Sürdürülebilir Kalkınma Amaçları
Yazarlar
- Gul, Muhammet(110)
- Güler, Ömer(70)
- Akkurt, Nevzat(69)
- Serdar, Osman(57)
- Yucesan, Melih(55)
- Celik, Erkan(53)
- Tekin, H.O.(52)
- ALMisned, Ghada(49)
- Bulut, Hasan(49)
- Baskonus, Haci Mehmet(48)
- Paksoy, Mehmet Yavuz(46)
- Yildirim, Numan(45)
- Kocabaş, Mehmet(41)
- Yildirim, Nuran Cikcikoglu(41)
- Zengin, Gokhan(40)
- Alataş, Mevlüt(39)
- Ince, Muharrem(38)
- Benzer, Fulya(37)
- Mete, Suleyman(34)
- Aslan, Naim(33)
- Kutlu, Banu(33)
- Yildirim, Ozal(33)
- Topal, Murat(32)
- Tanyol, Mehtap(30)
- Batan, Nevzat(28)
- Özkul, İskender(28)
- Kök, Mediha(27)
- Utku, Anıl(27)
- Can, Erkan(26)
- Danabas, Durali(26)
- Sulaiman, Tukur Abdulkadir(26)
- Ates, Mehmet(25)
- Ezer, Tülay(25)
- Guler, Omer(25)
- Kutluyer, Filiz(25)
- Say, Yakup(25)
- Serin, Faruk(25)
- Erguven, Gokhan Onder(24)
- Onat, Onur(24)
- Cakilcioglu, Ugur(23)
Yayınlar
- MakaleAçık Erişim2013EFFECT OF EMBEDDED DELAMINATIONS ON IMPACT BEHAVIOR OF LAMINATED COMPOSITES
Sabanci, Eray; Karakuzu, Ramazan
In this study, the influence of size and location of embedded delamination on impact behavior of laminated composite was investigated, experimentally. The specimens were produced as for with and without delamination by vacuum assisted resin infusion molding method (VARIM). CEAST-Fractovis plus impact test machine was used in the experiments. As a result of the experiments, the location of delamination on the impact behavior was seen to be more effective than the size of delamination.
AtıfWoS3OpenAlex5
İncele - MakaleYalnız künye2013Scopus SJRQ2Molecular characterisation of the genus Papaver section Oxytona using ISSR markers
Gürkök, Tugba; Kaymak, Elif; Boztepe, Gulsen; Koyuncu, Mesut; Parmaksiz, Iskender
Papaver bracteatum Lindl., P orientate L., and P. pseudo-orientale (Fedde) Medw., species of section Oxytona Bernh. in the genus Papaver L., are found widely in the native flora of Turkey. They are commercially important for their high alkaloid content. Because genus Papaver section Oxytona has similar morphological characters, it is not easy to distinguish these species. We used the inter-simple sequence repeat (ISSR) molecular marker system to determine the molecular characterisation of this section. In this study, 20 ISSR primers have been studied in 180 accessions collected from 5 different regions of Turkey. A total of 82 bands were obtained, of which 80 were polymorphic. Average genetic distance was found to be 0.35, the Shannon index was 0.50, and the polymorphism rate was 96.97%. The primer AT10 had the smallest number of bands, which was 3, while the primers AT19 and AT3 had the greatest number of bands, which was 5. In conclusion, the ISSR marker system can be used for the classification of section Oxytona.
AtıfWoS8OpenAlex12İncele - MakaleYalnız künye2013Scopus SJRQ3Effects of Intensive and Semi-Intensive Rearing on Growth, Survival, and V-Shaped (Lordotic) Skeletal Deformities in Juvenile Gilthead Sea Bream (Sparus aurata)
Can, Erkan
Intensive production can reduce production costs and improve efficiency of larvae culture. This study compared the effects of intensive and semi-intensive production on growth, survival, and V-shaped skeletal deformities in juvenile gilthead sea bream (Sparus aurata). At the end of the 50-day study, survival was 68.01 +/- 0.8%, mean weight was 1.32 +/- 0.03 g, and lordosis was 32% among juveniles raised in the intensive system. Survival and mean weight were significantly higher, 92.06 +/- 1.1% and 1.61 +/- 0.02 g, respectively, among juveniles raised in the semi-intensive system, and none had lordosis (p<0.05). Results suggest that semi-intensive systems are more advantageous than intensive for rearing sea bream juveniles.
