Sürdürülebilir Kalkınma Amaçları
Yazarlar
- Bulut, Hasan(53)
- Baskonus, Haci Mehmet(52)
- Alataş, Mevlüt(39)
- Gul, Muhammet(39)
- Serdar, Osman(38)
- Güler, Ömer(37)
- Akkurt, Nevzat(31)
- Benzer, Fulya(30)
- Sulaiman, Tukur Abdulkadir(29)
- Yucesan, Melih(29)
- Zengin, Gokhan(29)
- Kocabaş, Mehmet(28)
- Topal, Murat(26)
- Batan, Nevzat(25)
- Kök, Mediha(25)
- Ezer, Tülay(24)
- Paksoy, Mehmet Yavuz(24)
- Yildirim, Ozal(23)
- Tekin, H.O.(22)
- Utku, Anıl(22)
- ALMisned, Ghada(21)
- Ince, Muharrem(21)
- Öbek, Erdal(21)
- Erten, Fusun(20)
- Aslan, Naim(19)
- Celik, Erkan(19)
- Yildirim, Numan(19)
- Cakilcioglu, Ugur(18)
- Dal, Murat(18)
- Dal, Nursel Alp(18)
- Sahin, Kazim(18)
- Özkaynak, Fatih(18)
- Aslan, Alper(17)
- Erata, Hüseyin(17)
- Orhan, Cemal(17)
- Ergen, Burhan(16)
- Tanyol, Mehtap(16)
- Demir, Yakup(15)
- Etli, Serkan(15)
- Işık, Erdem(15)
Yayınlar
- MakaleAçık Erişim2026Scopus SJRQ4Effectiveness of organic tomato (Solanum lycopersicum L.) extracts added to yeast Cell Culture against H2O2 Toxicity; [Eficácia de extratos de tomate orgânicos adicionados à cultivos de células de levadura contra la toxicidad por H2O2]
Gonayli, Selahattin; Temizer, Ibrahim Akin; Aydin, Sevinq; Kirmizikaya, Gorkem; Okutan, Tuba; Yilmaz, Okke$
Growing tomatoes in season and organically are an important factor in terms of carrying higher levels of antioxidant molecules. This study aimed to demonstrate the protective effect of extracts obtained from naturally grown tomatoes, which are widely used as food, against oxidative damage caused by hydrogen peroxide on yeast cells (Saccharomyces cerevisiae L.). Lipophilic vitamins, phytosterol content, gluathione and oxidised gluathione content were analyzed by Shimadzu brand high performance liquid chromatography, while fatty acid analysis was performed by Shimadzu GC 2010 Plus Gas Chromatography. Protein content was analyzed spectrophotometrically. The study groups were designed as control, hydrogen peroxide, tomato and tomato + hydrogen peroxide. In all groups added with hydrogen peroxide and tomato extract compared to the hydrogen peroxide group; it was observed that vitamin D2, α-Tocopherol, β-Sitosterol and Stigmasterol contents increased significantly. Again, it was observed that ergosterol level increased significantly in the D + hydrogen peroxide group compared to the hydrogen peroxide group. When the fatty acid analysis results were examined, it was determined that in all groups added to the cultured yeast with hydrogen peroxide and tomato extracts (except the B + hydrogen peroxide group), there were increases in 16:0, 16:1, n-7, 17:0, 17:1 and 18:0 fatty acid levels compared to the hydrogen peroxide group. On the other hand, when its effect on protein and gluathione levels was examined, more significant increases were determined in all groups with tomato extract addition compared to the hydrogen peroxide group. At the end of the study, it was observed that tomato extracts had positive effects against hydrogen peroxide toxicity in yeast cells, although at different levels in terms of fatty acid, vitamin and phytosterol contents.
- MakaleAçık Erişim2026Scopus SJRQ2Cadmium-induced changes in haemato-immunological, oxidative stress and antioxidant parameters of Cyprinus carpio: Protective role of curcumin
Pala, Ayşegül; Eroğlu, Mücahit; Mişe Yonar, Serpil; İspir, Ünal; Yonar, Muhammet Enis
This study examined the adverse effects of sublethal concentrations of cadmium (Cd) and the potential of curcumin (CUR) to mitigate Cd-induced toxicity. We administered 1.5 and 3 mg/L of Cd and 100 mg/kg of CUR to fish (Cyprinus carpio) separately and in combination over 14 days. At the end of the experiments, various haematological and immunological parameters, oxidative stress levels and antioxidant parameters of fish were measured, and the differences between the groups were evaluated. Simultaneous CUR treatment with Cd reversed the changes in haematological parameters in fish, increased immune responses, reduced oxidative stress and normalized the impaired antioxidant enzyme activities. In summary, our study showed that dietary supplementation with CUR may be an effective strategy to reduce the toxic effects of Cd in carp.
