Yazarlar

  • MakaleYalnız künye2021Scopus SJRQ1
    Using Ochrobactrum thiophenivorans and Sphingomonas melonis for bioremediation of Imidacloprid

    Erguven, Gokhan Onder; Demirci, Ulas

    To solve the environmental problems of the pesticides, bioremediation methods are commonly useful for their environment friendly properties. These methods are more cheap, useful and have more advantages for remediate receiving environments In this study, imidacloprid which is one of the selective insecticide in all over the world is chosenfor bioremediation studies with two soil bacteria. The imidacloprid used in the Mediterranean climate for cotton, pistachios, tomatoes, peppers and eggplant cultivation. The bioremediation of this insecticide was investigated via the performance of O.thiophenivorans and S. melonis in agitated culture media. The agricultural soil used for the isolation of these two bacteria was taken from the cotton cultivated agricultural area in Adana province in Turkey. For this purpose, the isolated and enriched bacteria were added to the recommended insecticide concentrations, and the Imidacloprid active material, Chemical Oxygen Demand (COD), Biological Oxygen Demand (BOD5), Total Organic Carbon (TOC), pH and dissolved oxygen (DO) parameters were determined for two weeks on each day of the study. O. thiophenivorens and S. melonis bioremediate the Imidacloprid insecticide with high efficiency (over 90%). According to these results, it is understood that these bacteria can be preferred in the bioremediation of receiving environments that are contaminated with such pesticides and can be useful for scientists to handle the opposite effects of such persistent organic pollutants and COD, BOD5 and TOC parameters can easily give opinions about decreasing of pesticides like the active materials

    • SDG 12 · Sorumlu Üretim ve Tüketim
    • SDG 15 · Karasal Yaşam
    AtıfScopus28WoS27OpenAlex30
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2021Scopus SJRQ1
    Investigation on the properties of new palm-oil-based polyurethane modified bitumen

    Vural Kök, Baha; Aydoğmuş, Ercan; Yilmaz, Mehmet; Akpolat, Mustafa

    Polyurethane-derived polymer synthesized by the reaction of 4.4′-diphenylmethane diisocyanate (MDI) with the new modified palm-oil-based polyol was used as an alternative additive to thermoplastic-elastomers, such as styrene–butadienestyrene (SBS), the most commonly used additive. The study aimed to investigate the effect of polyurethane (PU) modification on the rheological and chemical structure of base bitumen. The softening point, rotational viscosity, dynamic shear rheometer (DSR), multi-stress creep recovery (MSCR), bending beam rheometer (BBR), and Fourier transform infrared (FTIR) tests were conducted on the binders. The effects of curing time and temperature, isocyanate/hydroxyl (NCO/OH) molar ratio, and PU content were examined and the best modification conditions were determined. It was found that 24 h curing conditions at 85 °C were sufficient for the formation of PU bonds and these processes increased the rutting parameter of the binder by 256% compared to 1 h curing. At 50 °C and a frequency of 5 Hz, the binder with a 4:1 NCO/OH ratio had 63% more complex modulus than the binder with a 10:1 NCO/OH ratio. The 7 wt% PU modified binder had the same performance level as 4% SBS modification and 10 wt% PU modified binder was one degree higher. Moreover, above 60 °C, all the PU modified binders gave lower phase angles compared to the 4% SBS modified binder. 7 wt% PU modified binder showed similar elastic properties against cracks at low temperatures compared to the 4% SBS modified binder. The use of palm oil in the synthesis of PU presents an environmentally friendly and cost-effective solution compared to the use of petrochemical derivatives.

    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus56WoS53OpenAlex60
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2021Scopus SJRQ3
    Determination of the estimated amounts of discarded face masks due to COVID 19 in Turkey

