Sürdürülebilir Kalkınma Amaçları

Yazarlar

  • MakaleYalnız künye2026Scopus SJRQ3
    New national and regional bryophyte records, 86

    Wilbraham, J.; Abdirasulov, F.; Aguirre, J.; Alataş, M.; Álvaro Alba, W.R.; Aslan Ergenekon, Z.; Aswathy Raj, K.; Ayhan, E.; Batan, N.; Bednarek-Ochyra, H.

  • MakaleYalnız künye2026Scopus SJRQ2
    A Bernstein polynomial estimation of the moment generating function

    Susam, Selim Orhun

    We study Bernstein polynomial smoothing for nonparametric estimation of the moment generating function (MGF) of a distribution supported on (Formula presented.). We prove strong consistency of the Bernstein-smoothed MGF estimator and show that, when the smoothing degree m grows sufficiently fast, it shares the same (Formula presented.) asymptotic normal distribution as the empirical MGF estimator, with variance (Formula presented.). A second-order bias–variance expansion reveals that Bernstein smoothing yields a bias of order (Formula presented.) and a variance-reduction term of order (Formula presented.). This leads to the optimal smoothing rate (Formula presented.) for pointwise mean squared error (MSE) minimization. Simulation results confirm that the Bernstein estimator is especially effective in challenging boundary-dominated settings, notably for U-shaped beta models and for larger positive t values. Overall, Bernstein polynomial smoothing provides a simple, theoretically justified, and practically effective tool for nonparametric MGF estimation on compact supports.

  • MakaleAçık Erişim2026Scopus SJRQ2
    Sustainable self-compacting mortars: mechanical, durability and microstructural evaluation with cement replacement materials under aggressive environmental conditions

    Karabulut, Büşra; Yön, Merve Şahin; Karataş, Mehmet

    The aim of this study is to assess the mechanical, physical and durability properties of environmentally friendly self-compacting mortars produced using materials containing industrial waste and natural stone. The test series were produced by substituting diatomite (D) and C class fly ash (F) with Portland cement (PC) up to 30% by weight. To evaluate the workability, mechanical and durability properties of self-compacting mortars (SCM), a total of 19 series, one of which was a reference sample, were prepared. The samples, whose mechanical properties and durability properties were investigated under sulphate attack and freeze-thaw effects, were prepared as 40 × 40 × 160 mm, and the series, whose physical properties were examined, were prepared as 50 × 50 × 50 mm. Also, SEM/EDS (Scanning Electron Microscope - Energy Dispersive X-Ray) and XRD (X-Ray Diffraction) analyses were carried out to evaluate the microstructural properties of the mixtures. When the 90-day compressive strength results were examined, it was determined that the highest decrease in compressive strength compared to the control sample occurred in the D20F10 sample with a rate of 61%, and the least decrease occurred in the D5 series with a rate of 10%. When the losses in compressive strength were evaluated after 50 freeze-thaw cycles, it was determined that there was a 100% reduction in the binary and ternary series containing D15 and D20. After six months of sulphate exposure, the D5F25 sample exhibited the most significant compressive strength reduction at roughly 40%, whereas the D15F15 series experienced the least compressive strength decline at around 5%.

    • SDG 9 · Sanayi, Yenilikçilik ve Altyapı
    • SDG 12 · Sorumlu Üretim ve Tüketim
  • MakaleAçık Erişim2026Scopus SJRQ2
    Design and Characterization of Y2O3/Pr2O3–Enriched Inconel-718 Alloys for Nuclear Applications

    Albayrak, Muhammet Gökhan; Güler, Ömer; Güler, Seval Hale; Evin, Ertan; ALMisned, Ghada; Sen Baykal, Duygu; Alkarrani, Hessa; Susoy, Gulfem; Kilic, Gokhan; Tekin, Hüseyin Ozan