AtıfWoS2İncele - MakaleAçık Erişim2013Scopus SJRQ2Effect of mixed use of thyme and fennel oils on biochemical properties and electrolytes in rainbow trout as a response to Yersinia ruckeri infection
Gulec, Azime Kucukgul; Danabas, Durali; Ural, Mesut; Seker, Engin; Arslan, Ali; Serdar, Osman
The aim of study was to compare the effects of supplementation of food with herbal oils (Thymus vulgaris and Foeniculum vulgare) on biochemical properties and electrolytes of rainbow trout infected with Yersinia ruckeri. In total, 120 healthy fish (mean weight 84 +/- 1.02 g) were equally divided into four experimental groups. The experimental study was carried out for one week. The first group was control without supplementation and infection, the second group was infected and without oil supplementation, the third group was supplemented with oils (10 ml.100 g(-1) rates) for one week and infected with Y ruckeri and the last group was oil supplemented without infection. Results indicated that fish fed with dietary supplements showed enhanced bactericidal activity, total protein, albumin, cholesterol, triglyceride and bilirubin compared to the control (P < 0.05). As the value of herbal oils was increased in diets, the plasma glucose level decreased. The levels of K, Na, Ca, and Mg increased whereas Cl values decreased, compared to the control. It can be concluded that diet supplementation with herb oils used in this study can increase disease resistance by increasing levels of some biochemical parameters and electrolytes in rainbow trout to Y ruckeri infection.
AtıfWoS41OpenAlex52İncele - MakaleÖn baskısı açık2013Scopus SJRQ2Effect of dietary n-3 series fatty acids on sperm production in the freshwater crayfish, Astacus leptodactylus (Eschscholtz) (Astacidae)
Harlioglu, Muzaffer Mustafa; Köprücü, Kenan; Harlioglu, Ayse Gul; Yonar, Serpil Mise; Duran, Tuba Cakmak; Çakmak, Mehmet Nuri; Aksu, Onder; Özcan, Sinan; Kutluyer, Filiz; Gündogdu, Hande
The objective of the present work was to evaluate the effects of three different rates of long chain n-3 polyunsaturated fatty acid (LC n-3 PUFA) on the sperm number of Astacus leptodactylus. The experiment was carried out with the four following treatments: control group (not supplemented LC n-3 PUFA), D1 (1 %), D2 (2 %) and D3 (3 %). The sperm number of A. leptodactylus was counted; the reproductive system was weighted; and the macroscopical analysis of the testes and vasa deferentia (DVD) were conducted. In addition, gonado-somatic index (GI) and testes index (TI) were also calculated. The results showed that there was a significant difference between the crayfish fed LC n-3 PUFA supplemented diets (D1, D2, D3) and control in mean sperm number (P < 0.05). The highest sperm number was found for the crayfish fed D3 (6.27 +/- A 0.14 x 10(8) sperm/distal vas deferens section). The results also showed that the reproductive system of the crayfish fed D3 and D2 was significantly heavier than that of the crayfish fed the control and D1 (P < 0.05). On the other hand, there was not a significant difference in the testes weight and vasa deferentia weight between the crayfish fed the control and D1, and between the crayfish fed D2 and D3 (P < 0.05). GI of the crayfish fed D3 and D2 was significantly higher than that of the crayfish fed control and D1 (P > 0.05), but there was not a significant difference in the TI of the crayfish fed control, D1, D2 and D3 (P > 0.05). In conclusion, diets containing different levels of LC n-3 PUFA significantly increase the sperm number of A. leptodactylus, and they are crucial for the production of higher number of sperm in this species.
