Sürdürülebilir Kalkınma Amaçları
Yazarlar
- Zengin, Gokhan(12)
- Gürler, Nedim(9)
- Aglar, Erdal(6)
- Omac, Basri(6)
- Torğut, Gülben(5)
- Cakilcioglu, Ugur(4)
- Caprioli, Giovanni(4)
- Darendelioglu, Ekrem(4)
- Erten, Fusun(4)
- Karataş, Mehmet(4)
- Koçak, Berna(4)
- Mustafa, Ahmed M.(4)
- Ozturk, Burhan(4)
- Polat, Rıdvan(4)
- Tanyol, Mehtap(4)
- Yeşiltepe, Akgün(4)
- Alan, Davut(3)
- Angeloni, Simone(3)
- Ayhan, Nagihan Karaaslan(3)
- Dall'Acqua, Stefano(3)
- Eroglu, Zeynep(3)
- Goksu, Ali(3)
- Işık, Erdem(3)
- Kaplan, Alevcan(3)
- Mahomoodally, Mohamad Fawzi(3)
- Nilofar(3)
- Sabanci, Serdal(3)
- Sabancı, Serdal(3)
- Say, Yakup(3)
- Serdar, Osman(3)
- Sinan, Kouadio Ibrahime(3)
- Tekin, Onur(3)
- Tuğan, Volkan(3)
- Uba, Abdullahi Ibrahim(3)
- Yagi, Sakina(3)
- Yazdıç, Ferit Can(3)
- Çakılcıoğlu, Uğur(3)
- İpek, Yeliz(3)
- Ak, Gunes(2)
- Akkoyun, H. Turan(2)
Yayınlar
- MakaleAçık Erişim2025Scopus SJRQ2Effect of Nano Titanium Dioxide on the Electrical and Thermal Properties of Poly(2,2,2-Trifluoroethyl Methacrylate) for Dielectric Materials
Barım, Esra; Torgut, Gülben
The increasing application areas of energy storage devices in recent years make it necessary to produce materials with sufficient efficiency. In this study, composites of poly(2,2,2-trifluoroethyl methacrylate) P(TFEM) homopolymer with nano titanium dioxide (TiO2 NPs) were prepared for applications of these devices requiring thermoelectric properties, and their thermal, dielectric, and electrical properties were investigated. Thermogravimetric analysis showed that TiO2 NPs in all composites limited the thermal diffusion of TiO2 NPs in the polymer matrix and increased the thermal stability of P(TFEM) from 341°C to 361.5°C. As dielectric properties, the dielectric constant (ε′), dielectric loss (ε″), AC conductivity (σac), and real (Z′) and imaginary (Z″) components of impedance of the composites containing TiO2 NPs were evaluated as functions of frequency and different weight percentages of TiO2 NPs. Increases in ε′ and ε″ at up to 15 wt% TiO2 NPs suggested increased dipole polarization. At 100 Hz, the ε″ value of P(TFEM) increased from 3.2 × 10−2 to 1.1 × 10−2, σac increased from 4.98 × 10−10 to 1.00 × 10−8, Z′ increased from 3.67 × 1010 to 8.66 × 1010, and Z″ increased from 2.09 × 108 to 4.42 × 108. Furthermore, ε′, ε″, and impedance decreased with increasing frequency for both P(TFEM) and TiO2 NPs composites, while σac increased with increasing frequency.
AtıfScopus3OpenAlex5
İncele - MakaleYalnız künye2025Scopus SJRQ1Patterns and Predictors of Nurse Turnover Intentions Based on Years of Nursing Experience: A Cluster Analysis Approach
Baris, Veysel Karani; Yesiltepe, Akgun; Celik, Gulbahar
Aim: To identify patterns and predictors of nurse turnover intentions based on years of nursing experience using a cluster analysis approach. Background: Nurses with varying years of experience have different characteristics. These differences can also lead to distinct patterns and predictors of turnover intentions. Methods: For this descriptive study, 785 nurses from hospitals across different regions of Türkiye participated in a survey. Data was collected through online questionnaires between April and May 2022. The K-means unsupervised machine learning algorithm was employed to classify nurses into distinct clusters based on their experience. Multiple linear regression analyses were conducted to identify the predictors of turnover intention specific to each cluster. The STROBE guideline was followed for reporting. Results: Cluster analysis grouped nurses into three categories by experience level: low, medium and high. The medium-experience group had the highest turnover intention, whereas the high-experience group had the lowest. Work stress was the only common predictor across all groups. Low income predicted turnover only for the low-experience group, and gender was significant only for the medium-experience group. Conclusion: This study revealed that turnover intention and its predictors vary by experience level, indicating a need for retention strategies tailored to nurses' years of experience. By considering subgroup characteristics, policymakers can develop targeted interventions to enhance nurse retention.
