Sürdürülebilir Kalkınma Amaçları
Yazarlar
- Gul, Muhammet(85)
- Serdar, Osman(72)
- Güler, Ömer(68)
- Akkurt, Nevzat(61)
- Baskonus, Haci Mehmet(54)
- Alataş, Mevlüt(53)
- Paksoy, Mehmet Yavuz(53)
- Yucesan, Melih(53)
- Bulut, Hasan(51)
- Tekin, H.O.(51)
- ALMisned, Ghada(48)
- Yildirim, Numan(48)
- Benzer, Fulya(47)
- Kocabaş, Mehmet(45)
- Yildirim, Nuran Cikcikoglu(44)
- Kutlu, Banu(41)
- Ince, Muharrem(39)
- Zengin, Gokhan(39)
- Batan, Nevzat(37)
- Utku, Anıl(35)
- Celik, Erkan(33)
- Topal, Murat(32)
- Ezer, Tülay(31)
- Tanyol, Mehtap(31)
- Can, Erkan(30)
- Sulaiman, Tukur Abdulkadir(29)
- Aslan, Naim(28)
- Özkul, İskender(28)
- Aslan, Alper(27)
- Cakilcioglu, Ugur(27)
- Erguven, Gokhan Onder(27)
- Kutluyer, Filiz(27)
- Kök, Mediha(27)
- Ates, Mehmet(26)
- Erten, Fusun(26)
- Kahraman, Gökhan(26)
- Onat, Onur(26)
- Dal, Nursel Alp(25)
- Danabas, Durali(25)
- Say, Yakup(25)
Yayınlar
- MakaleYalnız künye2026Scopus SJRQ2Investigation of the effect of ultrasonic assisted milling and minimum quantity lubrication methods on the machinability of Hardox 500 steel
Dalgıç, Aras; Mahmat, Aybars
Hardox steel is widely used in agriculture, mining and transportation due to its mechanical properties such as high wear resistance, high impact resistance, high hardness, high durability and long life. The machinability of Hardox 500 is difficult as its high hardness and wear resistance lead to tool wear and low machining speed. Recently, various processing and cooling methods have been developed to increase machinability. Ultrasonic assisted milling (UAM), one of these methods, is a method used as an alternative to conventional milling (CM) in the milling of traditionally difficult-to-machine materials. In addition, minimum quantity lubrication (MQL) is a cooling method used to provide lubrication and cooling in the cutting area. In this study, the impacts of machining method, feed rate and spindle speed on cutting force, surface roughness and tool wear in milling of Hardox 500 steel were investigated. In the MQL method, mixtures with nano-sized SiC particles were obtained and applied to the cutting area. In the study, MQL reduced cutting forces by up to 19 %, surface roughness by 18 %, and tool wear by 30 % compared to dry machining, while UAM further decreased cutting forces by 17 %, surface roughness by 15 %, and tool wear by 12 % compared to CM. These results demonstrate that MQL and UAM significantly enhance machining performance over conventional and dry methods.
- MakaleYalnız künye2026Scopus SJRQ1Mineralogical and geochemical controls on Co-V-Pt-Ni enrichment in manganese mineralization: evidence from the Dilli deposit, Eastern Türkiye
Gücer, Mehmet Ali; Çimen, Okay; Aktağ, Alican; Keskin, Serdar
The growing demand for critical minerals driven by the global energy transition and advanced technologies highlights the importance of unconventional metal reservoirs. This study investigates the Ni-, Co-, V-, and Pt-enriched Dilli manganese deposit (Kemaliye-Erzincan, Eastern Türkiye) to constrain the mineralogical, geochemical, and genetic controls on critical metal enrichment in Mn oxide mineralization. An integrated approach combining field observations, petrography, X-ray diffraction (XRD), whole-rock geochemistry, mineral chemistry, and stable C-O isotope analysis was applied to better understand the potential origin of critical mineral enrichments. The mineralization is dominated by Mn4+-bearing oxides, principally pyrolusite and hollandite, accompanied by minor rhodochrosite. High MnO (39-64 wt%) and very low Al2O3 and Fe2O3 contents indicate chemical precipitation with negligible detrital input. Discrimination diagrams and trace-element systematics consistently support a structurally controlled hydrothermal origin. Chondrite-normalized REE patterns display low total REE and very low Nd contents comparable to typical hydrothermal deposits, whereas neutral to slightly positive Ce anomalies and non-chondritic Y/Ho ratios suggest limited oxidative interaction with surface-derived fluids rather than primary marine hydrogenetic growth. Stable C–O isotope compositions of co-genetic calcite are inconsistent with a purely marine depositional environment and indicate precipitation from low-to moderate-temperature hydrothermal fluids. Mineral chemistry reveals strong phase-specific partitioning: hollandite preferentially incorporates V and Ba, whereas pyrolusite is enriched in Ni. Cobalt occurs in both phases, whereas Pt may also be present in both Mn oxide phases, suggesting that trace-element distribution is influenced by both crystallochemical and physicochemical controls. The enrichment of Ni, Co, and Pt is most plausibly linked to hydrothermal fluid circulation through ultramafic units, which likely acted as the primary metal source prior to precipitation. The Dilli deposit thus represents a structurally controlled hydrothermal Mn system enriched in critical metals, emphasizing the exploration relevance of Mn oxide mineral chemistry in identifying alternative sources of critical metals in Türkiye.
