Sürdürülebilir Kalkınma Amaçları

Yazarlar

  • MakaleAçık Erişim2023Scopus SJRQ1
    Yield and Composition of the Essential Oil of the Opopanax Genus in Turkey

    Babacan, Ebru Yüce; Demirpolat, Azize; Çakılcıoğlu, Uğur; Bagcı, Eyüp

    The genus Opopanax W. Koch (Apiaceae) is represented by four species in Turkey. The composition of the essential oil of Opopanax genus members (Apiaceae) growing in Turkey was investigated in this study. GC-MS was used to analyze the composition of Opopanax essential oil samples that were taken from their natural environments. The Clevenger apparatus was used to hydrodistill the plant’s aerial parts, and the yields were determined to be between 0.2% v/w (for O. siifolius) and 0.4% (for O. hispidus, O. chironium, and O. persicus). The results and the chemical data provided some information and clues on the chemotaxonomy of the genus Opopanax. In this study, γ-elemene, butanoic acid octyl ester, and cylopropane were the main compounds identified in the essential oils of O. chironium, O. hispidus, and O. persicus. In particular, hexynyl n-valerate was most abundant in the essential oil of O. chironium, cyclopropane in that of O. hispidus, γ-elemene in that of O. persicus, and n-hexadecanoic acid/palmitic acid in that of O. siifolius. In a chemotaxonomic approach, the essential oil analysis of the Opopanax species revealed that these species conformed in a cluster analysis with their morphological classification. The constituents of the essential oils of all examined in the genus Opopanax were determined in this study, which is the most thorough one to date. This study provides new information about the composition of the essential oils of the investigated species.

    AtıfScopus4WoS4
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  • MakaleYalnız künye2023Scopus SJRQ1
    Modeling the form, distribution and paleoclimatic implications of former glaciers in the Teke Peninsula (Eastern Mediterranean, Turkey)

    Keserci, Ferhat; Bayrakdar, Cihan; Çılğın, Zeynel; Evans, Ian S.

    The Western Taurus Mountains on the Teke Peninsula, Southwestern Turkey, saw substantial glaciation in the late Quaternary period. Accurate reconstructions of former glacier extent in this relatively marginal area of glaciation are important for establishing the paleoclimate in the Eastern Mediterranean Basin. From west to east, the mountains of Sandıras, Karadağ, Akdağ (Kaş), and Beydağları preserve clear evidence of cirques and moraines, representing glacial valley land systems. This study used calculation tools for Glacier Reconstruction, (GlaRe) and Equilibrium Line Altitude (ELA), with glacier outlines based on the geomorphological evidence and Digital Elevation Models (DEMs), to determine the distribution and ELAs of former glaciers and to estimate paleotemperature and paleo-precipitation during the maximum ice extent. The results are analyzed at three scales: for each glacier, between glaciers and between mountain ranges. While the glaciation was at its peak, we estimate that glaciers covered a total area of 26.4 km2 (1.28 ± 0.08 km2 on Sandıras Mountain, 3.86 ± 0.23 km2 on Karadağ, 16.17 ± 0.970 km2 on Akdağ (Kaş), and 5.09 ± 0.30 km2 in Beydağları): the longest glacier was in Akdağ (Kaş) with a length of 5787 m. Average paleo-ELA (pELA) was calculated as 2077 m a.s.l in Sandıras, 2097 m a.s.l in Karadağ, 2565 m a.s.l in Akdağ (Kaş), and 2468 m a.s.l in Beydağları. Glacier modeling estimated that the maximum ice thickness in Akdağ was 240 m ± 14, and the average thickness 75 ± 4 m. Among these mountains, Karadağ had the lowest elevation to which glaciers descended (1760 ± 16 m a.s.l). Topographic analyses revealed that glaciers formed in the four mountains mostly in the North-facing localities with highest slope values of 18 to 30°. During the maximum glaciation period air temperature depression has been estimated as 8 to 9° Celsius; That required a precipitation increase of some 40 to 60 % compared to present, to produce the former glaciers mapped in the Teke Peninsula.