AtıfWoS30OpenAlex34İncele - MakaleAçık Erişim2013Scopus SJRQ1Effect of cooking procedures of kiymali pide, a traditional Turkish fast-food, on destruction of Escherichia coli O157:H7
Ilhak, Osman Irfan; Dikici, Abdullah; Can, Ozlem Pelin; Seker, Pinar; Öksüztepe, Gulsum; Çalicioglu, Mehmet
The objective of the present study was to obtain data about cooking time and temperature of kiymali pide in the restaurants and to investigate thermal inactivation of E. coli O157:H7 during experimental kiymali pide making. A field study was conducted in randomly selected 23 of 87 pide restaurants. Processing parameters including oven temperature, cooking period and post-cooking temperature were determined. Kiymali pide samples were prepared using ground beef filling experimentally inoculated with E. coli O157:H7 (7.6 log(10) CFU/g). Pide samples were cooked at a conventional oven at 180 degrees C for 180, 240, 270, 300 and 330 s. Results of the current study suggest that cooking kiymali pide at 180 degrees C for at least 330 s (5.5 min) may provide sufficient food safety assurance (>= 6 log(10) CFU/g) for E. coli O157:H7. (C) 2013 Elsevier Ltd. All rights reserved.
AtıfOpenAlex3
İncele - BildiriYalnız künye2013EXAMINATION OF RADIAL FORCE WITH FINITE ELEMENT METHOD IN SWITCHED RELUCTANCE MOTOR
Polat, Mehmet; Öksüztepe, Eyyup; Omaç, Zeki; Yildirim, Merve; Kürüm, Hasan
The aim of this study is computation of radial forces shown as one of the main and important reasons of noise in Switched Reluctance Motor (SRM). In this paper, radial forces in saturation and unsaturation regions of a standart submersible pump type 8/6-pole SRM have been calculated and their changes have been obtained. ANSYS 10.0 package program which makes a solution with Finite Element Method (FEM) has been used for computation of radial forces. After geometric shapes are given, radial forces have been calculated from unaligned position of rotor towards aligned position with angle of one degree according to different current values.
- MakaleAçık Erişim2013Scopus SJRQ3Effects of essential oil compounds on survival of Listeria monocytogenes and Escherichia coli O157:H7 in cig kofte
Dikici, Abdullah; Ilhak, Osman Irfan; Çalicioglu, Mehmet
This study was undertaken to evaluate the effects of some essential oil compounds for the inactivation of Listeria monocytogenes and Escherichia coli O157:H7 in cig kofte. In experiment 1, a cig kofte batch was inoculated with high levels of E. coli O157: H7 or L. monocytogenes (7.00 log(10) cfu/g) and the batches were divided into 6 groups. Each group was treated with 18 mL/kg of normal saline, cineole, limonene, carvone, linalool, or eugenol. Treatment with carvone, linalool, and eugenol resulted in a significant (P < 0.05) decrease in the numbers of both pathogens. In experiment 2, the cig kofte was inoculated with the same pathogens and each group was treated with 0 (control), 20, 22.5, and 25 mL/kg of eugenol. Increases in concentration did not cause a difference in pathogen reduction. The results showed that eugenol, carvone, and linalool can be used for the inactivation of E. coli O157: H7 and L. monocytogenes in cig kofte or similar foods.
AtıfWoS3OpenAlex5İncele - MakaleYalnız künye2013Scopus SJRQ3Effects of harvesting time and modified atmosphere packaging on biochemical changes in potato tubers
Batu, Ali; Sen, Levent
Undamaged potato tubers (cv. 'Marfona') grown in Tokat, Turkey, were used in this study. The tubers were cured for two weeks at 15 degrees C and 75-85% relative humidity. The tubers were sorted for size, shape and physical damage and were divided into two groups. One group was left unwrapped and the other was placed on polystyrene trays and heat-sealed in 30, 40 or 60 mu m low density polyethylene (LDPE) film or 38 mu m c-polypropylene (CPP) film. The samples were kept in temperature-controlled rooms at 5 +/- 1 degrees C and 75-85% RH for eight months. Samples were taken every month during storage, and the internal colour, ascorbic acid, titratable acidity, pH and total soluble solids were determined. Results indicate that the harvesting time and storage period significantly affected quality parameters. The highest increases in total soluble solids, minimum change in pH, lowest titratable acidity and ascorbic acid values were found in tubers in 38 mu m CPP harvested on July 25th. The lowest pH and ascorbic acids were found in the 40 mu m LDPE packaged tubers, while maximum titratable acidity was found in the unwrapped tubers harvested on 20th September. The L* values indicate that the internal lightness of the tubers generally decreased during the storage period, indicating that they became a bit darker during storage.
