Sürdürülebilir Kalkınma Amaçları

Yazarlar

  • MakaleAçık Erişim2019Scopus SJRQ1
    Identification of optimum working conditions in hydroelectric power plants for cavitation

    Kahraman, Gökhan; Yücel, Halit Lütfi; Taşgin, Yahya

    Turbine faults in hydroelectric power plants not only reduce the operation time of the plant, but also cause a serious loss of income. One of the most important turbine faults is the turbine wheel wear caused by the cavitation and accordingly the other machine equipment faults which cause excessive vibration. In this study, cavitation intensity that the turbines have been exposed in operating conditions has been investigated. As a result of the calculations, optimum working conditions of the units have been determined with graphs obtained in various operating conditions. The obtained data can be easily applied to all hydroelectric power plants exposed to cavitation, and safe operating conditions can be determined.

    • SDG 7 · Erişilebilir ve Temiz Enerji
    • SDG 9 · Sanayi, Yenilikçilik ve Altyapı
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  • MakaleAçık Erişim2019Scopus SJRQ3
    Reassessment of Turkey’s objections to the exclusion of terrorism from the rome statute; [Terörizmin uluslararası ceza divanının yargı yetkisi dışında bırakılmış olmasına dair türkiyeʼnin İtirazlarının yeniden değerlendirilmesi]

    Kurtuluş, Şehmus

    Criminal justice response to terrorism and to the support for terrorism is still a hot topic in Turkey due to ongoing American military support for the PYD, which is Syrian wing of the internationally designated terrorist organization PKK whose indiscriminate attacks in Turkey has claimed lives of thousands of civilians. This article first discusses, in light of recent developments, whether exclusion of a separate crime of terrorism from the Rome Statute of the International Criminal Court can be a valid argument against Turkey’s accession to it. After discovering some of the possible contributions of Turkey’s Rome Statute accession to its decades-long struggle against terrorism, this study concludes that Turkey’s all other concerns regarding the accession should be periodically reevaluated.

    • SDG 16 · Barış, Adalet ve Güçlü Kurumlar
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  • MakaleYalnız künye2019Scopus SJRQ2
    An ethnobotanical survey of medicinal plants in karlıova (Bingöl-turkey)

    Nadiroğlu, Muharrem; Behçet, Lütfi; Çakılcıoğlu, Uğur

    This study aims to identify wild plants collected for medical purposes by the local people of Karlıova District located in the Eastern Anatolia region of Turkey and to determine the uses and local names of these plants. A field study had been carried out for a period of approximately 4 years (2013–2016). During this period, 99 vascular plant specimens were collected. Among them, 91 species are wild and 8 species are cultivated plants. Demographic characteristics of participants, names of the local plants, their utilized parts and preparation methods were investigated and recorded. 99 plants were found to be used for medical purposes before in the literature analysis of the plants used in our study, while 9 plants were found to have no literature records. In Turkey, local plant names display differences especially due to local dialects. The plants used in Karlıova are known by the same or different local names in various parts of Anatolia. In the research area, local people were found to use 99 plants from 26 families for curative purposes. The medicinal uses of Stenotaenia macrocarpa Freyn & Sint., Inula helenium L., Scorzonera incisa DC., Tripleurospermum caucasicum (Willd.) Hayek, Astragalus chamaephaca Freyn, Geranium libanoticum Schenk, Rhinanthus serotinus subsp. aestivalis (N.W.Zinger) Dostál, Verbascum songaricum Schrenk. and Bunium elegans (Fenzl) Freyn that we found were used in our study area and recorded for the first time. These plants, used for the treatment of various diseases, are abundantly found in this region. Drying of the medicinal plants enabled the local people to use them in every season of the year.

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  • MakaleAçık Erişim2019Scopus SJRQ2
    Microborings as indication of cryptic life modes in the foraminifer Orbitoides: Maastrichtian sediments of the Haymana and Nallihan districts (Ankara, Turkey)

    Görmüş, Muhittin; Demırcan, Huriye; Kadioğlu, Yusuf Kağan; Yağmurlu, Fuzuli; Us, Muhammed Sami