- MakaleAçık Erişim2026Scopus SJRQ2Corrosion behavior and constant load scratch adhesion properties of CeO2 doped ceramic composite layer via micro arc oxidation on Al 1050 alloy
Ayday, Aysun; Durmaz, Mustafa; Duru, Erhan; Kırsever, Derya; Doğan, Fatih
In this study, CeO2-doped ceramic coatings were produced on Al 1050 alloy by micro-arc oxidation (MAO) using a silicate-alkaline electrolyte containing 0, 0.5, 1, and 2% CeO2. The aim was to investigate the effect of CeO2 addition on the microstructure, phase composition, corrosion behavior, and constant-load scratch adhesion performance of the coatings. Surface characterization was carried out by SEM, EDS, XRD, and 3D profilometry, while corrosion performance was evaluated by potentiodynamic polarization and electrochemical impedance spectroscopy in 3.5 wt% NaCl solution. Scratch tests were also performed to assess the mechanical integrity of the coatings. The results showed that increasing CeO2 content improved coating uniformity, reduced surface roughness and porosity, and promoted the formation of a denser oxide structure. XRD analysis confirmed that γ-Al2O3 was the predominant alumina phase in all coatings, while Ce-containing species were incorporated into the oxide layer without forming additional detectable phases. Electrochemical results revealed that CeO2 addition significantly improved corrosion resistance by lowering the corrosion current density and increasing the polarization resistance. Scratch test results further showed improved adhesion-related behavior with reduced crack formation and surface damage. Overall, CeO2 addition effectively enhanced both the corrosion protection and mechanical performance of MAO coatings on Al 1050 alloy.
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İncele - MakaleYalnız künye2026Scopus SJRQ2High-entropy rare-earth tungstate (PrEuYLaSm)2(WO4)3: Synthesis, physical, structural evolution and shielding properties
Durmus, Hasan; Özkul, İskender; Güler, Ömer; Güler, Seval Hale; Baykal, Duygu Sen; ALMisned, Ghada; Tekin, H.O.
In this study, a novel high-entropy rare-earth tungstate, (PrEuYLaSm)2(WO4)3, was synthesized by high-energy ball milling followed by calcination, and its structural, microstructural, thermal, gamma-ray, and neutron shielding properties were systematically investigated. X-ray diffraction results revealed that ball milling induced partial amorphization of the initial oxide mixture, while calcination at 1100 °C promoted the formation of a single-phase monoclinic A2W3O12-type structure without detectable secondary phases. SEM-EDS mapping showed the homogeneous distribution of Pr, Eu, Y, La, Sm, W, and O throughout the synthesized material. Differential thermal analysis showed sequential desorption, crystallization, and structural ordering processes, together with the absence of sharp decomposition up to 1100 °C, indicating good thermal stability. Radiation shielding evaluation demonstrated that the synthesized high-entropy tungstate exhibited strong gamma-ray attenuation performance, with high mass attenuation coefficient values, low half-value layer values, and stable effective atomic number behaviour over a wide photon energy range. Although some individual oxides showed superior performance at specific energies, the high-entropy composition provided a more balanced shielding response overall. In neutron shielding, the material showed competitive fast neutron removal capability among oxide systems. It can be concluded that the multifunctional potential of (PrEuYLaSm)2(WO4)3 for competitive high-temperature and radiation shielding applications.
- MakaleYalnız künye2026Scopus SJRQ1Sufi thought in the diwan of the French Christian poet Charles Vernay
Kayaokay, İlyas
This article examines how the French Christian poet Charles Vernay (1842–1866) engaged with Ottoman Sufi poetic discourse in his Divan-ı Verne (1858), a collection of poems written in Ottoman Turkish and Persian. While openly preserving his Christian identity, Vernay frequently employs key Sufi concepts, including ‘tevhid’ (divine unity), ‘aşk-ı hakiki’ (mystical love), ‘irfan’ (gnosis), ‘hakikat’ (truth) and the ‘tarik’ (spiritual path). Through a close textual analysis of selected poems, this study explores the relationship between Vernay’s Christian identity and the Sufi vocabulary that shapes his poetic imagination. The findings demonstrate that Vernay’s use of Sufi terminology extends beyond conventional imitation of classical Ottoman poetry. He employs these concepts to articulate his own spiritual worldview while simultaneously referring to the Bible, Jesus Christ and the doctrine of the Trinity. Although Vernay adopts the metaphysical language of Ottoman Sufism, he does not reproduce its Prophet Muhammad-centred framework. Instead, he reinterprets Sufi concepts within a Christian religious horizon and constructs a spiritual discourse shaped by unity, love, truth and faith. Divan-ı Verne thus reveals how Ottoman Sufi poetic language could be appropriated across religious boundaries and provides new insight into intercultural literary exchange in the nineteenth-century Ottoman world.
