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- MakaleYalnız künye2023Scopus SJRQ2Effect of Using Eccentric Braces with Different Link Lengths on the Seismic Demand of CFST Column-Composite Beam Frames Subjected to Near-Field and Far-Field Earthquakes
Etli, Serkan; Güneyisi, Esra Mete
In recent years, in the light of technological developments, the utilization of composite members that enable the use of superior properties of concrete and steel together in earthquake-resistant building design has become widespread. In this study, 5-, 8-, 10-, 13- and 15-story composite moment-resisting framed buildings were designed using composite beams and concrete filled steel tube columns. The effect of using steel braces and the variation of the link length of the eccentric steel braces on the seismic demand of the composite buildings were investigated. For this, eight different cases with braces were considered and compared with the bare structure. The first case had concentric braces (having no link), and the other seven cases had eccentric steel braces with different link lengths classified as short, medium and long. The nonlinear dynamic response of braced and non-braced composite structures was evaluated under the effect of earthquake groups of far-field, near-field with and without pulse effects. Each earthquake group includes ten different ground motion records. SeismoStruct which is a fiber element-based software was used in modeling and analysis of the structures. Seismic behavior of the case studied structures was investigated comparatively through the demand parameters such as the maximum inter-story drift ratios, the maximum roof drift ratios and the deformation states in the structural elements. It was observed that the inclusion of the steel braces provided significant gains in dissipating seismic energy acting through composite buildings and the beam/column deformations decreased considerably, depending on the length of the link and the height of the structure. In some cases, significant damage was monitored in the link members; however, this type of deformation was limited.
AtıfScopus3WoS3OpenAlex18İncele
- MakaleYalnız künye2025Scopus SJRQ2Impact of green innovation on environmental issues: Findings from BRICS-T countries based on spatial analysis
Han, Ayşegül; Pehlivan, Ceren; Konat, Gökhan; Koncak, Ahmet
This study examines the impact of green innovations on environmental sustainability in BRICS-T countries between 2008 and 2021. Using indicators such as renewable energy consumption, R&D investments, industrial design activities, and carbon emissions, the analysis employs both conventional and spatial panel estimation techniques. The findings reveal that investments in renewable energy play a crucial role in reducing carbon emissions and positively contribute to environmental sustainability. However, the effectiveness of environmental innovation policies and R&D expenditures in mitigating emissions remains limited, particularly in the short term. Additionally, industrial design activities are identified as a significant contributor to rising emissions, highlighting the need for a transition toward more sustainable industrial practices. The study also uncovers spatial dependencies among countries, demonstrating that carbon emissions in one nation can influence those in neighboring countries, emphasizing the necessity of regional cooperation and coordinated environmental policies. Based on these findings, the study provides policy recommendations to enhance the effectiveness of green innovations, stressing the importance of increasing investments in renewable energy, aligning R&D expenditures with environmentally sustainable technologies, and promoting sustainable industrial practices across BRICS-T countries.
AtıfScopus2WoS2OpenAlex3İncele
- MakaleAçık Erişim2024Scopus SJRQ1Mechanical, wear and thermal properties of natural fiber-reinforced epoxy composite: cotton, sisal, coir and wool fibers
Tasgin, Yahya; Demircan, Gokhan; Kandemir, Seckin; Acikgoz, Abuzer
Natural fiber-reinforced epoxy composites (NFRCs) have gained significant attention in recent years due to their potential as environmentally friendly and sustainable materials. These composites combine natural fibers, derived from plants, with epoxy resins to create a material with enhanced properties. The objective of this study is to investigate the mechanical, wear and thermal properties of NFRCs incorporating cotton, sisal, coir and wool fibers. The vacuum-assisted resin transfer molding (VARTM) technique was employed to produce composite plates, followed by conducting tests on tensile, wear and thermal properties. The cotton composite showcased the highest tensile strength, reaching 52.81 MPa, while the coir composite exhibited the lowest, measuring 15.34 MPa. Sisal composite exhibited a moderate wear rate (1.423 mm3/Nm) and a lower coefficient of friction (0.233), implying smoother relative motion. Coir composite presented the highest wear rate (4.615 mm3/Nm), attributed to its coarse fiber nature. Thermal conductivity is highest at cotton composite (1.017 W/mK) and is lowest at coir composite (0.187 W/mK). Additionally, the highest specific heat was observed in the coir composite (26.313 MJ/m3K). Cotton demonstrated potential for efficient heat transfer, while wool outperformed in insulation. Sisal displayed versatility for structural applications. Coir emerged as an effective insulator with energy-saving applications.