- MakaleYalnız künye2013Scopus SJRQ3The Effect of Different Feeding Protocols on Compensatory Growth of Black Sea Trout Salmo trutta labrax
Kocabas, Mehmet; Basçinar, Nadir; Kayim, Murathan; Er, Halil; Sahin, Halit
The objective of this study was to determine the effects of different feeding protocols on compensatory growth, feeding rate, and feed conversion efficiency of Black Sea Trout Salmo trutta labrax. To our knowledge, no previous feeding experiments with Black Sea Trout have incorporated a fasting period to simulate the handling and acclimation conditions experienced by farmed fish. Fifteen fish per tank (10.69 +/- 0.06cm and 13.22 +/- 0.14g, mean +/- SE) were stocked into 40-L fiberglass tanks. Fish were fed with different fasting-feeding regimes for 95 d and were equally allotted to four treatments (T-cont: control; T5-10: 5 d fasting, 10days feeding; T10-10: 10 d fasting, 10 d feeding; and T15-10: 15 d fasting, 10 d feeding) with three replicates per treatment. The results indicated that length (P = 0.0005), weight (P = 0.000), condition factor (P = 0.013), and specific growth rate (P = 0.014) were significantly affected by the interaction between feeding and time. All fasting treatments showed partial compensation during refeeding. There was an increase in daily feeding rate and feed conversion efficiency in fasting treatments compared with the control treatment. In contrast, at the end of the experiment specific growth rate, condition factor, and body weight in fasting treatments were significantly lower compared with the control treatment. We concluded that there was partial compensation of growth with regular refeeding after periods of feed deprivation (e.g., 5, 10, or 15 d) over a long term and a shorter fasting period may be preferred in order to achieve compensatory growth. Received November 9, 2012; accepted April 9, 2013
AtıfWoS6OpenAlex7İncele - MakaleYalnız künye2013Scopus SJRQ3COMPARATIVE ANATOMY OF STEM AND LEAF OF RICOTIA L. GROWING IN TURKEY
Selvi, Selami; Paksoy, Mehmet Yavuz
The present paper deals with a comparative anatomy of stem and leaf of Ricotia species growing in Turkey. In addition, stomatal index and rate of these species were calculated. A diagnostic key based on combined stem, leaf and leaf epidermal characteristics were presented. The presence or absence of trichome, cortex parenchyma layer, sclerenchyma, mesophyll structure and epidermal surface were found to be important characters for the identification of Ricotia species.
AtıfWoS8İncele - MakaleAçık Erişim2013Scopus SJRQ3Effect of Fly Ash and Silica Fume on compressive strength, sorptivity and carbonation of SCC
Turk, Kazim; Karatas, Mehmet; Gonen, Tahir
In this paper, ASTM C 618 Class F Fly Ash (FA) at 25%, 30%, 35% and 40% and Silica Fume (SF) at 5%, 10%, 15% and 20% replacement of Portland Cement (PC) CEM I 42.5 in SCC was used to evaluate the effect of types and quantity of powder additions on compressive strength and permeations properties of SCC. To this end, eight types of SCC were designed, in comparison with Vibrated Traditional Concrete (VTC). The results indicated that SCC specimens with SF15 had the highest compressive strength with 73.87 MPa for 130 days. The sorptivity values of SCC specimens with FA and SF were lower than those of VTC specimens regardless of type and quantity of powder additions. On the other hand, the carbonation resistance of VTC was higher than that of SCC specimens containing both SF and FA for all accelerated carbonation periods. Consequently, it can be said that type and quantity of powder additions had an important effect on the correlation among the compressive strength and permeation properties of SCC.