- MakaleAçık Erişim2026Scopus SJRQ2Electrochemical analysis of tetracycline in drug formulations with glutardialdehyde-Fe2O3 modified glassy carbon electrode
Koçak, Berna; İpek, Yeliz
In this study, a glutardialdehyde-Fe2O3 modified glassy carbon electrode (GA2–Fe2O3/GCE) was used as a sensor for the electrochemical analysis of tetracycline (TC) in drug formulations. The electrochemical behavior of TC on GA2-Fe2O3/GCE was investigated using cyclic voltammetry (CV), while the quantitative determination was performed via differential pulse voltammetry (DPV). After optimizing the experimental conditions, the linear working range, limit of (LOD) detection, and limit of quantification (LOQ) of the GA2-Fe2O3/GCE electrode developed for the electrochemical analysis of TC were found to be 1.0 × 10−6–2.0 × 10−5 M and 2.0 × 10−5–9.9 × 10−6 M; 4.78 × 10−7 M; 1.59 × 10−6 M, respectively. In the sensor application study conducted on a Tetra® Gensenta tablet to demonstrate the applicability of the developed method, the linear working range, LOD, and LOQ values of the sensor were found to be 1.0 × 10−6–14.8 × 10−5 M; 5.72 × 10−7 M and 1.74 × 10−6 M, respectively. The applicability of the method was demonstrated through tablet recovery studies, and the tablet recovery ratio was determined to be 100.94%.
- MakaleAçık Erişim2026Scopus SJRQ3Analysis of Visible Light Communication Performance in LOS Propagation Model with PSO-Cosh-Based Filter
Fethiye Merve, Kavak Imak; Fatmanur, Atar; Duygu, Kaya; Turgay, Kaya
Due to the increasing data transfer in wireless communication technologies, Visible Light Communication (VLC), one of the branches of wireless communication technology, is also developing within this framework. VLC holds an advantage over other communication branches in terms of energy efficiency, high bandwidth, and reliability. In this context, research on VLC-based Light Fidelity (Li-Fi) technology has gained momentum in recent years. In systems built with this Li-Fi technology, data is transmitted through an LED bulb, which is used for illumination. In this study, to analyze the performance of systems where data transmission is provided by VLC, the capacity to improve the shape of the transmitted signal is investigated using systems designed with different filtering techniques under LOS channel conditions. The main objective of this study is to demonstrate the improving effect of the proposed PSO-Cosh-based model on the shape of the transmitted signal compared with traditional filtering methods. In this way, in addition to IIR digital filtering techniques, the analysis of the filter coefficients obtained by optimizing the Cosh window function with Particle Swarm Optimization (PSO) demonstrates the originality of the study.
- MakaleAçık Erişim2026Scopus SJRQ1Thematic Evolution of Educational Technology Research: A Large-Scale Topic Modeling Perspective
Aslan, Alper; Aktı Aslan, Seda; Turgut, Yiğit Emrah; Allison, Jordan; Özyurt, Özcan
This study aims to reveal the thematic evolution of the educational technology field by analyzing 17,393 articles published between 2000 and 2024 in ten leading journals using the Latent Dirichlet Allocation (LDA) based topic modeling. Based on the analysis of title, abstract, and keywords, 20 themes were identified and grouped under seven broader meta-themes such as “Teacher Professional Competence and Technology Adoption”, “Digital and Disciplinary Literacy Development”, and “Immersive and Experiential Learning Technologies”. The model achieved its highest coherence at K = 20 (c_v = 0.4091), and the stability of the thematic structure was supported through additional runs with alternative hyperparameter configurations and expert validation. The findings show that there has been a significant increase in themes such as “Technology Integration”, “Teacher Roles in Online Learning Design”, and “Technology Acceptance and Self-Efficacy” in recent years. Temporal trend and growth analyses indicate that these themes will continue to shape the research landscape in the upcoming years. This holistic approach, which overcomes the contextual limitations of traditional bibliometric analysis, makes a significant contribution to the literature by mapping the last 25 years of scholarly accumulation in educational technology.
