Yazarlar
- Yildirim, Numan(27)
- Tanyol, Mehtap(21)
- Topal, Murat(19)
- Kutlu, Banu(18)
- Yildirim, Nuran Cikcikoglu(17)
- Ince, Muharrem(16)
- Serdar, Osman(16)
- Erguven, Gokhan Onder(14)
- Öbek, Erdal(14)
- Danabas, Durali(13)
- Acar, Ramazan(11)
- Demir, Veysel(11)
- Arslan Topal, E. Işıl(8)
- Ogedey, Aysenur(8)
- Yonten, Vahap(8)
- Tatar, Sule(7)
- Ince, Olcay Kaplan(6)
- Aksu, Onder(5)
- Alp, Hevidar(5)
- Ates, Mehmet(5)
- Korkmaz, Volkan(5)
- Oguz, Ensar(5)
- Topal, E.Işıl Arslan(5)
- Ural, Mesut(5)
- Arslan, Zikri(4)
- Aslan, Naim(4)
- Can, Erkan(4)
- Demirbilek, Deniz(4)
- Goksu, Ali(4)
- Kocabaş, Mehmet(4)
- Korkmaz, Meral(4)
- Kurnaz Yetim, Nurdan(4)
- Lassabatere, Laurent(4)
- Mutlu, Ekrem(4)
- Yilmaz, Deniz(4)
- Akkurt, Nevzat(3)
- Angulo-Jaramillo, Rafael(3)
- Arslan Topal, E.I.(3)
- Aydın, Ayşe Nur(3)
- Camas, Mustafa(3)
Yayınlar
- MakaleAçık Erişim2017Scopus SJRQ2The ability of Phanerochaete chrysosporium (ME446) on chemical oxygen demand remediation in submerged culture medium supplemented with malathion insecticide
Erguven, Gokhan Onder; Yildirim, Numan; Adar, Elanur
This present study aims to evaluating the efficiency of P. chrysosporium (P.c) to degrade the different concentrations of malathion (MLT) (50, 100 and 150 ppm) under agitated (130 rpm) submerged culture conditions via reduction of chemical oxygen demand (COD). We have previously screening the growth of fungus in sabouraud dextrose agar (SDA) medium for 6 days. We have also determined the laccase activity during degradation process for 15 days. According to our results the fungus has achieved 99.6, 98.8 and 98.7 % COD reduction at concentration of 50, 100 and 150 ppm respectively the end of the 15 days. The highest laccase activity (180 ± 5.69 U/L) was measured at concentration of 50 ppm the end of the 15 days and the lowest activity (36 ± 3.26) was determined at concentration of 150 ppm the end of the 15 days. The dried biomass of fungus was weighted at end of the 15 days and we have determined that malathion in culture medium reduced the biomass production compared the control group (SDB + P.c). Our results showed that, P. chrysosporium could be an effective bioremediation tool for treatment of malathion containing wastewater.
AtıfScopus11WoS11OpenAlex13
İncele - MakaleAçık Erişim2017Scopus SJRQ2Rapid malachite green removal from aqueous solution by natural zeolite: Process optimization by response surface methodology
Tanyol, Mehtap
In this study, malachite green removal from aqueous solutions by natural zeolite was investigated. The interaction between zeolite and malachite green was determined by SEM/EDX and FTIR. The parameters like adsorbent dosage (0.1–1 mg/100 mL), initial malachite green concentration (40–200 mg/L) and the contact time (10–600 s) were optimized using the central composite design of response surface methodology. Maximum removal yield (99.70%) was obtained at an adsorbent dosage of 0.68 mg/100 mL, an initial malachite green concentration of 79.02 mg/L, and at 414 s contact time. The equilibrium process complied better with the Langmuir isotherm model, which exhibits a single layer adsorption, when compared with the Freundlich isotherm model. Adsorption kinetics followed the pseudo-second-order type kinetic and intra-particle diffusion played an important role onto adsorption mechanism of malachite green. The findings of this study demonstrated that zeolite which is found abundant on earth as a cheap and efficient adsorbent could be used for rapid malachite green adsorption from aqueous solutions.