    • SDG 13 · İklim Eylemi
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  • MakaleYalnız künye2023Scopus SJRQ1
    A novel two-phase group decision-making model for circular supplier selection under picture fuzzy environment

    Kaya, Sema Kayapinar

    Circular supply chain management (CSCM), which incorporates circular thinking into supply chain management, promotes supply chain sustainability by offering a novel and compelling viewpoint. In the CSCM, supplier selection is crucial in establishing a competitive edge among businesses by decreasing environmental degradation and related supply chain expenses. This paper aims to propose a novel two-phase group decision-making approach, which combines the picture fuzzy Analytical Hierarchical Process (PF-AHP) and grey Measurement of Alternatives and Ranking According to Compromise Solution (MARCOS-G) model to select railway material suppliers within the scope of circular economy perspective. In group decision-making, a picture fuzzy number-based approach aggregates individual decision makers’(DMs) opinions and provides a lower level of computing complexity and a higher level of performance. The PF-AHP has been used to produce the weights of the criteria, and the MARCOS-G technique has been used to rank the suppliers and choose the most appropriate one. The results and verification of the novel method are carried out throughout a comprehensive sensitivity analysis. For this purpose, 50 scenarios with changes in the weight values of criteria were developed. In the validation analysis, a comparison with other grey COPRAS, TOPSIS, ARAS and WASPAS methods were performed. Due to the ranking results obtained from Spearman’s correlation analyses, the MARCOS-G is almost consistent and it can be seen that the A4 remains the top supplier in all 50 scenarios.

    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus34WoS30OpenAlex39
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  • MakaleYayıncıda açık erişim2023Scopus SJRQ1
    Geochemical and radiometric data for mafic rocks from the Guleman Ophiolite (SE, Turkey): New insights on the geodynamic evolution of the southern Neo-Tethyan ocean

    Sapancı, Özgür; Tokat, Gürkan; Eraslan, Nuh Kadri; Karakaya, Abdullah Onur; Gücer, Mehmet Ali; Çimen, Okay

    The Guleman Ophiolite is located in the southeast of Turkey and mainly consists of harzburgites and dunites hosting economically viable chromitite bodies, and lesser amounts of cumulate and isotropic gabbro, diabase dykes, pyroxenite and locally plagiogranite. This study reports the combined whole-rock geochemical and radiogenic isotope (Sr and Nd) data for gabbro and diabase dykes, and in-situ zircon U-Pb geochronological data for plagiogranite and gabbro from the Guleman Ophiolite. Two different geochemical groups were determined based on immobile minor and trace elements, and radiogenic isotope characteristics of gabbro and diabase dykes investigated here. The first group is represented by boninites and displays highly depleted elemental patterns compared to NMORB, and spoon-shaped rare earth element profiles. Contrarily, the second group resembles back-arc basin basalts and is characterized by NMORB-like rare earth element patterns associated with negative Nb anomalies. The boninitic samples are characterized by less radiogenic 143Nd/144Nd(i) (0.51229 to 0.51267; ƐNd = −4.8 to +2.7) and more radiogenic 87Sr/86Sr(i) (0.70549 to 0.70758) isotope compositions compared to the back-arc basin basalt-like samples (143Nd/144Nd(i) = 0.51289 to 0.51296; ƐNd = +7.0 to +8.4; 87Sr/86Sr(i) = 0.70496 to 0.70629), indicating derivation from distinct and/or heterogeneous mantle source regions within a supra-subduction zone. The LA–ICP–MS zircon U-Pb analyses yielded concordant late Cretaceous ages for gabbro (82 ± 2.9 Ma) and plagiogranite (79.9 ± 0.8 Ma) samples. The overall geochemical, isotopic and geochronological data presented here suggest that the Guleman Ophiolite consists of forearc and initial back-arc spreading sections of oceanic crust, which may have been formed in an intra-oceanic subduction zone within the Berit Ocean (northern branch of the southern Neo-Tethyan ocean). Moreover, the generation of continental arc magmatism (i.e. Baskil and Esence Granitoids) was well-documented on the active margin of the Malatya-Keban Metamorphics to the north. Therefore the closure of this oceanic basin should have resulted in multiple coeval northward subduction events during the late Cretaceous.