    Widespread Maastrichtian siliciclastics and carbonates cropping out in the Haymana (S Ankara) and Nallihan (NW Ankara) districts in the northwest and central Anatolia basins include rich Orbitoides occurrences. Microborings in the Orbitoides tests are interesting to notify. In this study, the details of their morphologic structures were investigated. Microborings were analyzed in more than 650 equatorial thin sections of the Orbitoides tests and 100 hard rock thin sections. The abundance of microborings increases in the siliciclastics towards the Cretaceous/Palaeogene boundary (K/Pg). They were identified as Maeandropolydora osmaneliensis Nielsen and Görmüs, Maeandropolydora isp. Curvichnus semorbis Nielsen, Oichnus simplex Bromley, Oichnus isp. Maeandropolydora osmaneliensis Nielsen and Görmüs. Maeandropolydora isp., semicircular to circular microborings of Curvichnus semorbis Nielsen and Oichnus simplex Bromley are related to parasitic life modes. Irregular wider unidentified microborings are hermit type life mode tunnels. Abundance of the microborings might be related to shallower siliciclastic environmental conditions such as feeding and suitable Eh-pH, test shape, and easy entrance to the test for parasites. Smaller benthic foraminifera are seen in both microspheric and megalospheric Orbitoides tests as parasites. In conclusion, occurrences of microborings and encrustations are associated with parasitism by appearances of Maeandropolydora osmaneliensis Nielsen and Görmüs, Curvichnus semorbis Nielsen and Oichnus simplex Bromley and commensally attachment by microalgae.

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  • MakaleYalnız künye2019Scopus SJRQ2
    Gamma ray shielding behavior of Li2O-doped PbO–MoO3–B2O3 glass system

    Ali, Atif Mossad; Sayyed, M.I.; Rashad, M.; Kumar, Ashok; Kaur, Ramandeep; Aşkın, A.; Algarni, H.

    In this work, five glasses for radiation shielding applications in the composition of (30 + x) PbO–5 MoO3–(25 − x) Li2O–40 B2O3 (where x = 0, 5, 10, 15 and 20 mol%) have been prepared. The density increases from 4.354 to 6.578 g cm−3 and the molar volume decreases from 25.144 to 22.520 cm3 with the replacement of Li2O by PbO. The indirect and direct band gap energies decrease from (2.2870–2.2297) eV and (2.9619–2.8660) eV, respectively, as lead content increases from 30 to 50 mol%. In addition, the refractive index of the samples lies between 2.6214 and 2.6429. Geant4 simulation code has been used to evaluate the gamma photon transmission through the prepared samples. Pb50Li5 sample has lower transmission fraction among the studied glasses. For the 2-cm glass thickness, the transmission fraction of Pb30Li25 sample was found to be 0.433 while at the same thickness the transmission fraction of Pb50Li5 sample is 0.265. At 1173 keV, the HVL values were found to be 1.752 cm for Pb50Li5 and 2.693 cm for Pb30Li25 glasses. At the same photon energy, the MFP values were calculated to be 2.529 cm and 3.886 cm for the Pb50Li5 and Pb30Li25 samples, respectively. Due to the higher Pb content existing in the Pb50Li5 glass, this glass effectively blocks the gamma rays compared to the other samples.

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  • MakaleYalnız künye2019Scopus SJRQ2
    The usability of oxidative stress and detoxification biomarkers in Gammarus pulex for ecological risk assessment of textile dye methyl orange

    Cikcikoglu Yildirim, Nuran; Yaman, Metin

    The present study was undertaken to determine the toxicity of the methyl orange by using the changes of some antioxidant and detoxification enzyme activities in Gammarus pulex. Lethal Concentration (LC) value of Methyl Orange (MO) was determined. Three sublethal doses of MO (1/4; 1/8 and 1/16 of LC value) were exposed to G. pulex for 24 and 96 h. Superoxide dismutase (SOD), Catalase (CAT), Glutathione peroxidase (GSH-P X ), Cytochrome p450 (CYP1A1), Glutathione S-transferase (GST) activities as well as Glutathione (GSH) and Malondialdehyde (MDA) levels were determined by using The enzyme-linked immunosorbent assay (ELISA) kit. The CAT and CYP1A1 activities were decreased in all the groups exposed to different doses of MO. GST activity and GSH, MDA levels were increased all the groups exposed to different doses of MO. The GSH-P X activities were changed in all the groups. MO affected SOD activity at different levels and in different concentrations. In our study, it has been found that exposure duration didn’t significantly affect the biochemical biomarkers except for GST and GSH. In conclusion, alterations in antioxidant and detoxification enzymes and lipid peroxidation may potentially be used as sensitive biomarkers for risk assessment of dyes in the environment and may contribute to the establishment of discharge regulations.