    This study explores the physical, structural, and radiation shielding enhancements in Inconel 718 superalloys reinforced with 1 wt% Y2O3 and varying Pr2O3 contents from 0 to 10 wt%, respectively. X-ray diffraction analysis confirmed preservation of the face-centered cubic structure, with increasing Pr2O3 inducing peak broadening and partial amorphization. The scanning electron microscopy/energy-dispersive X-ray spectroscopy results verified the homogeneous dispersion of oxides without agglomeration. Gamma-ray shielding parameters, including the mass attenuation coefficient (MAC), half-value layer, and effective atomic number, significantly improved with higher Pr2O3 content, particularly at low to mid photon energies. The 718Y-10PO sample exhibited the lowest transmission factors and the highest MAC values across all the tested energies. Buildup factors decreased in the Pr-rich samples, confirming reduced photon scattering. Notably, the fast neutron removal cross section for 718Y-10PO as 0.15521 cm−1 exceeded the benchmark materials like graphite and B4C. These findings establish the 718Y-10PO alloy as a promising candidate for advanced nuclear shielding applications, combining structural integrity with promising gamma and neutron attenuation capabilities.

  • MakaleYalnız künye2026Scopus SJRQ2
    Phytoremediation of elements in municipal wastewater treatment plant effluent by Lemna gibba L.: a full-scale study

    Topal, Murat; Öbek, Erdal; Çelik, Erdal; Arslan Topal, E. Işıl

    In this study, capacity of naturally growing Lemna gibba L. in removing elements (B, As, Al, Ca, Ba, Co, Fe, Cu, K, Cr, Li, Mo, Ni, Mn, Na, Mg, Sb, P, Si, Pb, Se, Ti, Zn, V, and Sr) from the effluent of secondary clarifier of a municipal wastewater treatment plant (MWWTP) was determined week by week (W1, W2, W3, and W4) and analyzed as a whole using statistical models. To determine the removal contribution of Lemna gibba L. to the MWWTP effluent, secondary clarifier without Lemna gibba L. was used as a control. The aim here is to determine the contribution of Lemna gibba L. to MWWTP’s removal efficiency. Trace elemental quantification was conducted via validated ICP-MS following microwave-assisted acid digestion. In this context, according to the analysis results, the removal efficiency of Lemna gibba L. for Al was highest at 89.66% over the weeks. Furthermore, treatment efficiencies above 50% were achieved for Co (57.86–60.61%), Sb (64.25–67.35%), and Ti (63.27–66.21%). Based on statistical analyses, PCA (principal component analysis)) and HCA (hierarchical cluster analysis) models explained 85% of the total variance. As a result, this study demonstrated that Lemna gibba L. removes elements from MWWTP effluent, contributing to the removal efficiency of the secondary clarifier and clearly showing its potential use in phytoremediation.

  • MakaleYalnız künye2026Scopus SJRQ2
    Optimization of native plant selection for phytomining of strategic/critical raw materials using Artificial Bee Colony algorithm

    Arslan Topal, E. Işıl; Topal, Murat; Çelik, Erdal; Öbek, Erdal

    This study investigates the potential of native plant species (NPs) as secondary sources for strategic/critical raw materials (SCRMs) through phytomining, aiming to identify the most efficient accumulator for sustainable element recovery. To achieve high-precision results, the Artificial Bee Colony (ABC) algorithm, a robust meta-heuristic optimization technique inspired by the foraging behavior of honeybees, was utilized to minimize the error between experimental data and predicted models to optimize the accumulation of key elements including cobalt (Co), strontium (Sr), antimony (Sb), vanadium (V), phosphorus (P), lanthanum (La), magnesium (Mg), titanium (Ti), aluminum (Al), and scandium (Sc). The research focused on three NP species—Musk thistle (MT), curly dock (CD), and Juncus (JS)—collected from a geothermal hot spring area. Methodological validation was performed through comparative statistical analysis and the calculation of bioconcentration factor (BCF) and translocation factor (TF) to assess phytoremediation efficiency. The ABC optimization results revealed that MT exhibited the most significant accumulation capacity, particularly for Mg, reaching a peak concentration of 3,910 mg/kgdw in the leaves. The concentration range (lowest to highest value) was between 0.01 (for La) and 3,910 mg/kgdw for the studied plants. Principal component analysis (PCA) corroborated these findings, explaining cumulative variances of 80.4% (MT), 89.4% (CD), and 76.4% (JS). The innovation of this study lies in the application of the ABC algorithm to the field of phytomining, which offers a more dynamic and flexible alternative to traditional regression-based models. The primary advantage of this proposed method is its superior global search capability and ability to handle multi-elemental interactions with high predictive accuracy. However, a potential disadvantage remains the computational complexity and the requirement for fine-tuning control parameters to ensure consistent convergence. Overall, MT is identified as a highly promising candidate for the phytomining of SCRMs, with Mg emerging as the most effectively accumulated element under the optimized ABC model.