AtıfScopus101WoS83OpenAlex102İncele
- MakaleYalnız künye2023Scopus SJRQ2Aluminum Recovery by Acid Leaching of Variously Enriched Pyrophyllite Ore: Effects of Pre-treatment Methods for Activation
Aydoğmuş, Ramazan; Erdemoğlu, Murat; Uysal, Turan
Effects of pre-treatment methods such as calcination for thermal activation and intensive milling for mechanical activation on the aluminum (Al) recovery by acid leaching of preliminarily enriched pyrophyllite ore via attrition scrubbing and froth flotation were investigated. XRD patterns of the calcined and the intensively milled samples were compared to determine the changes during the pre-treatment processes. Hot HCl solution was used for dissolution of aluminum to determine the Al recoveries from variously enriched and variously pre-treated pyrophyllite ore samples. Specific thermal and milling energies consumed per unit amount of ore were calculated, and the ideal activation method was suggested by comparing the activation methods in terms of energy consumption. Mechanical activation of the pyrophyllite concentrate obtained by attrition scrubbing rather than froth flotation was suggested for higher recoveries of aluminum from by acidic leaching. It was determined that operating cost (in terms of energy) of the mechanical activation is lower and aluminum recovery is higher than thermal activation. It was concluded that mechanical activation instead of thermal activation is more economical and environmentally friendly method.
AtıfScopus5WoS4OpenAlex5İncele
- MakaleYalnız künye2024Scopus SJRQ2Deep learning-assisted Hubble parameter analysis
Salti, Mehmet; Kangal, Evrim Ersin; Zengin, Bilgin
We turn our attention on evaluating the most recent Hubble parameter data measured via the differential evolution of cosmic-chronometers from a deep learning perspective. To achieve this goal, we start our investigation by introducing the selected theoretical setup and compiling the most recent statistical data obtained in cosmology experiments. Then we implement a tuned version of the long-short term memory (LSTM) architecture and run it to predict possible values of the Cosmic Hubble parameter for different red-shift states. Since we observe a good correlation between the observed and predicted datasets of the Hubble parameter, we conclude that the machine learning approaches can play important roles in the future cosmology investigations.
AtıfScopus2WoS2OpenAlex2İncele
- BildiriAçık Erişim2025LLM-Based Video Analytics Test Scenario Generation in Smart Cities
Yilmazer, Merve; Karakose, Mehmet
Rapid advances in the field of artificial intelligence have made significant contributions to the automation of software development and testing stages. Software created for use in various fields is tested with test scenarios created manually by software test experts or using test automation. Testing large-scale software with these methods complicates the testing phases because it requires increased human intervention and includes complex applications. In this study, an LLM-based scenario generation framework enhanced with prompt engineering is proposed for testing software to be used for video analysis in smart cities and smart campus areas. Thus, software test scenarios are created by strengthening large language models that are fast, flexible and have high learning ability using prompt engineering techniques. Test scenarios produced through LLM reinforced with prompt engineering techniques were evaluated with rarity and reality metrics and it was determined that more robust scenarios were produced compared to randomly generated test scenarios in the relevant field.
