Sürdürülebilir Kalkınma Amaçları

Yazarlar

  • MakaleYalnız künye2021Scopus SJRQ2
    Effects of lavender oil intervention before endoscopic retrograde cholangiopancreatography on patients' vital signs, pain and anxiety: A randomized controlled study

    Citlik Saritas, Seyhan; Buyukbayram, Zeliha; Kaplan Serin, Emine; Bilgic, Yilmaz

    Background: This study was carried out to determine the effects of lavender oil intervention before endoscopic retrograde cholangiopancreatography (ERCP) on patients' vital signs, pain and anxiety. Materials and methods: This study was designed as a randomized controlled study. The population of the study consisted of adult patients who were going to receive ERCP at the gastroenterology clinic of a university hospital. Ninety patients participated in the study. The data were collected using a Patient Information Form, a Pre-Post Test Record Form, VAS and the State Anxiety Scale. Results: After lavender oil intervention, the pulse rate, systolic-diastolic blood pressure, pain and anxiety levels of the patients in the experiment group were reduced, their oxygen saturation levels were increased, and the difference between the groups was statistically significant (p < 0.05). Conclusion: Lavender oil applied on the patients before the ERCP procedure reduced their pulse rate, systolic-diastolic blood pressure, pain and anxiety levels, while it increased their oxygen saturation levels.

    AtıfScopus14WoS9
    ScopusWeb of SciencePubMedİncele
  • MakaleYalnız künye2021Scopus SJRQ1
    Silane doped biodegradable starch-PLA bilayer films for food packaging applications: Mechanical, thermal, barrier and biodegradability properties

    Gürler, Nedim; Paşa, Salih; Temel, Hamdi

    In this work, pure potato starch (PPS) purified from waste potato starch, was recovered and used. PPS was modified by 3-APTMS (3-(aminopropyl) trimethoxy silane) to manufacture a crosslinked film. To obtain a bilayer PPS-3APTMS-PLA film, the polylactic acid (PLA) was employed with PPS-3APTMS by casting method. The resulting materials, PPS-3APTMS and PPS-3APTMS-PLA were characterized by attenuated total reflectance fourier transform ınfrared (ATR-FTIR), x-ray Diffraction (XRD), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA). The silane-doped bilayer films have more thermal stability compared to PPS. The mechanical, solubility, swelling, water vapor permeability, optical properties and biodegradability under controlled compost conditions were examined. When the tensile strength of the PPS, PPS-3APTMS and PPS-3APTMS-PLA films were evaluated, the tensile strength (TS) were to 1.017±0.35 MPa, 1.437 ± 0.19 MPa and 10.918 ± 1.30 MPa, respectively. The PPS and PPS-3APTMS films were not elongation at break, while it was found about 21.94 ± 9.48 for the bilayer PPS-3APTMS-PLA film. The solubility, swelling, water vapor permeability, and transparency decreased for bilayer films. The water vapor permeability of PPS, PPS-3APTMS and PPS-3APTMS-PLA films were obtained as 31.69±0.4 × 10−7 g s−1 m−1 Pa−1, 28.96±0.4 × 10−7 g s−1 m−1 Pa−1, and 14.26±0.3 × 10−7 g s−1 m−1 Pa−1, respectively. Then, the biodegradability of films was performed under controlled compost conditions for 46 days according to ISO-14,855 standard. The biodegradation of PPS, PPS-3APTMS and PPS-3APTMS-PLA was also calculated as 9.30%, 5.45% and 5.08%. Biodegradation of PPS-3APTMS film decreases compared to PPS. Furthermore, the biodegradation value of bilayer film, PPS-3APTMS-PLA, was also decreased due to the slower degradation tendency of PLA. The contribution to the reusability of waste starch and the modifying of starch for food packaging and coating applications are the novelty aspects of the current study.