    • SDG 2 · Açlığa Son
    • SDG 12 · Sorumlu Üretim ve Tüketim
    • SDG 15 · Karasal Yaşam
  • MakaleYalnız künye2026Scopus SJRQ3
    Green revolution in nanotechnology: phytogenic CuO nanoparticles for biomedical and pharmaceutical applications

    Ceylan, Yusuf; Korkmaz, Nesrin; Kaçan, Fatma N.; Aydin, Ali; Korkmaz, Şengül A.; Yildirim, Ebru Ş.

    Copper oxide nanoparticles (CuO NPs) were synthesized using a green approach with Vitis vinifera L. extract, a plant rich in secondary metabolites that act as natural reducing agents. The obtained CuO NPs were characterized by XRD, EDX, and STEM analyses. FT-IR analysis revealed the presence of functional groups originating from plant biomolecules and confirmed the formation of Cu–O bonds, indicating the successful synthesis and stabilization of CuO NPs. XRD confirmed distinctive CuO diffraction peaks at 32.38°, 35.35°, 38.61°, 40.75°, 48.79°, 51.90°, 57.66°, 61.38°, 65.94°, and 75.12°. STEM imaging showed predominantly spherical, well-dispersed nanoparticles with an average size of 23–38 nm. Antibacterial analysis revealed a minimum inhibitory concentration (MIC) of 4 µg mL−1 against Escherichia coli ATCC 25922. In anticancer assays, the CuO NPs demonstrated notable cytotoxicity at both low concentrations and even at levels below the control group in A549, Calu-1, and Saos-2 cancer cell lines, highlighting their strong biomedical potential.

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  • MakaleYalnız künye2026Scopus SJRQ1
    The Effect of Women’s Menstrual Attitudes and Hygiene Practices on Self-Care Behaviors

    Yeyğel, Çiler; Yeşiltepe, Akgün

    Objective: While menstrual attitudes and hygiene practices are often examined in the literature through informational, risk-based, and cultural lenses, studies that directly address their holistic relationship to self-care behaviors remain limited. This study aims to investigate the impact of women’s menstrual attitudes and hygiene practices on their self-care behaviors. Methods: This is a cross-sectional analytical study. The study was completed between 5 October 2024 and 23 January 2025, with 700 women aged 18–49 in their reproductive period. Data were collected using a Demographic Information Form, the Menstrual Attitude Questionnaire, and the Self-Care Inventory. Spearman’s correlation analysis, the Mann-Whitney U test, and the Kruskal-Wallis test were used for data analysis. To examine nonlinear relationships and multivariable interactions, a Random Forest regression analysis was performed. Results: A positive and statistically significant relationship was found between menstrual attitudes and overall self-care (r = 0.132, p < 0.001). MAQ scores did not differ significantly across variables (p > 0.05). However, SCI scores showed significant differences based on menstrual hygiene education status, type of underwear used during menstruation, hand hygiene practices, and frequency of menstrual material use (p < 0.05). According to the Random Forest regression model, menstrual attitudes were identified as the strongest predictor of self-care behaviors. Conclusions: The results of this study supported the positive influence of women’s menstrual attitudes and hygiene practices on their self-care behaviors. The relationships between self-care and parameters such as menstrual hygiene education, frequency and type of menstrual material use, and hand hygiene during menstruation were clearly demonstrated. Given the limited number of studies in this field, randomized controlled trials and meta-analyses with high levels of evidence are recommended to generalize these results.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
  • MakaleYalnız künye2026Scopus SJRQ1
    Geochemical signature, detrital zircon U–Pb, and mica Ar–Ar age systematics from the Karadere Basement Unit of the İstanbul-Zonguldak Terrane (NW, Türkiye): evidence for an Avalonian-Cadomian active continental margin