- MakaleAçık Erişim2025Scopus SJRQ2PCL/chitosan composite films enhanced with Bi2O3 in nuclear shielding applications: Irradiation resistance, thermal and structural properties
Yılmaz, Demet; Pekdemir, Mustafa Ersin; Dik, Gamze; Selçuk Pekdemir, Sibel; Ulu, Ahmet; Taşgın, Yahya; Ateş, Burhan
In this work, irradiation resistance, thermal, and structural characteristics of Bi2O3-reinforced poly ε-caprolactone/chitosan composites for nuclear shielding applications were studied. PCL/CTS/Bi2O3 composite films were prepared by using different amounts of Bi2O3 (0.5%–4.0% (w/v)). The radiation shielding parameters of the synthesized composite films were both experimentally and theoretically measured at the high energy region. The equivalent dose rates of the prepared film samples were measured using a fast neutron source. Also, to determine the irradiation resistance, the samples were irradiated with Am-241 and Co-60 sources for 30 days. The MFP values at 80.99 keV changed by approximately 61% in samples PCL/CTS and PCL/CTS/4% Bi2O3. The results show that Bi2O3 content increases the gamma shielding abilities in PCL/CTS films. According to TGA results, the thermal stability of the polymer composite films is increased by the addition of Bi2O3 to the PCL/CTS blend film. The results show that PCL/CTS composite materials can be used as protective coating materials for nuclear shielding. Highlights: PCL/CTS/Bi2O3 composite films were prepared by the solvent casting method. The thermal stability of the composite films increased by increasing the Bi2O3 amount. Bi2O3 increased the LAC and MAC values of the composite films. PCL/CTS/Bi2O3 composite films have a neutron shielding effect.
AtıfScopus5WoS5
İncele - MakaleYalnız künye2025Scopus SJRQ1Identification and source provenance of jadeite-bearing jade axes from Ulucak Höyük, Western Anatolia
Sayit, Kaan; Çevik, Özlem; Aktağ, Alican; Erdoğu, Burçin; Bamyacı, Onur; Vuruşkan, Osman; Sivil, Coşkun
The jades from Ulucak Höyük (İzmir, Turkey) are green-colored in hand specimen, and combined petrographic, XRD, and whole-rock analyses indicate that they mainly comprise jadeitic clinopyroxene, characterizing them as jadeite-bearing jades. Primitive mantle (PM)-normalized multi-element patterns reveal two distinct chemical groups. Both groups display depletion in Th and U; however, Group 1 shows a narrower elemental range and marked positive Pb anomaly. The second group, on the other hand, displays a wide elemental range in most elements and strong negative anomalies in Zr and Hf ([Nd/Zr]PM = 1.6–4.2; [Sm/Hf]PM = 1.8–3.5). Regarding REE systematics, both groups are characterized by weak positive slopes ([La/Yb]Ch = 1.7–5.3). However, whereas Group 1 shows coherent LREE-enriched trends, Group 2 displays flat- to LREE-enriched patterns with a wide range in Eu. When the geochemical features of Ulucak jades are compared with the high-pressure (HP) metamorphic rocks from Turkey and Greece, the similar multi-element patterns of Syros eclogites (Greece) to Group 2 Ulucak jades make Syros a possible source area for the Ulucak artefacts. On the other hand, the geochemical resemblance of the Sifnos jadeite-bearing gneisses to Group 1 Ulucak jades may raise the possibility of this island being another source for the Ulucak jades.