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  • MakaleYalnız künye2019Scopus SJRQ2
    Effects of Vacuum Ohmic Evaporation on Some Quality Properties of Sour Cherry Juice Concentrates

    Sabancı, Serdal; Icier, Filiz

    Sour cherry juice (SJ) having total soluble solid (TSS) content of 19.2 % was concentrated to 65 % TSS by applying vacuum ohmic evaporation (VOE) and vacuum evaporation (VE) methods under constant absolute pressure (25 kPa). Total monomeric anthocyanin content (TMAC) of sour cherry concentrate (65 % TSS) was found in the range of 1561.67–1777.38 mg/L whereas total phenolic content (TPC) varied in the range of 9,071.22–78,347.53 mg/L concentrate. TPC and TMAC values of juice concentrates were affected less from VOE process compared to VE (p < 0.05) while there was no significant difference between the total antioxidant activities of SJ concentrates obtained by both methods (p > 0.05). TMAC and TPC values increased as the voltage gradient applied increased (p < 0.05). VOE process preserved the color properties of juice concentrates better compared to the VE process. It was concluded that VOE method could be an alternative fast evaporation method to obtain high-quality fruit juice concentrates.

    • SDG 2 · Açlığa Son
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  • MakaleYalnız künye2019Scopus SJRQ3
    Physicochemical and sensory evaluation of fish chips made from Luciobarbus esocinus (Heckel, 1843)

    Kuzgun, N.K.

    In this study, fish chips were produced using Luciobarbus esocinus, their fatty acids and amino acids profiles were determined and they were sensorially evaluated. For the preparation of experimental samples, L. esocinus meat was minced and added to a basic chips mixture. After that, the mixture was divided into in two: while pepper sauce was added to one half, the other half had no sauce added. The mixtures with sauce and without sauce were shaped into chips. Two samples of each batch of the chips prepared were cooked using two different methods (baking and frying). In this way four different groups were obtained. Analysis of fatty acids showed that the pre-frying and the pre-baking process resulted in a decrease in all fatty acids except for 18:1n-9 and 18:2n-6. Analysis of amino acids showed that isoleucine, lysine, threonine and, proline were present in the highest quantities respectively. After frying and baking the amounts of leucine, isoleucine, lysine, arginine, phenylalanine, and threonine decreased while the amounts of the valine and histidine remained at the same level. The essential amino acids for humans were found in the fish meat and in the fish chip groups, except for tryptophan. The general acceptability score of the fish chips was highest for group A which consisted of chips with sauce that had been fried (9.28±0.69).

  • MakaleAçık Erişim2019Scopus SJRQ1
    Petrology and 40Ar-39Ar dating of paragneisses from the Devrekani Massif (Central Pontides, Northern Turkey): Implications for the Jurassic high-T metamorphism in an extensional tectonic environment

    Gücer, Mehmet Ali; Arslan, Mehmet; Çimen, Okay; Sherlock, Sarah C.

    The Devrekani Massif in the northern part of the Central Pontides (Northern Turkey) provides important clues to the regional tectonics and geodynamic processes associated with Jurassic high grade metamorphic conditions. This study reports new paragenetic assemblages, mineral compositions, whole-rock geochemistry and 40Ar-39Ar geochronological data from the paragneisses in the massif, and, discusses the P–T conditions and geodynamic implications of the Jurassic metamorphism during continental extension in the Central Pontides. Upper amphibolite to lower granulite facies paragneisses form one of the main lithological units in the massif. Within these, there are five different mineral parageneses with diagnostic mineral assemblages of: quartz, K-feldspar (An0-1Ab4-26Or73-96), plagioclase (An18-35), biotite [XPhl: 0.28–0.57; Mg/(Mg + Fe2+): 0.33–0.61], sillimanite, cordierite [Mg/(Mg + Fe2+): 0.48–0.71] and garnet (Alm43-80Grs0-18Prp5-23And0-4Sps10-33) with minor hercynite. Based on Na-in-Crd thermometry and GASP barometry results, the peak metamorphic conditions are 775 ± 25 °C and 6 ± 1 kbar in the massif. The field relations, petrography and bulk chemical data suggest that the paragneisses, derived from shale-wackestone and pelitic sedimentary protoliths, are typical rock lithologies of an active continental margin. They display enrichments in LILE over HFSE, coupled with negative Nb and Ti anomalies, which are geochemical signatures of subduction-related sources. It is likely that the peak metamorphism took place during the Middle–Upper Jurassic period (ca. 174–156 Ma), suggesting that the metamorphic rocks cooled to 300–350 °C at ca. 156 Ma. The mineral assemblages reveal that the prograde history passed from sillimanite zone conditions up to the cordierite-garnet-K-feldspar zone. The petrological and geochronological data indicate that the protoliths are related to multiple sources such as volcano-sedimentary successions. We conclude that the Devrekani Massif represents the products of pre-Jurassic sedimentation, and Permo-Carboniferous continental arc magmatism, overprinted by Jurassic metamorphism.