- MakaleAçık Erişim2026Scopus SJRQ1Impact of Postharvest Oxalic Acid Treatments on Quality Properties and Biochemical Composition of Medlar (Mespilus germanica L.) Fruit
Çolak, Ayşen Melda; Gündoğdu, Özlem; Aglar, Erdal; Sezgin, Nevzat; Orman, Erdal; Gundogdu, Muttalip
This study was conducted to investigate the effects of oxalic acid (OA) applications at different concentrations on the quality traits and biochemical components of medlar (Mespilus germanica L.) fruit. Fruits harvested in Bolu province in 2024 were subjected to control (0) and 0.5, 1.0, and 1.5 mM OA applications and stored at 4°C and 90% ± 5% relative humidity for 45 days. Samples were taken from the fruits at certain intervals (0, 15, 30, and 45 days) and analyzed. Specifically, 1.0 and 1.5 mM OA applications significantly reduced fruit weight loss and decay rates. OA also inhibited increases in fruit respiration rate and pH and slowed the decline in total acidity, soluble solids content (SSC), vitamin C, phenolic compounds, and organic acids. Malic, citric, succinic, tartaric, and fumaric acids, vitamin C, and important phenolic compounds (chlorogenic acid, gallic acid, quercetin, catechin) were protected by OA applications, and this protection was most pronounced at 1.5 mM OA dose. The correlation analyses revealed significant relationships between quality parameters and biochemical contents. The weight loss and decay rate were negatively correlated with bioactive compounds such as gallic acid and ascorbic acid, indicating that quality deterioration progressed in parallel with the decrease in nutrient content. A strong positive correlation was found between titratable acidity and malic and citric acids. In principal component analysis (PCA), malic and citric acids were prominent in the early storage period, while weight loss, decay, and increased respiration became dominant in the late storage period. Phenolic compounds decreased significantly with storage time, and antioxidant capacity decreased. Heat map analysis visually supported the increase in spoilage parameters with the decrease in ascorbic acid and phenolic compounds. OA applications maintained the quality of medlar fruit and increased biochemical stability, extending postharvest life. 1.5 mM OA, in particular, stands out as an effective postharvest preservation method. These results demonstrate that OA offers significant potential for increasing the commercial value of perishable fruits like medlar and for developing preservation technologies.
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İncele - MakaleAçık Erişim2026Scopus SJRQ1Numerical analysis of PCM integrated in solar dryers for thermal efficiency
Bakır Gür, Eda; Işık, Erdem; Uçar, Aynur
Solar dryers using phase change materials buffer heat, yet the combined influence of airflow regime and PCM placement on melting remains underexplored. A controlled like-for-like study fixed geometry and PCM properties while varying placement and operating conditions. A 3D transient CFD model simulated a forced-convection dryer with RT28HC over Re = 3000–9000 and inlet temperatures Ti = 50–60 °C. Raising either Re or Ti shortened melt time, and three-wall coverage melted faster and more uniformly than a rear-wall-only layout. For three walls, melt time dropped from 13 h (50 °C, Re = 3000) to 7 h (60 °C, Re = 9000) (−46 %) for the rear wall it fell from 19 h to 11 h (−42 %). A 10 °C increase in Ti reduced overall melt time by 4 h across Re. Practically, three wall PCM with Re ≥ 6000 at Ti = 60 °C achieved reliably 7–9 h melting, enabling late afternoon heat release without auxiliary heating.
AtıfScopus17WoS16OpenAlex12İncele - MakaleAçık Erişim2026Scopus SJRQ2Engineering Superior Soft Magnetic Properties Through FeCo/Cr and FeCo/Fe Nanocrystalline Architectures
Yüzüak, Gizem Durak
Soft magnetic materials are integral to various technologies, including high-frequency transformers, spintronic devices, and magnetic sensors, because of their low coercivity (HC) and high magnetization. This study investigates nanocrystalline Fe70Co30(100 nm)/Cr(2-10 nm) and Fe70Co30(100 nm)/Fe(2-10 nm) thin films, deposited via magnetron sputtering. X-ray diffraction analysis reveals that Fe70Co30 films without buffer layers crystallize in a body-centered cubic phase. The Cr and Fe buffer layers enhance it by minimizing lattice mismatch and promoting a uniform crystalline growth of the Fe70Co30 layer. The most significant particle size variations observed were approximately 24% for the Cr buffer and 31% for the Fe buffer. Microstructural characterization using atomic force microscopy and scanning electron microscopy identified nanograins with an average size of 30–80 nm. Magnetic characterization with a vibrating sample magnetometer showed a marked reduction in HC. Additionally, the remanence-to-saturation magnetization ratio remains nearly constant at 0.95 across all Fe-buffered films, whereas it increases from 0.80 to 0.92 in Cr-buffered films as the Cr thickness increases. The results highlight the importance of buffer layer engineering in enhancing the microstructural and magnetic properties of FeCo thin films, thereby increasing their suitability for advanced magnetic technologies.