    Topal, Murat; Topal, Emine Işıl Arslan

    In this study, the estimated amounts of discarded face masks due to COVID 19 were investigated. In this context, the amount of waste face masks was determined separately according to the mask types used (nonwoven, meltblown, and 3-ply, pleated) and the importance of waste face masks was revealed. According to obtained data, the estimated total daily face mask use in Turkey is 72,351,638. The highest amounts of nonwoven, meltblown, and 3-ply face mask waste were determined as 26.88, 36.29, and 43.68 tonnes/day for İstanbul city, respectively. Total amounts of nonwoven, meltblown and 3-ply face mask waste in Turkey were calculated as 144.7, 195.35, and 235.14 tonnes/day, respectively. The top 5 provinces with the highest amount of waste masks are listed as follows; İstanbul (nonwoven=26.88, meltblown=36.29, 3ply=43.68 tonnes/day), Ankara (nonwoven=9.91, meltblown=13.38, 3ply=16.11 tonnes/day), İzmir (nonwoven=7.76, meltblown=10.47, 3ply=12.61 tonnes/day), Bursa (nonwoven=5.40, meltblown=7.29, 3ply=8.78 tonnes/day), and Antalya (nonwoven=4.45, meltblown=6.01, 3ply=7.23 tonnes/day), respectively. In Turkey, 91.3% of medical waste collected in health institutions in 2019 (90,920 tonnes) was sterilized and disposed of in storage areas (83,010 tonnes). 8.7% of medical waste was sent to incineration facilities and disposed (7,910 tonnes). Considering these values, 132, 178.35, and 214.7 tonnes/day of nonwoven, meltblown, and 3-ply face mask wastes can be disposed by sterilization and the remaining 12.7, 17, and 20.44 tonnes/day by incineration, respectively.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus5OpenAlex4
    Scopusİncele
  • MakaleAçık Erişim2021Scopus SJRQ2
    Drying of licorice root by novel radiative methods

    Icier, Filiz; Ozmen, Duygu; Cevik, Mutlu; Cokgezme, Omer Faruk

    In this study, licorice root was successfully dried using two different radiative dryers (Carbon fiber-assisted cabin drying-CFACD and infrared drying-ID), and their effects on some drying characteristics, quality properties, and energy-exergy efficiency were investigated. Page and Verma models were the best models describing the drying behavior of licorice root for CFACD and ID methods, respectively. ID protected total phenolic content (TPC) better than CFACD while the changes of color properties were higher for ID. Energy and exergy efficiencies of CFACD were 40.20 ± 0.20% and 31.87 ± 0.10%, respectively, while these values were 10.39 ± 0.33% and 9.99 ± 0.27% for ID, respectively. Practical applications: The radiative heating method has advantages such as shorter drying time, high-energy efficiency, and high heat transfer coefficient compared to convective drying methods. Infrared drying (ID) is known as the common energy efficient drying method for food materials while the information on the performance of other type of radiative carbon fiber assisted drying (CFACD) systems is limited. In this study, the use of carbon fiber assisted cabin dryer for drying of licorice was evaluated by comparing other radiative type infrared dryer. The drying characteristics of licorice samples having high amount of phenolic contents were compared both in terms of quality and energy performance characteristics of dryers. Energy and exergy efficiencies of CFACD were found to be higher than ID. In addition, more homogeneous temperature distribution and less color change were obtained in the CFACD process. It was determined that the CFACD process could be recommended for drying of licorice samples rather than ID.

    • SDG 2 · Açlığa Son
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus18WoS13OpenAlex15
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2021Scopus SJRQ1
    Silane doped biodegradable starch-PLA bilayer films for food packaging applications: Mechanical, thermal, barrier and biodegradability properties

