Koleksiyon/r/munzur/2

Yayınlar

Koleksiyondaki öğeler

  • MakaleAçık Erişim2022Scopus SJRQ1
    Transportation of thermal and velocity slip factors on three-dimensional dual phase nanomaterials liquid flow towards an exponentially stretchable surface

    Hussain, Azad; Akkurt, Nevzat; Rehman, Aysha; Alrihieli, Haifaa F.; Alharbi, Fahad M.; Abdussattar, Aishah; Eldin, Sayed M.

    The fundamental purpose of this research is to elaborate on slip boundary conditions and the flow of three-dimensional, stable, incompressible, rotating movements of nanoparticles lying across a stretchable sheet. The mathematical model for fluid flow is created using the assumptions stated above. The partial differentials are produced after utilizing boundary layer estimates. The partial differential governing equations are reduced into three coupled ordinary differential equations by using similarity transformations. After, applying transformations the system is solved numerically. Numerical results are approved with the help of the MATLAB bvp4c algorithm. The analysis shows that velocity and temperature are strongly dependent on essential parameters like stretching ratio, velocity slip, rotation, thermal slip parameter, and Prandtl number. Numerical values of distinct parameters on heat flux and skin friction factors are shown in a tabulated form. Partial velocity and thermal slip are applied to the temperature surface. The comparison among the nano-sized particles copper oxide and silver with water base nanofluid affecting velocity and temperature fields are used for analysis. Moreover, the Graphical depiction designates that the velocity and temperature spreading of the thermal slip parameter is increasing. It is observed that Ag-water is the best heat carrier as compared to CuO-water nanofluid.

    AtıfScopus15OpenAlex20
    ScopusWeb of SciencePubMedİncele
  • MakaleYalnız künye2023Scopus SJRQ2
    The protective effect of arbutin against potassium bromate-induced oxidative damage in the rat brain

    Akkoyun, H. Turan; Uyar, Ahmet; Bayramoglu Akkoyun, Mahire; Bengü, Aydın Şükrü; Melek, Şule; Karagözoğlu, Fatma; Aydın, Sevinç; Ekin, Suat; Erdem, Sinem Aslan

    This study aimed to investigate the protective effects of arbutin (ARB) against brain injury induced in rats with potassium bromate (KBrO3). The rats were divided into four groups as Group 1: Control (0.9% NaCl ml/kg/day p.), Group 2: KBrO3 (100 mg/kg (gavage), Group 3: ARB (50 mg/kg/day p.), and Group 4: KBrO3 + ARB (100 mg/kg (gavage) + 50 mg/kg/day p.). At the end of the fifth day of the study, the rats in all groups were killed, and their brain tissues were collected. In the collected brain tissues, malondialdehyde (MDA), superoxide dismutase (SOD), and catalase (CAT) levels were measured, and routine histopathological examinations were made. The MDA levels in the group that was exposed to KBrO3 were significantly higher than those in the control group (p ˂ 0.001). In comparison to the KBrO3 group, the MDA levels in the KBrO3 + ARB group were significantly lower (p ˂ 0.001). It was observed that SOD and CAT enzyme activity levels were significantly lower in the KBrO3 group compared to the control group (p ˂ 0.001), while these levels were significantly higher in the KBrO3 + ARB group than in the KBrO3 group (p ˂ 0.001). Additionally, the group that was subjected to KBrO3 toxicity, as well as ARB administration, had much lower levels of histopathologic signs than the group that was subjected to KBrO3 toxicity only. Consequently, it was found that KBrO3 exposure led to injury in the brain tissues of the rats, and using ARB was effective in preventing this injury.

    AtıfScopus10
    ScopusWeb of SciencePubMedİncele
  • MakaleAçık Erişim2023Scopus SJRQ1
    Investigation of Critical Raw Materials in Sludge of Municipal Wastewater Treatment Plant

