Sürdürülebilir Kalkınma Amaçları
Yazarlar
- Gul, Muhammet(74)
- Akkurt, Nevzat(39)
- Celik, Erkan(35)
- Serdar, Osman(35)
- Güler, Ömer(33)
- Kutlu, Banu(32)
- Paksoy, Mehmet Yavuz(32)
- Yucesan, Melih(31)
- Tekin, H.O.(30)
- Yildirim, Numan(30)
- Yildirim, Nuran Cikcikoglu(30)
- ALMisned, Ghada(28)
- Mete, Suleyman(26)
- Danabas, Durali(20)
- Ince, Muharrem(20)
- Serin, Faruk(20)
- Ates, Mehmet(19)
- Can, Erkan(19)
- Onat, Onur(18)
- Benzer, Fulya(17)
- Kocabaş, Mehmet(17)
- Tanyol, Mehtap(17)
- Kizak, Volkan(16)
- Alataş, Mevlüt(15)
- Aydin, Rahmi(15)
- Kahraman, Gökhan(15)
- Kilic, G.(15)
- Polat, Alper(15)
- Susam, Selim Orhun(15)
- Xu, Qian(15)
- Aslan, Naim(14)
- Guler, Omer(14)
- Gürler, Nedim(14)
- Karatay, Gülnaz(14)
- Utku, Anıl(14)
- Yildirim, N. C.(14)
- Özkul, İskender(14)
- Demirol, Ferhat(13)
- Erguven, Gokhan Onder(13)
- Firat, Erhan(13)
Yayınlar
- MakaleYalnız künye2026Scopus SJRQ3Sequence Analysis and Genetic Diversity of ndhF of the Chloroplast DNA (cpDNA) of Chrysophthalmum (Asteraceae) Species in Türkiye
Sevindik, Emre; Gelir, Seda Nur; Demircan, Şelale; Çiftçi, İbrahim; Paksoy, Mehmet Yavuz
Absract: In this study, chloroplast DNA (cpDNA) ndhF sequence analysis was used to determine the sequence analysis and genetic diversity of Chrysophthalmum Schultz Bip. species distributed in Türkiye. Genomic DNA was isolated from green leaves and cpDNA ndhF region was amplified by PCR. The results of the PCR, the forward and reverse sequences were edited using the Sequencher 5.4.6 programme and the contig sequences were obtained. To determine the phylogenetic relationships between species, MEGA 6.0 was used to construct a maximum likelihood (ML) tree. Using the same program, nucleotide composition, phylogenetic trees, genetic distance matrix, and genetic diversity analyses were performed. In addition, the physicochemical properties and 3D structure of ndhF proteins were determined. From the results of the ndhF analyses, the nucleotide length of Chrysophthalmum species was found to vary between 471 and 625. The genetic matrix value was determined to be between 0.000 and 0.009. In the phylogenetic tree constructed using ndhF sequences from Anvillea DC., Pulicaria Gaertn., Limbarda Adans, Inula L., Carpesium L., Pentanema Cass., Dittrichia Greuter, Rhanteriopsis Rauschert and Telekia Baumg species from NCBI, C. montanum was grouped with Inula, Pentanema and Rhanteriopsis species. C. gueneri was grouped with C. dichotomum and Pentanema alanyense. Previous phylogenetic studies were in agreement with our results. In addition, the ndhF results supported that Chrysophthalmum species are not a monophyletic group.