AtıfScopus2OpenAlex2
İncele - MakaleAçık Erişim2026Scopus SJRQ2Effect of Zinc Content on the Mechanical, Corrosion, Tribological and Electrical Properties of Spark Plasma-Sintered Copper/Graphene Composites
Özkaya, Serdar; Adabaş, Yaren; Çelebi, Müslim; Karabacak, Abdullah Hasan; Çelik, Ertuğrul
Copper-based hybrid metal matrix composites reinforced with graphene and zinc were developed to achieve a balanced combination of mechanical strength, corrosion resistance, wear performance, and electrical conductivity. In this study, Cu matrix composites containing a constant graphene content of 1 wt.% and varying Zn contents (0, 5, 10, and 15 wt.%) were fabricated through mechanical alloying followed by Spark Plasma Sintering (SPS). The effects of zinc content on microstructure, densification, hardness, corrosion behavior, tribological performance, and electrical conductivity were systematically investigated. Microstructural analyses revealed that the combined use of graphene and Zn significantly influenced grain refinement, interfacial stability, and densification behavior. The composite containing 10 wt.% Zn exhibited the highest relative density (~90.5%) and maximum hardness (62 HB), indicating an optimal reinforcement level. Corrosion tests conducted in 3.5 wt.% NaCl solution demonstrated that the 10 wt.% Zn composite showed the most noble corrosion potential and the lowest corrosion current density, which was attributed to reduced porosity and improved microstructural homogeneity. Tribological results confirmed that graphene contributed to a self-lubricating effect, while Zn enhanced load-bearing capacity, leading to improved wear resistance under increasing normal loads. Electrical conductivity measurements showed a gradual decrease with increasing Zn content, mainly due to solid-solution-induced electron scattering in the Cu matrix; however, the fixed graphene addition and effective SPS consolidation helped preserve conductive pathways, allowing all composites to retain acceptable conductivity levels. The results indicate that the hybrid Cu–graphene–Zn composites exhibit a balanced combination of mechanical, corrosion, tribological, and electrical properties, with 10 wt.% Zn emerging as the optimal composition.
AtıfScopus1WoS1OpenAlex1İncele - MakaleAçık Erişim2026Scopus SJRQ2Physical and gamma-ray shielding characteristics of Copper Matrix Refractory High Entropy Alloy Reinforced Composite: an extensive experimental and computational approach
Kuluöztürk, Zehra Nur; Kuluöztürk, Muhammed Fatih; Güler, Seval Hale; Doğru, Mahmut; Güler, Ömer
Refractory High Entropy Alloys (RHEAs) have become an attractive alternative for radiation shielding applications due to their high mechanical strength, thermal resistance, structural stability, and compositional diversity. In this study, Cu-based composites containing 0–20 wt% RHEAs were prepared, and the crystal structure, morphological properties, and radiation shielding performance of the synthesized Cu-RHEA were investigated experimentally and theoretically. Measurements were performed using a NaI(Tl) detector system with point sources of 133Ba, 137Cs, 22Na and 60Co emitting gamma energies in the range of 0.356–1.333 MeV. In addition, theoretical calculations were carried out using the FLUKA and Phy-X/PSD, showing good agreement with the experimental data. Linear attenuation coefficient (LAC) values were found to decrease with increasing photon energy and to increase with increasing RHEA content. In the 0.356–1.333 MeV energy range, the experimental LAC values ranged from 0.7599 to 0.3818 cm−1 for Cu-RHEA0 and from 0.9594 to 0.4221 cm−1 for Cu-RHEA20. At 0.662 MeV, the LAC value increased from 0.5426 cm−1 for Cu-RHEA0 to 0.6183 cm−1 for Cu-RHEA20. In terms of half-value layer (HVL), the Cu-RHEA20 sample exhibited a value of 0.729 cm at 0.356 MeV, approximately 20% lower than the 0.912 cm value of Cu-RHEA0. Compared with conventional shielding materials reported in the literature, the Cu-RHEA20 sample reached a maximum mass attenuation coefficient (MAC) of 76.279 cm2⋅g−1 at 0.015 MeV, demonstrating clear superiority over ordinary concrete with a value of 7.079 cm2⋅g−1. These findings demonstrate that increasing RHEA content improves gamma-ray attenuation performance, highlighting Cu-RHEA20 as a promising next-generation shielding material.