- MakaleAçık Erişim2026Scopus SJRQ1Biogenic amine profiling of fruit wines by high-performance liquid chromatography with fluorescence detection after OPA derivatisation: effect of fruit type
Tok, Fırat; Çetin, Burcu; Karaca Sanyürek, Nesrin
This study aimed to characterise the biogenic amine (BA) profiles of fruit wines produced from different raw materials and to investigate their association with pH and fruit type. Ten commercially available fruit wines, including pomegranate, black mulberry, sour cherry, strawberry, melon, blackberry, and blueberry, were analysed using HPLC with fluorescence detection (HPLC-FLD) following pre-column derivatisation with o-phthalaldehyde. Putrescine, tyramine (TYR), and histamine were identified as the predominant amines, with total BA concentrations ranging from 11.62 to 53.96 mg/L depending on the fruit type. The pH values of the wines (3.28-3.60) were inversely related to acidity and showed a strong positive correlation with total BA content (r = 0.97, p < .001). Among the detected compounds, TYR exhibited the highest sensitivity to pH variation. Multivariate analysis using principal component analysis clearly differentiated the samples into two distinct groups: low pH-low BA wines (pomegranate and blueberry) and high pH-high BA wines (blackberry and strawberry). The HPLC-FLD method demonstrated excellent analytical performance, with high chromatographic stability (retention time RSD < 1%) and reliable compound identification. Overall, the results indicate that BA formation in fruit wines is closely associated with both pH and fruit type, reflecting the combined effects of raw material composition and fermentation conditions. These findings provide valuable insights into the biochemical characterisation, quality assessment, and safety evaluation of fruit wines in oenological applications.
- MakaleYalnız künye2026Scopus SJRQ1Exogenous methyl jasmonate delays quality loss and maintains bioactive compounds in quince during long-term storage
Hanci, Mehmet Utku; Ozturk, Ahmet; Aglar, Erdal; Olcer, Mehmet Ali; Ozturk, Burhan
Quince (Cydonia oblonga Mill.) is a climacteric fruit species that, despite its high nutritional value and rich phenolic composition, is prone to quality changes during postharvest handling. However, under appropriate storage conditions it can be maintained at acceptable quality for several months. This study aimed to assess the effects of exogenous methyl jasmonate (MeJA) treatments on quality attributes, and phenolic metabolism of quince fruit during cold storage. Fruits were treated with 0 (control), 0.5, and 1.0 mM MeJA and stored at 0 ± 1 °C with 90 ± 5% relative humidity for 120 days. Analyses were conducted at 30-day intervals, including physiological, phytochemical, and antioxidant activity, as well as individual phenolic compounds. During cold storage, fruits treated with 1.0 mM methyl jasmonate (MeJA) exhibited lower weight loss and respiration rate. Higher fruit firmness was also observed in MeJA-treated fruits. At the end of storage, MeJA-treated fruits showed higher vitamin C content and titratable acidity, but lower soluble solids content than the control fruits. Similarly, at 60 and 90 days of storage, fruits treated with 1.0 mM MeJA were found to contain higher levels of total phenolics, total flavonoids, and antioxidant activity. Among the phenolic acids identified in quince fruit, chlorogenic acid and 4-aminobenzoic acid were present at higher concentrations compared to the other phenolic compounds. At the end of the storage, MeJA-treated fruits generally exhibited a slower decline in phenolic acids compared to the control, indicating a protective effect of the treatment on phenolic stability. As a result, methyl jasmonate applications were identified as an effective strategy for reducing post-harvest quality losses and preserving bioactive compounds in quince fruit. Specifically, the 1.0 mM MeJA application showed the strongest protective effect on quality parameters. These findings indicate that MeJA is a commercially viable method for extending shelf life and preserving quality in quince fruit.