AtıfScopus3OpenAlex3İncele
- MakaleYalnız künye2024Scopus SJRQ1The effect of high entropy oxide on radiation shielding parameters of erbium oxide doped glasses
Kanca, M. Sait; Taşgın, Yahya; Yılmaz, Demet; Pathman, Abdul Fatah; Güler, Ömer
High-entropy materials are one of the most studied topics in recent years due to the extraordinary properties they exhibit. High entropy oxide (HEO) is a group of materials that have been studied for different applications. However, the effects of HEOs on the radiation properties of glasses are not well known. In this study, the structural, radiation and neutron shielding properties of SiO2 glass systems doped erbium oxide reinforced with refractory high entropy oxide (RHEO) with the formula TiMoNbTaWZrO11 were investigated. RHEAs used in the study were produced and characterized in our laboratory. Then, they were added to the glass samples at different rates together with Erbium oxide. As a result of SEM-EDS and XRD analyses, it was determined that the additives were distributed very homogeneously on the glass. The composition of glass systems is [95SiO2+(5-x)Er2O3+x TiMoNbTaWZrO11], where (x = 0, 0.5, 1 and 2 %, mol). The linear and mass attenuation coefficients (LAC and MAC), mean free path (MFP), half-value layer (HVL) and effective atomic numbers (Zeff) and effective electron density (Nel) of the glass structures were experimentally measured at the energy region of 53.16–661.62 keV. Also, the equivalent dose rates due to fast neutrons absorption were measured by using an 241Am–Be fast neutron source. Exposure buildup factor (EBF) and fast neutron removal cross section (ΣR) were theoretically determined. The proton and alpha shielding parameters of glasses were calculated. It is observed that glasses containing higher amounts of refractory high entropy oxide, within the SiO2–Er2O3 composition, demonstrated enhanced capabilities for shielding against radiation and neutrons.
AtıfScopus15WoS15OpenAlex17İncele
- MakaleYalnız künye2025Scopus SJRQ2Green synthesis of environmentally friendly Ag/AgCl nanoparticles for use as solid phase extraction materials
Kurnaz Yetim, Nurdan; Hasanoğlu Özkan, Elvan; Aslan, Naim; Koç, Mümin Mehmet; Nartop, Dilek; Özcan, Cemile
Green synthesis is a prominent procedure used to easily and environmentally friendly fabricate nanostructures and nanoparticles (NPs), without complex instrumentation, intricate procedures, and harmful chemicals. This study investigated the green synthesis of silver NPs (AgNPs), with Aronia melanocarpa fruit extract as the reducing agent. Following synthesis optimization, AgNPs were characterized using a range of analytical techniques, including UV–Vis, XRD, SEM-EDX, BET, and TEM analyses. Based on the characterization results, an Ag/AgCl hybrid structure was formed. The Ag/AgCl NPs obtained were utilized as adsorbents to remove Cd(II) and Pb(II) heavy metals. The experimental factors that were optimized included pH (5.5), sample volume (5 mL), eluent type and concentration (2 M HNO3), adsorbent amount (5 mg), and extraction time (30 min). Under optimized conditions, the limits of detection were determined to be 9.6 and 4.8 µg/L for Pb(II) and Cd(II), respectively. These limits were established within a concentration range of 50–3,000 µg/L.
AtıfScopus3WoS3OpenAlex3İncele
- MakaleAçık Erişim2023Scopus SJRQ3Optimization of shape factor by the response surface method, and the effect on sphalerite flotation recovery
Uysal, T.
Various morphological parameters that affect the flotation recovery of sphalerite were modelled and optimized using the response surface method (RSM). The effects of roughness value, shape factor, and collector concentration were investigated using the central composite full design method. The results were evaluated by analysis of variance. The optimum roughening time was found to be 25 minutes, the optimum roughness value was 2.9071 μm, and the optimum collector concentration was 0.001 M. Using these values, a flotation recovery of 98.01% was obtained. Similarly, in shape factor studies, the optimum grinding time was 15 seconds, the optimum roundness value 0.7421, and the optimum collector concentration 0.0009 M, which resulted in a flotation recovery of 94.30%. The average error between the optimization results and the experimental results was estimated to be less than 6%, and the R2 values were greater than 90%. The study shows that RSM can be effectively applied in finding the economic optimum condition for obtaining maximum flotation recovery with minimum reagent consumption.