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  • MakaleYalnız künye2019Scopus SJRQ1
    TUNCELİ-ANBAR FORTRESS AND THE URARTIAN MULTIROOMED ROCK-CUT TOMB

    Danışmaz, Harun

    This study aims to evaluate Anbar Fortress and its multi-roomed rock-cut tomb, located in the Tunceli region. It is a place rarely mentioned in archaeological literature. For the first time the plan of the rock-cut tomb of Anbar is presented here and accordingly the fortress’ place in the Urartian administration system is evaluated. In addition, material culture residues from the site, such as wall foundations, mortared walls, rock steps, cisterns/storage spaces and a rock chapel were analysed and their connection to the tomb is explained. Traces of two different periods are detected in Anbar Fortress. While the wall foundations, multi-roomed rock-cut tomb, and a part of the rock steps can be associated with the Urartian period, the mortared walls, towers, rock steps, cisterns/storage spaces and rock chapel that is located in the southwest of the fortress is dated to the Medieval period.

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  • MakaleYalnız künye2019Scopus SJRQ4
    Water quality changes and goldfish growth (carassius auratus) in microgreen aquaponic and recirculating systems

    Kizak, Volkan; Kapaligoz, Serdar

    Goldfish (Carassius auratus) growth was studied comparatively in microgreen aquaponic (APS) and sump filter systems (SFS), and the ef fects of these two different filter systems on water quality parameters were investigated. Arugula (Eruca vesicaria) was used in APS and produced as microgreens. NH3-N, NO2-N, NO3-N, POj and NH4 were measured at specific periods for 60 days. No statistical differences were found between both systems in terms of food conversion ratio (FCR), specific growth rate (SGR), survival and mean body weight of goldfish. In the beginning of the experi-ment, water pH level was around 8.5 while trend towards declining at the end of period. Nitrification process was successful in both systems, and declin ing pH towards from basic medium to approaching neutral levels made positive contribution to perfor mance of nitrifying bacteria. Although there was a significant decrease in the level of NH4, the level of NO3-N increased continously after the 30,h day in APS. According to these results, arugula micro-greens used mostly NH4 instead of NO3-N in higher pH level. Goldfish-arugula microgreen aquaponic system is similar with SFS in terms of keeping water quality in optimal conditions and any adverse effect on goldfish growth and welfare was not ob served in both systems. Although in high pH, it was also seen that arugula seedlings can be produced efficiently as microgreens.

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  • MakaleAçık Erişim2019
    THE BRYOPHYTE FLORA OF THE SAMANLI MOUNTAINS (SAKARYA, KOCAELI, YALOVA, BURSA) IN NORTH-WEST TURKEY; [ФЛОРА МХОВ ГОР САМАНЛИ (ОБЛАСТИ САКАРЬЯ, КОДЖАЭЛИ, ЯЛОВА И БУРСА) НА СЕВЕРО-ЗАПАДЕ ТУРЦИИ]