- MakaleYalnız künye2026Scopus SJRQ1FedMedIDS: A non-IID-resilient federated DCNN framework for securing IoMT and IoHT devices
Gencer, Burak; Dogan, Gurkan
The diversity of devices in the Internet of Medical Things (IoMT) and Internet of Health Things (IoHT) networks creates significant security vulnerabilities against cyberattacks. Traditional centralized machine learning approaches, however, are not always suitable for these environments due to data privacy regulations. In this study, a new Deep Convolutional Neural Network (DCNN) architecture is proposed for attack detection in IoMT/IoHT networks. The proposed architecture integrates the Residual Squeeze-and-Excitation (RSE) Block, the Squeeze-and-Excitation attention mechanism (SEM), and a one-dimensional multi-pooling approach. The model was evaluated within a federated learning (FL) framework called Federated Medical Intrusion Detection System (FedMedIDS), which preserves data privacy and demonstrates robustness in heterogeneous client scenarios. Four different training strategies—Centralized, FedAvg, FedProx, and Local-Only—were adopted for the evaluations. The proposed model and existing models were tested on the Canadian Institute for Cybersecurity – Internet of Medical Things 2024 (CICIoMT2024) and Edith Cowan University – Internet of Health Things (ECU-IoHT) datasets and compared with current deep learning models. The DCNN proposed for the CICIoMT2024 dataset and a Dirichlet distribution with α = 1.0 achieved F1 scores of up to 99.92% under FedAvg and 94.64% under FedProx with α = 0.5. At α = 0.05, the highest level of heterogeneity, it outperformed the Long Short-Term Memory (LSTM) by as much as 27%. On the ECU-IoHT dataset, F1 scores of up to 89.57% under FedAvg and 89.50% under FedProx were achieved at α = 1.0. This represents an improvement of up to 37% over LSTM at the same level of heterogeneity.
- MakaleAçık Erişim2026Scopus SJRQ1Optimization of scours downstream of conduit aerators
Arici, Erdinc; Tuna, M. Cihat; Aytac, Ayca; Acar, Ramazan; Tunc, Mustafa
Dams, wastewater treatment plants, and aquaculture areas often require aeration, making it crucial for hydraulic engineers to predict the physical properties of scour holes occurring on the downstream side of conduits. Conduit systems that provide high aeration performance necessitate multiple optimization studies to simultaneously maximize the scour parameters and the system’s physical properties. In this study, the physical parameters of conduit systems and downstream scour parameters were optimized using Artificial Neural Networks (ANN). The optimum system parameters were identified based on the experimental results through ANN-based optimization. Additionally, the real and optimal effects of the parameters on aeration performance and scour were determined. The results of the study demonstrated that ANN can be effectively used in studies aimed at optimizing the aeration performance and scour values of conduits. This study is the first to apply ANN for the simultaneous optimization of both aeration efficiency (Qa/Qw) and scour characteristics (dmax and δ) in a conduit-based hydraulic system. Previous studies have typically focused on either scour or aeration individually; this study integrates both through a multi-objective ANN model. The findings provide novel insights for the design and retrofitting of energy-dissipating conduit structures in high-head dam applications. Unlike traditional empirical or regression-based approaches, the ANN model captures complex, nonlinear relationships among multiple interacting hydraulic variables. It identified optimal parameter combinations — such as 70% gate opening, 1.30–1.50 m conduit length, and 9 mm air hole diameter — that improve both aeration and scour behavior. These outcomes offer direct applicability for real-world hydraulic system optimization.
AtıfOpenAlex1İncele - MakaleAçık Erişim2026Scopus SJRQ3An Artificial Neural Network Modeling of Solar Drying of Mint: Energy, Exergy, and Drying Kinetics
Gülçimen, Fevzi; Karakaya, Hakan; Durmuş, Aydın
Abstract: Solar drying is an environmentally friendly method for preserving agricultural products; however, limited studies have jointly examined energy–exergy performance and data-driven prediction methods under varying airflow conditions, which restricts performance optimization. This study aims to investigate the effects of inlet airflow rate on energy utilization ratio, energy generation, exergy loss, exergy efficiency, and drying kinetics of mint leaves, and to evaluate the predictive capability of artificial neural network modeling. Thin-layer drying experiments were conducted in a forced convective solar dryer equipped with a newly designed solar air collector at different air mass flow rates. Energy and exergy analyses were conducted using experimental thermodynamic data, and energy utilization and exergy loss were modeled with a feed-forward back-propagation artificial neural network. The energy utilization ratio ranged from 7.45 to 87.1% and increased with decreasing airflow rate. The average exergy losses for air mass flow rates of 0.012, 0.026, and 0.033 kg s–1 were 16.2, 8.2, and 6.88 W, respectively. Both experimental and artificial neural network results showed that increasing airflow rate reduced energy utilization ratio and exergy loss. The artificial neural network predictions exhibited very close agreement with experimental data. The results show that artificial neural networks can accurately predict energy utilization ratio and exergy loss in a forced convective solar dryer. Airflow rate is a key parameter for thermodynamic performance, and the integrated experimental–ANN approach offers a robust tool for optimizing and designing solar drying systems.