AtıfWoS69OpenAlex85İncele - MakaleAçık Erişim2013Scopus SJRQ2Bioaccumulation, Subacute Toxicity, and Tissue Distribution of Engineered Titanium Dioxide Nanoparticles in Goldfish (Carassius auratus)
Ates, Mehmet; Demir, Veysel; Adiguzel, Ragip; Arslan, Zikri
The increased use of nanosized materials is likely to result in the release of these particles into the environment. It is, however, unclear if these materials are harmful to aquatic animals. In this study, the sublethal effects of exposure of low and high concentrations of titanium dioxide nanoparticles (TiO2 NPs) on goldfish (Carassius auratus) were investigated. Accumulation of TiO2 NPs increased from 42.71 to 110.68 ppb in the intestine and from 4.10 to 9.86 ppb in the gills of the goldfish with increasing exposure dose from 10 to 100mg/L TiO2 NPs. No significant accumulation in the muscle and brain of the fish was detected. Malondialdehyde as a biomarker of lipid oxidation was detected in the liver of the goldfish. Moreover, TiO2 NPs exposure inhibited growth of the goldfish. Although there was an increase (8.1%) in the body weights of the goldfish for the control group, in the low and high exposure groups 1.8% increase and 19.7% decrease were measured, respectively. The results of this study contribute to the current understanding of the potential ecotoxicological effects of nanoparticles and highlight the importance of characterization of NPs in understanding their behavior, uptake, and effects in aquatic systems and in fish.
AtıfWoS53OpenAlex80İncele - MakaleYalnız künye2013Scopus SJRQ3EFFECTS OF SEAWATER ACCLIMATIZATION ON GILL Na+-K+-ATPase ACTIVITIES AND CHLORIDE CELLS IN RAINBOW TROUT (Oncorhynchus mykiss) AND BROWN TROUT (Salmo trutta forma fario)
Kizak, V.; Ozden, O.; Guner, Yusuf
In this study, rainbow trout (Oncorhynchus mykiss) (162.7 +/- 3.03 g) and brown trout (Salmo trutta forma fario) (160.9 +/- 2.94 g) were transferred to full-strength seawater (36.5 gl(-1)) for directly and gradually (21 days), then changes in gill Na+-K+-ATPase activity and size of chloride cells associated with environmental salinity were investigated and also survival of trouts were evaluated in seawater. All fish died when brown trouts were transferred into seawater directly but rainbow trouts survived 50 - 58.3 %. However, significant difference was recorded between brown and rainbow trouts in terms of survival rates by gradual acclimation. Survival of brown trout and rainbow trout that were transferred in seawater gradually, was 66.7 - 75 % and 83.3 - 91.7 %, respectively (p < 0.05). Gill chloride cell sizes in both species increased at 36.5 gl(-1) salinity. The lowest sectional area of chloride cells was determined at the point of death in brown trouts which were transferred directly. Following direct transfer to seawater, the largest sectional area of chloride cells were determined in rainbow trout. There are significant differences between acclimated and non-acclimated fish in terms of chloride cell sizes and Na+-K+-ATPase activities (p < 0.05). The highest gill Na+-K+-ATPase activity was in brown trouts which were transferred gradually, while the lowest activity was detected in freshwater phase. According to the results, gradually acclimated trouts can perform better adaptation than their directly acclimated counterparts.
AtıfWoS1İncele - MakaleAçık Erişim2013Scopus SJRQ4Column Studies on Effect of Phosphate Immobilization on Removal of Metals from Stormwater Runoff in Bioretention Cell
Demir, V.; Bin-Shafique, S.
Batch studies indicated that low cost native materials such as loam soil, juniper mulch, hardwood mulch, pine mulch and sawdust performed efficiently as media in bioretention cell for removal of copper and lead from stormwater runoff. Juniper mulch performed best in batch studies was used in column studies. Column studies suggested that the presence of phosphate has a pronounced effect on metal immobilization. This is due to the formation of metal phosphates that have extremely low solubility. The remaining metals were adsorbed on bioretention media of the bioretention cell. Breakthrough adsorption and desorption curves for lead and copper were measured in presence and absence of phosphate immobilization. Copper reached a breakthrough curve in around 20 days and lead in 30 days. Column studies showed that in all samples addition of phosphate also decreased the leaching of lead and copper back to aqueous solution consistent with lead and copper immobilization.