AtıfWoS1
İncele - MakaleYayıncıda açık erişim2026Scopus SJRQ1Phenolic Profiling of Some Bryophyte Species: In Vitro and In Silico Assessment of Their Antimicrobial Potentials
Çambay, Zafer; Uslu, Harun; Coteli, Ebru; Göktaş, Bünyamin; Özdemir Bayçinar, Kevser; Emre, Mustafa Yunus; Güngören, Muhammed; Alataş, Mevlüt
This study explores the phytochemical composition and antimicrobial potential of Palustriella commutata, Philonotis calcarea, Cinclidotus riparius, Rhynchostegium riparioides, Plagiomnium ellipticum, and Porella platyphylla, with a focus on bryophyte species phenolic constituents and biological activities. HPLC analysis identified seven phenolic acids (4-hydroxybenzoic acid, 2,5-dihydroxybenzoic acid, 3,4-dihydroxybenzoic acid, caffeic acid, vanillic acid, syringic acid, and p-coumaric acid) across all species in varying concentrations. In in vitro antimicrobial tests, the bryophyte extracts used showed significant activity against Pseudomonas aeruginosa (ATCC 9027), while exhibiting relatively lower inhibition against Staphylococcus aureus (ATCC 25923). The study showed that all species extracts exhibited comparable activity to erythromycin against P. aeruginosa, while Cinclidotus riparius and Plagiomnium ellipticum extracts showed no activity against S. aureus, and the remaining species exhibited lower activity compared to erythromycin. Molecular docking studies demonstrated strong binding affinities of these phenolics to the active site of the target macromolecule (PDB ID: 3FRQ), suggesting meaningful interactions with residues such as ARG122 and ASN123, similar to erythromycin binding patterns. The findings indicate that bryophyte-derived phenolic compounds possess significant antimicrobial potential and may serve as promising candidates for the development of novel bioactive agents. This study provides a broad framework for the insufficiently researched antimicrobial potential of bryophytes by establishing direct links between species-specific phenolic fingerprints, experimentally observed antibacterial activities, and predicted receptor-level interactions. Further complementary biological studies are needed to confirm and expand upon these results.
- MakaleYalnız künye2026Scopus SJRQ2Influence of Boron Addition on the Microstructure, Mechanical, and Corrosion Behavior of NiCrBSi Alloys Prepared by Spark Plasma Sintering
Çelik, Ertuğrul
This study investigates the effect of boron addition on the microstructural, mechanical, and corrosion properties of NiCrBSi alloy fabricated by the spark plasma sintering (SPS) method. Boron was added at levels of 1.5, 3, and 4.5 wt.%, and sintering was conducted at 950 °C for 5 min. Microstructural characterization was carried out using SEM–EDS and XRD analyses, hardness was measured by the Vickers method, and densities were determined according to Archimedes’ principle. The transverse rupture strength (TRS) was obtained by three-point bending tests, while wear performance was evaluated in a reciprocating wear mode. Corrosion behavior was examined through potentiodynamic polarization in a 0.1 M HCl solution. Increasing boron content promoted the formation of nickel and chromium boride phases, enhancing hardness (up to 675 HV0.5) and wear resistance but reducing TRS values due to brittle intermetallic formation. Furthermore, corrosion protection efficiency improved, reaching about 65.9% at 4.5 wt.% B addition.
- MakaleYalnız künye2026Scopus SJRQ1Regionalized Bayesian site amplification models for Türkiye
İçen, Abdullah
Accurate representation of site amplification is essential for seismic hazard analysis, particularly in regions with complex geological structure. This study develops a Bayesian hierarchical site amplification model that captures nonlinear, period-dependent, and regionally variable behavior using an extensive strong-motion dataset from Türkiye. The model employs a piecewise VS30 functional form derived from nonparametric scaling and clustering, and incorporates nonlinear scaling with reference rock motion intensity (PSArock). Regional variability is introduced through random-slope adjustments, enabling spatial differences in amplification to be represented while maintaining statistical stability through partial pooling. Results indicate pronounced nonlinear and regional variability for soft soils and reduced regional differences for stiff sites (VS30 > 600 m/s). A key observation is a systematic amplification peak within the 400–550 m/s velocity range, where the model exhibits consistent underprediction across periods. Because this feature persisted even for stations located on flat basin interiors, a detailed investigation of stations in this VS30 interval was conducted and is presented in the study. Mapping and site-specific examination reveal that many of these stations are located near slope breaks, basin edges, or transitional geological settings, suggesting that 2D/3D wave-propagation or impedance-transition effects—rather than VS30 alone—may drive the increase in the amplification. Additionally, residual underprediction persists at high-VS30 rock sites, highlighting the need for improved empirical characterization of stiff-soil and rock conditions. Overall, the proposed Bayesian framework provides a flexible, data-driven, and uncertainty-aware approach for modeling site amplification, with direct applications in probabilistic seismic hazard analysis and performance-based earthquake engineering.
AtıfOpenAlex1İncele - MakaleYalnız künye2026Scopus SJRQ2Structural evolution and dual γ–neutron shielding performance of nano-Gd2O3 reinforced lithium borotellurite glasses
Durmus, Hasan; Kilic, G.; Ilik, E.; Kavaz, E.; Güler, Ömer; Birdogan, Selcuk; ALMisned, Ghada; Tekin, H.O.