AtıfOpenAlex1İncele - MakaleYalnız künye2026Scopus SJRQ2Lithium Recovery from Boron Processing Wastes via Mechanical Activation-Assisted Water Leaching: Application of Planetary Milling
Boylu, F.; Obuz Teker, Gülsen; Ersever Angur, Gafure; Ozdemir, O.; Çelik, M.S.
In this study, a more sustainable, cost-effective, and environmentally friendly approach for selective lithium extraction via water leach assisted by planetary mill mechanical activation was applied on clayey wastes of the Kırka Boron Plant. A detailed systematic study on wastes was performed to optimize both mechanical activation and leaching conditions and to characterize the active powders by XRD, FTIR and EDS/EDX. The results show that lithium can be recovered at relatively low leach temperatures of 50–60°C and short leach times of 3–5 min, achieving leach recoveries of 44.71 (without salt addition) and 57.71% (with 20% salt addition, w/w) without the need for pre-concentration of the waste. Despite relatively low lithium recoveries, water leaching of activated powder produced remarkably low concentrations of co-leached ionic impurities less than 10 ppm Mg, 20 ppm Ca, and 250 ppm K, compared to significantly higher concentrations observed during 1 M acid leaching (9422 ppm Mg, 564.5 Ca, and 72.5 ppm K, upon 1 M acid leaching, respectively). The presence of Mg ions, in particular, is known to be highly detrimental competing ion in metal recovery processes. Therefore, the proposed method offers both economic and environmental advantages by enabling higher purity lithium recovery under much milder conditions.
AtıfScopus1OpenAlex1İncele - MakaleAçık Erişim2026Scopus SJRQ1Influence of apple pomace and asparaginase on acrylamide levels in cookies and behavior during simulated gastric digestion: risk assessment perspectives
Sevim, Sumeyra; Macit, Arife; Farıa, Miguel A.; Viegas, Olga; Cunha, Sara C.; Kizil, Mevlude; Ferreira, Isabel M.P.L.V.O.
Cookies are widely consumed baked products; however, their contribution to dietary acrylamide (ACR) intake raises increasing health concerns. This study investigated the effects of apple pomace addition and asparaginase treatment on ACR levels in cookies, the fate of ACR during simulated gastric digestion using the INFOGEST semi-dynamic model, and the associated health risks of ACR exposure from cookie consumption. Risk assessment was conducted for adults (18–65 years) and children (3–10 years) using Monte Carlo simulation. Three formulations were evaluated: a control cookie, a cookie in which wheat flour was partially replaced with apple pomace, and a cookie containing asparaginase. Cookies formulated with apple pomace contained significantly lower ACR levels than the control (132 ± 8 μg/kg vs. 215 ± 11 μg/kg; p < 0.05), although the reduction was less pronounced than in cookies containing asparaginase (65 ± 14 μg/kg). During gastric digestion, ACR exhibited formulation-dependent release kinetics. Nevertheless, the total ACR released at the end of digestion was similar for control and pomace cookies, likely due to additional ACR formation in the stomach, despite differences in release patterns throughout digestion. Margin of Exposure (MOE) values for children remained well below 10,000, indicating a potential carcinogenic risk, although reductions of up to 59% were observed for control and pomace cookies after digestion. Target Hazard Quotient (THQ) values showed a slight increase after digestion in both age groups but remained below 1, suggesting no concern for chronic toxicity. Control cookies indicated a potential carcinogenic risk for children (ILCR = 1.56 × 10−4), whereas pomace and asparaginase formulations reduced this risk (ILCR = 9.59 × 10−5 and 4.72 × 10−5, respectively). However, simulated gastric digestion increased ILCR values for both control and pomace cookies (2.24 × 10−4 and 2.33 × 10−4, respectively). These findings indicate that dietary exposure to ACR cannot be assessed solely based on its concentration in food, and that digestive kinetics should be incorporated into health risk assessment.
- MakaleYalnız künye2026Scopus SJRQ1Computational fluid dynamics analysis of battery pack with cooling channel integrated with innovative thermoelectric cooling stations
Yardımcı, Uğurcan; Tuğan, Volkan
In this study, a novel liquid cooled battery thermal management system integrated with a thermoelectric assisted cooling channel has been designed. To prevent battery cells from operating at high temperatures and to ensure a uniform temperature distribution among the cells, multiple thermoelectric stations were placed at various positions along the cooling channel. The performance of four different models created with various temperature combinations, as well as a conventional model without thermoelectrics, was investigated through Computational Fluid Dynamics simulations. In the analyses, five different thermoelectric temperatures (293.15–298.15 K), two different mass flow rates (0.0013 and 0.0018 kg/s), and two different initial temperatures (298.15 and 303.15 K) were examined. The results demonstrated a significant improvement in the performance of the battery thermal management system with the use of the thermoelectric assisted cooling channel. It was determined that lowering the initial temperature from 303.15 K to 298.15 K and increasing the mass flow rate from 0.0013 kg/s to 0.0018 kg/s resulted in better cooling performance and more uniform distribution for the thermoelectric assisted system. Under the conditions of a 0.0013 kg/s mass flow rate and an initial temperature of 303.15 K, the highest reduction in maximum battery temperature, compared to the non-thermoelectric design, was achieved in Model B with 9.207 K. Under the same conditions, the most significant reduction in maximum temperature difference was observed in Model D with 4.758 K. Furthermore, the Root Mean Square Spread analysis results revealed that Model B provided the best performance in terms of temperature distribution.