AtıfScopus2WoS2OpenAlex2İncele
- MakaleYalnız künye2023Scopus SJRQ2A New S-box Generator Algorithm Based on 3D Chaotic Maps and Whale Optimization Algorithm
Artuğer, Fırat
Encryption provides security in cases such as storing confidential information or transmitting it over a network. Today, block cipher algorithms are generally used for encryption. Undoubtedly, one of the most important units of block cipher algorithms to ensure confidentiality is substitution box (s-box) structures. Because s-boxes are nonlinear structures, making the algorithm resistant to differential cryptanalysis. Therefore, the higher the nonlinearity value of the s-box, the stronger it will be. In this study, a new algorithm is proposed to generate s-boxes with high nonlinearity value. In the proposed algorithm, Lorenz and Chua systems, which are 3D chaotic maps, are used for the initial population. The s-boxes produced with these chaotic maps were then increased to 110.5 using the whale optimization algorithm (WOA). WOA is one of the important optimization algorithms developed in recent years and was used for the first time in s-box production in this study. Looking at the results of the analysis, the proposed method has outstripped most of the other existing studies, thanks to effective 3D chaotic maps and WOA.
AtıfScopus44WoS38OpenAlex45İncele
- Derleme MakaleYalnız künye2025Scopus SJRQ2Is sexual function impaired in patients with primary headaches? A systematic review of observational studies
Ataş, Kübra; Kaya Mutlu, Ebru
Introduction: Primary headaches, particularly migraine and tension-type headaches, as chronic and painful conditions, have a significant impact on individuals' health and overall quality of life, including aspects such as sexual health parameters. Objectives: The aim of this study was to review observational studies and to summarize the presence of sexual dysfunction in patients with primary headache and to discern whether it is more common in patients with primary headache than in healthy control subjects. Methods: Observational studies published between January 1, 2000, and May 21, 2023 were searched in Medline (PubMed), Web of Science, Scopus, and EBSCO. This review included 23 observational studies that evaluated sexual dysfunction with or without comparison with healthy control subjects. Results: As a result, the mean Female Sexual Function Index score, a score of <26.55 indicating sexual dysfunction, ranged from 19.25 ± 8.18 to 27.5 ± 7.5 in patients with primary headache. The prevalence of sexual dysfunction and erectile dysfunction was found to be between 10.7% and 93.75% in female patients and between 54.83% and 80% in male patients. Both migraineurs and tension-type headache sufferers had statistically significantly lower sexual function scores in females and lower erectile function scores in males compared with healthy control subjects. Conclusion: Sexual function is significantly affected in patients with primary headache, which is a chronic painful disorder. Therefore, it is very important to ask these patients about their sexual health and, if necessary, to seek support from a sexual health professional. Additionally, future studies may prioritize tension-type headaches and male patients due to the limited amount of research available on these subjects.
AtıfScopus1WoS1OpenAlex1İncele
- MakaleAçık Erişim2023Scopus SJRQ1Numerical simulation for peristalsis of Quemada fluid: A dynamic mesh approach
Ali, Shahbaz; Nadeem, Sohail; Akkurt, Nevzat; Ali Ghazwani, Hassan; Eldin, Sayed M.
Introduction: Flow dynamics due to the peristaltic pumping has been the topic of great interest for the researchers. But numerical and analytical analyses for the peristaltic motion are limited where flow domain is deformed real-time. Research on peristalsis has a limitation where theoretical aspects of walls motion are considered, neglecting the real time deformation of the walls. Objectives: This paper aims to propose a more reliable and accurate numerical methodology for peristaltic motions to address the above-mentioned challenge. Stream traces, velocities, and pressure drops along the tube is to be visualized more accurately. Methods: In present study a finite volume based dynamic mesh motion method is adopted to analyze the peristaltic motion of a non-Newtonian Quemada fluid in an axisymmetric channel. The walls and interior domain of the channel is dynamically deformed for a sinusoidal wave traveling on boundary. Results: Simulation of unsteady flow behavior for time t=0s to 2s and amplitude ratio Φ=0.2,0.4,and0.6. predicts fluid trapping phenomenon. Rotation of fluid particles is more prominent for higher amplitude ratios. Pressure gradient increases with increasing amplitude ratios. Conclusion: A novel dynamic mesh method is proposed for peristaltic pumping. It provides more accurate and more physical results for stream traces; pressure drops and velocities along the tube. A limited case of the study validates the theoretical and analytical results already presented in literature; hence the method is reliable.