    Gürler, Nedim; Paşa, Salih; Temel, Hamdi

    In this work, pure potato starch (PPS) purified from waste potato starch, was recovered and used. PPS was modified by 3-APTMS (3-(aminopropyl) trimethoxy silane) to manufacture a crosslinked film. To obtain a bilayer PPS-3APTMS-PLA film, the polylactic acid (PLA) was employed with PPS-3APTMS by casting method. The resulting materials, PPS-3APTMS and PPS-3APTMS-PLA were characterized by attenuated total reflectance fourier transform ınfrared (ATR-FTIR), x-ray Diffraction (XRD), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA). The silane-doped bilayer films have more thermal stability compared to PPS. The mechanical, solubility, swelling, water vapor permeability, optical properties and biodegradability under controlled compost conditions were examined. When the tensile strength of the PPS, PPS-3APTMS and PPS-3APTMS-PLA films were evaluated, the tensile strength (TS) were to 1.017±0.35 MPa, 1.437 ± 0.19 MPa and 10.918 ± 1.30 MPa, respectively. The PPS and PPS-3APTMS films were not elongation at break, while it was found about 21.94 ± 9.48 for the bilayer PPS-3APTMS-PLA film. The solubility, swelling, water vapor permeability, and transparency decreased for bilayer films. The water vapor permeability of PPS, PPS-3APTMS and PPS-3APTMS-PLA films were obtained as 31.69±0.4 × 10−7 g s−1 m−1 Pa−1, 28.96±0.4 × 10−7 g s−1 m−1 Pa−1, and 14.26±0.3 × 10−7 g s−1 m−1 Pa−1, respectively. Then, the biodegradability of films was performed under controlled compost conditions for 46 days according to ISO-14,855 standard. The biodegradation of PPS, PPS-3APTMS and PPS-3APTMS-PLA was also calculated as 9.30%, 5.45% and 5.08%. Biodegradation of PPS-3APTMS film decreases compared to PPS. Furthermore, the biodegradation value of bilayer film, PPS-3APTMS-PLA, was also decreased due to the slower degradation tendency of PLA. The contribution to the reusability of waste starch and the modifying of starch for food packaging and coating applications are the novelty aspects of the current study.

    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus93WoS77OpenAlex90
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2021Scopus SJRQ1
    The bioremediation of glyphosate in soil media by some newly isolated bacteria: The COD, TOC removal efficiency and mortality assessment for Daphnia magna

    Korkmaz, Volkan; Yildirim, Numan; Erguven, Gokhan Onder; Durmus, Barbaros; Nuhoglu, Yasar

    In this study, the bioremediation capacity of three isolates of Bacillus aryabhattai, Pseudomonas azotoformans and Sphingomonas pseudosanguinis and their consortia at glyphosate added soil medium investigated via the reduction of chemical oxygen demand (COD) and total organic carbon (TOC) parameters in filtrate waters obtained from a designed bioremediation setup. Additionally, mortality assays were performed on the filtrate waters with model organism Daphnia magna. According to the results of the experiments, at the end of the 11 days, the highest COD reduction rate seen in media with S. pseudosanguinis as 92.1% while TOC rate was 69.13% in consortia media. While the mortality rate was 10, 10 and 5% on B, P and S application groups at the end of the 72th respectively, these rates were 100% in control group at the end of the 48th. According to the results obtained from bioremediation and mortality assessment, these bacteria can reach the high bioremediation rate one by one and in consortia media.

    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
    • SDG 15 · Karasal Yaşam
    AtıfScopus14OpenAlex16
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2021Scopus SJRQ1
    Electrocoagulation induced treatment of indigo carmine textile dye in an aqueous medium: the effect of process variables on efficiency evaluated using biochemical response of Gammarus pulex

    Tanyol, Mehtap; Yildirim, Nuran Cikcikoglu; Alparslan, Dilek

    Indigo carmine removal from aqueous solutions was investigated by the electrocoagulation process and biochemical responses of Gammarus pulex to solutions before and after treatment were studied. Electrocoagulation experiments in the first stage were carried out with central composite design (CCD) using response surface methodology (RSM). Optimization of process variables that maximize indigo carmine removal by electrocoagulation process was carried out by using a second-order model within the studied test range of various process variables. According to the optimization results, optimum conditions for obtaining 82.55% maximum indigo carmine removal were pH 5.86, a current density of 13.31 mA/cm2, an indigo carmine concentration of 20.01 mg/L, and a time period of 115.80 min. Under optimum conditions for indigo carmine removal, the amount of sludge formed was 0.928 kg/m3, electrode consumption was 0.0305 kg/m3, and energy consumption was 7.461 kWh/m3. The operating cost was calculated as 0.79 US$/m3 under treatment conditions where optimum indigo carmine removal was achieved. In the second stage, G. pulex was exposed to treated and untreated synthetic indigo carmine solutions obtained from experiments according to optimum conditions in order to investigate the biochemical response for 24 and 96 h. Treatment efficiency was evaluated with superoxide dismutase (SOD), catalase (CAT), glutathione S-transferase (GST), and cytochrome P450 1A1 (CYP1A1) biomarkers. Results clearly showed that the electrocoagulation process was a simple and effective treatment method for the decolorization of wastewaters containing indigo carmine dye. The bioassays used in the present study provided good credibility for checking the detoxification of treated and untreated indigo carmine solutions.