- MakaleYalnız künye2025Scopus SJRQ3Eco-Friendly and Practical Electrochemical Determination of Lactic Acid in Milk Using Boron Doped Diamond Electrode
İpek, Yeliz.; Koçak, Berna; Keçeci, Ali
In this study, an economical, environmentally friendly, sensitive, selective, and rapid voltammetric quantitative analysis method was developed using a boron doped diamond electrode to determine lactic acid (LA). Two linear working ranges were determined for LA determination in phosphate buffer solution (PBS, pH of 2). The first linear working range (LR1) was between concentrations of 1.5 × 10−6–8 × 10−6 mol· L−1, with a detection limit of 1.3 × 10−6 mol·L−1, and the limit of quantification (LOQ) was found to be 4.4 µmol· L−1. The second linear working range (LR2) was determined in the concentration range of 8.0–89.2 µmol·L−1. LOD was calculated as 15.8 µmol·L−1, and the LOQ value was calculated as 52.6 µmol·L−1 in the LR2. Intraday repeatability of the BDD electrode for LA determination was (RSD) 6.8% in LR1 and 11.8% in LR2. The interday repeatabilities of the BDD electrode in LR1 and LR2 were calculated as 7.7% and 4.7%, respectively. The developed electrochemical sensor was successfully applied for the determination of LA in milk sample. The sensor exhibited a short response time of about 10 s in PBS at pH 2. The recovery values of LA in PBS and milk sample were 97.3% and 96.1%, respectively.
AtıfScopus2WoS2OpenAlex2İncele - MakaleAçık Erişim2025Scopus SJRQ1Transauricular vagal nerve stimulation suppresses inflammatory responses in the gut and brain in an inflammatory bowel disease model
Atalar, Kerem; Alim, Ece; Yigman, Zeynep; Belen, Hayrunnisa Bolay; Erten, Fusun; Sahin, Kazım; Soylu, Ayse; Dizakar, Saadet Ozen Akarca; Bahcelioglu, Meltem
Inflammatory bowel disease (IBD) encompasses Crohn's disease (CD) and ulcerative colitis (UC), is a major health problem on a global scale and its treatment is unsatisfactory. We aimed to investigate the effects of transauricular vagal nerve stimulation (tVNS) on inflammation in rats with IBD induced by trinitrobenzene sulfonic acid (TNBS). A total of 36 adult female Sprague–Dawley rats were given TNBS, or vehicle, and tVNS, or sham, every other day for 30 min for 10 days. Postmortem macroscopic and microscopic colon morphology were evaluated by histological staining. Additionally, IL-1β, IL-6, IL-10, and TNF-α cytokine levels in the colon and the brain were evaluated by immunohistochemistry and western blotting analysis. TNBS induced epithelial damage, inflammation, ulceration, and thickened mucosal layer in the colonic tissues. Administration of tVNS significantly ameliorated the severity of TNBS-induced tissue damage and inflammatory response. TNBS also alters pro-inflammatory and anti-inflammatory balance in the brain tissue. TVNS application significantly suppressed the protein levels of pro-inflammatory cytokines, namely IL-1β, IL-6, and TNF- α while augmenting the level of anti-inflammatory cytokine IL-10 in the colonic and the brain tissue. We have shown that TNBS-mediated colonic inflammation and tissue damage are associated with neuroinflammatory responses in the brain tissue. Also demonstrated for the first time that neuroinflammatory response in the gut-brain axis is suppressed by tVNS in the IBD model. Non-invasive tVNS stands out as a new potential treatment option for types of IBD.
AtıfScopus13OpenAlex12
İncele - MakaleYalnız künye2025Scopus SJRQ3Development of alternative carbon fibre powder and rare earth element-based filler for high density polyethylene; [Entwicklung von alternativen Kohlenstofffaserpulvern und Seltene Erden-basierten Füllstoffen für Polyethylen hoher Dichte]
Ayikurt, P.; Kısmet, Y.; Dogan, A.; Höchstötter, K.H.; Fiedler, B.