    Topal, Murat; Arslan Topal, E. Işıl

    In the present research, lanthanum, vanadium, tungsten, scandium, bismuth, antimony, gallium, phosphorus, magnesium, and cobalt from critical raw materials (CRMs) were monitored for one year in the sewage sludges from an advanced biological wastewater treatment plant with the aim of presentation of possibility of using sewage sludge as a secondary source of critical raw materials. The amounts of the critical raw materials in sewage sludge were calculated annually, and economic values ​​were revealed. Maximum concentrations of lanthanum, scandium, tungsten, bismuth, antimony, gallium, vanadium, cobalt, magnesium, and phosphorus were 4.3, 1.6, 0.5, 1.51, 1.27, 1.7, 23, 5.6, 6500, and 16,170 mg/kg, respectively. In the sewage sludge, the amount of CRMs, which have been formed annually, have been listed as tungsten < scandium < antimony < bismuth < gallium < lanthanum < cobalt < vanadium < magnesium < phosphorus. In autumn, summer, spring, and summer season, the mean highest concentration was for P, while the minimum concentration was for W. In sewage sludge, P and W elements were the highest and the least of the CRMs, respectively. With the recovery of CRMs in sewage sludge, the highest theoric achievable income is for Mg, while the lowest income is for Sb. It is determined that a total of 26,083.8 USD/year could be obtained by recovering the CRMs mentioned here from the sewage sludge.

    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus1WoS1OpenAlex3
    ScopusWeb of Scienceİncele
  • MakaleYayıncıda açık erişim2023Scopus SJRQ3
    Contamination and Ecological Risk Assessment of Heavy Metals in Surface Sediments of the Munzur Stream, Turkey

    Kutlu, Banu

    The aim of the present study is to determine the heavy metal concentrations in the surface sediment between 2019-2020 in Munzur Stream,Turkey. The impact of pollution level in the study area was evaluated by geoaccumulation index (Igeo), Contamination Factor (CF), enrichment factor (EF), pollution ecological risk (PER) index, and pollution load index (PLI). The average amount of heavy metals detected in sediment in the study in mg/kg was, in descending order, Fe>Al>Mn>Ni>Cr>Zn >Cu>Pb>Cd>Hg. The data evaluated by several statistical methods indicated that the metals with a positive relationship between them in the Pearson correlation analysis and the elements of the same factor in the factor analysis were mostly the same. The comparison of the results with the sediment quality criteria showed that only the mean value of Mn and Ni exceeded the values of PEL. Heavy metal levels in Munzur Stream sediment exposed to domestic and agricultural wastes, agricultural fertilizers and pesticides, and mines were not high enough to pose a threat to aquatic life.

    • SDG 6 · Temiz Su ve Sanitasyon
    AtıfScopus9WoS8OpenAlex11
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2023Scopus SJRQ2
    Computational assesment of Carreau ternary hybrid nanofluid influenced by MHD flow for entropy generation

    Ramzan, Muhammad; Ali, Farhan; Akkurt, Nevzat; Saeed, Anwar; Kumam, Poom; Galal, Ahmed M.

    Tri-hybrid nano-particles in shear rate-dependent viscous fluid are essential for improving heat and mass transmission in many industries. The current study explores the two-dimensional flow of the Carreau-ternary hybrid nanoliquid with a magnetic field over the stretching surface. The heat transport mechanism is deliberated through the applications of thermal radiation and heat source/sink effects. The entropy minimization of the flow of Carreau ternary hybrid nanofluid has also been scrutinized. Further, the concepts of convective conditions are employed for the numerical solution of the existing model. In the present flow analysis, silver (Ag), Molybdenum disulfide (MoS2), and multi-wall carbon nanotube (MWCNT) nanoparticles are studied. Carboxymethyl cellulose (CMC-water) is used as a base liquid. The well-established numerical collocation finite difference scheme and three-stage Lobatto III as the built-in function of the bvp4c solver via MATLAB have been used to solve the system of equations in the form of concentration, energy, and momentum. Numerous features, such as flow speed, temperature, drag friction, and Nusselt number, are described in figures and tables. From the existing model, some key outcomes are that the rising values of the radiation parameter increased the heat transfer rates. Further, it is dissected that the greater importance of the magnetic field parameter declined the entropy generation and velocity of the liquid.