    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus14WoS12OpenAlex16
    ScopusWeb of SciencePubMedİncele
  • MakaleAçık Erişim2021Scopus SJRQ3
    Removal of total organic carbon and color from slaughterhouse wastewaters using electrocoagulation process: Central composite design optimization

    Tanyol, Mehtap; Tevkur, Servet

    In the present work, the process of electrocoagulation was utilized to remove total organic carbon (TOC) and color from slaughterhouse wastewaters and response surface methodology (RSM) inte-grated central composite design (CCD) was applied to optimize the operating factors of the pro-cess, that used iron electrodes. The optimal values for the removal of TOC and color were achieved with the quadratic regression model obtained from CCD. The optimum points for current density, inter-electrode distance, and reaction time obtained by the numerical analysis were 22.97 mA/m2, 12.03 mm, and 78.95 min for TOC, while these values were 23.08 mA/m2, 15.84 mm, and 80.77 min for color, respectively. At the optimum values, maximum TOC and color removal were obtained as 94.77% and 99.32%, respectively. The results indicated that the electrocoagulation process is an effective treatment technique for the removal of TOC and color from slaughterhouse wastewaters.

    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus5WoS4OpenAlex3
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2021Scopus SJRQ1
    Effect of pumice powder and artificial lightweight fine aggregate on self-compacting mortar

    Etli, Serkan; Cemalgil, Selim; Onat, Onur

    An experimental program was conducted to investigate the fresh properties, mechanical properties and durability characteristics of the self-compacting mortars (SCM) produced with pumice powder and Artificial Lightweight Fine Aggregate (aLWFA). aLWFA was produced by using fly ash. A total of 16 different mixtures were designed with a constant water-binder ratio of 0.37, in which natural sands were partially replaced with aLWFA and pumice powder at different volume fractions of 5%, 10% and 15%. The artificial lightweight aggregates used in this study were manufactured through cold bonding pelletisation of 90% of class-F fly ash and 10% of Portland cement in a tilted pan with an ambient temperature and moisture content. Flowability tests were conducted on the fresh mortar mixtures beforehand, to determine the self-compacting characteristics on the basis of EFNARC. To determine the conformity of the fresh mortar characteristics with the standards, mini-slump and mini-V-funnel tests were carried out. Hardened state tests were conducted after 7, 28 and 56 days to determine the flexural strength and axial compressive strength respectively. Durability, sorptivity, permeability and density tests were conducted at the end of 28 days of curing time. The test results showed that the pumice powder replacement improved both the fresh state and the hardened state characteristics of the mortar and the optimum mixture ratio was determined as 15%, considering other studies in the literature. In the aLWFA mixtures used, the mechanical and durability characteristics of the modified compositions were very close to the control mixture. It is concluded in this study that mixtures with pumice powder replacement eliminated the negative effects of the aLWFA in the mortars and made a positive contribution.

    • SDG 9 · Sanayi, Yenilikçilik ve Altyapı
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus16WoS15OpenAlex17
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2021Scopus SJRQ1
    Green supplier selection for textile industry: a case study using BWM-TODIM integration under interval type-2 fuzzy sets

    Celik, Erkan; Yucesan, Melih; Gul, Muhammet

    Although environmental awareness has reached a high level, enterprises—regardless of their working domains—follow the concept of greenness for their practices. This awareness among the stakeholders and supply chain experts has a positive impact on the purchasing departments of enterprises in various sectors to consider greenness in their procurement processes. The critical decision that must be made in green supply chain management (GSCM) is supplier selection. In the textile industry, a highly competitive market in recent years, suppliers for this industry have crucial roles in business activities considering environmental issues. Therefore, green supplier selection (GSS) in the textile industry is considered a must-be process for the stakeholders. In this study, a GSS problem is tackled as a multi-criteria decision process. Best worst method (BWM) and TODIM (an acronym in Portuguese of interactive and multi-criteria decision-making) methods are merged under an improved fuzzy concept of interval type-2 fuzzy sets (IT2FSs). In determining green suppliers’ evaluation criteria, BWM with interval type-2 fuzzy numbers (IT2F-BWM) is used. In selecting green suppliers, an interval type-2 fuzzy TODIM (IT2F-TODIM) is applied. Considering the characteristics of IT2FSs, BWM, and TODIM methods either individually and in integrated style, the proposed approach can handle uncertainty in the decision-making of GSS. To demonstrate the applicability of the approach, a case study in the Turkish textile industry is performed. Three green supplier alternatives (S1, S2, and S3) are assessed under forty-two sub-criteria. The study shows the most significant sub-criteria are recognized as dye and print quality, product design and pattern suitability, profit on the product, variation in price, and purchase cost. S2 green supplier has been selected as the most appropriate one. A sensitivity analysis is also fulfilled to check variation in the ranking of green suppliers.