AtıfScopus7WoS7OpenAlex10İncele - MakaleAçık Erişim2026Scopus SJRQ1Structural and radiation shielding properties of high-entropy rare-earth oxide-doped borosilicate glass
Güler, Ömer; Yılmaz, Demet; Kanca, Muhammed Sait; Kök, Mediha; Taşgın, Yahya
In this study, the incorporation of a high-entropy rare-earth oxide, (GdLaEuPrDyY)2O3 (RE-HEO), into a borosilicate glass matrix was investigated with the aim of improving radiation shielding performance while preserving the structural integrity of the glass. The RE-HEO was first synthesized by high-energy mechanical alloying and then introduced into the glass system at concentrations ranging from 0 to 8 wt% using a conventional melt-quenching process. The structural and microstructural properties of the prepared samples were examined using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy combined with energy-dispersive spectroscopy (SEM–EDS). The analyses confirmed that the amorphous nature of the borosilicate glass was maintained and that the rare-earth elements were homogeneously distributed within the matrix. The radiation shielding performance was evaluated experimentally using Am-241, Ba-133, and Ra-226 gamma sources, and supported by theoretical calculations of key parameters including mass attenuation coefficient (MAC), half-value layer (HVL), mean free path (MFP), effective atomic number (Zeff), exposure buildup factor (EBF), and fast neutron removal cross-section (ΣR). The results showed that increasing RE-HEO content leads to a noticeable improvement in gamma-ray attenuation. In particular, the sample containing 8 wt% RE-HEO exhibited a MAC value of 0.131 cm2/g and an HVL of 2.03 cm at 356 keV, indicating shielding performance comparable to that of conventional lead-containing glasses. In addition, irradiation tests performed using a Co-60 gamma source revealed that the amorphous structure remains stable after exposure. Overall, the findings suggest that RE-HEO-doped borosilicate glass can be considered a promising lead-free alternative for radiation shielding applications.
AtıfScopus1WoS1OpenAlex1İncele - MakaleAçık Erişim2026Scopus SJRQ2Radiation shielding performance of CeO2-reinforced ternary nanocomposites based on biodegradable polymers and waste-derived polystyrene
Pekdemir, Mustafa Ersin; Yilmaz, Demet; Selçuk Pekdemir, Sibel; Gülhan, Aleyna; Yalçin Kuzu, Serpil; Altun, Sedanur; Taşgin, Yahya
The development of sustainable polymer-based materials for radiation shielding has attracted increasing interest, particularly for lightweight and flexible applications. In this study, ternary nanocomposites based on poly (hydroxyalkanoate) (PHA), poly (ε-caprolactone) (PCL), and polystyrene (PS) were prepared and reinforced with cerium oxide (CeO2) nanoparticles (5–15 wt%) to enhance radiation shielding performance. Structural characterization confirmed the preservation of polymer chemical structures and the successful incorporation of crystalline CeO2, while SEM observations revealed a relatively homogeneous nanoparticle dispersion within the ternary matrix, particularly at intermediate filler loadings. Thermal analysis demonstrated enhanced thermal stability with increasing CeO2 content, as evidenced by an increase in residual mass from 0.42% for the neat blend to 11.21% for the nanocomposite containing 15 wt% CeO2, along with a shift of degradation onset temperatures toward higher values. Photon shielding performance was experimentally evaluated in the energy range of 13.37–59.54 keV. The incorporation of 15 wt% CeO2 increased the mass attenuation coefficient (MAC) from 1.277 to 12.366 cm2 g−1 at 13.37 keV, corresponding to an approximately ninefold enhancement, while significantly reducing the half-value layer (HVL) and mean free path (MFP). Neutron shielding analysis showed a slight decrease in thermal neutron attenuation due to hydrogen dilution within the polymer matrix, whereas fast neutron attenuation and neutron removal cross sections exhibited only minor variations; the fast neutron removal cross section increased modestly from 0.1014 to 0.1047 cm−1 with 15 wt% CeO2 addition. Overall, the results highlight clear structure–property–performance relationships in CeO2-reinforced PHA/PCL/PS nanocomposites, demonstrating their potential as lightweight radiation shielding materials for low energy protection with improved thermal stability and shielding efficiency.