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  • MakaleYalnız künye2023Scopus SJRQ2
    Chemical Characterization of Different Extracts from Artemisia annua and Their Antioxidant, Enzyme Inhibitory and Anti-Inflammatory Properties

    Acquaviva, Alessandra; Nilofar; Bouyahya, Abdelhakim; Zengin, Gokhan; Di Simone, Simonetta Cristina; Recinella, Lucia; Leone, Sheila; Brunetti, Luigi; Uba, Abdullahi Ibrahim; Cakilcioğlu, Ugur

    Artemisia annua L. (Asteraceae Family) is an important plant in Asia that has been used for treating different diseases, including fever due to malaria, wounds, tubercolisis, scabues, pain, convulsions, diabetes, and inflammation. In this study we aimed to evaluate the effects of different polarity extracts (hexane, dichloromethane, ethyl acetate, ethanol, ethanol/water (70 %) and water) from A. annua against the burden of inflammation and oxidative stress occurring in colon tissue exposed to LPS. In parallel, chemical composition, antiradical, and enzyme inhibition effects against α-amylase, α-glucosidase, tyrosinase, and cholinesterases were evaluated. The water extract contained the highest content of the total phenolic with 34.59 mg gallic acid equivalent (GAE)/g extract, while the hexane had the highest content of the total flavonoid (20.06 mg rutin equivalent (RE)/g extract). In antioxidant assays, the polar extracts (ethanol, ethanol/water and water) exhibited stronger radical scavenging and reducing power abilities when compared to non-polar extracts. The hexane extract showed the best AChE, tyrosinase and glucosidase inhibitory effects. All extracts revealed effective anti-inflammatory agents, as demonstrated by the blunting effects on COX-2 and TNFα gene expression. These effects seemed to be not related to the only phenolic content. However, it is worthy of interest to highlight how the higher potency against LPS-induced gene expression was shown by the water extract; thus suggesting a potential phytotherapy application in the management of clinical symptoms related to inflammatory colon diseases, although future in vivo studies are needed to confirm such in vitro and ex vivo observations.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus45OpenAlex43
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  • MakaleAçık Erişim2023Scopus SJRQ1
    Numerical analysis of heat transfer and fluid flow in microchannel heat sinks for thermal management

    Singupuram, Raghav; Alam, Tabish; Ali, Masood Ashraf; Shaik, Saboor; Gupta, Naveen Kumar; Akkurt, Nevzat; Kumar, Mukesh; Eldin, Sayed M.; Dobrotă, Dan

    Electronic components used in a variety of applications, such as electronic devices, computers, automobiles, medical equipment, telecommunications, etc., can be effectively cooled using microchannel heat sinks (MHS). In this paper, a novel design of an MHS is presented, which can manage the heat load (dissipate the excess heat) and maintain the temperature of the MHS in the safe range. The passage of the MHS was modified with circular extruding ribs on the side wall of the passage. This technique in MHS was inspired by the study of heat transfer enhancement in heat exchangers. The effects of the sector angle of the circular protruding ribs ranging from 45° to 80° were studied in laminar flow (Re = 100–900). It was found that the maximum Nusselt number in the range of 7.26–64.11 was observed at sector angles of circular protrusion ribs of 80°. Also, the values of thermohydraulic performance parameter (THPP) are greater than one, which shows that the application of the proposed design for thermal management of MHS is reasonable and effective.

    AtıfScopus41OpenAlex43
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  • MakaleAçık Erişim2023
    A new approach based on convolutional neural network and feature selection for recognizing vehicle types

    Doğan, Gürkan; Ergen, Burhan

    The number of vehicles used in traffic life has reached enormous dimensions today. The increase in the number of vehicles day by day causes some traffic problems along with it; such as traffic congestion, accidents, pollution, and safety. To overcome all these problems, convolutional neural networks (CNN) methods are one of the trend methods used in recent years due to their success. In this study, a new approach is proposed to use this power of CNN in low-power devices. First of all, MobileNetv1, MobileNetv2, and NASNetMobile models were optimized to increase accuracy performance. Then, an approach is proposed in which these optimized mobile CNN approaches are used only as feature extractors, and methods such as combining, selecting, and classifying the obtained features are used together. As a result of the classification made with this approach, the classification accuracy has increased by approximately 5%.