    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus88WoS72OpenAlex100
    ScopusWeb of SciencePubMedİncele
  • MakaleAçık Erişim2021Scopus SJRQ3
    Optimization of the adsorption of methyl green dye on almond shells using central composite design

    Tanaydin, Mehmet Kayra; Goksu, Ali

    Almond shells, known as the agricultural industry’s waste, were utilized to adsorb methyl green dye from aqueous solutions. The effects of initial concentration (2–10 mg/L), the adsorbent dosage (0.1–0.5 g), shaking speed (150–250 rpm), pH (4–7), temperature (20°C–50°C), and particle size (137–892 μm) on methyl green adsorption on the almond shell were examined. The response surface methodology was used to optimize the methyl green dye’s adsorption process using the almond shell. The central composite design was utilized to obtain optimum experimental conditions. Performed experiments obtained the isotherm data, and it was analyzed by utilizing the Langmuir, Freundlich, and Temkin isotherm models. The isotherm data can be fitted well by the Langmuir model. The pseudo-second-order model can anticipate the adsorption kinetics. The thermodynamic parameters such as ΔG° ΔH°, and ΔS° were calculated and found to be –2.878, 42.12 kJ/mol, and 0.151 kJ/mol K, respectively. These values demonstrated that the present adsorption process was feasible, spontaneous, and endothermic in the temperature scope of (20°C–50°C). This study indicates that almond shells were considered an efficient adsorbent to remove from the aqueous solutions. The maximum adsorption capacity of the almond shell (1.1 mg/g) was obtained. In this system, the almond shell’s pre-activation process was not preferred because it will create an extra cost. Adsorption kinetics studies showed that the model is represented as a pseudo-second-order of adsorption data.

    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus19WoS19OpenAlex19
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2021Scopus SJRQ1
    Effect of waste textile dye adsorbed almond shell on self compacting mortar

    Cemalgil, Selim; Onat, Onur; Tanaydın, Mehmet Kayra; Etli, Serkan

    The aim of the current experimental study is to investigate the effect of waste textile dye absorbed almond shell on fresh and mechanical characteristics of self-compacting mortar (SCMs). In this context, eight SCMs were designed by substituting Violet Dye Solution adsorbed Almond shell (VDSA) at the rate of 0%, 2.5%, 5.0%, 7.5%, 10.0%, 12.5%, 15.0% and 17.5% as a cement on weight basis including the control mix. To measure the rheological properties of SCMs, mini slump and V-Funnel tests were conducted. A total of 72 beams of 40x40x160 mm3 dimension specimens were casted and immersed in water curing at the end of the 7, 28 and 56 days to determine the mechanical parameters. 48 cubes of 50x50x50 mm3 dimensions were casted and kept in the curing tank to determine durability characteristics such as porosity, sorptivity and specific gravity. Quantitative analyses are also performed by using Scanning Electron Microscopes (SEM), X-ray Diffraction Analysis (XRD), Energy-Dispersive X-ray Spectroscopy (EDS) and Fourier Transform Infrared (FTIR). The experimental results indicated that as the content of VDSA enchases, a remarkable enhancement in flexural strength at early days age and 28 days age strength. Whereas, increasing the content of VDSA resulted in a considerable decrease in compressive strength higher than 5%.