This study developed alternative fillers to enhance the flowability of high-density polyethylene (HDPE). Lanthanum and cerium oxide with over 90 % purity were used as binder interfacial elements in fillers developed using both carbon fiber powder wastes and powder coating wastes. Polyethylene gel was used to make the fillers thermoplastic and homogenous. A total of six different fillers were developed and melt flow index analyses were performed. As a result of these analyses, it was found that the fluidity of high-density polyethylene improved significantly, especially with fillers containing carbon fiber powder. As a result, high-density polyethylene mixtures containing 10 %, 20 %, 30 %, 40 %, and 50% by weight of carbon fiber powder-based fillers were pressed into molds by a plastic injection molding machine, and samples were produced. According to the mechanical analysis results of these specimens, tensile and flexural strengths decreased slightly depending on the filling ratio, while the impact strengths remained constant. Differential scanning calorimetry analysis was performed to determine the glass transition temperature and melting/crystallization temperatures of the obtained mixtures, while thermogravimetric analysis was performed to determine the mass losses. At the same time, electron microscope analysis of the cross sections of the samples were performed.
- MakaleAçık Erişim2025Scopus SJRQ1Psychological effects of the COVID-19 pandemic on primary healthcare professionals in Turkey: One year into the pandemic
Yücel, Ummahan; Erkal Aksoy, Yasemin; Yaşar Yetişmiş, Habibe; Gök, Çiğdem
Aim and Objectives: This study aimed to determine the psychological effects of the COVID-19 pandemic on healthcare professionals working in primary care settings in the first year of the pandemic. Background: The healthcare industry has faced an unprecedented burden in the COVID-19 pandemic. Primary care professionals experienced the high level of psychological problems. Design and Methods: A total of 793 healthcare professionals from different regions of Turkey participated in this cross-sectional study. The STROBE (Strengthening the reporting of observational studies in epidemiology) checklist was used in the study. Data were collected online. Results: It has been found that more than half of healthcare professionals experienced severe depression, three-quarters experienced anxiety, and almost half experienced stress. It was also found that about half of the participants experienced a high degree of acute and chronic fatigue, and one-fifth experienced low inter-shift recovery. Conclusion: The effects of the COVID-19 pandemic on the mental health of primary care professionals, especially nurses and midwives, are alarming. The problems that arise from the flawed healthcare delivery models and gender inequality, which worsen the usual psychological effects of the pandemic on primary care professionals, should be addressed urgently. Relevance to Clinical Practice: Psychological support and rehabilitative services should be expanded to eliminate the short- and long-term psychological effects of the pandemic on healthcare professionals.
AtıfScopus1WoS1OpenAlex1İncele - MakaleYalnız künye2025Scopus SJRQ3Cotton Fabric and Polypropylene Fabrics Treated with Synthesized Zinc Diborate
İpek, Yeliz; Ertekin, Özlem
Cotton fabrics and polypropylene fabrics are mostly used fabrics in many areas. Zn(B4O7) powder was synthesized with a sequential wet precipitation and sintering method. Focused ion beam scanning electron microscopy (FIB-SEM) figures and energy dispersive X-ray spectroscopy (EDS) mapping results showed that zinc diborate was highly and homogeneously adsorbed on the surface of the treated fabrics. When differential thermal analysis (DTA) results were examined, heat release seemed to decrease by 0.71 kJ g−1, 0.61 kJ g−1, and 0.46 kJ g−1for cotton fabric treated with zinc diborate (C-117-ZB), polypropylene fabric (20 g m−2) treated with zinc diborate (PP-20-ZB), and polypropylene fabric (65 g m−2) treated with zinc diborate (PP-65-ZB), respectively. According to vertical burning test, burning rates of cotton fabric (C‒117), C‒117‒ZB, polypropylene fabric (PP‒65), PP‒65‒ZB, polypropylene fabric (PP‒20), and PP‒20‒ZB were calculated as 3.25 cm s−1, 1.93 cm s−1, 0.75 cm s−1, 0.36 cm s−1, 0.88 cm s−1, and 0.71 cm s−1, respectively. Heat releases and burning rate decreases were in good agreement for all treated fabrics. Also breaking strengths of both fabric types were improved. The washing test exhibited that the amount of zinc diborate powder on the cotton fabric sample was released by 25.49% while PP-65-ZB and PP-20-ZB fabrics released about 90% by weight of adsorbed powder. Although improvement was observed in the fire resistance of PP fabrics, antibacterial activity against Escherichia coli and Staphylococcus aureus could not be achieved. However, antibacterial activity was provided only for the cotton fabric.