This study investigates the structural, physical, and radiation-shielding properties of nano-Gd2O3-reinforced lithium borotellurite glasses with the composition 50TeO2-30B2O3-(20-x)Li2O-xGd2O3 (x= 0-10 mol %). X-ray diffraction and transmission electron microscopy confirmed the fully amorphous nature of the glasses and the homogeneous distribution of nanoscale Gd clusters. Density increased from 4.03 to 4.77 g/cm3, accompanied by compositional shifts, decreasing boron and increasing oxygen and tellurium contents, indicating enhanced structural compactness and electron density. Gamma-ray attenuation measurements revealed a 74 % increase in the linear attenuation coefficient from 8.33 to 14.53 cm−1 at 81 keV and a nearly 27 % reduction in the half-value layer from 1.21 to 0.89 cm. Effective atomic number values remained highest for Gd(n)10 across the photon energy range investigated. Experimental neutron dose measurements showed absorption improvements from 37.66 % to 51.91 %, while the effective removal cross-section increased from 0.1066 to 0.1096 cm−1, outperforming water, B4C, and graphite. Compared with the Gd-doped zinc borotellurite glasses reported in the literature, the present lithium-based system exhibited higher densification and superior dual γ-neutron attenuation. These results demonstrate that controlled nano-Gd2O3 integration into the lithium borotellurite matrix yields a stable, lead-free amorphous material with outstanding radiation-shielding efficiency for advanced photonic and nuclear applications.
AtıfScopus3OpenAlex3İncele - MakaleYalnız künye2026Scopus SJRQ2Institutions, gendered informality, and intrahousehold distribution: A dual-economy model
Ateş-Saygılı, Çiğdem
We study how enforcement institutions shape formalization and the intrahousehold distribution of resources in a developing economy. The model combines an enforcement wedge inside informal technology, gendered formal-attachment margins, and a collective household with a state-dependent female Pareto weight. In the benchmark wage-responsive specification, enforcement raises formalization by compressing informal wages and reallocating work toward formal jobs. Yet aggregate formalization and women's intrahousehold gains need not move together. When women are more exposed to informality and men convert the induced formal-to-informal wage ratio into formal attachment more strongly in level terms, enforcement can lower women's relative earnings, relative formal status, the female Pareto weight, and the consumption ratio during adjustment. An exact effective-access transition and local calculations for the effective-access and reduced-form labor-disutility margins show that this adverse incidence can be offset within the model while preserving formalization gains. Descriptive quarterly evidence for Türkiye documents gendered dynamics in non-agricultural social-security non-registration around salient macroeconomic and institutional episodes. The empirical evidence motivates the labor-market exposure and access channels but does not observe household bargaining or individual consumption.
- MakaleYayıncıda açık erişim2026Scopus SJRQ1Thematic Structure of Pedagogical Agent Studies: LDA Analysis for the Period 2020–2025
Turgut, Yigit Emrah; Aktı Aslan, Seda; Kopuz, Tuba; Aslan, Alper; Allison, Jordan; Özyurt, Özcan
This study examines 2,360 pedagogical agent (PA) articles published between 2020 and 2025 to identify thematic structures, trends, and research gaps through bibliometric analysis and LDA-based topic modeling. The optimal model produced 10 themes (c_v = 0.4767). The dominant themes—Learner Interaction with Virtual Assistants in Education, Student-Centred Learning and Individual Guidance, and NLP Foundations for Pedagogical Agents—account for 51.3% of publications. Trend analyses revealed consistent growth in both Artificial Intelligence and Pedagogical Design in Education and NLP Foundations for Pedagogical Agents, while Learner Interaction with Virtual Assistants in Education reached saturation. Interaction network results showed these themes at the conceptual core of the field, whereas AI-Driven Medical Chatbots, Knowledge-Based Learning Models, and Student Experiences in Intelligent Learning Environments emerged as future research areas. Overall, findings highlight a strong thematic shift toward artificial intelligence, natural language processing, and student-centered learning.