    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus20WoS16OpenAlex26
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2020
    Katı Atık Yönetiminde Kompostlaştırmanın Önemi, Problemler ve Çözüm Önerileri: Türkiye Örneği

    Erguven, Gokhan Onder; Kanat, Gurdal

    Organik atıkların yüksek üretim oranları ve bu atıkların açık çöp sahalarına veya sıhhi olmayan depolama alanlarına atılması olumsuz birtakım çevresel, ekonomik ve sosyal sorunlara neden olmaktadır. Kompostlama, organik atıkların yönlendirilmesinde daha temiz teknolojilerden birini temsil eder. Elde edinilen son raporlara göre, Türkiye'de 2018 yılında üretilen belediye atık miktarı 32,2 milyon ton olarak gerçekleşti. Diğer ülkelere benzer şekilde, Türkiye'de belediye atıklarının en uygun ve ekonomik yöntemlerle bertaraf edilmesi planlanmaktadır. Belediye atık yönetimi planlaması yönetmeliklerin amaçlarına dayanmaktadır. Mevcut durumda, Çevre Bakanlığı verilerine göre Türkiye'de 8 adet biyolojik atık işleme tesisi bulunmaktadır. Ayrıca, karışık belediye atıklarının işlendiği 6 mekanik-biyolojik ön arıtma ve geri dönüşüm tesisi bulunmaktadır. Atık yönetim planlarında, 2023 yılında oluşan atıkların %65'i düzenli depolama ve %35'i geri kazanımı hedeflenmiştir. Bu çalışmada, Türkiye ve diğer benzer ülkelerdeki belediye atık yönetimi sorunlarının detayları ve başarı öyküleri incelenmiş ve bunlara ilave olarak sonuçlar tartışılmıştır. Kompostlamanın birçok ülke ve Türkiye'de, bazı sorunlarından dolayı hala yaygın bir yöntem olmadığı görülmektedir. İdari ve teknik faktörler değerlendirildiğinde, atık transferi ile düzenli depolama ve biyogaz geri kazanımı ülkedeki en iyi, en kolay ve ekonomik yöntemdir. Biyolojik ve katı atık yönetimi oldukça önemli bir iştir. Bu proses yönetim sistemi için önemli bir rol oynar. Buna ilave olarak Türkiye’deki ve özellikle İstanbul ilindeki ulusal sıfır atık faaliyetleri ile ilgili yönetim ilk aşamadadır ve bu işlemlerin daha iyi sonuç almaları için uzun bir zaman periyoduna ihtiyacı olduğu aşıkardır.

    • SDG 11 · Sürdürülebilir Şehirler ve Topluluklar
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfOpenAlex6TR Dizin4
    TR Dizinİncele
  • MakaleAçık Erişim2020
    Kırmızı Biber Tohumundan Ultrason Destekli Fenolik Ekstraksiyonunun Tepki Yüzey Metodu ile Optimizasyonu

    İnanç, A. Levent; Atalay, A. Burcu

    Bu çalışmada, kırmızı biberlerin işlenmesi sonucu atık ürün olarak elde edilen Kahramanmaraş kırmızı biber (Capsicum annuum L.) çekirdeklerinin içerdiği fenolik bileşenler, ultrason-destekli ve geleneksel çözücü ekstraksiyon yöntemleri ile ekstrakte edilmiştir. İki farklı ekstraksiyon yöntemi, toplam fenolik içerik ve antioksidan kapasite yönünden değerlendirilmiştir. Daha yüksek antioksidan kapasite ile maksimum toplam fenolik içeriği elde etmek amacıyla, fenolik ekstrakların, ekstraksiyon sıcaklığı (40, 50 ve 60 °C), ekstraksiyon süresi (20, 40 ve 60 dk.) ve çözücü hacmi (50, 75 ve 100 mL) aralığını içeren ultrason-destekli ekstraksiyon koşullarını optimize etmek için tepki yüzey yöntemi kullanılmıştır. Fenoliklerin ekstraksiyonuna, çözücü hacmi, ekstraksiyon sıcaklığı ve süresinin etkileri değerlendirilmiştir. Tepki yüzey yöntemi sonuçlarına göre, optimum koşullar, 51 °C ekstraksiyon sıcaklığı, 60 dakika ekstraksiyon süresi ve 50 mL çözücü hacmi olarak belirlenmiştir. Fenolik bileşenlerin ekstraksiyonu üzerine ultrason uygulamasının, geleneksel yönteme göre daha etkili olduğu görülmüştür.