    Çimen, Okay; Gücer, Mehmet Ali; Göncüoğlu, Mehmet Cemal; Akal, Cüneyt; Arslan, Mehmet; Simonetti, Antonio; Karaoğlan, Fatih

    The İstanbul-Zonguldak Terrane is located in northwest Anatolia and includes several outcrops with pre-Cambrian basement units. The Karadere Basement Unit represents the easternmost basement of this terrane and is composed of paragneiss, quartzite, and orthogneiss. The paragneiss and quartzite are cut by orthogneisses and disconformably overlain by Lower Ordovician to Middle Devonian cover units. Its pre-Cambrian to Palaeozoic tectonic evolution remains poorly understood, and therefore, this study reports whole-rock trace element signatures, detrital zircon U–Pb, and muscovite Ar–Ar age data for samples of paragneiss, quartzite, amphibolite, and orthogneiss. The whole-rock geochemical data indicate that the protoliths of the paragneiss and quartzite samples investigated here could have been derived from arc-related felsic magmatic units located in an active continental margin. The protoliths of amphibolites and orthogneiss samples are gabbro and granite, respectively, and their geochemical signatures are akin to those from continental arc igneous suites. The detrital zircon U–Pb data are characterized by predominantly Mesoproterozoic (84%) and lesser amount of Palaeoproterozoic and Neoproterozoic ages and suggest an early Tonian (youngest peak age of 915 ± 18 Ma) maximum depositional age. Moreover, zircon U–Pb dating analyses from an orthogneiss sample yielded an age of 603 ± 2 Ma, indicating the occurrence of mid-Ediacaran arc magmatism. This represents one of the oldest Ediacaran ages obtained from the metamagmatic basement rocks of the İstanbul-Zonguldak Terrane. Ar–Ar dating of muscovite from ortho- and paragneiss samples yielded ages of 533 ± 25 Ma and 530 ± 9 Ma, respectively, which are interpreted as early Cambrian cooling ages. Overall, the combined results reported here reveal that the Karadere Basement Unit is markedly different from NE African basement units but displays similarities to the basement rocks of both Avalonian and Amazonian terranes. It may have been formed and metamorphosed in an Avalonian–Cadomian active continental margin during the mid- to late Neoproterozoic and early Cambrian.

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  • MakaleYalnız künye2026Scopus SJRQ1
    Psychological well-being and aggression in handball players: examining the mediating role of exercise addiction

    Güler, Muhammed; Yeşiltepe, Akgün; Topcuoğlu, Ceyhun

    Objective: This study aimed to examine the relationship between psychological well-being and aggression among handball players and to determine whether exercise addiction mediates this relationship. Methods: A descriptive, cross-sectional, and correlational design was used. The population consisted of players competing in the Turkish Handball Leagues during the 2024–2025 season, and 442 athletes participated using a non-probability sampling method. Data were collected via an online survey including a personal information form, the Psychological Well-Being Scale, the Buss–Perry Aggression Questionnaire, and the Exercise Addiction Inventory. Results: Psychological well-being showed a significant negative correlation with aggression (r = −0.242, p < 0.001). Exercise addiction was positively associated with both psychological well-being (r = 0.212, p < 0.001) and aggression (r = 0.105, p = 0.027). Mediation analysis indicated that exercise addiction significantly and partially mediated the relationship between psychological well-being and aggression (indirect effect 95% CI: 0.0246–0.1654). The direct effect of psychological well-being on aggression remained significant (β = −0.7093, p < 0.001). Conclusion: Higher psychological well-being was associated with lower aggression among handball players, whereas exercise addiction was associated with both higher psychological well-being and higher aggression and emerged as a partial statistical mediator of this relationship. These findings may help inform future studies and preventive strategies focusing on athlete mental health and behavioral regulation. However, because of the cross-sectional design, causal inferences cannot be drawn.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
  • MakaleYalnız künye2026Scopus SJRQ3
    A multi-parametric unit distribution via Bernstein polynomials