- MakaleYalnız künye2026Scopus SJRQ2Synthesis of Aminothiophene derivative complexes and electrochemical sensor application for carbofuran pesticide
Taş, Abdurrahim; İpek, Yeliz; Adiguzel, Ragip
In this study, a ligand named 2-amino-6-ethyl-4,5,6,7-tetrahydrothieno[2,3-c]pyridine-3‑carbonitrile (ATL), which is an aminothiophene ligand, was synthesized. ATL was used to synthesize ATL-Co(II), ATL-Cu(II), and ATL-Zn(II) complexes. The chemical structures of the complexes were elucidated by spectroscopic methods such as FT-IR, UV–visible, and LC-MS analysis, as well as TG-DTA analysis, magnetic susceptibility measurements, and elemental analysis. Finally, the electrochemical characterization of ATL and the electrochemical sensor application of its complexes was performed. In electrochemical sensor studies, a carbofuran pesticide sensor application was investigated. ATL exhibited an irreversible oxidation peak around 1.0 V. It was observed that ATL-Co(II), ATL-Cu(II), and ATL-Zn(II) complexes behaved similarly to ATL and exhibited an irreversible oxidation peak at the same potential. Carbofuran pesticide was added to the sensor medium using the standard addition method. The changes in peak current with different carbofuran concentrations constituted the data of the amperometric sensor application, and the changes in the peak potential constituted the data of the voltammetric sensor application. Linear working ranges, LOD, and LOQ values were calculated for ATL, ATL-Co(II), ATL-Cu(II), and ATL-Zn(II) complexes, separately. The widest operating range as a voltammetric sensor was achieved with the ATL: 20 μmol L−1 to 350 μmol L−1. The lowest LOD and LOQ values were achieved with the ATL-Co(II) complex for voltammetric detection as 8.8 μmol L−1 and 29.2 μmol L−1, respectively. The lowest LOD and LOQ values were achieved with the ATL-Co(II) complex as 1.6 μmol L−1 and 5.2 μmol L−1 with the amperometric technique, respectively.
- MakaleYalnız künye2026Scopus SJRQ3Analytical Solution of Discontinuous Contact Problem in Functionally Graded Layer and Homogeneous Layer
Kaya, Yusuf; Polat, Alper; Şükrü Özşahin, Talat; Bora, Pınar
In the study, the problem of discontinuous contact in two layers, one of which is functionally graded is solved using the theory of elasticity. In this problem functionally graded (FG) layer resting on homogeneous layer and loaded with two different rigid flat blocks. In addition, homogeneous layer is resting on a rigid plane. Frictions on all surfaces are neglected. The heights of the FG layer and the homogeneous layer are h1 and h2, respectively. When solving the problem, displacement and stress equations are substituted in the boundary conditions. Then the problem is demained to singular integral equations. Wherein unknown functions are the contact stresses under the two rigid flat blocks and the slope of the separation. These singular integral equations are solved numerically using the Gauss- Chebyshev integration formulas. The analyzes were performed for different inhomogeneity parameter (βh1), shear modulus ratio (μ2/μ-h1). distance between the rigid blocks ((a3-a2)/h1) and density parameter (γh1). Consequently, the stress distributions and starting and ending points of the separation area between the FG layer and homogeneous layer are determined for several dimensionless quantities.
- MakaleYalnız künye2026Scopus SJRQ1Assessment of microstructure and tribological performance of ZrO2-reinforced MAO coatings on 7075 aluminum alloy using grey relational analysis
Yıldıztaş, Mesut; Ayday, Aysun; Candan, Gökçe; Duru, Erhan; Doğan, Fatih
In this study, micro-arc oxidation (MAO) coatings containing different concentrations of ZrO2 were fabricated on 7075 Al alloy in a silicate-based electrolyte to evaluate their microstructural evolution, surface characteristics, and tribological performance. The coatings were produced at 390 V for 30 min in an electrolyte containing 10 g/L Na2SiO3 with ZrO2 additions of 0, 3, 6, and 9 g/L. Surface and cross-sectional morphologies were examined by SEM/EDS, while surface topography and wear track profiles were characterized by profilometry. Tribological behavior was evaluated under dry sliding conditions using a reciprocating tribometer. The results revealed that ZrO2 incorporation markedly influenced the coating growth behavior and surface morphology. The Zr0-MAO coating exhibited a rough and porous structure with large discharge channels, whereas the addition of ZrO2 led to a more compact and homogeneous morphology with reduced porosity. Among the coated samples, Zr6-MAO exhibited the most refined microstructure and the lowest surface roughness (Ra = 4.24 µm). This sample also showed the best tribological performance, with the lowest coefficient of friction (0.27), wear volume (0.0065 mm3), and wear rate (1.63 × 10−4 mm3/N·m). To provide a comprehensive multi-criteria assessment, grey relational analysis (GRA) was employed by simultaneously considering coating thickness, surface roughness, friction coefficient, wear volume, and wear rate. The GRA results were consistent with the experimental findings and identified Zr6-MAO as the optimum coating condition. These findings demonstrate that a moderate ZrO2 addition is highly effective in improving the compactness and wear resistance of MAO-coated 7075 Al alloy.