    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfOpenAlex6TR Dizin1
    TR Dizinİncele
  • MakaleAçık Erişim2020
    Investigation of Mechanical Properties of Granulated Waste Rubber Aggregates Substituted Self-Compacting Concrete Mortar Produced with Different Cement

    Etli, Serkan; Akgül, Melek; Doğan, Orhan

    Storage or disposal of waste vehicle tires is difficult, costly and time consuming. Waste tires, which cause the release of pollutant gases to the environment due to its chemical structure in the process of destruction, are considered as an important recycling material in the context of developing and advancing technology and alternative products. Waste vehicle tires are granulated in certain sizes after the disintegration phase and reused in many different fields. With this experimental study, it is aimed to examine the fresh and hardened properties of 12 different self-compacting mortar (SCM)samples of Granulated Vehicle Tire Aggregates, which are substituted with 5 different fine aggregates and prepared with two different cement types. The evaluation of the workability properties of fresh SCM samples prepared in accordance with EFNARC was done with mini slump-flow and mini V-funnel experiments. In order to determine the mechanical properties of the hardened SCM, compressive and flexuralstrength tests were performed on the 3rd, 7th and 28th days of prismatic samples in 40x40x160mm dimensions, and capillary water absorption test is carried out on cubic samples in 50x50x50 mm dimensions on the 28th day. The optimum usability rate of Granulated Vehicle Tire Aggregates in SCM mixtures produced separately with CEM-I 42.5R and CEM-IV 32.5R cement is interpreted through graphs and tables. With this study, it was observed that when the rate of Granulated Vehicle Tire Aggregates was increased in the SCM mixture, the capillary water absorption amount increased, while the compressive and flexural strength decreased.

    • SDG 9 · Sanayi, Yenilikçilik ve Altyapı
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfOpenAlex13TR Dizin7
    TR Dizinİncele
  • MakaleAçık Erişim2020
    Kızıltepe İleri Biyolojik Atıksu Arıtma Tesisi’nin KOİ, BOİ₅ ve AKMYönünden İşletme Verimliliğinin Değerlendirilmesi

    Tatar, Sule; Sağlam, Mehmet Nedim

    Son yıllarda kentleşme oranının artmasıyla evsel nitelikli atıksular, çevre kirliliğinin ortaya çıkmasında rol oynayan önemli sebeplerden biri haline gelmiştir. Kentsel atıksu arıtma tesisleri bu kirliliği engellemek için yapılmış olan, evsel nitelikli atıksularınaktarılacağı alıcı ortama varmadan önce zararlı etkilerini engelleyen veya olabilecek en düşük seviyeye indiren tesislerdir. Buçalışmada Kızıltepe Biyolojik Atıksu Arıtma Tesisi’nde 8 ay boyunca günlük tesis giriş ve çıkışından alınan 24 saatlik kompozitnumuneler ile KOİ, BOİ5 ve AKM parametreleri analiz edilmiş ve tesis verimliliği gözlemlenmiştir. Buna göre tesis; %93 KOİ, %93BOİ5 ve %94 AKM giderimi ile çalışmaktadır. Mardin Su ve Kanalizasyon İdaresi Genel Müdürlüğü kontrolündeki Kızıltepe İleriBiyolojik Atıksu Arıtma Tesisi, Kentsel Atıksu Arıtma Yönetmeliği deşarj limitlerine göre değerlendirilmiştir.

    • SDG 2 · Açlığa Son
    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfOpenAlex2TR Dizin2
    TR Dizinİncele
  • MakaleAçık Erişim2020
    Elektrokoagülasyon Prosesi Kullanılarak Mezbaha Atıksularının Arıtımı Üzerine Ortam Parametrelerinin Etkisi