AtıfScopus10OpenAlex12İncele
- MakaleAçık Erişim2023Scopus SJRQ1Evaluation of pea/rice and amylopectin/chromium as an alternative protein source to improve muscle protein synthesis in rats
Ozdemir, Oguzhan; Erten, Fusun; Er, Besir; Orhan, Cemal; Komorowski, James R.; Sylla, Sarah; Perez Ojalvo, Sara; Sahin, Kazim
Background: A preclinical study reported that the combination of an amylopectin/chromium complex (ACr) of branched-chain amino acids (BCAA) significantly enhanced muscle protein synthesis (MPS). This study was conducted to determine the effects of the addition of ACr complex to a pea/rice (PR) protein on MPS, insulin, muslin levels, and the mTOR pathway in exercised rats. Methods: Twenty-four rats were divided into three groups: (i) exercise (Ex); (ii) Ex + PR 1:1 blend (0.465 g/kg BW); (iii) Ex + PR + ACr (0.155 g/kg BW). On the day of single-dose administration, after the animals were exercised at 26/m/min for 2 h, the supplement was given by oral gavage. The rats were injected with a bolus dose (250 mg/kg BW, 25 g/L) of deuterium-labeled phenylalanine to determine the protein fractional synthesis rate (FSR) one h after consuming the study product. Results: The combination of PR and ACr enhanced MPS by 42.55% compared to the Ex group, while Ex + PR alone increased MPS by 30.2% over the Ex group (p < 0.0001) in exercised rats. Ex + PR plus ACr significantly enhanced phosphorylation of mTOR and S6K1 (p < 0.0001), and 4E-BP1 (p < 0.001) compared to the Ex (p < 0.0001). PR to ACr also significantly increased insulin and musclin levels (p < 0.0001) in exercised rats. Additionally, compared to Ex + PR alone, Ex + PR + ACr enhanced mTOR (p < 0.0001) and S6K1 (p < 0.0001) levels. Conclusion: These data suggested that PR + ACr may provide an alternative to animal proteins for remodeling and repairing muscle by stimulating MPS and mTOR signaling pathways in post-exercised rats. More preclinical and clinical human studies on combining pea/rice and amylopectin/chromium complex are required.
AtıfScopus4OpenAlex4İncele
- MakaleYalnız künye2024Scopus SJRQ1Nutrification and fat reduction of deep-fried protein isolates
Erol, Nida Demirtas; Cakli, Sukran; Szymczak, Mariusz; Shen, Cangliang; Matak, Kristen E.; Jaczynski, Jacek
Deep-fried (DF) foods are considered nutritionally-inferior due to increased fat content, although they are popular with consumers due to desirable sensory characteristics. This study attempted to reduce fat of DF surimi, DF fish-protein-isolate (FPI), and DF chicken-protein-isolate (CPI) by pre-baking or pre-roasting. Surimi, FPI, and CPI were also nutrified with ω-3-rich oil, fiber, and KCl-based salt substitute. Pre-baking decreased (p < 0.05) fat content, while pre-roasting increased (p < 0.05) it. Pre-baking resulted in less (p < 0.05) changes to cook loss, moisture loss, expressible moisture, water-holding-capacity, whiteness, and texture when compared to pre-roasting. Pre-baking also better maintained ω-3 PUFAs concentration than pre-roasting, resulting in higher (p < 0.05) concentration of α-linolenic (ALA, 18:3ω3), eicosapentaenoic (EPA, 20:5ω3), and docosahexaenoic (DHA, 22:6ω3) FAs as well as unsaturated FAs and total ω-3 FAs in DF surimi, DF FPI, and DF CPI. Pre-baking in combination with nutrification using ω-3 PUFAs improved nutritional value of DF foods, while causing minimal quality changes.