    • SDG 9 · Sanayi, Yenilikçilik ve Altyapı
    AtıfScopus10OpenAlex12
    Scopusİncele
  • MakaleAçık Erişim2023Scopus SJRQ1
    Body appreciation around the world: Measurement invariance of the Body Appreciation Scale-2 (BAS-2) across 65 nations, 40 languages, gender identities, and age

    Swami, Viren; Tran, Ulrich S.; Stieger, Stefan; Aavik, Toivo; Ranjbar, Hamed Abdollahpour; Adebayo, Sulaiman Olanrewaju; Afhami, Reza; Ahmed, Oli; Aimé, Annie; Akel, Marwan

    The Body Appreciation Scale-2 (BAS-2) is a widely used measure of a core facet of the positive body image construct. However, extant research concerning measurement invariance of the BAS-2 across a large number of nations remains limited. Here, we utilised the Body Image in Nature (BINS) dataset – with data collected between 2020 and 2022 – to assess measurement invariance of the BAS-2 across 65 nations, 40 languages, gender identities, and age groups. Multi-group confirmatory factor analysis indicated that full scalar invariance was upheld across all nations, languages, gender identities, and age groups, suggesting that the unidimensional BAS-2 model has widespread applicability. There were large differences across nations and languages in latent body appreciation, while differences across gender identities and age groups were negligible-to-small. Additionally, greater body appreciation was significantly associated with higher life satisfaction, being single (versus being married or in a committed relationship), and greater rurality (versus urbanicity). Across a subset of nations where nation-level data were available, greater body appreciation was also significantly associated with greater cultural distance from the United States and greater relative income inequality. These findings suggest that the BAS-2 likely captures a near-universal conceptualisation of the body appreciation construct, which should facilitate further cross-cultural research.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    • SDG 10 · Eşitsizliklerin Azaltılması
    AtıfScopus108OpenAlex109
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  • MakaleAçık Erişim2023Scopus SJRQ2
    Silver and Copper Coating Effects on Surface Morphology, Crystal Structure and Corrosion Behavior of NiTinol Shape Memory Alloy Plate

    Say, Yakup; Kanca, Muhammed Sait; Kök, Mediha

    NiTinol alloy has recently been in high demand in biomaterials applications due to its excellent superelasticity and shape memory properties. This demand has increased the studies on improving the negative properties of the NiTinol alloy, even if it is less. In this study, it was aimed to coat the nickel element in the NiTi alloy with biocompatible elements in order to prevent it from secreting its toxic effect after its implantation into the body. In accordance with this purpose, NiTi shape memory alloys were coated with silver and copper element by using thermal evaporation system, and the surface morphology of the alloys after coating was investigated by SEM–EDX (Scanning Electron microscope), and AFM (Atomic force Microscope). After the measurements, it was observed that the coating was successful and homogeneously distributed on the entire surface of the alloy. In addition, an important and positive result was that, the roughness value of the NiTi alloy was decreased with the coating. The change in the crystal structure of the uncoated and coated NiTi alloy was evaluated using an X-ray device, and it was observed that the silver and copper element peaks were formed along with the B2 phase, which is the main phase of the NiTi alloy. In order to examine the effect of coating on the biocompatibility of NiTi alloy, electrochemical test was performed by rapid measurement method in simulated body fluid and corrosion behavior was investigated. According to these experiments, it was concluded that silver plating is more successful in term of biocompatibility than copper coating.

