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- MakaleYalnız künye2020Scopus SJRQ2Modeling and optimization of indigo carmine adsorption from aqueous solutions using a novel polymer adsorbent: RSM-CCD
Torğut, Gülben; Tanyol, Mehtap; Meşe, Zeynep
A novel adsorbent was prepared via the free radical copolymerization of 2-(dimethylamino) ethyl methacrylate (DMAEMA) and acrylonitrile (AN) using 2,2′-azobisizobutyronitrile (AIBN) as an initiator at 65 °C. Poly(DMAEMA-co-AN) was characterized by FT-IR, 1H-NMR, and SEM techniques. Its thermal properties were determined by TGA and DSC. The copolymer was used to remove indigo carmine (IC) from aqueous solutions. The optimum IC removal percentage was determined to be 99.53% with poly(DMAEMA-co-AN) of 0.10 g/100 mL, contact time of 31.37 min, 46.58 mg/L initial concentration of IC using a central composite design in response surface methodology. The high maximum adsorption capacity (196.07 mg/g) proved that poly(DMAEMA-co-AN) can be used as a promising adsorbent for the removal of IC from wastewaters.
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İncele - MakaleAçık Erişim2020Scopus SJRQ1Optimization of tetracycline removal with chitosan obtained from mussel shells using RSM
Topal, Murat; Arslan Topal, E. Işıl
In this study, the removal of tetracycline from aqueous solutions with chitosan obtained from mussel shells was optimized and investigated using responce surface methodology. For this aim, the central composite design was used to optimize the four variable factors (sorbent dosage (0.4–1.0 g), time (20−60 min), temparature (10−30 °C) and initial TC concentration (50−100 mg/L)) for the removal of TC from aqueous solutions by chitosan obtained from mussel shells. According to the RSM analysis results, optimum conditions for maximum TC removal efficiency were determined as 90.5 mg/L for initial TC concentration, 35.9 min for time, 29.9 °C for temperature and 0.4 g for sorbent dosage. It was observed that the tetracycline was crystallized on mussel shells. According to the results of XRD after adsorption, the content of mussel shells were observed as 60% calcite, 5.6% overite, 9.4% aragonite and calcium hydroxide 25%, respectively. As a result, experiments showed that chitosan obtained from mussel shells were a good adsorbant for tetracycline removal from aqueous solutions.
AtıfScopus53WoS52OpenAlex53İncele - MakaleYalnız künye2017Scopus SJRQ1A food waste utilization study for removing lead(II) from drinks
Ince, Olcay Kaplan; Ince, Muharrem; Yonten, Vahap; Goksu, Ali
This is the first study about removal of lead (Pb(II)) from energy drinks. In this paper, food waste, namely eggshell (hydroxyapatite) utilization, was used to remove Pb(II) from mineral water and energy drinks. Mineral water and energy drinks were chosen for removal of lead since the latter is severely hazardous to human health even in small amounts. Response Surface Methodology (RSM) was performed to optimize the application process by practice of the quadratic model united with the Central Composite Design (CCD) and quadratic combined program was utilized to study the most effective parameters on aforementioned liquids. Through the application of variance analysis (ANOVA) factors critical to removing of lead were identified for each experimental design response. Maximum adsorption capacity of eggshell was achieved as 923 mg g(-1) for Pb(II). The obtained optimum conditions were applied to drinks. Results showed that used adsorbent was quite effective in removing Pb(II) from drinks. (C) 2016 Elsevier Ltd. All rights reserved.
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İncele - MakaleYalnız künye2017Scopus SJRQ1Investigation of optimum conditions for efficient COD reduction in synthetic sulfamethazine solutions by Pleurotus eryngii var. ferulae using response surface methodology
Yonten, Vahap; Alp, Hevidar; Yildirim, Numan; Yildirim, Nuran Cikcikoglu; Ogedey, Aysenur
This study aims to explore the optimum conditions for P. eryngii var. ferulae in adsorption of sulfamethazine (SM) from synthetic solutions via reduction of chemical oxygen demand (COD). The optimum conditions were optimized using the response surface methodology (RSM) developed by the application of the quadratic model associated with the central composite design. For this aim, RSM was employed to determine the effects of some parameters on this adsorption process by fungal biomass as an effective and available adsorbent. The investigated parameters were initial concentration of sulfamethazine (70–235 mg L−1), solution pH (3–7), adsorbent dosage (0.3–1.5 g), and contact time (5–25 min). The significant factors on each experimental design response were identified from the analysis of variance. The results of RSM analyzes revealed that optimum conditions of initial SM concentration, pH, adsorbent dosage, and contact time for maximum COD removal (82%) were achieved as 400 mg L−1, 11, 1.46 g, and 15.4 min, respectively. The results showed that dead biomass of P. eryngii var. ferulae were an appropriate adsorbent for the removal of COD in the SM medium from synthetic solutions.