    AtıfScopus88OpenAlex96
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2022Scopus SJRQ1
    2D MHD Mixed Convection in a Zigzag Trapezoidal Thermal Energy Storage System Using NEPCM

    Abderrahmane, Aissa; Younis, Obai; Al-Khaleel, Mohammad; Laidoudi, Houssem; Akkurt, Nevzat; Guedri, Kamel; Marzouki, Riadh

    In a magnetic field, two-dimensional (2D) mixed convection is investigated within a zigzagged trapezoidal chamber. The lower side of the trapezoidal chamber is irregular, in particular, a zigzagged wall with different zigzag numbers N. The fluid particles move in the room due to the motion of the upper wall, while the porosity-enthalpy approach represents the melting process. The thermal parameters of the fluid are enhanced by what is called a nano-encapsulated phase change material (NEPCM) consisting of polyurethane as the shell and a nonadecane as the core, while water is used as the base fluid. In order to treat the governing equations, the well-known Galerkin finite element method (GFEM) is applied. In addition, the heat transfer (HT) and the dynamic behavior of flow are treated in terms of average Nusselt number and contours of streamlines. The main results show that the melt band curve of heat capacity behaves almost parabolically at smaller values of Reynolds number (Re) and larger values of Hartmann number (Ha). Moreover, minimizing the zigzag number is better in order to obtain a higher heat transfer rate.

    AtıfScopus30OpenAlex34
    ScopusWeb of SciencePubMedİncele
  • MakaleAçık Erişim2021Scopus SJRQ3
    The protective effects of lupine (Lupinus albus) fruit extract against to destructive effects of hyperglycemia in type I diabetic rats

    Aydın, Sevinç; Kaya, Tubay; Erman, Orhan; Yılmaz, Ökkeş

    Background: Lupinus albus is a member of the Fabaceae family. As a natural or cultivat-ed plant, Lupinus albus is distributed in Europe, the Balkans and Turkey, especially in Marmara and Aegean regions. The lupine is a nutritious and protective plant against diabetes. Objective: In the present study, the effects of Lupinus albus fruits on malondialdehyde (MDA), reduced glutathione (GSH), total protein, ADEK vitamins, and cholesterol values, which are the indi-cators of oxidative damage and antioxidant defense. In this regard, muscle, liver, renal, and brain tissues of STZ-induced type I diabetes rats were studied. Methods: The analyzes of ADEK vitamins and cholesterol levels in tissues were performed via Shimadzu HPLC device. The lipid peroxidation levels were measured at 532 nm in spectrophotome-ter. Determination of GSH was read at 412 nm against blank, and for the total protein levels Lowry method was applied. Results: According to the results obtained, it was determined that among the rats with induced type I diabetes, the group applied lupine fruit extract was found to have increased GSH level and decreased MDA levels in all the tissues. The protein values were increased in liver tissues but decreased in the other tissues. The level of vitamins was significantly increased in almost all the tissues in the diabetic group. Conclusion: In the present study, it was shown that the lupine reduced the devastating effects of type I diabetes by decreasing the fasting blood glucose and lipid peroxidation values and increasing the glutathione level in comparison to the diabetic group.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus4WoS4OpenAlex4
    ScopusWeb of SciencePubMedİncele
  • MakaleYalnız künye2022Scopus SJRQ3
    Characterization of the antioxidant activity, total phenolic content, enzyme inhibition, and anticancer properties of Achillea millefolium L. (yarrow)

    Karaaslan Ayhan, Nagihan; Karaaslan Tunc, Merve Goksin; Noma, Samir Abbas Ali; Kurucay, Ali; Ates, Burhan

    The antioxidant activity, total phenolic content, enzyme inhibition, anticancer properties of Achillea millefolium L. (yarrow), which is generally consumed by humans as herbal tea, were investigated. Yarrow extracts were prepared with different extraction techniques and solvents and the optimum conditions were determined. When the antioxidant activity and total phenolic content results were evaluated, the best yield was obtained with ultrasound-assisted extraction for all solvents. Moreover, the yields from highest to lowest were methanol, water, and acetonitrile. The enzyme inhibition and anticancer of Achillea millefolium L. extracts using methanol were evaluated. The IC50 values for the inhibition of xanthine oxidase and acetylcholinesterase were 4.974 ± 0.54 and 21.891 ± 1.118 µg/mL, respectively. The extract concentration was determined to be 23.85 μg/mL for 50% reduction in growth inhibitory activity cell viability (IC50) against breast cancer (MCF-7).