- MakaleAçık Erişim2025Scopus SJRQ3Experimental and Theoretical Study on the Freshwater Productivity of a Single-Slope Solar Still
Tuğan, Volkan; Işık, Erdem; İnallı, Mustafa
Converting saline water into freshwater using renewable energy resources is crucial to address global shortages of freshwater. This study aims to investigate the freshwater productivity of a single-slope solar still (SSS) operating with solar energy, one of the renewable energy sources. The main motivation of this study is to evaluate the experimental, theoretical, and economic performance of the solar still under climate conditions that have not been sufficiently studied before. Experimental analyses were conducted under the climatic conditions of Tunceli, a city located in the Eastern Anatolia Region of Türkiye. In addition, a comprehensive theoretical analysis was carried out using energy equations, and the experimental and theoretical results were compared with each other. Finally, the economic feasibility of the system was evaluated through a cost analysis. The SSS's experimental and theoretical productivity were found to be 1883.9 and 2458.7 g/m2/day, respectively. The experimental thermal efficiency for this still was 15.1%, whereas the theoretical thermal efficiency was 19.7%. It was concluded that the theoretical productivity and efficiency values were close to the experimental values and the difference between them originated from the assumptions of theoretical calculations. The cost of water distilled by the single-slope solar distillation unit was found to be $0.077/kg, and the payback period was found to be 9 months.
AtıfScopus2WoS3OpenAlex2İncele - MakaleAçık Erişim2025Scopus SJRQ1Improvement of mechanical, dynamic mechanical, and thermal properties of almond shell powder reinforced acrylonitrile butadiene styrene composites by addition of cerium oxide
Doğan, Akar; Güneş, Çağdaş
Currently, natural materials are gradually replacing synthetic materials in polymer composites due to factors including cost-effectiveness, sustainability, and the availability of raw materials. This study examined the variations in thermal, mechanical, and dynamic mechanical properties of acrylonitrile butadiene styrene (ABS) thermoplastic composite materials incorporating varying ratios of almond shell powder (ASP) and Cerium Oxide (CeO2). Tensile tests, three-point bending tests, dynamic mechanical analyses, and thermogravimetric analyses were conducted. Scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS) analyses were employed to assess pure ABS and nine distinct composite materials. The tensile strength, elastic modulus, and three-point bending strength of the composite material exhibited increases of 6%, 7%, and 7.5%, respectively, compared to pure ABS, with various ratios of almond shell powder and CeO2 reinforcement. Moreover, composite materials exhibit elevated glass-transition temperatures and storage moduli compared to pure ABS. Microstructure images obtained through SEM and EDS element mapping illustrate the distribution of ASP and CeO2 in ABS, influencing its mechanical and thermal properties. Highlights: Almond shell powder and cerium oxide were used as filler materials in ABS. Mechanical, morphological, and dynamic mechanical properties were investigated. Almond shell powder enhanced the mechanical properties of the ABS composite. Low cerium oxide supplementation improved the mechanical properties.