- MakaleYalnız künye2026Scopus SJRQ2Correlative Investigation on physical, microstructure, magnetism, and gamma-neutron attenuation properties of mechanically alloyed multifunctional (Fe/Co/Ni)Nb10V10B10 soft magnetic alloy systems
Simsek, Tuncay; Simsek, Telem; Chattopadhyay, Arun K.; Avar, Barış; Yakin, Alican; Guler, Seval Hale; Almisned, Ghada; Sen Baykal, Duygu; Tekin, H.O.
In this study, mechanically alloyed Fe70Nb10V10B10, Co70Nb10V10B10, Ni70Nb10V10B10, and (FeCoNi) 70Nb10V10B10 high-entropy alloys were successfully synthesized, and their structural, magnetic, and radiation shielding properties were systematically investigated. Structural analysis revealed that Fe favored bcc phase formation, while Co and Ni stabilized fcc structures; the equiatomic alloy resulted in a single-phase fcc solid solution with the smallest crystallite size (2.1 nm). All samples exhibited soft ferromagnetic behavior, with the Fe-based alloy achieving the highest saturation magnetization (120 emu/g), and the (FeCoNi) 70Nb10V10B10 alloy displaying the lowest coercivity. Among all compositions, Co70Nb10V10B10 demonstrated the best gamma and neutron shielding performance, showing the highest linear attenuation coefficient and fast neutron removal cross-section. The equiatomic alloy also exhibited well-balanced and stable shielding behavior. These findings position Co70Nb10V10B10 as a promising candidate for multifunctional applications requiring both efficient radiation protection and favorable magnetic properties.
AtıfScopus1İncele - MakaleYalnız künye2026Scopus SJRQ1Oxidative Polycondensation of Pyrazolone-Based Schiff Bases: Synthesis, Structural Characterization, Thermal and Electrical Properties
Solmaz, Adnan; Çakmak, Reşit; Kaya, İsmet
Schiff base derivatives, namely 3-(((2-hydroxynaphthalen-1-yl)methylene)amino)-1-phenyl-1-pyrazole-5-one (3-APPHNA) and 4-(((2-hydroxynaphthalen-1-yl)methylene)amino)-1,5-dimethyl-2-phenyl-1H-pyrazol-3-one (4-APPHNA), were synthesized via the condensation reaction of 3-amino-1-phenyl-2-pyrazolin-5-one (3-APP) and 4-amino-2,3-dimethyl-1-phenyl-3-pyrazolin-5-one, (4-APP) with 2-hydroxynaphthaldehyde (2-HNA) in ethanol. Synthesized monomers were then converted into their oligomeric derivatives via oxidative polycondensation carried out using NaOCl. The structural, thermal, optical, electrochemical, and morphological properties of the obtained monomers were comprehensively characterized using fourier transform infrared (FT-IR), proton nuclear magnetic resonance (1H-NMR), carbon-13 nuclear magnetic resonance (13C-NMR), ultraviolet-visible spectrophotometer (UV–vis), thermogravimetry-derivative thermogravimetry (TG-DTG), and cyclic voltammetric analyses. Spectroscopic studies confirmed the successful synthesis of Schiff bases and the presence of stable azomethine bonds. Molecular weight, glass transition temperature, and surface morphologies of oligomers were determined by gel permeation chromatography (GPC), differential scanning calorimetry (DSC), and field emission scanning electron microscope (FE-SEM) measurements, respectively. The Mn values of oligo(3-APPHNA) and oligo(4-APPHNA) were found to be 3400 and 2900 Da, respectively. The results revealed an oxidative oligomerization process yielding relatively narrow molecular weight distributions. Oligo(4-APPHNA) has shown more pronounced semiconductor properties compared to other oligomers, considering its 2.30 eV optical band gap and frequency-dependent electrical behavior. Additionally, dielectric measurements showed that oligo(4-APPHNA) exhibited higher dielectric constant, dielectric loss, and AC conductivity values throughout the investigated frequency range. These findings suggest that the synthesized oligomers are promising candidate materials for future optoelectronic and semiconductor applications, but further research at the device level is needed.
