutions to slow down CO2 emissions is the use of photocatalysis to produce hydrogen as a clean fuel. However, the efficiency of the photocatalysts is not at the desired level, and they usually need precious metal co-catalysts for reactions. In this study, to achieve efficient photocatalytic hydrogen production, a high-entropy oxide was synthesized by a mechano-thermal method. The synthesized high-entropy oxide had a bandgap of 2.45 eV, which coincided with both UV and visible light regions. The material could successfully produce hydrogen from water under light, but the main difference to conventional photocatalysts was that the photocatalysis proceeded without a co-catalyst addition. Hydrogen production increased with increasing time, and at the end of the 3 h period, 134.76 µmol/m2 h of hydrogen was produced. These findings not only introduce a new method for producing high-entropy photocatalysts but also confirm the high potential of high-entropy photocatalysts for hydrogen production without the need for precious metal co-catalysts.
AtıfScopus33WoS30İncele - MakaleYalnız künye2023Scopus SJRQ3Synthesis, Characterization and Biocompatibility of Cross-linked Dicarboxylic Acids from Waste Potato Peel Starch
Paşa, S.; Gürler, N.; Erdoğan, Ö.; Cevik, O.
Abstract: People have become conscious about recycling or reusing many things they use in the 21st century because diminishing vital resources make it necessary, both personally and socially. The evaluation of waste is also critical in terms of national economies. In this study, starch dicarboxylic compounds were synthesized using waste potato peels (WPP) in the presence of sodium hypophosphite monohydrate as a catalyst for the formation of the ester cross-links. Adipic acid, succinic acid, and glutaric acid were employed with waste potato starch (WPS) to obtain cross-linked samples: WPS-A, WPS-S, and WPS-G, respectively. The obtained compounds were characterized by attenuated total reflectance Fourier transform infrared (FTIR-ATR), scanning electron microscopy with energy-dispersive X-ray analysis (SEM-EDX), X-ray diffraction (XRD), and their cytotoxicity properties were investigated. The biocompatibility of the obtained WPS-dicarboxylic acid compounds against NIH-3T3 and L929 murine fibroblast cells with MTT assay was determined. Studies have shown that these compounds do not harm healthy cells and are found to be bioavailable.
AtıfScopus6OpenAlex6İncele - MakaleAçık Erişim2024Scopus SJRQ2Enhanced impedance, electrical conductivity, dielectric properties for colloidal starch-g-poly (methyl methacrylate) supported with semiconductor cadmium sulfide
Torğut, Gülben; Gürler, Nedim
In this study, starch-graft-poly (methyl methacrylate) (starch-g-PMMA) composites doped with different amounts (5, 10, and 15 wt%) of cadmium sulfide (CdS) particles were fabricated for electrical measurements using in-situ polymerization technique. The structural characterization of the samples was studied. The dielectric and conductivity properties of the composites were investigated using impedance analyzer depending on the frequency (100 Hz–20 kHz) at room temperature. Spectroscopy revealed that the dielectric constant (ε′), dielectric loss (ε′′), and real (Z) components of impedance are found to decrease with increasing frequency for both starch-g-PMMA and starch-g-PMMA (5, 10, and 15 wt%) composites. On the contrary, the AC conductivity (σac) of samples increased with increasing frequency. In addition, ε′ and ε′′ values of starch-g-PMMA were lower than composites that added CdS. When the CdS content increased from 0 to 15%, ε′ increased from 5.62 to 15.10 at 100 Hz. AC conductivity was improved after adding the CdS particles. The maximum conductivity value for starch-g-PMMA15%CdS is found to be 3.07 × 10–7 at 100 Hz. When the dielectric properties of composites are evaluated, it is concluded that it is an exciting material for electronic applications in technology.
