Sürdürülebilir Kalkınma Amaçları

Yazarlar

  • MakaleYalnız künye2018Scopus SJRQ1
    Biochemical responses of Gammarus pulex to malachite green solutions decolorized by Coriolus versicolor as a biosorbent under batch adsorption conditions optimized with response surface methodology

    Yildirim, Nuran Cikcikoglu; Tanyol, Mehtap; Yildirim, Numan; Serdar, Osman; Tatar, Sule

    The current study was aimed to investigate the detoxifying and antioxidant enzyme response of Gammarus pulex exposed to malachite green (MG) after decolorization by Coriolus versicolor. Response surface methodology (RSM) was utilized to optimize the decolorization conditions of MG synthetic solutions by C. versicolor. Glutathione (GSH), malondialdehyde (MDA) levels and glutathione peroxidase (GPX), catalase (CAT), superoxide dismutase (SOD), glutathione S-transferase (GST), cytochrome P450 1A1 (CYP1A1) activities in G. pulex exposed to undecolorized (A1) and decolorized (A2) MG synthetic solution during 24 and 96 h were tested by using ELISA method. SOD and GPX enzyme activity was increased after decolorization (p > 0.05). CAT enzyme activity was increased in A2 group during 24 h (p > 0.05) but decreased during 96 h (p < 0.05). GSH levels were increased in A2 group during 24 and 96 h (p < 0.05). GST, CYP1A1 enzyme activity and MDA levels were decreased after decolorization during 96 h (p < 0.05). In this study, GSH levels, CAT, GST and CYP1A1 activities in G. pulex approved the capability of C. versicolor in MG decolorization, optimized with RSM.

    AtıfScopus28WoS24OpenAlex31
    ScopusWeb of SciencePubMedİncele
  • MakaleAçık Erişim2017Scopus SJRQ1
    Application of response surface methodology for optimization of Remazol Brilliant Blue R removal onto a novel polymeric adsorbent

    Torgut, Gulben; Tanyol, Mehtap; Biryan, Fatih; Pihtili, Guzin; Demirelli, Kadir

    The poly[2-hydroxy-3-(1-naphthyloxy)propyl] methacrylate [poly(NOPMA)] was used as a novel adsorbent for the removal of Remazol Brilliant Blue R (RBBR) known as a reactive dye. Physico-chemical properties of polymer were analyzed by FT-IR and SEM before and after dye adsorption. The Langmuir and Freundlich isotherms were used to explain the adsorption equilibrium, and when it was compared with each other it was seen that the adsorption process was well explained by the Langmuir isotherm model and showing a monolayer adsorption capacity for RBBR of 238.10 mg/g. Kinetic models known as pseudo-first-order, pseudo-second-order and intra-particle diffusion model were utilized to analyze the mechanism of adsorption, and results indicated that was an adsorption kinetic suitable with the pseudo-second-order. The thermodynamic parameters (∆Ho, ∆So, ∆Go) indicated that the adsorption process was spontaneous and endothermic. To optimize the study conditions, the effects of the concentration of RBBR, adsorbent amount and contact time on the adsorption were investigated by response surface methodology (RSM). According to RSM results, maximum RBBR removal was reached at the optimum initial dye concentration of 60.85 mg/L, adsorbent dosage of 0.04 g/50 mL and contact time of 59.91 min.

    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus40WoS37OpenAlex43
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2017Scopus SJRQ2
    Optimizing electrocoagulation process using experimental design for COD removal from unsanitary landfill leachate

    Ogedey, Aysenur; Tanyol, Mehtap

    Leachate is the most difficult wastewater to be treated due to its complex content and high pollution release. For this reason, since it is not possible to be treated with a single process, a pre-treatment is needed. In the present study, a batch electrocoagulation reactor containing aluminum and iron electrodes was used to reduce chemical oxygen demand (COD) from landfill leachate (Tunceli, Turkey). Optimization of COD elimination was carried out with response surface methodology to describe the interaction effect of four main process independent parameters (current density, inter-electrode distance, pH and time of electrolysis). The optimum current density, inter-electrode distance, pH and time of electrolysis for maximum COD removal (43%) were found to be 19.42 mA/m2, 0.96 cm, 7.23 and 67.64 min, respectively. The results shown that the electrocoagulation process can be used as a pre-treatment step for leachate.

    AtıfScopus15WoS16
    ScopusWeb of SciencePubMedİncele
  • MakaleAçık Erişim2017Scopus SJRQ2
    Rapid malachite green removal from aqueous solution by natural zeolite: Process optimization by response surface methodology

    Tanyol, Mehtap

    In this study, malachite green removal from aqueous solutions by natural zeolite was investigated. The interaction between zeolite and malachite green was determined by SEM/EDX and FTIR. The parameters like adsorbent dosage (0.1–1 mg/100 mL), initial malachite green concentration (40–200 mg/L) and the contact time (10–600 s) were optimized using the central composite design of response surface methodology. Maximum removal yield (99.70%) was obtained at an adsorbent dosage of 0.68 mg/100 mL, an initial malachite green concentration of 79.02 mg/L, and at 414 s contact time. The equilibrium process complied better with the Langmuir isotherm model, which exhibits a single layer adsorption, when compared with the Freundlich isotherm model. Adsorption kinetics followed the pseudo-second-order type kinetic and intra-particle diffusion played an important role onto adsorption mechanism of malachite green. The findings of this study demonstrated that zeolite which is found abundant on earth as a cheap and efficient adsorbent could be used for rapid malachite green adsorption from aqueous solutions.

    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus12WoS11OpenAlex13
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2016Scopus SJRQ3
    Optimization of Cadmium Removal from Water by Hydroxyapatite Using Experimental Design Methodology

    Ince, Olcay Kaplan; Ince, Muharrem; Karaaslan, Nagihan M.; Yonten, Vahap

    The presence of cadmium in water is a serious threat to the environment. The removal of cadmium using hydroxyapatite as an adsorbent was studied in an aqueous system. Hydroxyapatite was prepared to process the adsorption of cadmium from aqueous solution. Experimental design methodology and response surface methodology (RSM) with a quadratic model associated with central composite design was used to optimize the pH, initial heavy metal concentration, final volume, and adsorbent dosage for the removal of cadmium. Analysis of variance identified significant factors on each parameter. RSM indicated that a pH of 8.5, a sample volume of 166 mL, an adsorbent of dosage 0.57 g, and a contact time of 82 min were optimal for the adsorption of Cd(II). Under these conditions, the removal of Cd(II) was 895 mg g(-1).

    • SDG 6 · Temiz Su ve Sanitasyon
    AtıfWoS17OpenAlex15
    Web of Scienceİncele