AtıfScopus4WoS4OpenAlex5İncele - MakaleAçık Erişim2025Scopus SJRQ1The effect of nursing services management efficiency on nurses’ professional commitment: A cross-sectional study
Arslan Seker, Sevda; Coskun Palaz, Simge
Aim: To determine the effect of nurses' perceptions of the effectiveness of nursing services management on their professional commitment. Background: Effective healthcare management is crucial for improving patient care quality. Understanding nurses' perspectives on nursing services management and their commitment provides valuable insights for management strategies, improving well-being and healthcare outcomes. Methods: This descriptive, cross-sectional, and correlational study involved 265 state hospital nurses. Data were collected between November 2020 and June 2021 using descriptive characteristic form, Nursing Services Management Effectiveness Scale, and Nursing Professional Commitment Scale. This study adhered to the STROBE checklist. Results: Nurses' views on the effectiveness of nursing services management and their professional commitment were found to be influenced by age, professional experience, and institutional positions. The average scores for nursing services management perception and professional commitment were 2.65 ± 0.72 and 66.63 ± 12.40, respectively. A statistically significant positive and low-level correlation was observed between nurses' nursing services management perception and professional commitment scores. Nurses' positive perception of nursing services management explains 17.1% of the variance in nurses' professional commitment levels. Discussion and conclusion: This study outlines how nurses' views on effective nursing services management can enhance their professional commitment. Managers should contribute to increase nursing services management efficacy by eliminating deficiencies in management practices to make their institutions successful and to increase their employees’ professional commitment level. Implications for nursing and health policy: Assuming positive perceptions of nursing management increase nurses' professional commitment, developing policies to boost organizational support is vital. Managers should focus on improving nursing services management to increase organizational success, increase nurses' professional commitment, and achieve the best health outcomes by eliminating management deficiencies.
AtıfOpenAlex2İncele - MakaleYalnız künye2025Scopus SJRQ1Using Camelina Seed Mucilage as a Fat Replacer in the Production of Cookies and Its Effect on Physicochemical and Technological Properties
Ozcan, Yasemin; Ozdemir-Orhan, Necla; Eroglu, Zeynep; Yilmaz, Merve Silanur
In this study, for the first time, camelina (Camelina sativa (L.) Crtz.) seed mucilage (CM) was used as a fat substitute in a cookie formula, and the physicochemical, textural, and functional properties of mucilage-incorporated cookies were investigated. The moisture, protein, ash, fat, and carbohydrate content of the CM was 6.46% ± 0.35%, 17.44% ± 0.62%, 11.49% ± 0.39%, 1.27% ± 0.10%, and 63.16% ± 0.58%, respectively. Fourier transform infrared (FTIR) spectroscopy identified acidic (–COOH) functional groups in the CM. Four distinct cookie samples were examined: The control-cookie, 20% CM-cookie, 40% CM-cookie, and 60% CM-cookie were prepared by replacing shortening with CM at 0%, 20%, 40%, and 60% levels, respectively. The mucilage-incorporated doughs were softer, springy, cohesive, and resilient compared to the control dough (p < 0.05). As for the cookies, the fat content of the 20% CM-cookie, 40% CM-cookie, and 60% CM-cookie samples decreased by 12.52%, 31.49%, and 50.12%, respectively, compared to the control-cookie. The control-cookie had the lowest baking loss (p < 0.05), and the baking loss values of the mucilage-incorporated cookies increased with increasing fat replacement level. The highest spread ratio was recorded in the 20% CM-cookie, followed by the control-cookie (p < 0.05). The highest hardness and brittleness values (70.68 ± 3.37 N and 11.52 ± 0.34 mm) belonged to the 60% CM-cookie, whereas the lowest (19.42 ± 1.42 N and 8.80 ± 0.26 mm) belonged to the control-cookie (p < 0.05). Incorporating mucilage into the cookie formula increased the total phenolic compound content but decreased the antioxidant activity. These results show that CM has potential utility as a fat substitute in cookie production without significant quality loss.