    Susam, Selim Orhun

    This study develops the method of constructing a multi-parametric distribution on the unit interval using Bernstein polynomials and investigates its key statistical properties. The performance of the proposed distribution’s parameter estimators was evaluated by Monte Carlo simulation under both maximum-likelihood (MLE) and minimum-distance frameworks, with the MLE approach generally yielding lower estimation error. A real data example illustrates the advantages of the construction method. The results reveal that the Bernstein distribution provides superior goodness-of-fit to the dataset compared with competing models.

  • MakaleAçık Erişim2026Scopus SJRQ2
    Enhanced Radiation Shielding and Structural Modifications in Samarium (III) Oxide-Reinforced Type 316L Stainless Steel Composites for Nuclear Applications: A Comprehensive Evaluation of Physical, Structural, Mechanical, Gamma-Ray, and Neutron Attenuation Properties

    Yayla, Nihal; Albayrak, M. Gökhan; Güler, Ömer; Sen Baykal, Duygu; Alkarrani, Hessa; ALMisned, Ghada; Tekin, H.O.

    Type 316L stainless steel (316L-SS) is widely recognized for its exceptional corrosion resistance, making it a preferred material in various industries. However, conventional stainless steel materials are inadequate for radiation shielding applications. While oxide dispersion-strengthened alloy composites with a 316L-SS matrix have been extensively studied in the literature for their mechanical creep properties, their radiation shielding capabilities remain insufficiently explored. This study investigates the potential of samarium oxide (Sm2O3) doped to improve the structural, physical, mechanical, and radiation shielding properties of 316L-SS composites. Samples containing 1%, 5%, 10%, and 20% Sm2O3 by weight were synthesized and extensively characterized using X-ray diffraction and scanning electron microscopy. These analyses revealed enhanced homogeneity and refined grain structure with increasing Sm2O3 content. Gamma-ray and neutron shielding properties demonstrated significant improvements, particularly in composites with 20% Sm2O3 reinforcement, as evidenced by lower half-value layer and mean free path values, along with an increased fast neutron removal cross section. However, a trade-off was observed between radiation shielding performance and mechanical properties: As the Sm2O3 content increased, the elastic modulus decreased, indicating reduced stiffness due to the incorporation of Sm2O3. This trade-off suggests that while Sm2O3 reinforcement effectively enhances radiation shielding, it may not be ideal for structural applications requiring high mechanical strength. Nevertheless, these findings highlight the potential of Sm2O3-doped 316L-SS composites for nonstructural radiation protection systems, particularly in applications where improved shielding performance is prioritized over mechanical stiffness.

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  • MakaleYalnız künye2026Scopus SJRQ2
    From Material to Meaning: The Sensory and Conceptual Life of Silk in Turkish

    Korkut, Gizem; Bayraktar Erten, Nesrin

    This article examines silk as a meaning-generating material in Turkish, where sensory, material, and cultural dimensions intersect. Rather than treating silk as a mere lexical item, it approaches ipek as a semantic and conceptual field shaped by the sensory properties of textile materiality. Drawing on lexical, historical, and semantic evidence, the study shows that ipek refers not only to a fiber but also to qualities such as softness, brightness, delicacy, and visual appeal. These qualities enable the term to extend beyond its literal meaning into broader domains, including the body, plants, animals, objects, technical terminology, and place names. Expressions like “silk hair” and “silk skin” demonstrate how silk functions as a medium for articulating embodied perception and aesthetic value. The article argues that ipek holds a distinctive position in Turkish as both a material substance and a cultural signifier. By tracing the semantic and conceptual range of ipek, the study contributes to textile studies by showing how cloth persists in language as a carrier of sensory memory, bodily imagination, and cultural meaning, offering a linguistic and cultural perspective within material and visual culture.