AtıfScopus12WoS11OpenAlex13İncele - MakaleAçık Erişim2017Scopus SJRQ2Adsorption of hazardous crystal violet dye by almond shells and determination of optimum process conditions by taguchi method
Goksu, Ali; Tanaydin, Mehmet Kayra
Almond shells are classified as an agricultural waste of the food industry. In this study, almond shells were prepared as efficient adsorbents for removing Crystal Violet (CV) dye. The effects of adsorbent dosage, pH, initial concentration, shaking speed, temperature and particle size were studied. The Taguchi L25 experimental design method was used to obtain the optimum experimental condition. The data were analyzed using the signal to noise (S/N) ratio and analysis of variance (ANOVA) for removal of CV from aqueous solutions. The isotherm data were obtained from the experiments performed. The obtained isotherm data were analyzed via the Langmuir, Freundlich and Temkin isotherm models of which the Langmuir isotherm model fitted the best. Thermodynamic parameters such as ΔH°, ΔS° and ΔG° were calculated and the results were 18.5 kJ/mol, 0.057 kJ/mol K and –1.514 kJ/mol at 25°C, respectively. The results of this study indicate that almond shells are efficient adsorbents for removing Crystal Violet (CV) from aqueous solutions. The maximum adsorption capacity was found to be 1.075 mg/g on the almond shells. Adsorption kinetics studies showed that adsorption data can be modeled by a pseudo-second-order model. The optimum conditions for the adsorption on almond shells were found to be: adsorbent dosage = 0.5 g, concentration = 4 ppm, pH = 6, shaking speed = 200 rpm and shaking time = 180 min.
AtıfScopus27WoS23OpenAlex25İncele - MakaleAçık Erişim2016Scopus SJRQ2Optimization of Remazol Brilliant Blue R dye removal by novel biosorbent P. eryngii immobilized on Amberlite XAD-4 using response surface methodology
Yonten, Vahap; Tanyol, Mehtap; Yildirim, Numan; Yildirim, Nuran Cikcikoglu; Ince, Muharrem
This study investigates preparation of biosorbent Pleurotus eryngii immobilized on Amberlite XAD-4 and the optimal conditions for removal of Remazol Brilliant Blue R (RBBR) reactive dye from synthetic aqueous solutions. The process was optimized using the response surface methodology (RSM) developed by the application of the quadratic model associated with the central composite design. For this purpose, RSM was employed to determine the effects of operational parameters on this material as effective and available adsorbent. The investigated variables were dye initial concentration (10-60 mg L-1), solution pH (2-9), adsorbent dosage (0.1-0.5 g), and temperature (20-45 degrees C). The significant factors on each experimental design response were identified from the analysis of variance (ANOVA). The RSM indicated that optimum conditions of initial dye concentration, pH, adsorbent dosage, and temperature for maximum RBBR removal (98%) were achieved as 36.3 mg L-1, 2.0, 0.304 g, and 38.7 degrees C, respectively. The results showed that this biosorbent was an appropriate adsorbent for the removal of RBBR from aqueous solutions.
AtıfWoS17OpenAlex20İncele - MakaleYalnız künye2016Scopus SJRQ3Optimization of Cadmium Removal from Water by Hydroxyapatite Using Experimental Design Methodology
Ince, Olcay Kaplan; Ince, Muharrem; Karaaslan, Nagihan M.; Yonten, Vahap
The presence of cadmium in water is a serious threat to the environment. The removal of cadmium using hydroxyapatite as an adsorbent was studied in an aqueous system. Hydroxyapatite was prepared to process the adsorption of cadmium from aqueous solution. Experimental design methodology and response surface methodology (RSM) with a quadratic model associated with central composite design was used to optimize the pH, initial heavy metal concentration, final volume, and adsorbent dosage for the removal of cadmium. Analysis of variance identified significant factors on each parameter. RSM indicated that a pH of 8.5, a sample volume of 166 mL, an adsorbent of dosage 0.57 g, and a contact time of 82 min were optimal for the adsorption of Cd(II). Under these conditions, the removal of Cd(II) was 895 mg g(-1).
AtıfWoS17OpenAlex15İncele - MakaleAçık Erişim2016Scopus SJRQ2Nickel, Lead, and Cadmium Removal Using a Low-Cost Adsorbent - Banana Peel
Ince, Muharrem; Ince, Olcay Kaplan; Yonten, Vahap; Karaaslan, Nagihan M.