    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus93WoS77OpenAlex90
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2021Scopus SJRQ1
    The bioremediation of glyphosate in soil media by some newly isolated bacteria: The COD, TOC removal efficiency and mortality assessment for Daphnia magna

    Korkmaz, Volkan; Yildirim, Numan; Erguven, Gokhan Onder; Durmus, Barbaros; Nuhoglu, Yasar

    In this study, the bioremediation capacity of three isolates of Bacillus aryabhattai, Pseudomonas azotoformans and Sphingomonas pseudosanguinis and their consortia at glyphosate added soil medium investigated via the reduction of chemical oxygen demand (COD) and total organic carbon (TOC) parameters in filtrate waters obtained from a designed bioremediation setup. Additionally, mortality assays were performed on the filtrate waters with model organism Daphnia magna. According to the results of the experiments, at the end of the 11 days, the highest COD reduction rate seen in media with S. pseudosanguinis as 92.1% while TOC rate was 69.13% in consortia media. While the mortality rate was 10, 10 and 5% on B, P and S application groups at the end of the 72th respectively, these rates were 100% in control group at the end of the 48th. According to the results obtained from bioremediation and mortality assessment, these bacteria can reach the high bioremediation rate one by one and in consortia media.

    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
    • SDG 15 · Karasal Yaşam
    AtıfScopus14OpenAlex16
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2021Scopus SJRQ2
    Electrical conductivity and performance evaluation of verjuice concentration process using ohmic heating method

    Cevik, Mutlu

    The verjuice sample (14.5 ± 0.2% total soluble solid [TSS] content) was concentrated (at 102 ± 2°C evaporation temperature) until reach 50% TSS content by applying ohmic heating at 13, 15, 17, and 19 V/cm voltage gradients. The total process times up to 50% TSS content were determined as 2,100, 1,500, 1,200, and 1,020 s for 13, 15, 17, and 19 V/cm, respectively. The electrical conductivity values increased until reach 32% TSS content and then showed a decrease until the final TSS content. The total energy consumption values increased as the voltage gradient decreased. The total power and specific water removal ratio (SWRR) values decreased as the voltage gradient decreased. The efficiency of ohmic heating assisted concentration process increased with the applied voltage gradient and it ranged from 71.27 to 75.22%. By evaluating the effects of ohmic heating conditions applied in the present study on total process time, total energy consumption, and process efficiency, 19 V/cm voltage gradients could be recommended to be optimum evaporation conditions of verjuice concentration in case of decreasing process time and higher energy efficiency. Practical applications: Fruit juices are generally concentrated to extend their shelf life. Therefore, for concentration purposes, various techniques, such as thermal evaporation, freezing methods, and membrane techniques, are applied in the fruit juice industry. This technique has some disadvantages, such as high energy requirements, the formation of undesirable compounds, high initial investment cost, and high failure rate to reach the desired total soluble solid content. The ohmic heating method, which is among the alternative heating methods, has advantages such as high energy efficiency, shorter processing time, higher product quality, and not causing wastewater. As a result of this study, it is thought that the verjuice samples were successfully concentrated up to 50% TSS content by using the ohmic heating method and this method can be used as an alternative method instead of the traditional method due to higher process efficiency and shorter process time.

    • SDG 2 · Açlığa Son
    • SDG 7 · Erişilebilir ve Temiz Enerji
    AtıfScopus23WoS19OpenAlex26
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2021Scopus SJRQ1
    BEST-WR: An adapted algorithm for the hydraulic characterization of hydrophilic and water-repellent soils

    Di Prima, Simone; Stewart, Ryan D.; Abou Najm, Majdi R.; Ribeiro Roder, Ludmila; Giadrossich, Filippo; Campus, Sergio; Angulo-Jaramillo, Rafael; Yilmaz, Deniz; Roggero, Pier Paolo; Pirastru, Mario

    Water-repellent soils usually experience water flow impedance during the early stage of a wetting process followed by progressive increase of infiltration rate. Current infiltration models are not formulated to describe this peculiar process. Similarly, simplified methods of soil hydraulic characterization (e.g., BEST) are not equipped to handle water-repellent soils. Here, we present an adaptation of the BEST method, named BEST-WR, for the hydraulic characterization of soils at any stage of water-repellency. We modified the Haverkamp explicit transient infiltration model, included in BEST for modeling infiltration data, by embedding a scaling factor describing the rate of attenuation of infiltration rate due to water repellency. The new model was validated using analytically generated data, involving soils with different texture and a dataset that included data from 60 single-ring infiltration tests. The scaling factor was used as a new index to assess soil water repellency in a Mediterranean wooded grassland, where the scattered evergreen oak trees induced more noticeable water repellency under the canopies as compared to the open spaces. The new index produced results in line with those obtained using the water drop penetration time test, which is one of the most widely test applied for quantifying soil water repellency persistence. Finally, we used BEST-WR to determine the hydraulic characteristic curves under both hydrophilic and hydrophobic conditions.