  • MakaleYalnız künye2026Scopus SJRQ2
    Exploring Nuclear Radiation Shielding Capabilities of High-Entropy Carbides: A Study on Composition and Effectiveness

    Yilmaz Alan, Hatice; Guler, Omer; Yilmaz, Ayberk; Susam, Lidya Amon; Kavaz, Esra; Kilic, Gokhan; Ilik, Erkan; Oktik, Sener; Akkus, Baki; ALMisned, Ghada

    High-entropy carbides (HECs) are emerging as promising materials for shielding against gamma-ray and neutron radiation due to their unique structural and compositional properties. This study systematically evaluates the shielding capabilities of 12 carbide-reinforced high-entropy alloys (HEAs) composed of elements such as hafnium, niobium, titanium, zirconium, tungsten, tantalum, vanadium, and molybdenum. Various gamma-ray and neutron shielding parameters, including attenuation coefficients, shielding thicknesses, and neutron removal cross sections, were calculated using the Phy-X/PSD software. The findings reveal a strong correlation between material density and shielding efficiency, with the highest density samples, particularly (Zr0.2Hf0.2Ta0.2Mo0.2W0.2)C and (Ti0.2Hf0.2Nb0.2Ta0.2W0.2)C, demonstrating superior gamma-ray attenuation. Additionally, neutron shielding performance was maximized in compositions containing high concentrations of heavy elements, with (Ti0.2V0.2Nb0.2Ta0.2W0.2)C exhibiting the most effective neutron absorption properties. The interactions of photons and charged particles with these materials were further examined through mass stopping power and projected range calculations for alpha particles, protons, and electrons. It can be concluded that HEC-based alloys, due to their high density, optimized composition, and superior radiation attenuation properties, could be strong candidates for advanced shielding applications in nuclear and aerospace environments.

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  • MakaleYalnız künye2026Scopus SJRQ2
    Manufacturing, Structural Characterization, and Radiation Interaction Evaluation of Lightweight 6061-Al/Ytterbium(III) Oxide Composites with Emphasis on Gamma-Ray Shielding and Fast Neutron Removal Potential

    Guler, Seval Hale; Yayla, Nihal; Guler, Omer; ALMisned, Ghada; Sen Baykal, Duygu; Kilic, Gokhan; Tekin, Huseyin Ozan

    In this study, 6061-aluminum metal matrix composites doped with varying concentrations of ytterbium(III) oxide were synthesized using high-energy mechanical alloying to evaluate their structural, physical, and radiation shielding properties. X-ray diffraction confirmed the retention of the aluminum crystal structure with no secondary phase formation, while scanning electron microscopy and energy-dispersive X-ray spectroscopy revealed homogenous dispersion of Yb2O3 particles within the matrix. With increasing Yb2O3 content, particle densification and structural integrity were significantly enhanced. Gamma-ray and neutron shielding performance was assessed through theoretical modeling and Monte Carlo simulations. At low photon energy, the 20 wt% Yb2O3 composites showed a remarkable increase in linear attenuation coefficients compared to the undoped 6061-aluminum matrix. Neutron removal efficiency also increased by 32% at the highest Yb2O3 content. It can be concluded that Yb2O3 incorporation significantly improves both the photon and neutron shielding performance of the 6061-aluminum metal matrix.