AtıfScopus9WoS8OpenAlex10İncele - MakaleYayıncıda açık erişim2024Scopus SJRQ1Effect of pretreatment temperature and time on fat bonding and fat reduction in deep-fried surimi
Erol, Nida Demirtas; Cakli, Sukran; Szymczak, Mariusz; Shen, Cangliang; Matak, Kristen E.; Jaczynski, Jacek
Deep frying (DF) is a popular cooking technique resulting in desirable sensory quality. However, DF also results in negative perception related to increased fat uptake and thus poor nutritional quality. In this study, a development of a novel strategy for fat reduction in DF surimi without additives and coatings was attempted. Novel pre-baking and pre-roasting were applied to surimi prior to DF. This novel pre-treatment strategy for DF surimi has not been reported in literature. Total, free, and bonded fat contents and corresponding fat reductions in DF surimi were determined. Cook and moisture losses as well as water holding capacity, expressible moisture, in addition to color and texture were also investigated. Fat uptake during DF of surimi was reduced (P < 0.05) by ≥ 25 % with pre-baking. Pre-baking improved (P < 0.05) or did not (P > 0.05) affect cook and moisture losses, water holding capacity, expressible moisture, color, and texture. However, pre-roasting increased (P < 0.05) fat content and adversely affected most quality parameters. Pre-baking of surimi at lower-temperature (116 °C) for longer-time (12–15 min) followed by DF at lower-temperature (170 °C) for longer-time (4 min) was most optimal for fat reduction, cook and moisture losses, water holding capacity, expressible moisture, color, and texture of surimi.
AtıfScopus6WoS5OpenAlex5İncele - MakaleAçık Erişim2024Scopus SJRQ1Integrated Approach Using Intuitionistic Fuzzy Multicriteria Decision-Making to Support Classifier Selection for Technology Adoption in Patients with Parkinson Disease: Algorithm Development and Validation
Ortiz-Barrios, Miguel; Cleland, Ian; Donnelly, Mark; Gul, Muhammet; Yucesan, Melih; Jiménez-Delgado, Genett Isabel; Nugent, Chris; Madrid-Sierra, Stephany
Background: Parkinson disease (PD) is reported to be among the most prevalent neurodegenerative diseases globally, presenting ongoing challenges and increasing burden on health care systems. In an effort to support patients with PD, their carers, and the wider health care sector to manage this incurable condition, the focus has begun to shift away from traditional treatments. One of the most contemporary treatments includes prescribing assistive technologies (ATs), which are viewed as a way to promote independent living and deliver remote care. However, the uptake of these ATs is varied, with some users not ready or willing to accept all forms of AT and others only willing to adopt low-technology solutions. Consequently, to manage both the demands on resources and the efficiency with which ATs are deployed, new approaches are needed to automatically assess or predict a user’s likelihood to accept and adopt a particular AT before it is prescribed. Classification algorithms can be used to automatically consider the range of factors impacting AT adoption likelihood, thereby potentially supporting more effective AT allocation. From a computational perspective, different classification algorithms and selection criteria offer various opportunities and challenges to address this need. Objective: This paper presents a novel hybrid multicriteria decision-making approach to support classifier selection in technology adoption processes involving patients with PD. Methods: First, the intuitionistic fuzzy analytic hierarchy process (IF-AHP) was implemented to calculate the relative priorities of criteria and subcriteria considering experts’ knowledge and uncertainty. Second, the intuitionistic fuzzy decision-making trial and evaluation laboratory (IF-DEMATEL) was applied to evaluate the cause-effect relationships among criteria/subcriteria. Finally, the combined compromise solution (CoCoSo) was used to rank the candidate classifiers based on their capability to model the technology adoption. Results: We conducted a study involving a mobile smartphone solution to validate the proposed methodology. Structure (F5) was identified as the factor with the highest relative priority (overall weight=0.214), while adaptability (F4) (D-R=1.234) was found to be the most influencing aspect when selecting classifiers for technology adoption in patients with PD. In this case, the most appropriate algorithm for supporting technology adoption in patients with PD was the A3 - J48 decision tree (M3=2.5592). The results obtained by comparing the CoCoSo method in the proposed approach with 2 alternative methods; (simple additive weighting and technique for order of preference by similarity to ideal solution) support the accuracy and applicability of the proposed methodology. It was observed that the final scores of the algorithms in each method were highly correlated (Pearson correlation coefficient >0.8). Conclusions: The IF-AHP-IF-DEMATEL-CoCoSo approach helped to identify classification algorithms that do not just discriminate between good and bad adopters of assistive technologies within the Parkinson population but also consider technology-specific features like design, quality, and compatibility that make these classifiers easily implementable by clinicians in the health care system.