    • SDG 6 · Temiz Su ve Sanitasyon
    AtıfScopus26OpenAlex26
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2021Scopus SJRQ2
    Failure modes and effects analysis based on neutrosophic analytic hierarchy process: method and application

    Yucesan, Melih; Gul, Muhammet

    Failure modes and effects analysis (FMEA) is a commonly used method in risk evaluation. In this paper, a novel FMEA model based on neutrosophic analytic hierarchy process (NAHP) is proposed to overcome shortcomings of the risk prioritization of classical FMEA. Neutrosophic sets approach real-world decision-making problems from a three-aspect structure (i.e., truthiness, indeterminacy and falsity). Therefore, initially, AHP is merged with neutrosophic sets to assign importance weights to risk parameters in FMEA. The encountered failure modes are then prioritized with respect to the previously weighted risk parameters. Each element in AHP comparison matrices is considered as triangular neutrosophic numbers, and score functions are used to transform NAHP elements to deterministic values. The flexibility of determining the weight to each parameter of FMEA (severity, occurrence and detection) and evaluation of each failure mode against these parameters are more well-suited to the real decision-making condition. Finally, a case study in the textile industry is provided to show the applicability of the novel model. Sensitivity and comparative analysis are also performed to validate the results.

    AtıfScopus42WoS27OpenAlex33
    ScopusWeb of Scienceİncele
  • Kitap BölümüYalnız künye2021
    Fine–kinney-based occupational risk assessment using intuitionistic fuzzy todim

    Gul, Muhammet; Mete, Suleyman; Serin, Faruk; Celik, Erkan

    This chapter applies a novel occupational risk assessment approach which merges TODIM with the Fine–Kinney method under the intuitionistic fuzzy set concept. Risk parameters of Fine–Kinney and OHS experts are weighted by an intuitionistic fuzzy weighted averaging (IFWA) aggregation operator. Hence, hazards are quantitatively evaluated and prioritized using the proposed approach. To illustrate the novel risk assessment approach, processes of the gun and rifle assembly line of a factory are handled. A comprehensive risk assessment is carried out to improve operational safety and reliability in the industry. We adapt intuitionistic fuzzy sets in the existing study since they reflect uncertainty with the aid of their membership and nonmembership functions in decision-making better than classical fuzzy extensions. An additional sensitivity analysis by changing the attenuation parameter of TODIM is performed to test the validity of the approach. Finally, the Python codes in the implementation of the proposed approach are given for scholars and practitioners for usage in further studies.

    AtıfScopus5OpenAlex9
    Scopusİncele
  • MakaleYalnız künye2021Scopus SJRQ1
    Development of comprehensive liquid chromatography with diode array and mass spectrometric detection for the characterization of (poly-)phenolic and flavonoid compounds and application to asparagus

    Karaaslan Ayhan, Nagihan; Rosenberg, Erwin

    The main objective of the present work was to develop a method for the simultaneous and comprehensive analysis of (poly-)phenolic and flavonoid compounds with liquid chromatography with diode array and mass spectrometric detection and its application to green asparagus samples. To this end, a representative set of polyphenols was used to develop the method. A through method validation was carried out with these. The method was applied to asparagus samples known as a healthy vegetable being rich in bioactive compounds. Polyphenol contents of asparagus samples were determined by carrying out quantitative and qualitative analyses by LC-DAD-ESI/MS. In this context asparagus sample extracts were obtained using solvents of different polarity. The results were evaluated statistically and showed that rutin is the major phenolic compound in asparagus. This demonstrates the versatility of this rapid and sensitive method for the simultaneous analysis of (poly-)phenolic and flavonoid compounds which was successfully applied to asparagus samples.