AtıfScopus13WoS12OpenAlex15İncele - MakaleAçık Erişim2016Scopus SJRQ2Optimization of Remazol Brilliant Blue R dye removal by novel biosorbent P. eryngii immobilized on Amberlite XAD-4 using response surface methodology
Yonten, Vahap; Tanyol, Mehtap; Yildirim, Numan; Yildirim, Nuran Cikcikoglu; Ince, Muharrem
This study investigates preparation of biosorbent Pleurotus eryngii immobilized on Amberlite XAD-4 and the optimal conditions for removal of Remazol Brilliant Blue R (RBBR) reactive dye from synthetic aqueous solutions. The process was optimized using the response surface methodology (RSM) developed by the application of the quadratic model associated with the central composite design. For this purpose, RSM was employed to determine the effects of operational parameters on this material as effective and available adsorbent. The investigated variables were dye initial concentration (10-60 mg L-1), solution pH (2-9), adsorbent dosage (0.1-0.5 g), and temperature (20-45 degrees C). The significant factors on each experimental design response were identified from the analysis of variance (ANOVA). The RSM indicated that optimum conditions of initial dye concentration, pH, adsorbent dosage, and temperature for maximum RBBR removal (98%) were achieved as 36.3 mg L-1, 2.0, 0.304 g, and 38.7 degrees C, respectively. The results showed that this biosorbent was an appropriate adsorbent for the removal of RBBR from aqueous solutions.
AtıfWoS17OpenAlex20İncele - MakaleAçık Erişim2015Scopus SJRQ4Optimization of lipase production on agro-industrial residue medium by Pseudomonas fluorescens (NRLL B-2641) using response surface methodology
Tanyol, Mehtap; Uslu, Gulsad; Yönten, Vahap
The aim of our research was to explore the most cost-efficient and optimal medium composition for the production of lipase from Pseudomonas fluorescens (NRLL B-2641) culture grown on sunflower oil cake (SuOC) by applying response surface methodology (RSM). The oil cake was used instead of carbon sources. Peptone, ammonium sulphate and the carbon source (SuOC) were the most important factors as it is obligatory for microbial growth. Subsequently, the optimum values for the carbon source, peptone and ammonium sulphate were found to be 11.10% (w/v), 1.18% (w/v) and 0.83% (w/v), respectively. Experiments carried out under optimum conditions revealed a maximum lipase activity of 10.8 U mL(-1), which was achieved after 48 h of fermentation. The obtained results were finally verified with batch experiments carried out under the optimum conditions evaluated and it was demonstrated that the SuOC from agro-industrial residue as substrates can be used as an inexpensive base (carbon source) for the production of lipase by P. fluorescens (NRLL B-2641).
AtıfWoS19İncele - MakaleYalnız künye2014Scopus SJRQ3EXPLORING THE OPTIMUM CONDITIONS FOR MAXIMIZING THE MICROBIAL GROWTH OF Candida intermedia BY RESPONSE SURFACE METHODOLOGY
Yönten, Vahap; Aktas, Nahit
Exploring optimum and cost-efficient medium composition for microbial growth of Candida intermedia Y-1981 yeast culture growing on whey was studied by applying a multistep response surface methodology. In the first step, Plackett-Burman (PB) design was utilized to determine the most significant fermentation medium factors on microbial growth. The medium temperature, sodium chloride and lactose concentrations were determined as the most important factors. Subsequently, the optimum combinations of the selected factors were explored by steepest ascent (SA) and central composite design (CCD). The optimum values for lactose and sodium chloride concentrations and medium temperature were found to be 18.4g/L, 0.161g/L, and 32.4 degrees C, respectively. Experiments carried out at the optimum conditions revealed a maximum specific growth rate of 0.090 1/hr; 42% of total lactose removal was achieved in 24h of fermentation time. The obtained results were finally verified with batch reactor experiments carried out under the optimum conditions evaluated.
AtıfWoS14OpenAlex16İncele