AtıfWoS3OpenAlex3İncele - MakaleYalnız künye2013Scopus SJRQ3Comparison of Growth Performance, Gonadal Structure and Erythrocyte Size in Triploid and Diploid Brown Trout (Salmo trutta fario L, 1758)
Kizak, Volkan; Güner, Yusuf; Türel, Murat; Kayim, Murathan
The aim of this study was to compare growth, gonadal structure and red blood cell sizes of triploid and diploid brown trout (Salmo trutta fario). Triploidy was induced by providing a heat shock treatment to the fertilized eggs. From the 18th month post-fertilization triploid (TBT) and control diploid (CBT) brown trout groups were investigated up to 32nd month. Survival, specific growth rate, feed conversion ratio, condition factor, relative growth rate, absolute growth rate, gonadosomatic index, hepatosomatic index and carcass yield were determined in both groups. It has been determined that the triploid fish showed greater live weight than diploid fish despite the difference was not significant (P>0.05). In triploid group triploidisation success was obtained as 95% and male/female ratio was found as 44.4-55.6%. The red blood cells were significantly larger in triploids than diploid ones (P<0.05). Regarding histological section of gonads, triploidy resulted in reduced gonadal development in female, while triploid males seem to exhibit normal gonadal development. Our results suggest that since triploid females could grow more than males, the growth performance studies on triploid brown trout should be performed with all-female stocks under fish farming practices especially for the production of large size trout.
AtıfWoS24OpenAlex22İncele - MakaleYalnız künye2013Scopus SJRQ3FLAME ATOMIC ABSORPTION SPECTROMETRIC DETERMINATION OF NICKEL AND CHROMIUM IN VARIOUS PLANT LEAVES USED AS BIOMONITORS IN ENVIRONMENTAL POLLUTION
Avci, Halim; Kaya, Gokce; Akdeniz, Ismail; Ince, Muharrem; Yaman, Mehmet
Levels of nickel and chromium in leaves of 14 plant species grown in industrial sites of Gaziantep and surrounding were examined for biomonitoring of atmospheric pollution using flame atomic absorption spectrophotometry (FAAS). The plant leaf samples were collected from different locations with different degrees of metal pollution. The metal levels in the plants were in the ranges of (with mean values) 0.4-28.0 (3.1) mg kg(-1) for Ni and 0.1-6.6 (1.5) mg kg(-1) for Cr. On the other hand, the Ni and Cr levels in the plant leaf samples collected from control) areas were in the ranges of 0.4-2.1 (1.1) and 0.1-1.4 (0.58) mg kg(-1), respectively. It was concluded that Pinus nigra L., Acacia robinia L., Platanus orientalis L., Nerium oleander L., Pyracantha coccinea M.Roem. and Populus nigra L. for Ni, Pinus nigra L., Acacia robinia L., Olea europaea L. and Nerium oleander L. for Cr could be biomonitors. Therefore, it was demonstrated that the plant leaves could be used for heavy metal air pollution monitoring in urban and industrial regions.