    AtıfScopus15WoS15OpenAlex17
    ScopusWeb of SciencePubMedİncele
  • MakaleYalnız künye2021Scopus SJRQ3
    Study on vibrational spectroscopy, molecular property, UV-VIS, HOMO-LUMO energies and MEP analysis of N-[2-(4-Bromo-benzoyl)-benzofuran-3-yl]-acrylamide monomer by DFT method

    Barim, Esra; Akman, Feride

    Purpose: This study aimed the synthesis and theoretical/experimental characterization of novel benzofuran-based acrylamide monomer. Design/methodology/approach: Novel N-substituted acrylamide monomer, i.e. N-[2–(4-Bromo-benzoyl)-benzofuran-3-yl]-acrylamide (BBFA), was synthesized by reacting (3-Amino-benzofuran-2-yl)-(4-bromophenyl) methanone with acryloylchloride at 0–5oC. Nuclear magnetic resonance (1H-NMR), infrared (FT-IR) and UV-Visible spectrophotometer were used to elucidate the chemical structure of BBFA. Computational studies were performed using the DFT (B3LYP) method on the basis of 6-31 + G (d, p) using Gaussian 09 W and Gauss View 5.0 package in addition to the VEDA program, gauge-independent atomic orbital (GIAO) and time-dependent density functional theory (TD-DFT) methods. Findings: Molecular geometry and vibration assignments of the BBFA monomer were calculated. The molecular structure of the monomer was examined. Both longest and shortest bonds were determined in the structure. The nucleophilic and electrophilic regions of the monomer were determined. The theoretical spectroscopic data of the monomer were compared with the experimental data; both were consistent with each other. The chemical reactivity of the monomer was also determined. Originality/value: The synthesized BBFA monomer can be evaluated in many areas; from medicine to industry (such as textiles) owing to the presence of various active functional groups. Indeed, acrylamide copolymers are remarkable materials for polymer science and industry. The data produced in this study is original and adds to the scientific community.

    AtıfScopus5WoS5OpenAlex3
    ScopusWeb of Scienceİncele
  • Kitap BölümüYalnız künye2021
    Fine–kinney-based occupational risk assessment using single-valued neutrosophic topsis

    Gul, Muhammet; Mete, Suleyman; Serin, Faruk; Celik, Erkan

    Neutrosophic sets are initially recommended by Smarandache (First international conference on neutrosophy, neutrosophic logic, set, probability, and statistics. University of New Mexico, Gallup, NM, pp 338–353, 2002 [1]). These sets reflect uncertainty and vagueness in real-world problems better than classical fuzzy set theory. It takes into consideration three decision-making situations called indeterminacy, truthiness, and falsity. In Zadeh traditional fuzzy set theory, there is just membership function fuzzy set degree. But, in neutrosophic environment, it considers three membership functions. Unlike intuitionistic fuzzy sets, an indeterminacy degree is considered. In this chapter, we applied a special form of neutrosophic set as single-valued neutrosophic set (SVNs) with the technique for order preference by similarity to ideal solution (TOPSIS) under the concept of Fine–Kinney occupational risk assessment. Since the mere TOPSIS has failed to handle imprecise and vague information which usually exist in real-world problems, we follow the integration of SVNs and TOPSIS. To demonstrate the applicability of the novel approach, a case study of risk assessment of a wind turbine in times of operation was provided. Comparative analysis with some similar approaches and sensitivity analysis by changing the weights of Fine–Kinney parameters are carried out. Finally, the Python implementation of the proposed approach is executed to be useful for those concerned in the future.