  • MakaleYayıncıda açık erişim2026Scopus SJRQ1
    Thematic Structure of Pedagogical Agent Studies: LDA Analysis for the Period 2020–2025

    Turgut, Yigit Emrah; Aktı Aslan, Seda; Kopuz, Tuba; Aslan, Alper; Allison, Jordan; Özyurt, Özcan

    This study examines 2,360 pedagogical agent (PA) articles published between 2020 and 2025 to identify thematic structures, trends, and research gaps through bibliometric analysis and LDA-based topic modeling. The optimal model produced 10 themes (c_v = 0.4767). The dominant themes—Learner Interaction with Virtual Assistants in Education, Student-Centred Learning and Individual Guidance, and NLP Foundations for Pedagogical Agents—account for 51.3% of publications. Trend analyses revealed consistent growth in both Artificial Intelligence and Pedagogical Design in Education and NLP Foundations for Pedagogical Agents, while Learner Interaction with Virtual Assistants in Education reached saturation. Interaction network results showed these themes at the conceptual core of the field, whereas AI-Driven Medical Chatbots, Knowledge-Based Learning Models, and Student Experiences in Intelligent Learning Environments emerged as future research areas. Overall, findings highlight a strong thematic shift toward artificial intelligence, natural language processing, and student-centered learning.

    • SDG 4 · Nitelikli Eğitim
  • MakaleYalnız künye2026Scopus SJRQ2
    Correlative Investigation on physical, microstructure, magnetism, and gamma-neutron attenuation properties of mechanically alloyed multifunctional (Fe/Co/Ni)Nb10V10B10 soft magnetic alloy systems

    Simsek, Tuncay; Simsek, Telem; Chattopadhyay, Arun K.; Avar, Barış; Yakin, Alican; Guler, Seval Hale; Almisned, Ghada; Sen Baykal, Duygu; Tekin, H.O.

    In this study, mechanically alloyed Fe70Nb10V10B10, Co70Nb10V10B10, Ni70Nb10V10B10, and (FeCoNi) 70Nb10V10B10 high-entropy alloys were successfully synthesized, and their structural, magnetic, and radiation shielding properties were systematically investigated. Structural analysis revealed that Fe favored bcc phase formation, while Co and Ni stabilized fcc structures; the equiatomic alloy resulted in a single-phase fcc solid solution with the smallest crystallite size (2.1 nm). All samples exhibited soft ferromagnetic behavior, with the Fe-based alloy achieving the highest saturation magnetization (120 emu/g), and the (FeCoNi) 70Nb10V10B10 alloy displaying the lowest coercivity. Among all compositions, Co70Nb10V10B10 demonstrated the best gamma and neutron shielding performance, showing the highest linear attenuation coefficient and fast neutron removal cross-section. The equiatomic alloy also exhibited well-balanced and stable shielding behavior. These findings position Co70Nb10V10B10 as a promising candidate for multifunctional applications requiring both efficient radiation protection and favorable magnetic properties.

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  • MakaleAçık Erişim2026Scopus SJRQ2
    Pollution estimation and health risks assessment related to the agricultural application of mussel shell-derived chitosan as organic amendment

    Arslan Topal, E. Işil; Topal, Murat; Çelik, Erdal; Öbek, Erdal

    In this study, estimation of pollution and assessment of health risks related to the agricultural application of mussel shell–derived chitosan as organic amendment were evaluated. Furthermore, considering WHO maximum permissible levels in soil, the application rates of chitosan to agricultural soils were calculated. Geo-accumulation index (Igeo), enrichment factor (EF), contamination factor (CF), pollution load index (PLI), and ecological risk index (ERI) were calculated. Mussel shell-derived chitosan generally did not contribute to soil metal loading when evaluated in terms of those indices. The highest hazard quotient for ingestion (HQing) across male (ML), female (FML), and children (CL) followed the order Cr > Ni > Mn >Pb >Zn >Cu, while maximum HQing among metals was observed in the order CL > FML > ML. For inhalation exposure, highest HQinh for all metals was also found in the order CL > FML > ML, with individual metal contributions following Mn > Ni > Cr >Zn >Pb >Cu. Maximum HQder exhibited the trend ML > FML > CL, and the metal-specific order for HQder was Cr > Pb > Ni >Zn >Mn >Cu. Hazard Index (HI) and Total HI for ingestion, inhalation and dermal exposure were all less than 1. Cancer risk was less than 1 × 10−6. Consequently, there were no pollution and health risks associated with the use of musselshell‑derived chitosan in agriculture as organic amendment.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
  • MakaleAçık Erişim2026Scopus SJRQ2
    Solvent extraction of rare earth elements and α-alumina production from pregnant leaching solution obtained from Turkish bauxite-related ore