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus7OpenAlex9
    ScopusWeb of Scienceİncele
  • MakaleYayıncıda açık erişim2021Scopus SJRQ2
    The Impact of Game-Based, Modeling, and Collaborative Learning Methods on the Achievements, Motivations, and Visual Mathematical Literacy Perceptions

    İlhan, Aziz

    The present study aimed to investigate the effects of geometry instruction activities conducted in nature based on modeling, game-based, and cooperative learning methods on achievement, mathematical motivation, and visual mathematical literacy perceptions of third-grade elementary school students. The present study is a quantitative study conducted with a pre-test/post-test experimental design with a control group. The study was conducted with 61 students (35 students in the experimental group and 26 students in the control group). Modeling-, game-, and collaborative learning-based activities were conducted with the students in the experimental group. It was determined that the achievements of students who were instructed with modeling-based activities in geometry were high when compared to that of the students instructed with collaborative learning- and game-based methods, and those in the control group where no intervention was applied. This group was followed by the game-based and collaborative learning groups. Based on the variable of motivation, the mean motivation of the students in the modeling group was higher when compared to that of the students in the collaborative learning, game-based, and conventional instruction groups. This group was followed by the collaborative and game-based learning groups. Also, based on the visual mathematical literacy perception variable, the mean visual mathematics literacy perception of the students in the collaborative learning group was higher when compared to that of the students in the groups where the modeling, game-based, and conventional instruction methods were used. This group was followed by the modeling and game-based learning groups.

    AtıfScopus13WoS7
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2023Scopus SJRQ1
    Radiation mechanism on dissipative ternary hybrid nanoliquid flow through rotating disk encountered by Hall currents: HAM solution

    Shamshuddin, M.D.; Akkurt, Nevzat; Saeed, Anwar; Kumam, Poom

    The energy transition to enhance heat transport during the flow of ternary hybrid nanofluid comprised of Copper (Cu), Iron oxide (Fe3O4), Silicon dioxide (SiO2) nanoparticles and Polymer as base liquid over a revolving disk surface has been reported. From the several existing techniques, adding nanoparticles to standard working fluids is an effective approach that might dramatically improve the rate of heat transfer. The Hall and radiation impacts are also considered. A mathematical model is developed by assuming the flow as incompressible and purely radial in a cylindrical coordinate system and appropriate similarity variables are introduced for problem simplification and dimensionless analysis. The solution of complex generated PDEs was calculated using semi analytical method known as Homotopy Analysis Method (HAM) after translating them into corresponding ODEs. It has been observed that the consequences of thermal radiation, dissipation term, unsteadiness and rotation parameters boost the energy transmission rate and enhances the heat transfer rate of tri hybrid nanofluids. However, Cu-Fe3O4 nanoparticles in the base fluid remarkably magnifies the energy transmission rate. The unitary ternary hybrid nanofluid (Cu, Fe3O4, SiO2) has higher velocity profiles as compared to unitary nano fluid (Cu) and hybrid nano-fluid (Cu-Fe3O4).

    AtıfScopus133WoS121OpenAlex138
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2022Scopus SJRQ3
    Effects of Arbutin on Fatty Acid Levels of Erythrocyte and Serum in Wistar Albino Rats Treated with Potassium Bromate

    Akkoyun, H. Turan; Aydın, Sevinç; Akkoyun, Mahire Bayramoglu; Bengü, Aydın Şükrü; Ekin, Suat; Erdem, Sinem Aslan

    Background: In the presented study; the Effects of Arbutin (ARB) on the Rat Erythrocyte and serum fatty acid profile which is exposed to potassium bromate (KBrO3 ) were investigated. Materials and Methods: In this study, 32 Wistar albino rats weighing 250-300 g were used divided into 4 groups. Groups 1: control, group 2: KBrO3 (single dose 100 mg / kg gavage), group 3: ARB (50 mg / kg / day (ip) for 5 days), group 4: KBrO3 + ARB. At the end of the 5th day, alteration of fatty acid profile in erythrocyte and serum of rats in all groups was examined. Results: Rat serum essential fatty acid; palmitic acid (C16:0), myristic acid (C14:0), stearic acid (C18:0), oleic acid (C18:1), linoleic acid (C18:2), erythrocyte major fatty acids; palmitic acid (C16:0), myristic acid (C14:0), stearic acid (C18:0), oleic acid (C18:1), linoleic acid (C18:2), arachidic acid (C20:0), eicosenoic acid (C20:1), and lignoceric acid (C24:0). In addition, in our studied serum and erythrocytes; Total monounsaturated fatty acids (MUFA) varied between 8.91 ± 0.53-11.71 ± 2.55 and 33.71 ± 2.12-37.11 ± 2.12, respectively. It was determined that total polyunsaturated fatty acids (PUFA) varied between 5.90 ± 1.29-9.96 ± 1.18 and 14.72 ± 3.66-22.13 ± 4.82, respectively. Conclusion: In our study, alterations in fatty acid contents were observed, and results suggesting that arbutine affects the enzymes involved in Fatty acid metabolism and has an effect on fatty acid amounts.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfOpenAlex1
    ScopusWeb of Scienceİncele
  • Kitap BölümüYalnız künye2021
    Fine–kinney-based occupational risk assessment using interval type-2 fuzzy qualiflex