    AtıfScopus12OpenAlex9
    Scopusİncele
  • MakaleAçık Erişim2021Scopus SJRQ2
    Comparison of quality attributes of minced beef samples thawed by ohmic and conventional methods

    Cevik, Mutlu; Icier, Filiz

    Frozen minced meat samples having different fat contents (2%, 10%, or 18%) were thawed using two different standard thawing methods (RT: +4°C refrigeration thawing, URWT: +4°C under running water thawing), and a novel alternative method (ohmic thawing-OT at voltage gradients of 10, 13, and 16 V/cm). The drip loss values of meat samples changed in the range of 0.01%–1.65%. For OT, the change in the color increased as the fat content increased. OT shortened the thawing time, on average, by 64% and 87% compared to URWT and RT, respectively, while it resulted in similar effects on proximate composition and microbiological load with standard thawing methods. This novel thawing method did not cause any mutagenic formation, and the metal migration was in allowable limits. It is thought that the results showed that OT method has the potential to be applied as a novel alternative method for thawing of meat products. Practical applications: For long-term storage of meat and meat products, freezing is commonly used. However, frozen food must be thawed before use. For this reason, two different conventional thawing methods were recommended by US-FDA. However, conventional thawing methods have some disadvantages such as long process times, high energy consumptions, and waste water formation. Ohmic thawing has shorter process time, high energy efficiency, and does not produce any waste water. In this study, frozen minced meat samples (with fat content of 2%, 10%, or 18%) were thawed using different thawing conditions (RT, URWT, and OT at voltage gradients of 10, 13, and 16 V/cm). OT shortened the thawing time. Drip loss was found to be high for OT. The effect of OT on microbiological load and proximate composition was not different from conventional thawing. OT method did not cause any mutagenic formation.

    • SDG 2 · Açlığa Son
    AtıfScopus26WoS23OpenAlex27
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2021
    Fermatean fuzzy TOPSIS-based approach for occupational risk assessment in manufacturing

    Gul, Muhammet; Lo, Huai-Wei; Yucesan, Melih

    The importance of risk assessment in the context of occupational health and safety by manufacturing operators strengthens their hands in solving the problems they may encounter in business processes related to health and safety. One of the most important phases of conducting an exhaustive occupational risk assessment is to analyze potential hazards and associated risks quantitatively. Since manufacturing is one of the industries that require workers to be highly exposed to work, creating a safer environment to reduce occupational injuries is an important task. This study proposes a novel fuzzy risk assessment approach developed by integrating Fermatean fuzzy sets (FFSs) and technique for order preference by similarity to ideal solution (TOPSIS) method for ranking potential hazards in manufacturing. FFSs are a new version of fuzzy set theory that covers the intuitionistic fuzzy sets and Pythagorean fuzzy sets. This version of the fuzzy set is crucial in the decision-making process to handle uncertain information more easily and reflect uncertainty better. A linguistic scale under Fermatean fuzzy documentation has also been developed for experts/decision makers to disclose their judgments easily. Occupational risk analysts can benefit from this approach since FFSs are used for the first time in occupational risk assessment, and the approach is presented in integration with TOPSIS. The proposed approach is applied in the aluminum plate-manufacturing process risk assessment. In the conclusion of the implementation, risks arising in the production are prioritized. In addition, this study made comparisons with other fuzzy methods to demonstrate the proposed approach’s difference and practicality. This study’s results can support practitioners and risk analysts in formulating the improvement measures to increase the safety of the work environment further.

    AtıfScopus105WoS86OpenAlex108
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2021
    Phylogenetic analysis of the genus conringia heist. Ex fabr. (brassicaceae) in turkey based on nuclear (nrits) and chloroplast ((trnl-f)) dna sequences

    Sevindik, Emre; Aydogan, Melike; Paksoy, Mehmet Y.

    In this study, phylogenetic analysis of Turkish Conringia (Brassicaceae) species was conducted based on nuclear ribosomal DNA (nrITS) and chloroplast DNA (trnL-F) sequences. In addition, the relationships between the sequences of some Brassicaceae family species retrieved from NCBI, and Conringia species were documented. All of the plant specimens were collected at their flowering and vegetation periods from different regions of Turkey, and brought to the laboratory. Total genomic DNA was extracted using the GeneMark kit. In PCR analyses, ITS4 and ITS5A primers were used for the amplification of the nrITS region, while the trnLe and trnLf primers were used for the cpDNA trnL-F region. The DNA sequences obtained were then edited using BioEdit and FinchTV, and analyzed using MEGA 6.0 software. Neighbor joining (NJ) and bootstrap trees were constructed in order to identify the relationships among Conringia taxa. The nrITS sequences ranged between 573 and 672 nucleotides, while the trnL-F sequences ranged between 346 and 764 nucleotides. The divergence values of nrITS sequences differed between 0.177 and 0.00 and divergence values of trnL-F sequences differed between 0.902 and 0.00. NJ tree generated using nrITS and trnL-F sequences consisted of two clades. In trees generated with both the nrITS and trnL-F sequences, C. orientalis, C. grandiflora and C. austriaca appeared within the same group. In addition, according to the phylogenetic analysis results obtained with other Brassicaceae species, it is revealed that the Conringia genus is polyphyletic.