Water pollution because of inorganic contaminants is a serious problem due to the acute toxicities and carcinogenic nature of pollutants. Recently, much attention has been focused on using natural and low-cost adsorbents, especially food residues, for removing toxic metal ions. Batch removal of nickel (Ni(II)), lead (Pb(II)), and cadmium (Cd(II)) from aqueous solution using a natural adsorbent is described in this study. Effects of various parameters on adsorption capacities such as pH, adsorbent dose, and stirring time were investigated by batch experiments. The maximum adsorption capacities for Ni(II), Pb(II), and Cd(II) ions were 1.6 mg g(-1), 125 mg g(-1), and 84 mg g(-1), respectively. Characterization of the surface modification was performed with FTIR measurements. FTIR spectra showed that chemisorption takes place at the surface of the adsorbent. The Freundlich and Langmuir adsorption isotherms were used to evaluate the equilibrium data. The characteristic parameters for each isotherm were determined. The Langmuir and Freundlich isotherm provided the best correlation for Ni(II), Cd(II), and Pb(II) using banana peel.
AtıfWoS10OpenAlex13İncele - MakaleAçık Erişim2016Scopus SJRQ2Correlations between some operation parameters and efficiency evaluation of domestic wastewater treatment plant in Tunceli (Turkey)
Tanyol, Mehtap; Demir, Veysel
The purposes of this work are to monitor certain operating parameters in influent and effluent of domestic wastewater treatment plant in Tunceli, Turkey, to determine the relationships among these parameters, and also to evaluate the effectiveness of the treatment plant. The mean values of the parameters measured in the samples taken from the plant influent like pH, temperature, electrical conductivity, dissolved oxygen, total dissolved solids, suspended solids, the total solids, volatile suspended solid, biological oxygen demand, and chemical oxygen demand, are 7.60 +/- 0.07, 11.66 +/- 0.74 degrees C, 1,070.75 +/- 10.67 mu s/cm, 3.78 +/- 0.32 mg/L, 524.42 +/- 5.28 mg/L, 390.58 +/- 40.22 mg/L, 857.50 +/- 61.30 mg/L, 496.17 +/- 82.30 mg/L, 195.33 +/- 8.11 mg/L, and 653.67 +/- 42.12 mg/L, respectively. The values of these parameters after the treatment are 7.68 +/- 0.08, 10.61 +/- 0.70 degrees C, 1,041.25 +/- 15.31 mu s/cm, 8.38 +/- 0.10 mg/L, 510.17 +/- 7.49 mg/L, 49.17 +/- 8.88 mg/L, 443.08 +/- 38.95 mg/L, 152.33 +/- 27.95 mg/L, 13.67 +/- 2.33 mg/L, and 44.66 +/- 12.72 mg/L, respectively. Correlation analyses conducted to explain the potential relationship between the analyzed parameters demonstrated that there were both negative and positive correlations between the influent and effluent operational parameters. Results supported the fact that there were significant improvements in wastewater quality after treatment.
AtıfWoS12OpenAlex15İncele - MakaleAçık Erişim2016Scopus SJRQ2Adsorption of bisphenol A from aqueous solutions by Pleurotus eryngii immobilized on Amberlite XAD-4 using as a new adsorbent
Yonten, Vahap; Ince, Muharrem; Tanyol, Mehtap; Yildirim, Numan
The adsorption of bisphenol A (BPA) in a fixed-bed column was evaluated in this work. Fungus Pleurotus eryngii isolated from Tunceli (Turkey) immobilized on XAD-4 resin was used as an adsorbent for decontamination of BPA from aqueous solutions. The extent of BPA removal capacity was evaluated as a function of parameters such as pH, volume of the sample, and column bed height. Adsorption isotherms of BPA on immobilized P. eryngii were determined and correlated with common isotherm equations such as Langmuir and Freundlich models. The mechanism of adsorption of BPA was analyzed preadsorption (XAD-4+fungus) and postadsorption (XAD-4+fungus+BPA) using fourier transform infrared spectroscopy. The results show that adsorption ability of BPA by immobilized P. eryngii is possible and this system yields the best degree of BPA removal (90%) at pH 11 for an initial load of 120mgL(-1). Therefore, this material can be used as a very effective adsorbent for BPA decontamination in aqueous solutions.