    Gul, Muhammet; Mete, Suleyman; Serin, Faruk; Celik, Erkan

    In this chapter, we improved Fine–Kinney occupational risk assessment approach with interval type-2 fuzzy QUALIFLEX (IT2FQUALIFLEX). QUALIFLEX is an outranking multi-attribute decision-making method proposed by an extension of the Paelinck’s (Pap Reg Sci Assoc 36:59–74,[1]), generalized Jacquet-Lagreze’s permutation method. Similar to other outranking solution-based approaches, it considers the solution which is a comparison of hazards. In this chapter, we adapted the interval type-2 fuzzy sets (IT2FSs) into QUALIFLEX as it reflects the uncertainty well in decision-making. IT2FQUALIFLEX algorithm under the Fine–Kinney concept provides a useful and solid approach to the occupational health and safety risk assessment. In addition to proposing this new approach, a case study is performed in the chrome plating unit. A validation is also performed in this study. Finally, the proposed approach is implemented in Python.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus7OpenAlex7
    Scopusİncele
  • Kitap BölümüYalnız künye2021
    Fine–kinney-based occupational risk assessment using interval type-2 fuzzy topsis

    Gul, Muhammet; Mete, Suleyman; Serin, Faruk; Celik, Erkan

    This chapter proposed an improved Fine–Kinney occupational risk assessment approach using a well-known MCDM method “TOPSIS” under interval type-2 fuzzy set concept. It is defined as a technique for order preference by similarity to ideal solution by Hwang and Yoon [1]. It is based on separation from ideal and anti-ideal solution concept. Since the initial crisp data-based version is insufficient by time in reflecting the uncertainty in decision-maker’s opinions, fuzzy sets are integrated to the TOPSIS algorithm to provide a solid and comprehensive method. Interval type-2 fuzzy set is an improved version of the type-1 fuzzy set. It is also a special version of a general type-2 fuzzy set. Since general type-2 fuzzy systems contain complex computational operations, they cannot be easily applied to real-world problems such as occupational risk assessment. Interval type-2 fuzzy sets are the most frequently used type-2 fuzzy sets due to their ability in handling more uncertainty and producing more accurate and solid results. The Fine–Kinney concept is merged with the interval type-2 fuzzy set concept and TOPSIS for the first time through the literature. To demonstrate the applicability of the proposed approach, a case study is carried out in a chrome plating unit of a gun factory. Some beneficial validation and sensitivity analysis are also performed. Finally, as a creative contribution of our book, the implementation of the proposed approach in Python is performed.

    AtıfScopus2OpenAlex3
    Scopusİncele
  • Kitap BölümüYalnız künye2022
    Geo-polymer concretes: Structure, properties and materials

    Polat, Berivan Yilmazer

    In recent years, different types of special concretes have been produced and used according to the usage principles of the buildings. One of these concretes is alkali active concretes produced without the need for cement production which is known as geopolymer concrete. Their high early strength, less drying-shrinkage, high fire, abrasion & acid resistance, less CO2 emissions, least setting time, and high freeze-thaw & corrosion resistance are reasons this type of concrete has emerged as an alternative to portland cement concrete. This concrete is formed by the reaction of material rich in alumina and silica with the activator. Since geopolymer concrete is more environmentally friendly than cementitious concrete, it has been the subject of many studies. Geopolymer concretes have some disadvantages despite all these advantages. One of them is brittleness. It is known that adding fibers to geopolymer concretes positively affects brittleness and ductility, compressive strength, and flexural strength. Also, mineral additives strengthen the durability of concrete. This work presents a summary of the literature on geopolymer concrete's foundations and disadvantages compared to portland cement concrete, mix proportions that give the best strength, management of fiber additives, performance analysis against burst rate, and resistance to attack.