    Gözcü, Merve Can; Uyar, Güray; Ören, Muhammet; Ezer, Tülay; Alataş, Mevlüt

    The present study was performed on the Samanlı Mountains, which is extending from Sakarya province to Yalova province, in North-West Turkey. During this study, eight field trips were organized to the research area at different seasons between the years 2013 and 2016. Throughout these studies, with an examination of 3630 bryophyte specimens collected from 189 stations, together with 2 from Anthocerotophyta (hornworts), 61 from Marchantiophyta (liverworts), 306 from Bryophyta (mosses), in total 369 specific and infraspecific taxa, belonging to 70 families and 156 genera, have been identified. According to grid square system of Turkey which was adopted by Henderson, 68 taxa for A1 square and 24 taxa for A2 square are new records. Among them, Fissidens curvatus Hornsch., Thamnobryum neckeroides (Hook.) E.Lawton, Plagiothecium neckeroideum Schimp. and Riccia beyrichiana Hampe were recorded for the second time in Turkey. In addition, the present paper reports the first records of Cephaloziella massalongi (Spruce) Müll.Frib, which has been classified as rare (R) in the Red data book of European bryophytes, and Scapania scandica (Arnell et H.Buch) Macvicar in Turkey. Some morphological features, the ecological characteristics and the distribution map of the species are given, along with photographs of diagnostic details.

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  • MakaleYalnız künye2019Scopus SJRQ1
    Measuring development levels of NUTS-2 regions in Turkey based on capabilities approach and multi-criteria decision-making

    Ozdemir, Yasal; Gul, Muhammet

    Regional development seeks to better understand the issues and problems facing the regions because of the contemporary economic and social changes, including the formulation of territorial policies accordingly. In Turkey, in order to coordinate regional development, 26 regional development agencies were founded relating to the nomenclature of territorial units for statistics-2 (NUTS-2) regions. Since these regions have different development levels, it is useful for stakeholders to determine performance measures related to the regional development and propose a ranking model among these regions to provide a balance in delivering financial support mechanisms. Therefore, in this study, an iterative multi-criteria decision-making (MCDM) model is proposed. Firstly, Pythagorean Fuzzy Analytic Hierarchy Process (PFAHP) is used to assign weights to indicators of well-being index for provinces (WiP) in Turkey. Then, a TODIM (an acronym in Portuguese of interactive and multiple attribute decision making) based ranking model for 26 regions was applied. Also, this model takes capabilities and well-being approach into account differently from traditional utilitarian development models which take only some macro-economic and financial parameters. In order to do this, the model uses data from WiP. On conclusion, a comparative ranking projection with two other MCDM methods and WiP is provided and an effective and broader point of view was gained by the regional development performance measuring model.

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  • MakaleYalnız künye2019Scopus SJRQ2
    Modelling cadmium bioaccumulation in Gammarus pulex by using experimental design approach

    Serdar, Osman; Pala, Aysegul; Ince, Muharrem; Onal, Ali

    Recently, although dynamic approaches have been used increasingly to describe metal bioaccumulation in aquatic organisms, the validation of such laboratory-derived modelling is rarely assessed under environmental conditions. The present study aims to evaluate and verify statistical and mathematical models for the bioaccumulation of cadmium (Cd) and to evaluate the suitability of Gammarus pulex as a biomonitor for Cd. To optimise Cd2+ ion bioaccumulation conditions a Box–Behnken design was used and whether G. pulex can be used as an estimated tool to assess aquatic quality was investigated. A Box–Behnken experimental design combined with response surface modelling (RSM) was employed for Cd2+ bioaccumulation in G. pulex. Independent variables including temperature, contact time and Cd2+ ion concentration significance and their interactions were tested using analysis of variance. The selected variables’ optimum values were obtained by solving the quadratic regression model along with by analysing the response surface contour plots. Based on Box–Behnken design, the applied model is significant because model F-value and R2 were obtained as 5121.49, 0.9998, respectively. Bioaccumulation of Cd amount was analysed using electrothermal atomic absorption spectrophotometer. The obtained data suggest that G. pulex can be evaluated as Cd biomonitor.

    • SDG 6 · Temiz Su ve Sanitasyon
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  • MakaleAçık Erişim2019
    Ghanaian Mangrove Wetland Endophytic Fungus, Penicillium herquei strain BRS2A-AR produces (9Z, 11E)-13-oxooctadeca-9,11-dienoic acid with activity against Trichomonas mobilensis

    Hayibor, Kennedy; Kwain, Samuel; Osei, Enoch; Nartey, Adwoa Padiki; Tetevi, Gilbert Mawuli; Owusu, Kofi Baffour-Awuah; Camas, Mustafa; Camas, Anil Sazak; Kyeremeh, Kwaku