    Tanyol, Mehtap; Tevkur, Servet

    Mevcut çalışmada, mezbaha atıksuyunun arıtımı üzerine elektrokoagülasyon prosesinin etkinliği kesikli bir reaktörkullanılarak araştırılmıştır. Akım yoğunluğu (5-20 mA m-2), başlangıç pH’ı (3-10) ve elektrotlar arası mesafe (4-16 mm) gibiçeşitli parametrelerin etkisi optimum elektrokoagülasyon koşulunu belirlemek için incelenmiştir. Paralel bağlanmışmonopolar demir elektrotlar tüm deneyler için kullanılmıştır. Deneylerin performansı temel olarak kimyasal oksijen ihtiyacı(KOİ) giderimi kullanılarak değerlendirilmiştir. 15 mA m-2akım yoğunluğu, doğal pH (7.47) ve 16 mm elektrotlar arasımesafe optimum koşullar olarak seçilmiştir. Bu koşullar altında %90.63’lük KOİ giderim verimi elde edilmiştir. Sisteminişletme maliyeti, enerji ve elektrot tüketimi dikkate alınarak hesaplanmış ve 9.15 TL kg-1 KOİ-1 olarak bulunmuştur.

    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
  • MakaleYalnız künye2020Scopus SJRQ1
    Mechanical, thermal, and morphological properties of powder coating waste reinforced acetal copolymer

    Kismet, Yilmaz; Wagner, Manfred H.

    The present study investigates the individual effects of three different thermosetting waste materials, used as fillers, on the mechanical, thermal and flow properties of acetal copolymers (POM). Different amounts ranging from 5% to 30% by weight of hydrolyzed powder coating recyclates were mixed as filler material in POM. The matrix and the fillers were first dry-mixed and then compounds were prepared through melt extrusion. The resulting compounds were cooled, granulated, and then standard tensile test bars were produced through use of an injection-molding machine. We investigated the mechanical and thermal properties of test specimens, and tensile strength, bending strength and impact strength were evaluated as a function of type and amount of filler material in the POM matrix. In addition, the change in melt flow index of POM/filler mixtures was determined, before and after extrusion. Furthermore, the morphology of the specimens was examined via electron microscopy. The results of this investigation are encouraging and present an innovative approach to reutilize hydrolyzed electrostatic powder coating wastes with thermoset structures as fillers in acetal copolymers.

    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus10WoS8OpenAlex13
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2020Scopus SJRQ1
    Roles of aluminium shavings and calcite on engineering properties of cement-based composites

    Gulmez, Nihan

    In the construction industry, which large amounts of raw materials are consumed, substituting even small parts of concrete components with waste materials may lead to significant savings in consumed energy and natural resources hence support prevention of environmental pollution. In this study, an experimental program was carried out to find a reliable and eco-friendly method for eliminating large quantities of calcite powders originating from the marble processing industry and also aluminium shavings, a nondisposable product of metal working and shaping industry. Physical, mechanical and microstructural properties of the mortars produced with industrial wastes at different replacement percentages were evaluated. Adding up to 20% calcite to the mortar mixtures instead of cement did not cause a significant change in water absorption values compared to control mortar. In addition, the gradual increase of aluminium shavings in all mortar mixtures resulted in a significant decrease in apparent porosity. In mortars based on 10% calcite, an increase of 52% in 7-days flexural strength was achieved with the addition of 4% aluminium shavings.

    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus23WoS20OpenAlex24
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2020Scopus SJRQ2
    Phycoremediation of Precious Metals by Cladophora fracta From Mine Gallery Waters Causing Environmental Contamination

    Topal, Murat; Öbek, Erdal; Arslan Topal, E. Işıl

    We have presented a study to determine the possibility for the usage of Cladophora fracta as bioaccumulator of the metals (Au) and silver (Ag) both have characteristics of pollutant and precious in mine water. The highest concentrations accumulated by C. fracta were determined as 5.8 ± 0.3 and 5323 ± 75 µg/kg for Au and Ag, respectively. The results showed that the accumulation of the metals measured followed the order of Ag > Au. The Metal Pollution Index (MPI) values calculated between 39.37 × 10−3 and 175.7 × 10−3 were used to determine the pollution degree of C. fracta. As a result, it was determined that C. fracta highly accumulated the precious metals from the gallery water. Therefore, C. fracta was a good bioaccumulator for the remediation of Au and Ag in mine gallery waters. In this way, it is possible to minimize or eliminate the environmental risks of the precious metals in the gallery waters.

    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus9WoS6OpenAlex6
    ScopusWeb of SciencePubMedİncele