  • MakaleAçık Erişim2022Scopus SJRQ2
    Antioxidant and Enzyme Inhibitory Properties, and HPLC–MS/MS Profiles of Different Extracts of Arabis carduchorum Boiss.: An Endemic Plant to Turkey

    Uba, Abdullahi Ibrahim; Zengin, Gokhan; Montesano, Domenico; Cakilcioglu, Ugur; Selvi, Selami; Ulusan, Musa Denizhan; Caprioli, Giovanni; Sagratini, Gianni; Angeloni, Simone; Jugreet, Sharmeen

    In this study, six extracts of Arabis carduchorum prepared from solvents of varying polarity (water, methanol, ethyl acetate, dichloromethane, and n‐hexane) were investigated for their chemical profiles and total phenolic and flavonoid contents (TPC/TFC) using HPLC–MS/MS and spectrophotometric/colorimetric assays, respectively, along with the assessment of their antioxidant and enzyme inhibitory effects. In general, the polar extracts (methanol, water, and infusion) showed higher TPC/TFC than the other extracts (range:13.73–26.62 mg GAE/g; 2.66–52.95 mg RE/g, respectively). The total antioxidant capacity of the polar extracts ranged from 0.90–1.85 mmol TE/g in phosphomolybdenum assay, while the free radical scavenging potential ranged from 4.36–32.13 mg TE/g and 12.58–67.73 mg TE/g in DPPH and ABTS assays, respectively. While the water and infuse extract inhibited only butyrylcholinesterase (2.68 and 2.39 mg GALAE/g, respectively), the other extracts were found to inhibit both acetyl‐ and butyryl‐cholinesterases (0.96–2.73 mg GALAE/g and 1.86–5.11 mg GALAE/g, respectively). On the contrary, all extracts exhibited anti‐tyrosinase (40.24– 59.22 mg KAE/g) and anti‐amylase (0.09–0.63 mmol ACAE/g) activities. Overall, this study highlighted the effect of solvent polarity on the extraction of bioactive compounds and the biological properties of the extracts of A. carduchorum; hence, the results obtained could be used to guide optimum extraction in future studies.

    AtıfScopus37OpenAlex39
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2022Scopus SJRQ4
    Molecular Structure, Vibrational, Spectral Investigation and Quantum Chemical DFT Calculations of Poly(N-isopropyl acrylamide-co-nbutyl methacrylate)

    Pihtili, Güzin; Hekim, Seda; Pekdemir, Mustafa Ersin

    A new copolymer poly(N-isopropylacrylamide-co-nbutylmethacrylate) was synthesized by free radical solution polymerization process using 2,2′-Azobis(2-methylpropionitrile) as an initiator in 1,4-dioxane at 70 °C. The structure of the copolymer was characterized by Fourier Transform Infrared Spectrometer (FTIR), the proton nuclear magnetic resonance (1H NMR), and the ultraviolet-visible spectroscopy (UV-vis) method. Theoretically, density functional theory (DFT) (B3LYP) was utilized to identify the molecular geometry and then examine the vibrational frequencies and electrical characteristics of this molecule, with the 6-31G basis set in the ground state. In dichloromethane solution, UV-vis spectra of the molecule were calculated using the Time-Dependent DFT method. 1H NMR chemical shifts have been calculated with GIAO approximation, and the calculated results show good agreement with experimental chemical shifts.

    AtıfScopus2WoS2OpenAlex2
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2022Scopus SJRQ1
    Graphene-reinforced novel poly(acetoxystyrene-co-glycidylmethacrylate) composites: Synthesis and optimization of dielectric behaviors using response surface methodology