    Sub-Sahara Africa is burdened with a high incidence of parasitic infections, including schistosomiasis, trypanosomiasis, trichomoniasis, and leishmaniasis. Currently, there is a rapid widespread development of resistance to prescription drugs for these neglected diseases. Microbes provide the largest chemical and biological diversity in drug discovery screening programs; therefore, our project seeks to explore microbes in the sub-region for new drugs. The oxylipin (9Z,11E)-13-oxooctadeca-9,11-dienoic acid (1) was isolated from the Ghanaian endophytic fungus, Penicillium herquei strain BRS2A-AR obtained from the leaves of a Laguncularia racemosa tree growing on the banks of the River Butre in the Western Regional wetlands of Ghana. Compound 1 was isolated on reverse phase HPLC at tR of 34.3 minutes. The structure of compound 1 was confirmed by a combination of mass spectrometry, 1D and 2D-NMR techniques. Compound 1 showed minimal antiparasitic activity when tested against Plasmodium falciparum 3d7 (IC50>100µM; aretesunate, IC50 36nm), Trypanosoma brucei brucei (IC50>100µM; Coptis japonica, IC50 8.20µM), Leishmani donovani (IC50>100µM; amphotericin B, IC50 0.32µM) and Leishmania major (IC50>100µM; amphotericin B, IC50 0.31µM). Compound 1 produced IC50 of 44.47µM when tested against Trichomonas mobilensis with metronidazole (IC50 5.20µM) as standard. These results show the potential to further engineer the structure of compound 1 into a potent anti-Trichomonas scaffold.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
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  • MakaleAçık Erişim2019Scopus SJRQ3
    Study of the bioaccumulation of UO2 2+ onto the green microalgae botryococcus braunii using response surface methodology

    Celik, Fatih; Aslani, Mahmoud Ali Asker; Can, Safak Seyhaneyildiz

    The bioaccumulation of UO2 2+ (uranyl ion) was investigated by using dry biomass of Botryococcus braunii. Experiments were conducted based on a rotatable central composite design (CCD) and analyzed using response surface methodology (RSM), which was used to optimize the bioaccumulation process. In this goal, the effects of parameters such as initial uranium (VI) concentration, pH, temperature and contact time were studied. The optimum conditions for maximum removal (87%) of UO2 2+ from an aqueous solution were as follows: initial uranium (VI) concentration (55 mg/l), pH (3.6), temperature (46°C) and contact time (74 min). Langmuir and Freundlich isotherms and also thermodynamic parameters like Enthalpy (∆H°), Entropy (∆S°), standard Gibbs free energy (∆G°) were investigated, as well.

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  • MakaleYalnız künye2019Scopus SJRQ2
    Polytropic Carnot heat engine

    Askin, M.; Salti, M.; Aydogdu, O.

    Recent astrophysical datasets have implied that the universe has entered a speedy expansion phase. The Polytropic gas model, which describes a unified formulation of dark contents (matter plus energy), is one of the most reasonable definitions of this mysterious phenomenon. This interesting formulation allows to simulate the dark contents in the cosmic form of the perfect fluid and gives an interesting point of view in the discussion of fundamental theories of physics. In the first step of our investigation, we discuss the thermal equation-of-state (EoS henceforth) and obtain the EoS and deceleration parameters as explicit functions of temperature. Subsequently, we obtain a relation for the thermal efficiency of the Carnot heat engine which depends on free parameters given in the cosmological Polytropic gas description and the limits of maximal and minimal temperatures imposed on the Carnot cycle.

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  • MakaleYalnız künye2019Scopus SJRQ2
    Comprehensive study on the structural, optical, physical and gamma photon shielding features of B2O3-Bi2O3-PbO-TiO2 glasses using WinXCOM and Geant4 code

    Sayyed, M.I.; El-Mesady, I.A.; Abouhaswa, A.S.; Askin, A.; Rammah, Y.S.

    Glass samples of titanium-lead bismuth borate with the composition of (60B2O3 – 20Bi2O3 – (20-x)PbO – xTiO2), where 0 ≤ x ≤ 10 wt% labeled as BBPT0.0 (x = 0) to BBPT10.0 (x = 10) were synthesized. The melt quenching technique was used in the preparation. The amorphous character and vibrational groups for all samples were confirmed through XRD and FTIR measurements, respectively. The optical band gap (Eopt), Urbach's energy (Eurbach), and the optical dispersion constants have been determined using UV–Vis spectra. Results reveal that the values of the optical band gap energy exhibit a decrease with the TiO2 concentration, in contrast with Urbach's energy which displays a linear increase from 0.43 to 0.64 eV. In addition, the values of single-oscillator energy (Eo) has the same behavior of the optical energy gap (Eopt), while the dispersion energy parameter (Ed) has an inversely behavior. Mass attenuation coefficients (μ/ρ) of the investigated glasses have been computed using the Geant4 simulation toolkit and WinXCOM database software. Geant4 model of a HPGe detector has been employed to perform the Monte Carlo simulations for the glass samples with five thicknesses from 1 to 3 cm at the gamma ray energies in the range of 356–2510 keV. The transmission fractions as a function of the thickness at 356 keV photon energy for all studied glasses has been performed. Half value layer (HVL) was derived from the μ/ρ values. Results showed the studied glasses have good shielding capability according to their mass attenuation coefficients, transmission fractions and HVL values.