    AtıfScopus1
    Scopusİncele
  • MakaleAçık Erişim2021Scopus SJRQ1
    Magnesium picolinate improves bone formation by regulation of rank/rankl/opg and bmp-2/runx2 signaling pathways in high-fat fed rats

    Sahin, Emre; Orhan, Cemal; Balci, Tansel Ansal; Erten, Fusun; Sahin, Kazim

    Magnesium (Mg) deficiency may affect bone metabolism by increasing osteoclasts, de-creasing osteoblasts, promoting inflammation/oxidative stress, and result in subsequent bone loss. The objective of the present study was to identify the molecular mechanism underlying the bone protective effect of different forms of Mg (inorganic magnesium oxide (MgO) versus organic magnesium picolinate (MgPic) compound) in rats fed with a high-fat diet (HFD). Forty-two Wistar albino male rats were divided into six group (n = 7): (i) control, (ii) MgO, (iii) MgPic, (iv) HFD, (v) HFD + MgO, and (vi) HFD + MgPic. Bone mineral density (BMD) increased in the Mg supplemented groups, especially MgPic, as compared with the HFD group (p < 0.001). As compared with the HFD + MgO group, the HFD + MgPic group had higher bone P (p < 0.05) and Mg levels (p < 0.001). In addition, as compared to MgO, MgPic improved bone formation by increasing the levels of osteo-genetic proteins (COL1A1 (p < 0.001), BMP2 (p < 0.001), Runx2 (p < 0.001), OPG (p < 0.05), and OCN (p < 0.001), IGF-1 (p < 0.001)), while prevented bone resorption by reducing the levels of RANK and RANKL (p < 0.001). In conclusion, the present data showed that the MgPic could increase osteogenic protein levels in bone more effectively than MgO, prevent bone loss, and contribute to bone formation in HFD rats.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus21WoS20OpenAlex21
    ScopusWeb of SciencePubMedİncele
  • DüzeltmeAçık Erişim2021Scopus SJRQ1
    Corrigendum to “Carbon and water balance of an afforested shallow drained peatland in Iceland” [For. Ecol. Manage. 482 (2021) 118861] (Forest Ecology and Management (2021) 482, (S0378112720316303), (10.1016/j.foreco.2020.118861))

    Bjarnadottir, Brynhildur; Sungur, Guler Aslan; Sigurdsson, Bjarni D.; Kjartansson, Bjarki T.; Oskarsson, Hlynur; Oddsdottir, Edda S.; Gunnarsdottir, Gunnhildur E.; Black, Andrew

    The authors regret that the total evapotranspiration shown in Fig. 7 (821 mm) was the measured H2O flux for the whole two year measurement period. The correct average value for the two years was 411 mm yr−1, or 33% of the measured annual average precipitation. This left 827 mm yr−1 as the “estimated runoff” (see corrected figure). The sign of the average NEE values in the Abstract and Conclusions should be negative. All other information is correct, including the equations and interpretations. The authors would like to apologise for any inconvenience this has caused. [Figure presented]

    • SDG 13 · İklim Eylemi
    • SDG 15 · Karasal Yaşam
  • MakaleAçık Erişim2021
    Mineralogical And Gemological Characteristics Of Metaophiolite Hosted Corundum (Malatya-Türkiye)

    Kaydu Akbudak, İlkay; Gürbüz, Meltem; Başibüyük, Zeynel; Hatipoğlu, Murat; Öztüfekçi Önal, Ayten; İşler, Fikret