    Pihtili, Güzin

    In this work, a new copolymer synthesis of Poly(acetoxystyrene-co-glycidylmethacrylate) (P[AOS-co-GMA]) by free radical polymerization (FRP) method is reported. The polymer composites (P[AOS-co-GMA]/graphene), containing different amounts of graphene, were prepared by the solution casting technique. Composites of Poly(acetoxystyrene-co-glycidylmethacrylate) loaded with 2.03 mass%, 5.00 mass%, 7.97 mass%, and 10 mass% graphene. The structure of AOS-GMA systems was characterized by fourier transform infrared, 1H-NMR and scanning electron microscopy. Thermal features were evaluated by the thermogravimetric analysis and differential scanning calorimetry. The aim of this study is to optimize the ε′ (dielectric constant) and ε′′ (dielectric loss factor) of pure polymer and graphene-doped (2.03-5-7.97-10 mass%) P(AOS-co-GMA) composite using response surface methodology. For optimization of the process and creation of the mathematical model, the central composite design package was used. The significance of the process parameters in the model was evaluated by analysis of variance (ANOVA) research. The effects of process parameters, frequency (Hz), voltage (V), and graphene ratio (mass%) on ε′ and ε′′ were examined at ambient temperature. The maximum ε″ value (8.01) was reached at around the 699 Hz frequency and at 11.43 V voltage at the graphene content of 9.82 mass%. The model estimated the maximum value of the ε′′ (0.08) when the frequency was set at 51.20, the voltage was fixed at 1.16 and the graphene content was fixed at 9.97 wt%. The ANOVA results showed that frequency and graphene content were the main model parameters and had a remarkable effect on the dielectric properties. This article presents the development of a new polymeric composite and optimize effect of process parameters, such as frequency (A), voltage (B) and amount of graphene (C).

    AtıfScopus4WoS4OpenAlex4
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2021Scopus SJRQ1
    Influence of partial sodium replacement on proximate composition, physical and sensory quality of marinated anchovy (Engraulis encrasicolus)

    Demirtas Erol, Nida; Erdem, Ömer Alper; Cakli, Sukran; Yavuz, Arzu Burcu

    Several studies are conducted to reduce the salt and various strategies are being developed for this purpose. Consumption of processed meat products is often preferred and salt is used for purposes such as ripening, flavouring, and preservation during their production. Many studies have shown that the excessive salt consumption has negative health effects and so that reducing sodium is important. In this study, the physical and sensory quality of the marinated anchovy produced with potassium salt instead of sodium salt was investigated. Anchovy used in this study was purchased from a local fish market as filleted. Anchovy fillets were transported to the laboratory in ice. Anchovy marinades were produced on the same day. The study consisted of 5 groups and all groups were produced the same day. During the marination acid and salt amounts and pH were monitored. Proximate composition (protein, fat, ash, moisture, sodium, and potassium), physical (colour measurement, cooking loss, texture profile analyses), and sensory (appearance-colour, odour, taste, texture, overall acceptability) quality analyses were performed on day 0. As a result, the best partial sodium replacement was obtained with 50% potassium salt by preserving the physical and sensory quality as in marinates prepared with only 100% sodium salt.

    • SDG 2 · Açlığa Son
    AtıfScopus9WoS9OpenAlex9
    ScopusWeb of Scienceİncele
  • BildiriYalnız künye2022
    Assessment of protective properties of glasses with the application of golmium oxide against Gamma radiation

    Shirmanov, I.A.; Strugov, E.D.; Aladailah, M.W.; Tashlykov, O.L.; Abualsayed, M.I.; Askin, A.

    An assessment of the radiation-protective parameters of glass samples with different ratios of holmium oxide Ho2O3 was carried out using a system of libraries for computer modeling of the processes of passage of elementary particles through the Geant4 substance and the NIST XCOM database. The results of calculations of the mass attenuation coefficient and the half-attenuation layer for the samples under study at the energy of gamma radiation varying from 0.122 to 1.408 MeV are presented.

  • Kitap BölümüYalnız künye2022
    X-Ray Computed Tomography and Magnetic Resonance Imaging Applications of Magnetic Nanoalloys and Nanocomposites

    Aslan, Naim; Koç, Mümin Mehmet

    Metallic nanoparticles were used in different medical and biological applications. Such applications can cover targeted drug delivery, biomarking, MRI imaging, CT imaging, magnetic hyperthermia, etc. Metallic nanoparticles show outstanding properties with high electron affinity and good electrical, electronic, and optoelectronic properties with possible magnetic characteristics. In this regard, magnetic nanoparticles and magnetic nanoalloys are found to be a suitable candidate to be used in imaging applications. In this chapter, concepts of X-ray computed tomography imaging and magnetic resonance imaging are briefly discussed. Magnetic nanoparticles, nanoalloys, and nanocomposites used in imaging, diagnostics, and theranostic applications were illustrated.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus2OpenAlex1
    Scopusİncele