AtıfWoS10İncele - MakaleAçık Erişim2013Scopus SJRQ1Fractionation of Ni, Cr and Cu from Soil by Sequential Extraction Procedure and Determination by Inductively Coupled Plasma Optical Emission Spectrometry
Akkus, Sukran; Bal, Tulin; Karaaslan, Nagihan M.; Yaman, Emre; Kilinc, Ersin; Yaman, Mehmet
Five-step sequential extractions were employed to fractionation of Ni, Cr and Cu in soil polluted by anthropogenic activities and determine the mobility of the metals. Twelve samples were collected on an agricultural area that was located near an airport and intercity roads in Elazig-Turkey. Exchangeable, organically bounded, carbonate bounded, adsorbed species on Fe and Mn oxides and residual species (except silicates) of Ni, Cr and Cu were extracted into solution by using CaCl2, Na4P2O7, Na(2)EDTA, NH2OH-HCl and HNO3-H2O2, respectively. Mobile metal concentrations in fractions and total recoverable in soils were determined by using inductively coupled plasma-optical emission spectrometry (ICP-OES). Total recoverable Ni, Cr and Cu concentrations were in the range of 40-119, 45-126 and 23-72mgkg(-1), respectively. It was observed that total concentrations of metals in some of the samples were higher than the permitted values. The sum of the mobile percentages of metals was found to be lower than 50%. The Ni, Cr and Cu percentages for exchangeable species are in the ranges of 0.18-1.64, 0.03-0.59 and 0.42-2.53%, respectively.
AtıfWoS6OpenAlex5İncele - MakaleYalnız künye2013Scopus SJRQ2Five complexes containing N,N-bis(2-hydroxyethyl)-ethylenediamine with tetracyanidopalladate(II): synthesis, crystal structures, thermal, magnetic, and catalytic properties
Korkmaz, S. Aslan; Karadag, A.; Korkmaz, N.; Andaç, O.; Gürbüz, N.; Özdemir, I.; Topkaya, R.
Five cyanide complexes, [Ni(N-bishydeten)Pd(CN)(4)] (1), [Cu(N-bishydeten)Pd(-CN)(2)(CN)(2)](n) (2), [Cu(N-bishydeten)(2)][Pd(CN)(4)] (3), [Zn(N-bishydeten)Pd(CN)(4)] (4), and [Cd(N-bishydeten)(2)][Pd(CN)(4)] (5) (N-bishydeten = N,N-bis(2-hydroxyethyl)-ethylenediamine), have been synthesized and characterized using various techniques. Different structures were formed when the M:L ratio was varied in copper complexes. The single-crystal X-ray diffraction analysis reveals that 2, a 1-D cyanide-bridged complex with 2,2-CT-type zigzag chain, was obtained by using 1:1M:L ratio whereas 3 was formed as a complex salt in a molar ratio of 1:2. The thermal stabilities determined from DTG(max) values of the first decomposition stages change in the order 1>5>4>3>2. Although an EPR signal was not observed for 1, the g parameters obtained from the EPR spectra of 2 and 3 indicate that Cu-II ions are located in tetragonally distorted octahedral sites (D-4h), and the ground state of the unpaired electron is (B-2(1g)). The magnetic behavior indicates a very small antiferromagnetic interaction below 10K for 1-3. In 3, there is a temperature-independent paramagnetism () due to the orbital moments of the d electrons. 1-3 were tested as catalysts in Suzuki and Heck coupling reactions.
AtıfWoS16OpenAlex15İncele - MakaleYalnız künye2013Scopus SJRQ3Seasonal Variations of Proximate and Total Fatty Acid Composition of Wild Brown Trout in Munzur River, Tunceli-Turkey
Ates, Mehmet; Çakirogullari, Gul Celik; Kocabas, Mehmet; Kayim, Murathan; Can, Erkan; Kizak, Volkan
Seasonal variations of proximate composition and fatty acid profiles of wild brown trout (Salmo trutta macrostigma Dumeril, 1858) caught from the Munzur River, Tunceli-Turkey were investigated in this study. It was determined that wild brown trout was high in mono-unsaturated, poly-unsaturated and saturated fatty acids, respectively. C18:1 omega-9 (oleic acid) was the most abundant fatty acid in all seasons ranging from 20.27 to 29.35 %. C22:6 omega-3 (docosahexaenoic acid-DHA), C18:3 omega-3c (cis-linolenic acid), C18:2 omega-6c (linoleic acid), and C20:5 omega-3 (eicosapentaenoic acid-EPA) were found to be predominant fatty acids in PUFAs. As a conclusion, wild brown trout living in Munzur river could be considered as an important protein and omega-3 fatty acid source according to the nutritional quality results evaluated in terms of proximate and fatty acid composition.
AtıfWoS13OpenAlex11İncele