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  • MakaleYalnız künye2023Scopus SJRQ1
    A holistic failure modes and effects analysis for university plastic injection laboratory under Bayesian Network

    Yucesan, Melih; Gul, Muhammet; Pamučar, Dragan

    University Research & Development (R&D) laboratories are facilities used for research and manufacturing activities in engineering and basic science fields. Various filling materials are used in plastic R&D laboratories to improve the mechanical properties of thermoplastics or to recycle waste materials. The use of filling materials causes changes in plastic production parameters. This study dealt with the risks arising from extrusion, injection and shredder in a plastic injection laboratory, which led to the inability to manufacture the appropriate product under a holistic methodology. The proposed holistic methodology merges the concepts of failure mode and effects analysis (FMEA), fuzzy best-worst method (FBWM), and a rule-based three-hierarchical Bayesian network (RB-THBN). First, 15 root risks have been identified under a three-stage hierarchy with the support of laboratory decision makers. Then, questionnaires were created using the FMEA concept. The importance values (degree of belief-DoB) of three different FMEA parameters (severity, occurrence and detection) by experts for each risk have been calculated with FBWM. And finally, the RB-THBN has been created, and the final risk values have been computed using the linear utility function for the network. The system has been analyzed via a Bayesian modeling software. A validity test and a control measures planning has also been executed. According to the results, the highest root risk has been determined as “E2-The prepared mixture is not homogeneous” with a crisp risk score of 0.639559. In addition, “Failure due to extrusion” has been determined as the highest risk category with a score of 0.564059. It was discussed in detail that these risks arise from homogenization and how the used mixture should be homogenized. A comparative study among traditional FMEA, FMEA extended under FBWM and the proposed approach is performed to observe the differences in final ranking of root risks and to highlight the arguments that strengthen the advantages of the proposed method over the other two.

    • SDG 9 · Sanayi, Yenilikçilik ve Altyapı
    AtıfScopus7WoS7OpenAlex8
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  • Kitap BölümüYalnız künye2023
    The degrowth movement in France: From the edges to the centre of the ecological debate

    Karakaş, Tahir; Orofino, E; Allchorn, W

    • SDG 16 · Barış, Adalet ve Güçlü Kurumlar
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  • MakaleYalnız künye2023Scopus SJRQ3
    EFFECT OF CRYOPROTECTANT AND PRE-FREEZING ON THE SPERM MOTILITY, VIABILITY AND FERTILITY OF GOLDFISH Carassius auratus (PISCES: CYPRINIDAE) POST SHORT-TERM CRYOPRESERVATION

    Nurlaili, Nurlaili; Eriani, Kartini; Salma, Itsnatani; Maulida, Siti; Rahayu, Sri Riska; Handayani, Luvi Syafrida; Kocabas, Filiz Kutluyer; Siti-Azizah, Mohd Nor; Wilkes, Martin; Muchlisin, Zainal Abidin

    BACKGRUND: Goldfish Carassius auratus is a popular ornamental fish extensively cultured worldwide. Sperm cryopreservation is a common fish breeding method that ensures sperm availability around the year. Studies on cryopreservation of goldfish sperm, especially on the suitability of cryoprotectant types and pre-freezing time, are scarcely available. OBJECTIVE: To determine the most suitable type of cryoprotectant and pre-freezing for the successful cryopreservation of goldfish sperm. MATERIALS AND METHODS: A completely randomized design with two factors was utilized in this study. The first factor is the type of cryoprotectants, which included methanol, ethanol, ethylene glycol, glycerol, and DMSO. The second is pre-freezing times of 10, 20, 30, and 40 min at each of the pre-freezing temperatures of 4 0C, -10 0C, and -79 0C, meaning that the total times for the ramping down of temperature were 30, 60, 90 and 120 min, respectively. The Ringer solution and 10% egg yolk were used as extender and extracellular cryoprotectant. The sperm was stored at -179 0C for 7 days. RESULTS: The ANOVA test showed that cryoprotectants and pre-freezing significantly affected the motility, viability, and fertility of goldfish sperm after freezing in liquid nitrogen for 7 days (P<0.05). Furthermore, 10% DMSO combined with 15% egg yolk with an pre-freezing time of 20 min can maintain sperm motility, viability, and fertility higher than other treatments, by 79%, 80%, and 33%, respectively. The agarose gel electrophoresis showed no DNA fragmentation in all samples, including fresh sperm. CONCLUSION: We conclude that 10% DMSO combined with 15% egg yolk and 20 min pre-freezing is the best treatment for goldfish sperm cryopreservation.