AtıfWoS17OpenAlex21İncele - MakaleYalnız künye2016Scopus SJRQ3Production Optimisation of a Land-Based Trout Farm and the Reduction of its Environmental Effects
Guner, Yusuf; Kizak, Volkan; Saygi, Hulya; Turan, Gamze; Tekogul, Hatice; Karacalar, Ulviye; Gulec, Fatih; Hekimoglu, Muge
In this study, certain water quality parameters (water temperature, dissolved oxygen (DO), pH, total inorganic nitrogen (TIN), phosphate (PO4), nitrite (NO2), nitrate (NO3), ammonium (NH4), and (BOD5) in the effluents and the efficiency of the treatment systems for eliminating wastes at a commercial trout farm with a capacity of 10 tons/year in Izmir (Kemalpasa) were examined. The DO, temperature, pH, TIN, PO4, NO2, NO3, and BOD5 measured, were different in the outlet waters when compared with the inlet waters (p<0.05). The settling basin did not reduce the TIN and PO4, on the contrary, it caused an increase in the nitrogen (N) up to 19.9% and phosphorus (P) up to 20.30%, while the wetlands reduced the N, P, and BOD5 up to 53.2%, 58.2%, and 36.5%, respectively (p<0.05). According to the chemical and biological methods, the averages of the TIN and P loads for one tone of cultured trout without treatment were estimated to be were 80 kg and 7 kg, respectively. The annual TIN load of this trout farm was estimated to be 21.3 kg while the TP load was 2.9 kg for one tone of cultured trout when the treatment efficiency was taken into account. The microbiological analyses conducted with the effluent waters showed that the rate of aerobic mesophilic bacteria was found to be high in the summer but low in the winter. It was also detected that the coliform group bacteria were present in the environment in the summer while their occurence was with-in standards in the winter. Interactions of the 9 water quality parameters were identified through the linear regression analysis in order to reduce the environmental effects of the facility DO=28.296 - (0.248 x BOD5)- (2.948 x pH) + (0.189 x temperature) + (0.851 x inlet water) + (0.163 x winter) (R-2=0.912). According to this model, the DO values were increased by the temperature, inlet water and the winter season while reduced by the BOD5 and pH. The dissolved oxygen content in the wetland outlet water was measured as being high because of the nutrient and temperature rises which boosted photosyntesis. It was concluded that using mechanical settling methods were inadequate to minimise the nutrients released into the receiving water body so wetlands should be constructed in such a way as to receive the flow of effluents from the trout farms. As a result the quality of water used by the facility has no adverse impact on the aquaculture and environmental ecosystem.
AtıfWoS1OpenAlex1İncele - MakaleAçık Erişim2016Scopus SJRQ3REMOVAL RATE OF HERBICIDE ACLONIFEN WITH ISOLATED BACTERIA AND FUNGI
Erguven, G. O.; Bayhan, H.; Ikizoglu, B.; Kanat, G.; Demir, G.
AtıfOpenAlex8İncele - MakaleAçık Erişim2016Scopus SJRQ3Uranium (VI) Biosorption on Marine Sponge, Sarcotragus foetidus (Schmidt, 1862) and Its Statistical Investigation Using Central Composite Design
Celik, Fatih; Camas, Mustafa; Camas, Anil Sazak; Ozalp, Hasan Baris
The biosorption of heavy metals, radionuclides, uranium and thorium for the recovery or removal from aqueous systems using various micro-organisms and biological substances has been investigated by several groups of workers. In this paper, the uptake of uranium (VI) from aqueous systems by a marine sponge, Sarcotragus foetidus (Schmidt, 1862) has been investigated. S. foetidus samples were collected from Babakale/Ayvacik/Canakkale in Turkey. Uranium (VI) uptake experiments were carried out by the batch technique. The affecting parameters were analyzed using Central Composite Design (CCD) as the experimental method. Four independent variables such-pH, temperature, contact time, and initial uranium concentration were selected for this study. The influences of initial pH, contact time, and initial uranium concentration on the biosorption process were considered statistically significant as main effects. On the other hand, interaction effects of pH and contact time, as well as pH and initial uranium concentration, were considered as significant parameters on the biosorption process. The optimum condition of biosorption process was found to be at initial pH: 4, temperature: 35 degrees C, initial uranium concentration: 20 mg/L, and contact time: 31 minutes. At these conditions, the biosorption yield of uranium (VI) ions was obtained to be 93.29 +/- 2%.