- MakaleYalnız künye2026Scopus SJRQ2A Parametric Study on a Thermoelectric-Integrated Battery Thermal Management System for Electric Vehicles: New Designs Utilizing Different Numbers of Thermoelectric Modules
Tuğan, Volkan
The safety, lifespan, and performance of battery systems in electric vehicles directly depend on the implementation of an effective thermal management strategy. In this study, a novel lithium-ion battery thermal management system integrated with a wavy cooling channel and different numbers of thermoelectric modules is proposed. Computational fluid dynamics-based numerical simulations were conducted at two ambient temperatures (298.15 K and 303.15 K) and three different thermoelectric temperatures (288.15 K, 293.15 K, and 298.15 K). Three configurations with four, six, and eight thermoelectric modules were analyzed and compared with the conventional case without thermoelectrics. The lowest maximum battery temperature was obtained with the design employing eight thermoelectric modules under the conditions of 298.15 K ambient temperature and 288.15 K thermoelectric temperature. It was found that integrating thermoelectrics into the battery thermal management system reduced the maximum battery temperature by up to 12.11 K and the maximum temperature difference by up to 5.83 K. Furthermore, maintaining the thermoelectric temperature approximately 5–10 K below the ambient temperature was identified as a critical design parameter to ensure both efficient cooling and thermal homogeneity. The use of different numbers of thermoelectric modules and the selection of appropriate operating temperatures were shown to play a decisive role in optimizing system performance.
- Derleme MakaleYalnız künye2026Scopus SJRQ1Assessing the Impact of Climate Change on the Sustainability of Sorghum Production: A Bibliometric Analysis
Zheng, Mingke; Tutar, Halit; Shaghaleh, Hiba; Alhaj Hamoud, Yousef; Er, Hasan; Omac, Basri; Yildirim, Gokhan; Eren, Ömer; Khalifa, Muhammad; Mwamahonje, Andekelile
Sorghum is a crucial crop for sustainable agriculture due to its drought resistance, low carbon footprint, and diverse applications in food, feed, and bioenergy. However, understanding the impact of climate change on sorghum production is essential for ensuring its future sustainability. This study conducts a comprehensive bibliometric analysis of scientific publications related to sorghum and climate change using the Web of Science (WoS) database, covering the period from 1984 to 2024. A total of 1053 relevant papers were analyzed, revealing an average annual growth rate of 12.73% and an average citation count of 32.02 per document. Most of the publications (83.5%) were research articles, while 9.7% were review papers. Among the contributing researchers, Prasad PVV emerged as the most productive author based on an h-index of 13, whereas the United States was identified as the most influential country, contributing 235 documents and 13,750 citations. Keyword clustering analysis identified five major research themes, including sustainable energy and environmental impacts, climate resilience, socioeconomic effects of climate change, and key crops. The findings of this study offer valuable scientific insights to guide future research and policymaking on climate change and sorghum sustainability.
AtıfScopus4OpenAlex3İncele - MakaleYalnız künye2026Scopus SJRQ3Optimization and Modeling of Brilliant Yellow Removal Via Neodymium-Infused Polymeric Hydrogel: A Central Composite Design Study
Pıhtılı Yıldız, Güzin; Tanyol, Mehtap; Demir, Ferhat
This study investigates the adsorption performance of a neodymium (III)-reinforced Poly(acrylamide-co-N-vinylimidazole) hydrogel composite [P(AAm-co-NVI)/Nd3+] for the removal of brilliant yellow (BY) dye from aqueous media. The hydrogel structure and metal–polymer interactions were characterized using FT-IR, TGA, SEM, and XRD analyses. The adsorption process was systematically optimized using a central composite design (CCD) approach combined with response surface methodology (RSM). The CCD-RSM second-order model exhibited a good fit to the experimental data (R2 = 0.9350), as supported by ANOVA. Numerical optimization revealed a maximum removal efficiency of 99.13% at a hydrogel dosage of 0.08 g/100 mL, an initial BY concentration of 81.68 mg/L, and a contact time of 61.73 min. Langmuir and the Freundlich isotherms were used in modeling the adsorption data. When the correlation coefficients of both models were compared, it was observed that the Langmuir isotherm provided a better fit for adsorption. The enhanced adsorption performance is attributed to the presence of Nd3+ ions, which promote additional electrostatic interactions and coordination sites between the hydrogel matrix and anionic dye molecules. The results demonstrate that Nd3+-reinforced hydrogels can serve as efficient and tunable adsorbent systems, particularly when process parameters are optimized statistically.