    AtıfScopus6WoS5OpenAlex5
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  • MakaleAçık Erişim2023Scopus SJRQ1
    The effect of oral administration of undenatured type II collagen on monosodium iodoacetate-induced osteoarthritis in young and old rats

    Sahin, Emre; Orhan, Cemal; Erten, Fusun; Saiyed, Zainulabedin; Azari, Elnaz Karimian; Durkee, Shane; Sahin, Kazim

    We investigated whether different doses of undenatured type II collagen (undenatured collagen, UC-II) help improve monosodium iodoacetate (MIA)-induced (osteoarthritis) OA in young and old rats. A total of 70 rats were divided into five groups: (1) control; (2) MIA (a single intra-articular injection of MIA); (3)–(5) MIA+ Undenatured Collagen with various oral doses (0.66, 1.33, and 2 mg/kg). The results showed that all doses of undenatured collagen in both age groups reduced knee diameter, while the two higher doses (1.33 mg/kg and 2 mg/kg) reduced the Mankin score and increased most gait measurements as early as day 14 compared to the MIA rats. However, the 2 mg/kg dose showed the best efficacy in improving Mankin score and gait measurements by 28 days post-OA induction. In young but not old rats, all doses of undenatured collagen reduced the Kellgren-Lawrence score compared to the MIA group. Undenatured collagen reduced the levels of most inflammatory and cartilage breakdown markers in serum and knee joint cartilage in both age groups. In conclusion, this data suggests that while all doses of undenatured collagen supplementation may ameliorate MIA-induced OA symptoms, the higher doses showed faster improvement in gait measurements and were more efficacious for overall joint health in rats.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus17WoS17OpenAlex15
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  • MakaleYalnız künye2023Scopus SJRQ2
    Graphene nanoplatelet-reinforced high entropy alloys (HEAs) through B4C incorporation: structural, physical, mechanical, and nuclear shielding properties

    Gul, Ali Oktay; Kavaz, Esra; Basgoz, Oykum; Guler, Omer; ALMisned, Ghada; Bahceci, Ersin; Guler, Seval Hale; Tekin, H.O.

    This study aims to explicate the diverse roles of high entropy alloys within nuclear environments. The study extensively investigates the impact of B4C on the structural, physical, mechanical, and nuclear shielding properties of synthesized high-entropy alloys (HEAs) comprising FeNiCoCrW, GNP, and B4C. The aim is to explore the monotonic effects of B4C on the behavioural changes of the HEAs. The present study initially investigates the internal morphology and structural characteristics of the produced composites through the utilization of X-ray diffraction, scanning electron microscopy, and energy dispersive spectroscopy. The determination of coefficient of friction values is obtained via wear testing, wherein the values are measured as a function of the sliding distance. The shielding properties of nuclear radiation are determined through the experimental setups for gamma-ray and neutron radiation. The sample encoded as G2, which incorporates both B4C and GNPs as reinforcing agents, exhibits the most noteworthy mechanical properties among the samples that were examined. The findings of our study indicate that augmenting the concentration of B4C has a significant impact on the efficacy of nuclear radiation shielding. The present study infers that the B4C produced within the framework of GNPs plays a significant role in enhancing the overall characteristics of HEAs. This is particularly noteworthy in the context of nuclear applications, where HEAs are being examined as a prospective constituent of forthcoming nuclear reactors. Moreover, B4C serves as a versatile instrument in scenarios, where there is a need to enhance mechanical and nuclear shielding properties across a spectrum of radiation energies.

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  • MakaleYalnız künye2023Scopus SJRQ1
    Evaluation of container port sustainability using WASPAS technique using on type-2 neutrosophic fuzzy numbers

    Kaya, Sema Kayapinar; Kundu, Pradip; Görçün, Ömer Faruk

    According to the common opinion in the literature, the sustainability of container ports is a tremendously complex topic owing to the maritime sector's excessively dynamic form and many highly complex, predictable and unpredictable uncertainties in this industry. The current paper proposes two powerful, practical, inspiring approaches to fill these gaps. It proposes a novel type-2 neutrosophic fuzzy numbers (T2NFNs) based Delphi method to determine the criteria logically and optimal and extends the WASPAS technique based on the T2NFNs for evaluating the alternatives. The current paper presents practical managerial implications that many stakeholders can consider, such as port authorities, ship owners, logistics service providers, governments, and local authorities, when making strategic and managerial decisions. In addition, the results of a comprehensive sensitivity analysis performed to test the robustness and applicability of the model approve the validity of the proposed T2NFN-based integrated approach.