- MakaleAçık Erişim2026Scopus SJRQ1Pomological and Biochemical Properties of Rosehip (Rosa canina L.) Genotypes
Ertugrul, Edanur; Aglar, Erdal; Ozturk, Burhan; Tekin, Onur; Alan, Davut; Ates, Umut
Rosehip (Rosa canina L.) is an important wild fruit species valued for its high nutritional and functional properties, particularly its richness in vitamin C, phenolic compounds, and antioxidant activity. Despite the widespread natural distribution of rosehip in Türkiye, many local genetic resources remain insufficiently characterized, limiting their effective utilization in breeding, conservation, and cultivation programs. The present study was conducted to evaluate the morphological, pomological, and biochemical characteristics of naturally growing rosehip genotypes in the Central District of Tunceli and to identify superior genotypes with potential for future breeding and cultivation efforts. Ten rosehip genotypes collected from natural populations at altitudes ranging from 1178 to 1256 m were evaluated for fruit and seed characteristics, fruit color, soluble solids content, titratable acidity, vitamin C, phenolic compounds, flavonoids, anthocyanins, antioxidant activity, and organic acid composition. Significant differences were observed among genotypes for all examined traits. Fruit weight ranged from 1.00 to 1.81 g, soluble solids content from 45.40% to 51.90%, titratable acidity from 1.03% to 2.77%, and vitamin C content from 235.67 to 1126.30 mg/100 g. Total phenolic content, total flavonoid content, total monomeric anthocyanin content, FRAP, and DPPH antioxidant activity values also varied significantly among genotypes. Organic acid analysis revealed considerable variation, particularly in citric and malic acid contents. Principal component analysis explained 92.4% of the total variation and grouped the genotypes into two major clusters. Based on the overall evaluation, genotypes TK2, TK5, TK9, and TK10 exhibited superior performance for several desirable traits. The results demonstrate the substantial genetic diversity present in the natural rosehip populations of Tunceli and highlight their potential value for germplasm conservation, selection breeding, and sustainable cultivation programs.
- MakaleAçık Erişim2026Scopus SJRQ1The Role of Graphene on Microstructural, Mechanical, and Tribological Properties of Cu–AlCrFeCuNi Metal Matrix Composites Fabricated via Spark Plasma Sintering
Yanar, Harun; Çelebİ, Müslİm; Sekban, Dursun Murat; Özkaya, Serdar; Karabacak, Abdullah Hasan; Çelİk, Ertuğrul
In this study, Cu-based AlCrFeCuNi high-entropy alloy (HEA) composites reinforced with graphene were fabricated using a mechanical-alloying-assisted spark plasma sintering (SPS) technique. The HEA reinforcement content was kept constant at 20 wt pct for all samples, while the graphene content was varied at 0, 0.5, 1.0, and 2.0 wt pct to investigate its influence on the microstructure, hardness, and tribological performance. The results indicate that both the HEA particles and graphene exhibit an almost homogeneous distribution within the matrix; however, increasing graphene content led to noticeable graphene accumulation along grain boundaries. With higher graphene fractions, the relative density decreased from 97.51 to 94.92 pct, whereas the hardness increased up to the 1.0 wt pct graphene addition, reaching 134.16 HB, followed by a slight decrease to 129.25 HB at 2.0 wt pct. Furthermore, graphene reinforcement significantly improved the tribological behavior of the composites, providing a substantial reduction in wear. The addition of graphene significantly decreased the coefficient of friction from about ~ 0.70 in the Cu–HEA alloy to 0.08 at 2.0 wt pct graphene. Graphene also suppressed the pronounced frictional fluctuations observed in the base alloy, leading to a much more stable sliding behavior. As a result, wear loss was reduced by nearly 99 pct, primarily due to the formation of a continuous lubricating tribofilm on the contact surface.