AtıfScopus3WoS3OpenAlex3İncele
- BildiriYalnız künye2024Exploring Triboelectric Properties in Sputtered Si(100)/SiO2/Cr/ZnO Thin Films - Ag/FEP Using Contact Speration Technique for Renewable Energy Harvesting
Yüzüak, Gizem Durak
Currently, there is an ongoing inquiry into triboelectric nanogenerators (TENG), which use the triboelectric phenomenon to capture electrical energy from mechanical vibrations. The work aims to figure out the magnetron sputtered Cr/ZnO-based films on SiO2/Si(100) substrates with the construction of a Cr/ZnO-Ag/FEP tribo-based nanogenerator (TENG) and a specific emphasis on measuring TENG properties. The structural investigation of these films was conducted using X-ray diffraction (XRD) photoluminescence (PL), attenuated total reflectance fourier-transform infrared spectroscopy (AT-FTIR), and current - voltage (I-V) analysis in contact-separation mode (CSM). The Cr/ZnO-Ag/FEP TENG has a notable instantaneous maximum output voltage of around 63 V and a current density of 7 μA/cm2 when compared to other nanogenerators based on semiconductors, as determined by a comparative analysis. The results of this study provide useful information on the possible application of optimized magnetron sputtered Cr/ZnO-based films in triboelectric and energy harvesting systems, which might contribute to the progress of sustainable and renewable energy technologies.
- MakaleAçık Erişim2024Scopus SJRQ2Effects of Ga, Nb, V, Zr, and Cr on the crystal structures and thermal behavior of CuAlMn shape memory alloys
Özkul, İskender; Karaduman, Oktay; Canbay, Canan Aksu
CuAlMn alloys are cheaper and more promising alloy types compared to NiTi alloys. In this study, based on CuAlMn shape memory alloy, thermodynamic and structural characteristics of some new alloys containing four elements were investigated in detail. In this study, five new quaternary shape memory alloys, each containing a CuAlMn base alloy and a different fourth additive element (Ga, Nb, V, Zr, and Cr), were produced. The properties of the obtained alloys were characterized using a series of analysis methods such as X-ray diffraction (XRD), optical microscopy, differential scanning calorimetry (DSC), and differential thermal analysis (DTA). The results showed the effects of different elements on the crystal structures of the alloys and how different elements could change the thermal behavior of the alloys.
AtıfScopus4WoS3OpenAlex6İncele
- BildiriYalnız künye2025Scopus SJRQ4A Hybrid Machine Learning Architecture for Acoustic Fault Diagnosis in Electric Motors: Offline and Online Modes via Mobile Phone
Yordanov, Nikolay; Zhilevski, Marin; Mikhov, Mikho; Ertargin, Merve
This paper proposes a hybrid ML architecture for non-invasive acoustic fault diagnosis in electric motors and machines using a.NET MAUI cross-platform mobile app for short audio capture (5-20s), audio-to-image transformations and dual-mode inference: embedded ML.NET/ONNX models for offline preliminary detection and Azure ML-hosted deep CNN/RNN for online probabilistic multi-fault analysis. The primary objective of this paper is to demonstrate the benefits of the proposed architecture and to show the specific tools which can be used for implementation. Architectures (embedded, cloud, hybrid) are evaluated by listing main advantages and disadvantage, highlighting hybrid approach that combines offline resilience, reduced latency and keeping the possibility for complex analysis by using online hosted model. Sample mobile application design is added to showcase the proposed user experience.