    The corundum is found in the rocks of the Berit metaophiolite in Eastern Anatolia, near Doğanşehir a province of Malatya. Metaophiolitic rocks consist mainly of garnet metagabbro, granulite, amphibolite, mylonitic amphibolite, garnet amphibolite, amphibole schist, pyroxenite, mylonitic pyroxenite, orthopyroxenite, harzburgite, serpentinized dunite and diorite units. Corundum occurrences are mostly found in pyroxenites, amphibolites, peridotites and granulites. Their colors change in range between reddish pink, pink and light pink. They are usually in structure of translucent, vitreous and sometimes cracked. They are seen scattered or clustered together inside the rocks in which they are found. The size of their crystals ranges from 0.5 cm to 10 cm and their euhedral crystals are observed in pseudohexagonal form. As a result of the petrographic examinations, it was observed that pyroxene, amphibole, garnet and plagioclase minerals accompanied with the corundum. The samples of the rocks containing the corundum has qualifications which will be as an object of gemstone and ornament by means of cutting and shining. Large specimens of corundum can be processed alone. Samples, being as scattered and small granules inside the rock can be processed together with the host rock. In the processed samples, it was obtained patterns like the samples of corundum with zoisite which were in great demand in the world gemstone market.

    AtıfScopus3OpenAlex4TR Dizin2
    ScopusTR Dizinİncele
  • MakaleYalnız künye2021Scopus SJRQ1
    Toxicological effects of di-(2-ethylhexyl) phthalate in Gammarus pulex: a biochemical and histopathological assessment

    Yildirim, Nuran Cikcikoglu; Ak, Tuba Parlak; Samasas, Omer

    This study aimed to reveal the toxic characteristics of di-(2-ethylhexyl) phthalate (DEHP) by examining the biochemical and histopathological changes in Gammarus pulex, exposed to different doses of DEHP. For this purpose, the lethal concentration 50 (LC50) value of the DEHP was determined by using a static test and found to be 0.079 ± 0.01 ppm. Three subletal doses of DEHP were applied to the G. pulex for 24 and 96 h. Superoxide dismutase (SOD), catalase (CAT), cytochrome P450 1A1 (CYP1A1), and glutathione S-transferase (GST) activities were measured using commercial ELISA kits. The caspase method, which is an immunohistochemical analysis method, was used to determine the apoptosis that occurred in the G. pulex. The results showed that the CYP1A1 activities decreased in the groups exposed to different doses of DEHP compared to the control group (p > 0.05). CAT activity was found to increase in the application groups at the 24 and 96 h compared to the control group. In addition, it was found that SOD and GST activities increased at the 96 h compared to the control group. In light of the microscope examination of the model organism, hemolymphatic lacunae filled with hemolymph and reduction or absence of hemolymphatic ducts were observed especially in the G. pulex gills. Collapse of the gills and hyperplasia were observed after 96 h. As a result, it is suggested that changes in SOD, CAT, and GST activities can potentially be used as sensitive biomarkers for risk assessment in the environment and increased immunoreactivity in G. pulex caused by DEHP depending on increased application doses and application times.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus6WoS3OpenAlex5
    ScopusWeb of SciencePubMedİncele
  • MakaleYalnız künye2021Scopus SJRQ3
    Enhanced Adhesion and Corrosion Properties of Boron Doped Bioceramic Coated 316L Implants

    Aksoy, M.E.; Aksakal, B.; Aslan, N.; Dikici, B.