AtıfWoS2OpenAlex1İncele - MakaleAçık Erişim2016Scopus SJRQ3Monitoring Aclonifen Remediation in Soil with a Laboratory-Scale Research
Erguven, G. Onder; Bayhan, Hurrem; Demir, Goksel; Ikizoglu, Bahar; Kanat, Gurdal
Aclonifen was used as the most preferable type of herbicide which is used in sunflower farming in the Thrace Region. Bacteria and fungi were isolated from the soil samples taken from the Thrace Region, and a mixed culture was prepared from equal volumes (10(8) CFU/mL) of liquid cultures of microorganisms. Including the witness sample, five different setups were prepared, to which Aclonifen, with a concentration of 1900 mu g/L, was added. Each unit was diluted with distilled water for six weeks. The water filtered at this stage was measured for chemical oxygen demand (COD), biochemical oxygen demand, total organic carbon (TOC), and Aclonifen. Additionally, pH and dissolved oxygen measurement was performed. According to the results of the study, the highest bioremediation was observed in the soil sample to which 10 mL of mixed culture of microorganisms was added and Aclonifen, COD, BOD5, and TOC remediation was observed as 93.2%, 97.8%, 98.8%, and 98.7%, respectively.
AtıfWoS11OpenAlex16İncele - MakaleÖn baskısı açık2016Scopus SJRQ2Cytokine Responses in Gills of Capoeta umbla as Biomarkers of Environmental Pollution
Danabas, Durali; Yildirim, Nuran Cikcikoglu; Yildirim, Numan; Onal, Ayten Oztufekci; Uslu, Gulsad; Unlu, Erhan; Danabas, Seval; Ergin, Cemil; Tayhan, Nilgun
Immunological biomarkers reflect the effects of exposure to environmental contaminants. In this study, the suitability and sensitivity of cytokine responses, interleukin 1 beta (IL-1 beta), interleukin-6 (IL-6), tumor necrosis factor-alpha (TNF-alpha) in gill tissues of Capoeta umbla (Heckel, 1843), collected from different regions, as early warning indices of environmental pollution and ecosystem health was evaluated. Fish and water samples were taken from ten stations in March and September 2011 and 2012. Tumor necrosis factor-alpha, IL-1 beta and IL-6 levels were determined in samples of the gill tissues by using an ELISA kit. Significant variations of TNF-alpha, IL-1 beta and IL-6 levels observed between stations and seasons. The results of this study show that seasonal variations of cytokine responses in gills of Capoeta umbla are sensitive to the contaminants present in Uzuncayir Dam Lake (Tunceli, Turkey) water and are valuable biomarkers for environmental pollution and ecosystem health.
AtıfWoS5OpenAlex4
İncele - MakaleYalnız künye2016Scopus SJRQ3The capacity of some newly bacteria and fungi for biodegradation of herbicide trifluralin under agiated culture media
Erguven, G. O.; Bayhan, H.; Ikizoglu, B.; Kanat, G.; Nuhoglu, Y.
Bioremediation is the use of microorganisms to degrade environmental contaminants (pesticides, polyaromatic hydrocarbons etc.) into less toxic forms or compounds. In this study microbial biodegradation of trifluralin was performed in liquid media with 11 different types of identified fungi and bacteria cultures and their mixtures in agiated culture media. The isolated fungi and bacteria mixtures showed the highest degradation, reaching 93% in the chemical oxygen demand (COD) parameter in four days and 82% as trifluralin active ingredient in five days. Bacteria and fungi mixtures achieved 69% and 66% degradations of trifluralin active ingredient respectively. In the fungi studies, the best removal was achieved by M. Chlamydosporia at 80%, in the bacteria studies, the best removal was achieved by Bacillus simplex about 95% in five days. These different removal rates were due to the microbial differencies.