    Erust, Ceren; Uysal, Turan

    The use of bauxite-related shales as a secondary source for the extraction of rare earth elements (REEs) is very important to meet the raw material supply, which is the keystone of advanced technology applications. This study presents the investigation into the recovery of REEs from Kızıldağ shale ore and the potential utilization of its leach residue as a silica source. Mineralogical analysis revealed that the ore predominantly consists of paragonite, muscovite, quartz, pyrophyllite, and calcite. Calcined ore was subjected to acid leaching, and the resulting pregnant solution was purified using solvent extraction to separate from aluminum the ∑REEs with a content of 1887.35 ppm. Optimal solvent extraction conditions 1.5 M D2EHPA, 50% O/A ratio, pH 1.5, and 15-minute mixing time achieved 95% total REE extraction, with efficiency in the order Pr > La > Nd > Ce > Dy > Y > Sc. To purify Al from the Fe- and K-rich solution post-SX, electrolysis was performed, resulting in 97.16% precipitation efficiency of Al as Al(OH)3 at pH 5. The precipitate was subsequently roasted at 1100°C to produce α-alumina with 75.2% Al2O3 content. These findings confirm the technical feasibility of recovering REEs and producing coarse-purity alumina from Kızıldağ shale ore.

    • SDG 12 · Sorumlu Üretim ve Tüketim
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  • MakaleYalnız künye2026Scopus SJRQ2
    Comprehensive Characterization of Nano-Eu2O3 Reinforced Borotellurite Glasses: Synthesis, Physical, Structural, and Gamma and Neutron Attenuation Properties

    Durmus, Hasan; Kilic, Gökhan; Ilik, E.; Kavaz, Erkan; Güler, Ömer; Birdoğan, Selcuk; Almisned, Ghada; Tekin, Hüseyin Ozan

    This study presents a systematic investigation of lithium borotellurite glasses reinforced with nano-Eu2O3, with the aim to enhance the structural stability and radiation shielding performance. Glasses were synthesized with Eu2O3 concentrations from 0 to 10 mol % and characterized through density, X-ray diffraction, and transmission electron microscopy. The results showed that the density increased steadily from 4.030 to 4.734 g/cm3 with the Eu addition, while the molar volume also expanded, indicating that the incorporation of larger Eu3+ ions induced network expansion alongside densification. The X-ray diffraction patterns showed amorphous structures for all the compositions except Eu(n)2, which exhibited local crystallinity, later suppressed at higher Eu levels. The transmission electron microscopy pictures and energy dispersive spectroscopy mapping showed homogeneous nanoparticle distribution without clustering. Gamma-ray attenuation studies demonstrated clear improvements with Eu doping: the linear attenuation coefficient increased from 8.33 cm−1 (Eu(n)0) to 12.42 cm−1 (Eu(n)10) at 81 keV, while the half-value layer values decreased, confirming superior low-energy absorption. Experimental neutron studies revealed ΣR values comparable to standard neutron moderators, with Eu(n)10 showing a favorable balance of gamma and neutron shielding. Limitations include the restricted photon energy window and single neutron source. Future work should extend testing to higher energies, thermal/epithermal neutron ranges, and mechanical and durability assessments. Overall, nano-Eu2O3 reinforcement provides a promising pathway toward multifunctional transparent shielding glasses.