AtıfScopus3WoS4OpenAlex4İncele - MakaleAçık Erişim2026Scopus SJRQ1Enhancing the mechanical and durability properties of fly ash/GGBS-based geopolymer mortars using dunite and polypropylene fibers
Cemalgil, Selim; Gülmez, Nihan; Yön, Merve Şahin; Karataş, Mehmet
Polypropylene (PP) fiber-reinforced geopolymer mortar reduces the high brittleness of conventional geopolymer made with natural aggregates. However, the effects of different precursor materials on the performance of PP fiber-reinforced self-compacting geopolymer mortar (SCGM) remain unclear. This study investigates the feasibility of using dunite (D), a magnesium-rich ultramafic rock with consistent mineralogy and low processing energy demand that enhances thermal stability and durability, as an alternative precursor for fly ash (FA)/ground granulated blast furnace slag (GGBS)-based geopolymers. The study examined the workability, flexural and compressive strengths, and sorptivity of mortars cured at 20 ± 2°C and 60 ± 5% relative humidity, as well as their durability under freeze–thaw cycles and high-temperature exposure. Interfacial interactions between aggregates and the geopolymer matrix, along with microstructural and morphological changes caused by fire, were analyzed using scanning electron microscopy (SEM). X-ray diffraction (XRD) and thermogravimetric analysis (TGA) were also performed for detailed material characterization. The mix containing 30% dunite exhibited the highest flexural strength, reaching 5.70 MPa at 28 days, the highest among all mixes. Under fire exposure, the mix containing 10% dunite significantly reduced mechanical strength loss and retained about 33.3% higher residual flexural strength than the FA–slag control mix at 600°C.
AtıfScopus1WoS1OpenAlex1İncele - MakaleAçık Erişim2026Scopus SJRQ2Pollution estimation and health risks assessment related to the agricultural application of mussel shell-derived chitosan as organic amendment
Arslan Topal, E. Işil; Topal, Murat; Çelik, Erdal; Öbek, Erdal
In this study, estimation of pollution and assessment of health risks related to the agricultural application of mussel shell–derived chitosan as organic amendment were evaluated. Furthermore, considering WHO maximum permissible levels in soil, the application rates of chitosan to agricultural soils were calculated. Geo-accumulation index (Igeo), enrichment factor (EF), contamination factor (CF), pollution load index (PLI), and ecological risk index (ERI) were calculated. Mussel shell-derived chitosan generally did not contribute to soil metal loading when evaluated in terms of those indices. The highest hazard quotient for ingestion (HQing) across male (ML), female (FML), and children (CL) followed the order Cr > Ni > Mn >Pb >Zn >Cu, while maximum HQing among metals was observed in the order CL > FML > ML. For inhalation exposure, highest HQinh for all metals was also found in the order CL > FML > ML, with individual metal contributions following Mn > Ni > Cr >Zn >Pb >Cu. Maximum HQder exhibited the trend ML > FML > CL, and the metal-specific order for HQder was Cr > Pb > Ni >Zn >Mn >Cu. Hazard Index (HI) and Total HI for ingestion, inhalation and dermal exposure were all less than 1. Cancer risk was less than 1 × 10−6. Consequently, there were no pollution and health risks associated with the use of musselshell‑derived chitosan in agriculture as organic amendment.
- MakaleAçık Erişim2026Scopus SJRQ1Post-disaster psychological effects: identifying earthquake-induced trauma in athletes
Uğurlu, Fatih Mehmet; Güler, Muhammed; Albayrak, Veysel; Aygören, Caner
Natural disasters not only cause physical destruction but also lead to various psychological problems affecting the mental health of individuals. This study was conducted to determine the levels of post-earthquake trauma in athletes who experienced earthquakes and whether certain variables made a difference in this situation. The sample of the study consisted of 359 athletes living in 11 provinces affected by the earthquakes centered in Kahramanmaraş, Turkey, on February 6, 2023. Participants were reached using the Snowball Sampling Method. The Sociodemographic Information Form and the Post-Earthquake Trauma Level Determination Scale were used to collect data. As a result of the descriptive statistics, it was seen that athletes experienced above-average earthquake trauma (M = 65.84). When examined in terms of sociodemographic variables, it was found that women showed more symptoms of earthquake trauma than men, those who experienced the loss of relatives showed more symptoms than those who did not, and those who experienced the loss of a home showed more symptoms than those who did not. In conclusion, while exercise and physical activity are methods used to cope with trauma, being an athlete alone is not sufficient to cope with earthquake trauma. Women, whether athletes or not, experience more earthquake trauma than men. Losing relatives exacerbates the trauma caused by the earthquake. Furthermore, the loss of a home, which prevents individuals from meeting some basic physiological needs, is a significant factor in earthquake trauma.
- MakaleAçık Erişim2026Scopus SJRQ1RGO-CBPAC versus CBPAC for diluted leachate treatment: adsorption isotherms, kinetics and thermodynamics
Ogedey, A.; Oguz, E.