AtıfWoS16OpenAlex2İncele - MakaleAçık Erişim2016Scopus SJRQ1Hardness removal from waters by using citric acid modified pine cone
Altundogan, Hamdi Soner; Topdemir, Aykut; Çakmak, Meltem; Bahar, Nurdan
In this study, an effective cation exchanger was developed from the pine cone by citric acid modification and its hardness removal properties from the waters were investigated. For this purpose, ground pine cone samples were subjected to a citric acid modification following NaOH saponification. Both of the raw (RPC) and modified pine cone (MPC) samples were subjected to standardized hardness removal tests by shaking with hard waters. These tests showed that citric acid modification significantly increases the cation exchange capacity of the pine cone. Most suitable size fraction of pine cone was determined as -16 + 30 mesh (600 mu m < x < 1200 mu m). Also, citric acid modified product obtained from this fraction was used in a continuous system to remove hardness from water. The results of this study showed that the MPC can be used for hardness removal from waters as a cheap, durable and environment -friendly material. Finally, regeneration experiments showed that the MPC can be used for hardness removal from water repeatedly by a simple HCl regeneration. (C) 2015 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
AtıfWoS28OpenAlex34İncele - MakaleAçık Erişim2016Scopus SJRQ2Toxicity of Engineered Nickel Oxide and Cobalt Oxide Nanoparticles to Artemia salina in Seawater
Ates, Mehmet; Demir, Veysel; Arslan, Zikri; Camas, Mustafa; Celik, Fatih
In this study, the effects of exposure to engineered nickel oxide (NiO 40-60 nm) and cobalt oxide (CoO < 100 nm) nanoparticles (NP) were investigated on Artemia salina. Aggregation and stability of the aqueous NP suspensions were characterized by DLS and TEM. Acute exposure was conducted on nauplii (larvae) in seawater in a concentration range from 0.2 to 50 mg/L NPs for 24 h (short term) and 96 h (long term). The hydrodynamic diameters of NiO and CoO NPs in exposure medium were larger than those estimated by TEM. Accumulation rate of NiO NPs were found to be four times higher than that of CoO NPs under the same experimental conditions. Examinations under phase contrast microscope showed that the nanoparticles accumulated in the intestine of Artemia, which increased with increasing exposure concentration. Differences were observed in the extent of dissolution of the NPs in the seawater. The CoO NPs dissolved significantly while NiO NPs were relatively more stable. Oxidative stress induced by the NP suspensions was measured by malondialdehyde assay. Suspensions of NiO NPs caused higher oxidative stress on nauplii than those of CoO NPs. The results imply that CoO and NiO NPs exhibit toxicity on Artemia (e. g., zooplankton) that is an important source of food in aquatic food chain.
AtıfWoS59OpenAlex71İncele - MakaleYalnız künye2016Scopus SJRQ3Experimental and modeling studies of methylene blue adsorption onto particles of peanut shell
Kiliç, Fatih; Sarici-Özdemir, Cigdem
In this study, adsorption of methylene blue from aqueous solution onto peanut shell has been investigated. Experimental data obtained from dye adsorption have been studied by five two-parameter (Langmuir, Freundlich, Dubinin-Radushkevich, Temkin, and Frumkin) and five three-parameter (Redlich-Peterson, Sips, Toth, Radke-Prausnitz, and Koble-Corrigan) isotherm models. Eight nonlinear error functions (sum squares errors, hybrid fractional error function, Marquardt's percent standard deviation, average relative error, sum of absolute error, the coefficient of determination, nonlinear chi-square test, and standard deviation of relative errors) were examined for isotherm equations. In order to explain the adsorption kinetics fit of pseudo-first-order, pseudo-second-order, Elovich, and intraparticle kinetic models were used. The best fitting isotherm model was the Radke-Prausnitz and kinetics model was pseudo-second-order. Adsorption experiment showed that the maximum capacity of agricultural waste for methylene blue was 67.57 L.g(-1) at 25 degrees C.