AtıfScopus5OpenAlex5İncele - MakaleAçık Erişim2023Scopus SJRQ1A comparative framework for criticality assessment of strategic raw materials in Turkey
Göçmen Polat, Elifcan; Yücesan, Melih; Gül, Muhammet
The rapid development of innovative technologies, population growth, shifting resource management patterns, and decarbonization challenges are expected to increase the demand for raw materials labeled as critical in the following years. The increasing concerns have led to evaluate the critical raw materials (CRMs) with high economic importance and supply risk. In this context, this paper aims to develop a conceptual methodology to identify CRMs in Turkey. The methodology integrates a multi-criteria decision-making method (MCDM) to provide the raw material criticality matrix regarding various criteria, the EU (European Union) method, which represents supply risk and economic importance indicators, and the time series analysis method, in which dynamic evaluation of materials over time instead of the static indicators. We first provide a Bayesian Best-Worst method (B-BWM) and TOPSIS (Technique for Order Preference by Similarity to Ideal Solution) based model for the criticality matrix, which enables evaluations of participated experts to be combined to reveal the weights of the criteria and sub-criteria from a probabilistic point of view without loss of knowledge. The main and sub-criteria include supply risk and economic importance, which are frequently studied in the literature, but also environment, price, secondary production, and socio-economic indicators are evaluated in the criticality matrix. Then, exponential smoothing forecast, one of the Time Series Analysis models, which determine the element criticality in the perspective of future years with the data of import figures of Turkey, is superior to the other models. Finally, with some modifications, the EU criticality methodology is used to quantify the raw materials regarding each material associated with the sector applications and their value-added and supply disruptions. Thus, a comprehensive criticality list integrating the results of the three mentioned methods is important because Turkey's raw materials characterize many sectors. The findings should also interest practitioners and researchers as the detailed assessment of raw material criticality ensures a sufficient database for future studies.
AtıfScopus24WoS14İncele - MakaleYalnız künye2024Scopus SJRQ4A Note on a New Bivariate Copula Defined with a Piecewise Generator Function
Chesneau, Christophe; Susam, Selim Orhun
Copulas are essential probability tools for characterizing the joint distribution of random variables. In this article, we contribute to the topic by studying special bivariate copulas. They have the property of being defined with piecewise components and are designed for the analysis of data that have dependence structures with distinct substructures in square zones. The theoretical properties of the copulas are studied, with emphasis on their mathematical validity and some dependence measures. In particular, it is shown that the Kendall tau coefficient has a simple expression that is governed by several parameters, demonstrating the flexibility of the approach. In addition, a real data example is provided to demonstrate the applicability of the copulas. Fair comparisons with other standard copulas motivate their use in other practical scenarios.
- Kitap BölümüAçık Erişim2024Scopus SJRQ4Heavy Metals in Cetraria islandica: Health Risk Assessment
Topal, Murat; Arslan Topal, E. Işıl; Öbek, Erdal; Aslan, Ali
In this chapter, potential human health risk of the heavy metals associated with usage of Cetraria islandica were evaluated. Heavy metals (lead, cadmium, manganese, chromium, copper, zinc, and nickel) were determined in Cetraria islandica. Highest and lowest heavy metal values were 87 ± 4.3 mg/kg for manganese (Mn) and 0.12 ± 0.01 mg/kg for cadmium (Cd). When potential health risk was assessed, the doses of exposure for man, woman, and child followed the order of bread > tea > dermal. Risk of health for bread and tea were child > woman > man. Also, risk of health for dermal was woman > child > man. Non-carcinogenic risk was woman > child > man for dermal way. Non-carcinogenic risks were child > woman > man for dietary. Highest total hazard index (THI) was 6.33 for chromium (Cr), lowest THI was 0.22 for zinc (Zn). THIs were zinc < copper < cadmium < nickel < lead < manganese < chromium. The THIs were higher than 1 for chromium, manganese and lead. Total highest carcinogenic value was 1.73E−03 for Ni and minimum was 1.19 E−05 for lead. Carcinogenic risks for bread (cadmium, nickel and chromium) were high. As a result, it was determined that Cetraria islandica may cause cancer risk if consumed as additive in bread. It was determined that if Cetraria islandica was consumed as tea and cream, there would be no risk of cancer and could not adversely affect human health.