AtıfScopus1WoS1OpenAlex1İncele - MakaleYalnız künye2026Scopus SJRQ1Thermodynamic assessment of an equiatomic FeNiCoCrMn precursor for a spinel high-entropy oxide produced via mechano-oxidation with structure–radiation interaction correlation
Güler, Ömer; Güler, Seval Hale; Özkul, İskender; ALMisned, Ghada; Sen Baykal, Duygu; Tekin, H.O.
Spinel high-entropy oxides (HEOs) can stabilize multiple transition-metal cations within a single lattice, yet their radiation-interaction behavior is scarcely explored. Here, a (FeNiCoCrMn)3O4 spinel HEO was produced via an alloy-to-oxide route: 40 h mechanical alloying of equiatomic FeNiCoCrMn powders followed by mechano-oxidation (1000 °C/3 h) and high-energy grinding. HEA-derived thermodynamic metrics were used to rationalize the stability of the equiatomic metallic precursor prior to mechano-oxidation, rather than to directly predict the formation of the final oxide phase. XRD evidenced progressive amorphization of the HEA and its conversion to a crystalline spinel oxide, while SEM–EDS confirmed homogeneous elemental distribution. XPS indicated a defect-rich, multivalent surface (Co2+/Co3+, Cr3+/Cr6+, Fe3+, mixed Mn states, Ni2+) with lattice oxygen and vacancy-related components. Moreover, the spinel oxide showed higher linear attenuation coefficients than 316L stainless steel, Inconel-718, and several lightweight Al-based entropy alloys, yielding lower HVL values, especially at low energies. Zeff exhibited the expected energy dependence and exceeded Al-dominant alloys across the spectrum. EBF/EABF at 1 and 40 mfp displayed Compton-region peaks and strong depth effects, consistent with attenuation behavior. It can be concluded that a (FeNiCoCrMn)3O4 spinel high-entropy oxide, produced via an alloy-to-oxide transformation route, exhibits structurally stable and compositionally homogeneous characteristics together with favorable gamma-ray attenuation behavior.
- MakaleYalnız künye2026Scopus SJRQ2Oxide Dispersion, Microstructure, and Functional Evolution in La2O3 Modified Cu-Al-Mn-Fe Shape Memory Alloys
Karaduman, Oktay; Doğan, Fatih; Dehghanpour, Heydar; Yüzüak, Gizem Durak; Yüzüak, Ercüment; Canbay, Canan Aksu
Cu-Al-Mn-Fe high-temperature shape memory alloys containing 0-1.0 wt.% La2O3 were fabricated by vacuum arc remelting to investigate oxide-dispersion effects on microstructure, martensitic transformation, wear, and corrosion behavior. XRD and SEM analyses revealed that low La2O3 additions (0.2-0.4 wt.%) promoted β1′ martensite refinement and enhanced crystallinity, while higher contents induced structural heterogeneity. The alloy with 0.4 wt.% La2O3 exhibited the highest transformation enthalpy (7.49 J g−1), reduced friction coefficient (~0.55), and the narrowest wear scar (~501 µm). Electrochemical tests in 3.5 wt.% NaCl showed a fivefold decrease in corrosion current density and increased charge-transfer resistance (2512 Ω cm2) for the same composition. Excessive La2O3 led to performance degradation due to particle agglomeration and interfacial defects. The results demonstrated that controlled La2O3 addition enabled microstructural refinement and multifunctional performance enhancement in Cu-based shape memory alloys.