AtıfWoS7OpenAlex8İncele - MakaleYalnız künye2015Scopus SJRQ1Biochemical response of crayfish Astacus leptodactylus exposed to textile wastewater treated by indigenous white rot fungus Coriolus versicolor
Aksu, Onder; Yildirim, Nuran Cikcikoglu; Yildirim, Numan; Danabas, Durali; Danabas, Seval
The discharge of textile effluents into the environment without appropriate treatment poses a serious threat for the aquatic organisms. The present study was undertaken to investigate biochemical response of crayfish Astacus leptodactylus exposed to textile wastewater (TW) treated by indigenous white rot fungus Coriolus versicolor. Glutathione S-transferase (GST), cytochrome P450 1A1 (CYP1A1), and acetylcholinesterase (AchE) levels in hepatopancreas and abdomen tissues of crayfish exposed to untreated, treated, and diluted rates (1/10) in both TW during 24 and 96 h were tested. Physiochemical parameters (electrical conductivity (EC), chemical oxygen demand (COD), pH, and total dissolved solid (TDS)) of TW were determined before and after treatment. Physiochemical parameters of TW decreased after treatment. The GST activity and AchE were generally increased, but CYP1A1 activity was decreased in hepatopancreas tissue of crayfish exposed to different kinds of untreated TW. After treatment by indigenous white rot fungus (C. versicolor), GST and CYP1A1 activities were returned to control values, while AchE activities were increasing further. In this study, only GST and CYP1A1 activities of A. leptodactylus confirmed the efficiency of TW treatment with C. versicolor.
AtıfWoS23OpenAlex27İncele - MakaleYalnız künye2015Scopus SJRQ2Removal of Phosphate from Aqueous Solutions by Chemical- and Thermal-Modified Bentonite Clay
Tanyol, Mehtap; Yonten, Vahap; Demir, Veysel
The study investigated phosphate adsorption from aqueous solutions using chemical- and thermal-modified bentonite in batch system. The adsorbent was characterized by SEM, BET, and FTIR spectroscopy. Contact time, beginning phosphate concentration, pH of the solution, and the effects of the temperature on phosphate adsorption capacity were determined by a series of experimental studies. In a wide pH range (3-10), high phosphate removal yields were obtained (between 94.23 and 92.26 %), and with the increase in temperature (from 25 to 45 degrees C), phosphate removal increased. Langmuir and Freundlich isotherms were used to determine the sorption equilibrium, and the results demonstrated that equilibriumdata displayed better adjustment to Langmuir isotherm than the Freundlich isotherm. Phosphate sorption capacity, calculated using Langmuir equation, is 20.37 mg g(-1) at 45 degrees C temperature and pH 3. Mass transfer and kinetic models were applied to empirical findings to determine the mechanism of adsorption and the potential steps that control the reaction rate. Both external mass transfer and intra-particle diffusion played a significant role on the adsorption mechanism of phosphate, and adsorption kinetics followed the pseudo-second-order-type kinetic. Furthermore, thermodynamic parameters (Delta H degrees, Delta G degrees, Delta S degrees) which reveal that phosphate adsorption occur spontaneously and in endothermic nature were determined. The results of this study support that bentonite, which is found abundant in nature and modified as an inexpensive and effective adsorbent, could be used for phosphate removal from aqueous solutions.
AtıfWoS26OpenAlex27İncele - MakaleAçık Erişim2015Scopus SJRQ3Changes in antioxidant defense system in gills of Capoeta umbla caught from Uzuncayir Dam Lake, Turkey
Danabas, Durali; Yildirim, Nuran Cikcikoglu; Yildirim, Numan; Onal, Ayten Oztufekci; Uslu, Gulsad; Unlu, Erhan; Danabas, Seval; Ergin, Cemil; Tayhan, Nilgun
The aim of this work was to determine the seasonal changes in the activities of selected biomarkers in Capoeta umbla (Heckel, 1843) caught from Uzuncayir Dam Lake (Tunceli, Turkey) and to evaluate the effects of environmental factors on these activities. Fish were sampled on seasonal basis, and superoxide dismutase, catalase, glutathione peroxidase activities and levels of glutathione and malondialdehyde in gills were determined. Significant variations of oxidative stress biomarkers were observed between seasons and sites. The results of this study show that seasonal variations of oxidative stress responses and lipid peroxidation in gills of C. umbla are sensitive to the contaminants present in water of Uzuncayir Dam Lake and selected parameters are in valuable biomarkers for monitoring of water systems, since they give an early warning signal of effects of xenobiotics on aquatic organisms at molecular levels which help to prevent their effects at organismal level. (C) 2015 Elsevier Ltd. All rights reserved.
AtıfWoS14OpenAlex10İncele