    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus20WoS16OpenAlex24
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  • Kitap BölümüYalnız künye2023
    Organizational change models in practice: The case of michelin group

    Uyan, Umut

    In a competitive business environment, it is vital that firms consider implementing techniques to cope with constant change to remain competitive and survive. Most change initiatives, however, suffer from several difficulties and are often hampered by resistance, primarily caused by fear of adopting new practices or concern about competence. As a result, such initiatives could result in unintended consequences. In fact, they might result in irreversible situations, impairing the dynamics of an organization. Michelin Shanghai underwent an organizational change initiative to enhance its competitiveness. The initiative resulted in significant improvements in the company's productivity and profitability as well as increased employee satisfaction. The main objective of the study is to understand the organizationalchange dynamics of Michelin Shanghai Co. The chapter also attempts to evaluate challenges encountered during the process and critically analyze the leadership approaches that were applied by Mr. Ballarin (plant manager of Michelin Co.) based on related theories.

    AtıfScopus1OpenAlex1
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  • MakaleYalnız künye2023Scopus SJRQ2
    Investigation of Leaching Kinetics of Molybdenum from MoO3 Concentrate in Ammonia–Ammonium Nitrate Solutions

    Karacahan, Mehmet Kayra

    MoO3 is a widely accessible foundation material and the primary compound used to produce numerous molybdenum products. The ore was first roasted, and the leaching behavior of concentrated molybdenite mineral was assessed. The optimal conditions for the leaching process were identified in the second step, and in a subsequent stage, the process' kinetics were assessed. Ammonia and ammonium nitrate concentration were used as independent variables in the trials, and the central composite design approach was used to analyze the results. At the conclusion of the tests, the optimum concentrations of ammonia and ammonium nitrate were found to be 2.42 mol/L and 1.86 mol/L, respectively. On the rate at which molybdenum leached from MoO3, the influences of temperature, stirring speed, solid-to-liquid ratio, and particle size were investigated. It was found that the leaching rate increased when temperature and stirring speed increased, along with decreasing the solid-to-liquid ratio and particle size. Leaching efficiency of molybdenum (93%) such as temperature 20 °C, 1.859 mol/L ammonium nitrate concentration, 2.419 mol/L ammonia concentration, solid/liquid ratio 6/100 g/mL, stirring speed 400 rpm, and average particle size 0.115 mm optimum conditions have been achieved. The kinetic study proposed a mathematical model for the leaching process, which revealed that the leaching kinetics matched the Avrami model. This process' activation energy was determined to be 22.66 kJ/mol. Calcium molybdate is used in various fields, such as construction, transportation, anti-corrosion pigments, and flame retardants. Graphical Abstract: [Figure not available: see fulltext.]

    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus8WoS7OpenAlex9
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  • MakaleYalnız künye2023Scopus SJRQ1
    Acrylamide formation in apple juice concentrates during storage

    Aktağ, Işıl Gürsul; Gökmen, Vural

    This study investigated the acrylamide formation in model systems, laboratory-scale produced apple juice concentrates obtained from different stages of process, and commercial apple juice concentrates at different Brix levels during the storage. Changes in the concentrations of reducing sugars, asparagine, 5-hydroxymethylfurfural, 3-deoxyglucosone, and acrylamide were monitored. In addition, Schiff bases of 3-deoxyglucosone and 5-hydroxymethylfurfural with asparagine were confirmed using high-resolution mass spectrometry in order to understand the contribution of intermediates to acrylamide formation. The results revealed that acrylamide formed in both acidic-aqueous model systems and laboratory-scale apple juice concentrates during production. The concentrations of 3-deoxyglucosone, 5-hydroxymethylfurfural, and acrylamide increased significantly (p < 0.05) with the increase in Brix levels whereas asparagine levels decreased in commercial apple juice concentrates during storage. The concentration of acrylamide reached at the maximum level of 0.30 ± 0.02 µmol/kg dry matter in 70°Bx of the concentrates. The findings showed that long-term storage of apple juice concentrates at high Brix levels contributes the acrylamide formation even in unsuitable systems such as acidic and high moisture medium. The confirmation of Schiff base of 3-deoxyglucosone and 5-hydroxymethylfurfural with asparagine demonstrated that the acrylamide formation was attributed to the accumulation of intermediates leading to the conversion of asparagine to acrylamide.