- MakaleAçık Erişim2023Determination of Rutting Resistance of SBS and Warm Asphalt Additive Binders by the MSCR Test
Akpolat, Mustafa
The MasterLife PAV110 Warm Mix Asphalt (WMA) additive’s rutting resistance in pure and Styrene-Butadiene-Styrene (SBS)-modified binders was examined using MSCR testing. Multiple Stress Creep Recovery (MSCR) tests were conducted on seven binders. The study’s findings indicated that the incorporation of WMA resulted in an increase in the Jnr values of both pure binders and binders modified with SBS at stress levels of 0.1 and 3.2 kPa. This finding implies that the occurrence of rutting will be negatively impacted. On the other hand, the performance level categorization showed that WMA additives had no impact on the performance levels of pure and SBS-modified binders. Since the Jnr and average percentage Recovery (R) values at 3.2 kPa, 1%, and 1.5% PAV110 additives exhibited similar properties, it was determined that the optimum usage rate in terms of cost was 1%.
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- MakaleAçık Erişim2024Scopus SJRQ2Is Cladophora fracta an efficient tool of accumulating critical raw materials from wastewater and there a potential health risk of use of algae as organic fertilizer?
Arslan Topal, E. Işıl; Öbek, Erdal; Topal, Murat
In this study investigation of accumulations of critical raw materials (cobalt (Co), antimony (Sb), vanadium (V), lanthanum (La) and tungsten (W)) from wastewater by using C. fracta were aimed. Besides, assessment of the potential health risks in terms of the use of organic fertilizer obtained from the macroalga to be harvested from the treatment were also aimed. Highest Co, Sb, V, La and W accumulations by algae in reactor were 125±6.2%, 201.25±10%, 318.18±15%, 357.97±18%, and 500±25%, respectively. When compared with control, Co, Sb, V, La and W in algae increased 2.25, 3.01, 4.18, 4.58, and 6 times, respectively. The algae was very high bioaccumulative for Co and La. Highest MPI was calculated as 3.94. Non-carcinogenic risk of CRMs according to different exposure types (ingestion, inhalation, and dermal) were calculated for man, woman and child. There is not any non-carcinogenic risk from the investigated exposure ways of algae as organic fertilizer.
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- MakaleYalnız künye2024Scopus SJRQ2Synthesis and characterization of TiNbZrMo medium-entropy bio-composites: Microstructure, mechanical properties, and in vitro degradation
Say, Yakup
This study reports the synthesis and characterization of hydroxyapatite (HA)-based bio-composites reinforced with varying amounts (by weight, 1–15 wt.%) of bio-medium entropy alloy (BioMEA) for load-bearing implant applications. BioMEA powders consisting of Ti, Nb, Zr, and Mo were mechanically alloyed for 100 h and subsequently added to HA using powder metallurgy techniques. To show the effect of BioMEA, the microstructure, density, and mechanical tests have been conducted and the synthesized BioMEA was characterized by scanning electron microscope (SEM), x-ray diffractometer (XRD), and Fourier-transform infrared spectroscopy (FTIR) analysis. In addition, in vitro degradation behavior and bioactivity analyses of bio-composites have been conducted. XRD analysis revealed the formation of BioMEA after 20 h of mechanical alloying. The highest density value of 2.47 g/cm3 was found in 15 wt.% BioMEA-reinforced bio-composite. The addition of BioMEA reinforcement led to a significant increase in hardness and tensile strength values, with the highest values observed at 15 wt.% reinforcement. Compression tests demonstrated a significant increase in compressive strength and deformation capability of the bio-composites with the highest values observed at 15 wt.% BioMEA addition. The highest toughness of 7.68 kJ/m2 was measured in 10 wt.% MEA-reinforced bio-composites. The produced bio-composite materials have an elastic modulus between 3.5–5.5 GPa, which may provide a solution to the stress shielding problems caused by the high elastic modulus of metallic implant materials. The most severe degradation occurred in 15 wt.% MEA-reinforced bio-composites, and the effect of degradation caused a decrease in Ca and an increase in Ti-Ni-Zr-Mo in all bio-composites. These findings suggest that HA/BioMEA bio-composites have the potential to be developed as advanced biomaterials with moderate mechanical and biological properties for load-bearing implant applications.
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