This study compares carbon-based activated carbon (CBPAC) and reduced graphene oxide-modified CBPAC (RGO-CBPAC) for removing COD, NH3–N, and turbidity from 1:4 diluted leachate from the Bingöl landfill site. Brunauer Emmett Teller (BET) analysis indicated severe micropore blockage in CBPAC after adsorption (887 → 0.76 m2/g), whereas RGO-CBPAC retained a higher surface area (908 → 23 m2/g) and mesoporous structure, demonstrating enhanced structural stability due to graphene incorporation. Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM–EDX) confirmed the presence of surface functional groups and effective pollutant uptake, with RGO-CBPAC showing stronger surface–pollutant interactions. Zeta potential analysis showed pH-dependent surface charge behaviour, with CBPAC exhibiting amphoteric characteristics and RGO-CBPAC maintaining a more negative surface. After adsorption, both became more negatively charged, indicating the accumulation of negatively charged species. Kinetic analysis showed that COD adsorption on CBPAC followed pseudo-first-order and intraparticle diffusion models, whereas NH3–N and turbidity followed pseudo-second-order kinetics. In contrast, RGO-CBPAC exhibited pseudo-second-order and intraparticle diffusion behaviour for all pollutants, suggesting chemisorption with diffusion-controlled contributions. Adsorption equilibrium was best described by the Langmuir isotherm, yielding maximum capacities of 500 and 588 mg O2/g for COD, 17.5 and 36.5 mg/g for NH3–N, and 18.1 and 58.5 mg/g ((NH2)2H2SO4)/g for turbidity on CBPAC and RGO-CBPAC, respectively. Thermodynamic analysis demonstrated that COD and turbidity removal using RGO-CBPAC were spontaneous (∆G° < 0) and endothermic (∆H° > 0), whereas NH3–N removal remained non-spontaneous for both adsorbents. RGO incorporation significantly enhanced adsorption performance.
AtıfScopus1WoS1OpenAlex1İncele - MakaleAçık Erişim2026Scopus SJRQ2Hybrid Supervised Classification and Deep Embedding–Based Profiling Framework for Electricity Consumption Analysis
Gunay, Mihriban; Yildirim, Ozal; Demir, Yakup; Zhilevski, Marin; Mikhov, Mikho; Yordanov, Nikolay
This study proposes a hybrid deep learning framework that integrates supervised classification and unsupervised profiling for electricity consumption analysis. In the supervised phase, a one-dimensional Convolutional Neural Network combined with Long Short-Term Memory (1D CNN–LSTM) architecture is developed to classify daily load patterns. The performance of the proposed model is compared with traditional machine learning and deep learning approaches, including Support Vector Machine (SVM), k-Nearest Neighbors (KNN), a standalone Long Short-Term Memory (LSTM) model, a Transformer-based model, and a standalone 1D CNN model. Experimental results on the Precon house dataset and the CU-BEMS dataset demonstrate that the proposed hybrid architecture outperforms the benchmark models, achieving classification accuracies of 87.59% and 86.40%, respectively. In the unsupervised phase, the trained CNN–LSTM encoder is utilized as a deep feature extractor. The resulting 32-dimensional latent embeddings are clustered using K-Means, Gaussian Mixture Model (GMM), Agglomerative, Spectral, and Ensemble methods. Clustering robustness is evaluated through bootstrap-based stability analysis using the Adjusted Rand Index (ARI) and the Normalized Mutual Information (NMI). The results demonstrate stable and interpretable electricity consumption profiles, particularly in the residential dataset, where near-perfect clustering stability is observed for K-Means. The proposed framework provides both improved classification performance and robust consumption profiling based on deep embedding, offering a practical tool for energy management.