- MakaleYalnız künye2026Scopus SJRQ2Damage diagnosis in CFRP/Al7075-T6 aeronautical structures using piezoelectric sensors: characterization and experimental monitoring
Gahlouz, Ibtissem; Guemmour, Mohamed Boutkhil; Chellil, Sadek; Chellil, Ahmed; Houari, Amin; Aribi, Chouaib; Polat, Alper; Adjout, Warda; Bey, Mohamed
Purpose – This study aims to design a damage detection and characterization system (targeting cracks and delamination) for aeronautical composite structures. Design/methodology/approach – This methodology relies on a multidisciplinary approach combining polymer-reinforced/metallic carbon fiber hybrid structures with an integrated network of PZT sensors. It leverages experimental data and employs advanced signal processing and imaging techniques to monitor structural integrity and assess the severity of damage. Findings – Verified experimental results confirm the method's reliability in real-life situations. Research limitations/implications – Research Limits: “The primary challenges involve signal processing complexity due to the hybrid nature of AL7075-T6 and CFRP materials, as well as the potential influence of environmental factors (temperature, pressure) on PZT sensor reliability”. Research Implications: “This work enables a shift toward condition-based maintenance, significantly reducing operational costs while enhancing structural safety and extending the service life of critical aerospace and maritime assets.” Practical implications – This study enables a shift from scheduled to real-time structural monitoring. There is a drastic reduction in inspection time and aircraft downtime. Monitoring the fatigue of hybrid AL/CFRP structures helps to safely extend their service life. The study helps in providing precise diagnostics to optimize repair strategies and minimize human error. Social implications – There is a drastic reduction of structural failure risks through early-stage damage detection. Cost savings in maintenance can lead to more affordable air travel for the general public. The study helps in promoting a circular economy by safely extending the lifespan of complex structures and reducing material waste and also in shifting maintenance roles toward high-tech data analysis and specialized software expertise. Originality/value – The study investigates the complex damage mechanics at the interface of AL7075-T6 and CFRP laminates and helps in combining PZT sensor networks with advanced imaging software for real-time damage characterization. Beyond mere detection, the system assesses “structural criticality, ” providing high-value diagnostic data for maintenance optimization and cost reduction.
- MakaleYalnız künye2026Scopus SJRQ1Mechanical and durability properties of sustainable alkali-activated mortars with ceramic insulator waste and andesite powder as partial substitutes for GBFS
Cemalgil, Selim; Yön, Merve Şahin; Dener, Murat; Karataş, Mehmet
This study explores the use of andesite powder (AP) and ceramic waste powder (CWP), derived from discarded electrical insulators, as supplementary precursors to ground granulated blast furnace slag (GBFS) in alkali-activated self-compacting mortars. The originality of the work lies in the combined utilization of these regionally sourced aluminosilicate wastes in binary and ternary binder systems, aiming to reduce GBFS dependency while ensuring adequate mechanical and durability performance. AP and CWP were used to replace GBFS at up to 50%, and the mixtures were evaluated for flowability, mechanical strength, density, porosity, water absorption, and capillary sorptivity. Durability was assessed through freeze–thaw cycling and high temperature exposure, and microstructural characteristics were examined using scanning electron microscope analysis. Results showed that while partial substitution with AP or CWP reduced compressive strength compared to the GBFS control, the incorporation of CWP in ternary systems partially compensated for the strength losses associated with AP. High temperature resistance improved markedly with increased CWP content; at 900°C, the 50% CWP mixture retained 44% of its original compressive strength, in contrast to 8% for the control. Although all mixtures containing waste exhibited reduced freeze–thaw resistance, mortars containing CWP exhibited superior performance compared to those with only AP. These findings highlight the potential of CWP, particularly in ternary systems, for developing sustainable alkali-activated mortars.
AtıfScopus16WoS14OpenAlex12İncele - MakaleYalnız künye2026Scopus SJRQ2Investigation of the effect of ultrasonic assisted milling and minimum quantity lubrication methods on the machinability of Hardox 500 steel
Dalgıç, Aras; Mahmat, Aybars
Hardox steel is widely used in agriculture, mining and transportation due to its mechanical properties such as high wear resistance, high impact resistance, high hardness, high durability and long life. The machinability of Hardox 500 is difficult as its high hardness and wear resistance lead to tool wear and low machining speed. Recently, various processing and cooling methods have been developed to increase machinability. Ultrasonic assisted milling (UAM), one of these methods, is a method used as an alternative to conventional milling (CM) in the milling of traditionally difficult-to-machine materials. In addition, minimum quantity lubrication (MQL) is a cooling method used to provide lubrication and cooling in the cutting area. In this study, the impacts of machining method, feed rate and spindle speed on cutting force, surface roughness and tool wear in milling of Hardox 500 steel were investigated. In the MQL method, mixtures with nano-sized SiC particles were obtained and applied to the cutting area. In the study, MQL reduced cutting forces by up to 19 %, surface roughness by 18 %, and tool wear by 30 % compared to dry machining, while UAM further decreased cutting forces by 17 %, surface roughness by 15 %, and tool wear by 12 % compared to CM. These results demonstrate that MQL and UAM significantly enhance machining performance over conventional and dry methods.