    Abstract: In order to provide an effective prevention to 316L implants, a synthesized bioceramic was coated by using electrophoretic deposition (EPD). The effect of boron addition into hydroxyapatite (HA) on surface morphology, adhesion and corrosion resistance of the implant has been examined. Boron doped HA (B–HA) was synthesized by a simple chemical acid-base method with 5, 10, and 15 wt % boron additions to coat on 316L implants. The synthesized B-HA was coated on the substrates and the coated surfaces with and without B additions. Sintering took place at different temperatures and sintering rates. The coatings were characterized by X-ray diffractometer (XRD), Fourier transform infrared spectroscopy (FT–IR) and scanning electron microscope (SEM). Furthermore, adhesion and in vitro corrosion tests were conducted. The influence of boron additons on adhesion and corrosion resistance of 316L have been revealed for the coated substrates at different B additions. It was shown that boron addition increased the adhesion and corrosion resistance of the bioceramic coatings. Furthermore, the sintering effect on adhesion was also evaluated and the highest adhesion as 25.8 MPa has been reached at 750°C for 90 s and 5°C min–1 sintering conditions. It was found that using iodine as EPD dispersant has increased the charging ability of the B–HA powders in the suspension and hence eased deposition rate. The study revealed that boron-containing hydroxyapatite coatings can provide crack-free surfaces that providing high adhesion and hence increase the corrosion resistance of metallic implants. Through the results, it was also shown that the network between powders was improved and hence adhesion was increased with increasing B addition.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus10WoS9OpenAlex12
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2021Scopus SJRQ3
    Pohlia hedw. And oleolophozia l.söderstr., de roo & hedd. species new to turkey and south-west asia

    Erata, Hüseyin; Özen, Öznur; Batan, Nevzat; Alataş, Mevlüt

    Pohlia lescuriana (Sull.) Ochi and Oleolophozia perssonii (H.Buch & S.W.Arnell) L.Söderstr., De Roo & Hedd. have been identified as new to Turkey and South-West Asia, following a recent bryological excursion in Giresun province of Turkey. The genus Oleolophozia L.Söderstr., De Roo & Hedd. is also new to Turkey. In this paper, brief descriptions, illustrations, information about geographic distribution, ecology and comparisons with morphologically similar taxa are given. A key to Pohlia Hedw. taxa in Turkey is added.

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  • MakaleAçık Erişim2021Scopus SJRQ1
    Sequential infiltration analysis of infiltration curves measured with disc infiltrometer in layered soils

    Moret-Fernández, D.; Latorre, B.; Lassabatere, L.; Di Prima, S.; Castellini, M.; Yilmaz, D.; Angulo-Jaramilo, R.

    The soil sorptivity, S, and saturated hydraulic conductivity, Ks, can be estimated from the inverse analysis of a cumulative infiltration curve using the quasi-exact implicit (QEI) formulation or its corresponding 4-Terms (4T) approximation. Although these models consider the soil as homogeneous media, there is no information about how heterogeneous profiles can affect the inferred soil properties. This work analyzes the influence of layered soils on Ks and S estimates using QEI and 4T models, and designs a new procedure for treating infiltration curves measured on layered soil profiles. The Sequential Infiltration Analysis (SIA) method considers a sequence of increasing time series from the cumulative infiltration data to estimate Ks and S, and its corresponding RMSE as a function of the number of samples used. A procedure to estimate the thickness of the upper uniform soil layer from the estimated wetting front advance (WFA) is also reported. The SIA method was applied on: (i) synthetic homogeneous profiles of loam soil and six layered profiles involving a 1, 2 and 3 cm thickness loam layer over silty or sandy loam soils, respectively, (ii) stratified laboratory soil columns, and (iii) 20 experimental infiltrations performed in a semiarid region of North-Eastern Spain. Similar results were found between QEI and 4T models for all cases. Erroneous estimates of Ks and S were observed when the total infiltration time series was considered for the analysis, regardless of the presence of soil layering. In opposite, estimates improved when the SIA method was applied to the layered systems. The SIA method exploits the fact that the RMSE increases when the wetting front reaches the interface between the soil layers. Such increase allows: (i) detection of the soil heterogeneity, (ii) determination of the infiltration time, to, required for the wetting front to reach the lower layer, and, (iii) accurate estimates of the upper layer Ks and S along with its thickness. Laboratory experiments on layered soils and field measurements demonstrated that the SIA method could be satisfactorily applied on different curves with contrasting shapes and magnitudes. Although soil layering encountered on most field samplings restricted the treatment of the observed infiltrations to short-medium times, the SIA method allowed robust estimates of Ks and S. These results indicate that the proposed method is a promising tool for characterizing the hydraulic properties of layered and heterogeneous soil profiles.

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