AtıfScopus1OpenAlex1İncele - MakaleAçık Erişim2026Scopus SJRQ2Ultrasound assisted extraction of phenolic compounds from Tunceli walnut varieties using deep eutectic solvents
Aydin, Çağlar Mert
This study aimed to improve a green way to enhance extraction of bioactive compounds from walnut, and to evaluate the effect of altitude on walnut bioactive content. Total phenolic content (TPC), total flavonoid content (TFC), and antioxidant activity were evaluated as bioactive compounds of walnut. In comparison with conventional solvents (water, ethanol and methanol), three DESs (Deep eutectic solvents) were formed from choline chloride, zinc chloride, and sorbitol as HBA and ethylene glycerol as HBD. The DESs (DES-1 and DES-2) generated from choline chloride and zinc chloride exhibited better extraction efficiencies for any bioactive compound than that of conventional solvents. Especially, the DES formed from the choline chloride: ethylene glycerol demonstrated the highest extraction efficiency. However, sugar-based DES showed the worst extraction efficiency. The altitude significantly affected extracted bioactive contents from walnuts (Hozat 1000m, Ovacik 1300m and Nazimiye 1550m). Walnut’s extracted bioactive content ordinarily decreased as the altitude increased, regardless of solvent type used in extraction. The result is a light to enhancing knowledge as to DES usage and its extraction efficiency of bioactive compounds for food applications. In addition, it gives better understanding of altitude effect on the content of bioactive compounds in walnuts.
AtıfScopus1WoS1İncele - MakaleAçık Erişim2026Scopus SJRQ2Solvent extraction of rare earth elements and α-alumina production from pregnant leaching solution obtained from Turkish bauxite-related ore
Erust, Ceren; Uysal, Turan
The use of bauxite-related shales as a secondary source for the extraction of rare earth elements (REEs) is very important to meet the raw material supply, which is the keystone of advanced technology applications. This study presents the investigation into the recovery of REEs from Kızıldağ shale ore and the potential utilization of its leach residue as a silica source. Mineralogical analysis revealed that the ore predominantly consists of paragonite, muscovite, quartz, pyrophyllite, and calcite. Calcined ore was subjected to acid leaching, and the resulting pregnant solution was purified using solvent extraction to separate from aluminum the ∑REEs with a content of 1887.35 ppm. Optimal solvent extraction conditions 1.5 M D2EHPA, 50% O/A ratio, pH 1.5, and 15-minute mixing time achieved 95% total REE extraction, with efficiency in the order Pr > La > Nd > Ce > Dy > Y > Sc. To purify Al from the Fe- and K-rich solution post-SX, electrolysis was performed, resulting in 97.16% precipitation efficiency of Al as Al(OH)3 at pH 5. The precipitate was subsequently roasted at 1100°C to produce α-alumina with 75.2% Al2O3 content. These findings confirm the technical feasibility of recovering REEs and producing coarse-purity alumina from Kızıldağ shale ore.
AtıfScopus1WoS3OpenAlex1İncele - MakaleAçık Erişim2026Scopus SJRQ1Path Dependence and Spatial Spillovers in Regional Digitalization: Evidence from Dynamic Spatial Panel Analysis in Europe
Kazar, Görkemli; Kazar, Altuğ
Digitalization is the driver of regional competitiveness and sustainable development, but its geographical impacts differ significantly across Europe. This study was conducted to determine if digital transformation results in regional sustainability or if it increases spatial inequalities, concentrating on European NUTS-1 regions for the period 2021–2025. A composite Regional Digitalization Index was developed by means of Principal Component Analysis (PCA) based on indicators measuring internet access, internet usage, and the availability of digital public services. Dynamic spatial panel econometric models were used for empirical investigation, including a Spatial Autoregressive (SAR) model and a Spatial Durbin model (SDM), which facilitated the exploration of both temporal dependence and spatial spillover. Three main conclusions can be derived from the results, as follows: The level of digitalization in a region is highly stable over time, whereby the development depends most on previous paths. Subsequently, human capital is highly significant for digital development, and its effects are not only local but also spill over to neighboring regions. Lastly, spatial interactions consist of two opposite forces—the positive diffusion from digitally advanced neighboring regions and the competitive effects related to the economic strength of neighboring regions—that further intensify the core–periphery divide.
AtıfScopus1WoS1OpenAlex1İncele - MakaleAçık Erişim2026Scopus SJRQ1Effect of dilute rare-earth addition on structural evolution, mechanical, magnetic, and radiation shielding properties of CoFeNiMnTi high-entropy alloy
Özkul, İskender; Kalay, Ece; Güler, Ömer; Karaduman, Oktay; Canbay, Canan Aksu; Hameed, Louis Ibrahim; Almisned, Ghada; Baykal, Duygu Sen; Tekin, H.O.