    • SDG 2 · Açlığa Son
    AtıfScopus9WoS8OpenAlex9
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  • MakaleYalnız künye2023Scopus SJRQ1
    Analysis of the mechanical characteristics and plasticity-hazardous zones development of natural gas pipeline under overload

    Zheng, Qiang; Shu, Zekai; Yang, Gang; Zhang, Hui; AKKURT, Nevzat; Guan, Ben; Chen, Weiwang; Xu, Qian; Zang, Yong; Ding, Yulong

    The problem of natural gas pipeline overload failure is of great significance, and the development law of critical mechanical properties of pipelines is of great importance to the safety design of natural gas pipelines. This study establishes a three-dimensional finite element computational model of the pipeline that integrates the changes in axial and circumferential mechanical characteristics, and uses the yield strength, safety factor and ellipticity indexes as criteria to dimensionless the axial depth and circumferential angle of the plastic zone to explore the characteristics of the plastic damage stage of the pipeline. By solving the plastic hazardous zones based on the safety factor, the applicability of the dimensionless parameters is extended to investigate the development laws of the hazardous zones and the correlation mechanism between failure criteria and hazardous zones. The results show that as the ground load increases, the pipeline deformation gradually develops into the plastic stage (P = 16 MPa) and then goes through three deformation stages. With the increase of safety factor, the change trend of the proportion of stage I in the whole loading process decreases to 4 %, the change trend of the proportion of stage III increases significantly to 52 %, while the proportion of stage II shows a change trend of decreasing and then increasing, the proportion of this stage ranges from 30 % to 38 %. Based on the law of variation of axial ellipticity of pipeline section, a high-risk section of pipeline was identified in the range of 0–2 m from the point of maximum local compression strain. The results of the study can serve as a basis for accurate evaluation of the safety status of natural gas pipelines under overload.

    • SDG 9 · Sanayi, Yenilikçilik ve Altyapı
    AtıfScopus3WoS3OpenAlex3
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2023Scopus SJRQ3
    Morpho-structural and compressive mechanical properties of graphene oxide reinforced hydroxyapatite scaffolds for bone tissue applications

    Fidan, Ferzan; Aslan, Naim; Koç, Mümin Mehmet

    Hydroxyapatite (HA) is a unique material that has the potential to be used to replace bones and teeth in the field of orthopedics and dentistry since HA exhibits quite similar biological and chemical characteristics to human bone. Hydroxyapatite ceramics are bioactive materials used to repair damaged human tissue. The pores in the porous hydroxyapatite ceramics provide a mechanical interlock, enabling a solid bond and fixation between the implant and bone. In this study, 0.5wt%, 1wt%, and 1.5wt% graphene oxide (GO) reinforced porous HA structures were obtained using the space-holder method to increase the strength of hydroxyapatite with low mechanical strength. NaCl was used as a spacer, and PEG 400 as a binder. Scaffold structures with 40% porosity rates were sintered at 1000 °C under vacuum. Finally, a compression test was applied to the samples which were previously analyzed by SEM, EDS and XRD. The compressive strengths of 0.5%, 1%, and 1.5% graphene oxide reinforced porous HA samples were determined between 8.04 and 31.14 MPa. The highest compressive strength was recorded as 31.14 MPa in the 1% GO added sample, and the lowest compressive strength was recorded as 8.04 MPa in the 1.5% GO added sample. In addition, it was understood that the mechanical properties did not increase regularly with the increase of graphene oxide reinforcing.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus4OpenAlex3
    ScopusTR Dizinİncele