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  • MakaleYalnız künye2019Scopus SJRQ3
    Anesthetic Efficiency of Three Medicinal Plant Oils for Aquatic Species: Coriander Coriandrum sativum, Linaloe Tree Bursera delpechiana, and Lavender Lavandula hybrida

    Can, Erkan; Kızak, Volkan; Can, Şafak Seyhaneyıldız; Özçiçek, Esin

    This study evaluated the potential of three essential oils (EOs) that were obtained from coriander Coriandrum sativum (CEO), linaloe tree Bursera delpechiana (BEO), and lavender Lavandula hybrida (LEO) as anesthetic agents. Convict Cichlids Amatitlania nigrofasciata (Günther 1867) were exposed to eight concentrations of anesthetic (50, 75, 100, 125, 150, 200, 250, and 300 μL/L). After exposure to the anesthetic, the fish were transferred to clean water to recover. All of the EOs produced an anesthetic effect after exposure to the compounds for 30 min at the minimal effective concentration (MEC), which was identified according to deep anesthesia (A5 < 3 min) and full recovery (R3 < 5 min) times. At 50 and 75 μL/L, the total loss of equilibrium was not observed for all tested EOs. The total loss of reflex was induced at a faster rate with higher concentrations of anesthetic in all groups. The recovery time generally increased as the concentration of the anesthetic increased. These findings suggest that CEO, BEO, and LEO are all novel potential anesthetics for aquaculture, and the optimal concentrations were identified as 150 μL/L (A5; 156 ± 1.7 s and R3; 165 ± 2.9 s), 125 μL/L (A5; 176 ± 3.5 s; R3; 125 ± 2.0 s), and 200 μL/L (A5; 20.1 ± 2.4 s and R3; 162 ± 3.4 s), respectively. When considering the active ingredients of EOs, this study also demonstrated that future studies should be focused on the major components such as linalyl acetate, 1.8-cineole, α-pinene, geraniol, and linalool. Their synergistic effects should be examined in herbal anesthetic treatments, since new commercial anesthetics will likely contain them.

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  • MakaleAçık Erişim2019Scopus SJRQ2
    Synthesis of poly(An-co-vp)/zeolite composite and its application for the removal of brilliant green by adsorption process: Kinetics, isotherms, and experimental design

    Tanyol, Mehtap; Kavak, Nevroz; Torlut, Gülben

    In this study, a poly(acrylonitrile-co-N-vinyl pyrrolidone)/zeolite (poly(AN-co-VP)/zeolite) composite was synthesized by in situ free radical polymerization (FRP). The structural properties of the composite were analyzed by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The characterization results indicated that the composite had a homogeneous and 3-dimensional (3D) structure. The decomposition temperature and glass transition temperature (Tg ) were found as 410∘ C and 152∘ C, respectively. A poly(AN-co-VP)/zeolite composite was used to investigate the adsorption of brilliant green (BG) which is a water-soluble cationic dye. The kinetics, isotherms, and thermodynamics of adsorption were examined, and results showed that equilibrium data fitted the Langmuir isotherm model, and the adsorption kinetics of BG followed pseudo-second-order model. According to the thermodynamic properties, the adsorption process was endothermic and spontaneous. Response surface methodology (RSM), which was improved by the application of the quadratic model associated with the central composite design, was employed for the optimization of the study conditions such as adsorbent mass, time, and initial dye concentration. The RSM indicated that maximum BG removal (99.91%) was achieved at the adsorbent mass of 0.20 g/50 mL, an initial BG concentration of 40.20 mg/L, and a contact time of 121.60 minutes.

    • SDG 12 · Sorumlu Üretim ve Tüketim
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