AtıfScopus2OpenAlex1İncele - MakaleYalnız künye2026Scopus SJRQ2Comprehensive Characterization of Nano-Eu2O3 Reinforced Borotellurite Glasses: Synthesis, Physical, Structural, and Gamma and Neutron Attenuation Properties
Durmus, Hasan; Kilic, Gökhan; Ilik, E.; Kavaz, Erkan; Güler, Ömer; Birdoğan, Selcuk; Almisned, Ghada; Tekin, Hüseyin Ozan
This study presents a systematic investigation of lithium borotellurite glasses reinforced with nano-Eu2O3, with the aim to enhance the structural stability and radiation shielding performance. Glasses were synthesized with Eu2O3 concentrations from 0 to 10 mol % and characterized through density, X-ray diffraction, and transmission electron microscopy. The results showed that the density increased steadily from 4.030 to 4.734 g/cm3 with the Eu addition, while the molar volume also expanded, indicating that the incorporation of larger Eu3+ ions induced network expansion alongside densification. The X-ray diffraction patterns showed amorphous structures for all the compositions except Eu(n)2, which exhibited local crystallinity, later suppressed at higher Eu levels. The transmission electron microscopy pictures and energy dispersive spectroscopy mapping showed homogeneous nanoparticle distribution without clustering. Gamma-ray attenuation studies demonstrated clear improvements with Eu doping: the linear attenuation coefficient increased from 8.33 cm−1 (Eu(n)0) to 12.42 cm−1 (Eu(n)10) at 81 keV, while the half-value layer values decreased, confirming superior low-energy absorption. Experimental neutron studies revealed ΣR values comparable to standard neutron moderators, with Eu(n)10 showing a favorable balance of gamma and neutron shielding. Limitations include the restricted photon energy window and single neutron source. Future work should extend testing to higher energies, thermal/epithermal neutron ranges, and mechanical and durability assessments. Overall, nano-Eu2O3 reinforcement provides a promising pathway toward multifunctional transparent shielding glasses.
- MakaleAçık Erişim2026Scopus SJRQ1Investigation of the structural, thermal and radiation shielding properties of (Er0.2Yb0.2Sm0.2La0.2Eu0.2)2Zr2O7 high entropy oxide reinforced tin matrix composite
Güler, Ömer; Yılmaz, Demet; Kanca, M. Sait; Kök, Mediha; Güler, Seval Hale; Taşgın, Yahya
This study investigates the structural, thermal, and radiation shielding properties of (Er0.2Yb0.2Sm0.2La0.2Eu0.2)2Zr2O7 high entropy oxide (HEO) reinforced tin (Sn) matrix composites. In the first stage of the study, HEO powders were synthesized by grinding at 350 rpm for 30 h using a solid-state method with mechanical alloying assistance, and then calcining at 1100 °C for 8 h. In the second stage, composites were produced by mixing HEO-reinforced Sn matrix materials containing 1%, 5%, and 10% reinforcement, pelleting them under 200 MPa pressure, and then sintering them at 300 °C for 3 h. In the first stage of the study, (Er0.2Yb0.2Sm0.2La0.2Eu0.2)2Zr2O7 HEO powders were synthesized using a mechanical alloying-assisted solid-state route. In the second stage, HEO-reinforced Sn matrix composites containing 1 wt%, 5 wt%, and 10 wt% reinforcement were produced. The phase formation and crystallographic structure of the synthesized powders and composites were characterized using X-ray diffraction. Thermal behavior and phase stability were investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The thermal analysis results revealed dehydration and structural stabilization processes at intermediate temperatures, while crystallization of the HEO phase was observed at elevated temperatures. In addition, oxidation behavior of the Sn matrix composites was evaluated, showing that the presence of HEO particles significantly suppresses mass gain during high-temperature oxidation, indicating improved thermal stability. Finally, the radiation shielding performance of the samples was experimentally evaluated within the photon energy range of 59.54–609.2 keV using Am-241, Ba-133, and Ra-226 radioactive sources together with a Ultra-Low Energy Germanium (ULEGe) detector. The results demonstrate that the incorporation of HEO particles leads to minor, energy-dependent variations in the radiation attenuation capability of the tin matrix, influenced by the presence of high atomic number rare-earth elements and modified microstructural characteristics. The gamma radiation protection coefficient (RPC) values indicate strong attenuation in the low photon energy region, decreasing to approximately 16–19% at 609.3 keV. Moreover, the measured neutron equivalent dose rates increase from 0.054 µSv/h for pure Sn to 0.285 µSv/h for the Sn–10%HEO composite, indicating that HEO incorporation modifies the neutron interaction behavior of the Sn matrix composites.