This study investigates the effect of 1 at.% rare-earth (RE = Sm, Gd, Dy) addition on the structural, mechanical, magnetic, and radiation shielding properties of CoFeNiMnTi high-entropy alloys produced by arc melting. X-ray diffraction results reveal an FCC-dominant structure accompanied by secondary Laves-type phases, with increased phase complexity observed in Gd- and Dy-containing alloys. Mechanical evaluation shows a significant hardness enhancement, reaching 581 HV for Gd and 548 HV for Dy, compared to 447 HV for the reference alloy. Magnetic measurements indicate soft-ferromagnetic behaviour for all compositions, with magnetization increasing in the order S0<S1<S2<S3, highlighting the strong influence of Dy on magnetic response. Elemental mapping confirms a homogeneous distribution with minor local compositional variations contributing to phase evolution. Thermodynamic analysis suggests that rare-earth addition increases lattice distortion and chemical complexity without strongly differentiating among RE types. In terms of radiation shielding, linear attenuation coefficients and effective atomic number values demonstrate improved gamma-ray attenuation, particularly at low energies, with Dy exhibiting the highest performance. In contrast, fast neutron removal cross section values remain nearly unchanged, indicating limited sensitivity to dilute RE addition. It can be concluded that the incorporation of Dy results in the most balanced multifunctional performance, whereas Gd primarily enhances mechanical strength, emphasizing the importance of rare-earth selection in the design of high-entropy alloys for radiation-related applications.
- MakaleAçık Erişim2026Scopus SJRQ1Multi-Response Kinetic Modeling of the Maillard Reaction in Milk During Heating at Ultra-High-Temperature Range
Hamzalıoǧlu, Aytül; Aktaǧ, Işıl; Gökmen, Vural
This study developed first a comprehensive multiresponse kinetic model to elucidate the mechanism of the Maillard reaction in milk during ultrahigh-temperature treatment. The model incorporates the alterations in precursors (sugars, amino acids), intermediates (α-dicarbonyl and Amadori compounds) and products (N-ε-carboxymethyllysine, N-ε-carboxyethyllysine) that occur in milk during heating between 110 and 140 °C. Kinetically important reactions steps were identified by multiresponse kinetic modeling. Results indicated that N-ε-carboxymethyllysine and N-ε-carboxyethyllysine were formed predominantly by the oxidation of lactulosyllysine. Among the intermediates, the formation of 1-deoxyglucosone and glucosone, and methylglyoxal from 1-deoxyglucosone and glyoxal from glucosone, were determined to be the kinetically important steps. The rate-limiting step was identified as lactulosyllysine formation, while methylglyoxal generation occurred most rapidly across all heating temperatures. In this study, the multiresponse kinetic modeling approach was applied to milk, offering a comprehensive understanding of the critical pathways leading to the formation of α-dicarbonyl compounds and advanced glycation end-products.
- MakaleAçık Erişim2026Scopus SJRQ1Dietary exposure and health risk assessment of fumonisins through the consumption of maize and maize-based gluten-free products in individuals with celiac disease
Tuyben, Eylem Ezgi; Sevim, Sumeyra; Macit, Arife; Kizil, Mevlude
Introduction: Individuals with celiac disease (CD) must adhere to a gluten-free diet (GFD) and are therefore at high risk of fumonisin exposure due to their high consumption of maize and maize-based products. This study aimed to determine the concentrations of fumonisins (FB1, FB2, and FB3) in packaged gluten-free (GF) maize and maizebased products sold in Turkey and to assess dietary exposure and health risks in adults with CD using a probabilistic approach. Methods: Fumonisin concentrations of 51 GF products were analyzed by Enzyme-Linked Immonosorbent Assay (ELISA) and daily food consumption data were collected from 67 individuals with CD through a food frequency questionnaire. Exposure was estimated using Estimated Daily Intake (EDI) values and probabilistic risk assessment with Monte Carlo simulation. Results: The highest fumonisins concentrations were detected in the pasta/rice/bulgur group, while the flour/starch group was the food group contributed most to total fumonisins exposure due to higher consumption. Although the average EDI values were below the Tolerable Daily Intake (TDI; 1 μg/kg bw/day) set by European Food Safety Authority’s (EFSA) and Provisional maximum tolerable daily intakes (PMTDI; 2 μg/kg bw/day) established by Joint Expert Committee on Food Additives’s (JECFA) values, individuals at the 95th percentile approached 132.88–167.89% of the PMTDI value in the flour/starch group and 79.00–82.38% in the pasta/rice/bulgur group. Discussion: These findings highlight the need for continuous monitoring and stricter regulatory oversight and dietary guidance to protect vulnerable populations.