AtıfScopus3WoS2OpenAlex3İncele - MakaleYalnız künye2024Scopus SJRQ2Synthesis and characterization of TiNbZrMo medium-entropy bio-composites: Microstructure, mechanical properties, and in vitro degradation
Say, Yakup
This study reports the synthesis and characterization of hydroxyapatite (HA)-based bio-composites reinforced with varying amounts (by weight, 1–15 wt.%) of bio-medium entropy alloy (BioMEA) for load-bearing implant applications. BioMEA powders consisting of Ti, Nb, Zr, and Mo were mechanically alloyed for 100 h and subsequently added to HA using powder metallurgy techniques. To show the effect of BioMEA, the microstructure, density, and mechanical tests have been conducted and the synthesized BioMEA was characterized by scanning electron microscope (SEM), x-ray diffractometer (XRD), and Fourier-transform infrared spectroscopy (FTIR) analysis. In addition, in vitro degradation behavior and bioactivity analyses of bio-composites have been conducted. XRD analysis revealed the formation of BioMEA after 20 h of mechanical alloying. The highest density value of 2.47 g/cm3 was found in 15 wt.% BioMEA-reinforced bio-composite. The addition of BioMEA reinforcement led to a significant increase in hardness and tensile strength values, with the highest values observed at 15 wt.% reinforcement. Compression tests demonstrated a significant increase in compressive strength and deformation capability of the bio-composites with the highest values observed at 15 wt.% BioMEA addition. The highest toughness of 7.68 kJ/m2 was measured in 10 wt.% MEA-reinforced bio-composites. The produced bio-composite materials have an elastic modulus between 3.5–5.5 GPa, which may provide a solution to the stress shielding problems caused by the high elastic modulus of metallic implant materials. The most severe degradation occurred in 15 wt.% MEA-reinforced bio-composites, and the effect of degradation caused a decrease in Ca and an increase in Ti-Ni-Zr-Mo in all bio-composites. These findings suggest that HA/BioMEA bio-composites have the potential to be developed as advanced biomaterials with moderate mechanical and biological properties for load-bearing implant applications.
AtıfScopus2WoS1OpenAlex3İncele - MakaleAçık Erişim2024Scopus SJRQ2Modeling the growth behavior of Salmonella spp. in grated carrots inoculated with different inoculum levels stored at various temperatures
Omac, Basri
The consumption of fresh and fresh-cut fruits and vegetables, such as carrots, has increased for the last decades for a healthy life and an adequate diet, but concerns regarding the microbial safety of them have been raised. The present study was conducted to develop predictive models for Salmonella spp. in grated carrots. The results showed that Salmonella spp. did not display growth at 5°C, but it grew in grated carrots at other temperatures (10, 15, 20, 25, and 37°C) for both inoculum levels. Also, the inoculum levels affected the growth of this pathogen in grated carrots when the storage temperatures ranged from 15 to 25°C. The theoretical minimum temperatures calculated using the Huang model were 3.48 and 5.79°C for inoculum levels of 101 and 102 CFU/g, respectively. The primary and secondary models performed well in terms of agreement between experimental and estimated values. Furthermore, compared to the Ratkowsky model, the theoretical minimum temperature was given a more reasonable value using the Huang model. The models developed in the present study will be a useful input for future quantitative microbial risk assessment to appraise the proliferation of Salmonella spp. in grated carrots throughout the production process, storage, and distribution.
AtıfScopus4WoS4OpenAlex5İncele - MakaleAçık Erişim2024Scopus SJRQ1Delamination Magmatism in Eastern Anatolia: A Geochemical Perspective
Aktağ, Alican; Sayit, Kaan; Furman, Tanya; Peters, Bradley J.
The Sr-Nd-Hf-Pb isotope geochemistry of the Late Miocene Tunceli Volcanics suggests that they are the products of mixed asthenospheric and lithospheric mantle melts. The combined elemental and mineral chemistry data additionally indicate that a pyroxenite component of lithospheric origin is involved in their genesis. Calculations favor melting depths of ∼2 GPa for the Tunceli lavas, that is, deeper than the current lithosphere-asthenosphere boundary beneath Eastern Anatolia. Geochemical data suggest that during regional Neo-Tethyan subduction, dense (i.e., pyroxenite-bearing) domains formed by progressive melt intrusion into the lower lithosphere resulted in gravitational instabilities. This unstable density configuration eventually led to the foundering of the eastern Anatolian lithosphere in the Late Miocene, resulting in progressive melting of fusible pyroxenite-bearing domains at asthenospheric depths. We demonstrate that these pyroxenitic melts mixed with ambient asthenospheric melts and generated the Tunceli lavas.
AtıfScopus7OpenAlex9İncele - MakaleAçık Erişim2024Scopus SJRQ3Exploring Sorbus torminalis Leaves: Unveiling a Promising Natural Resource for Diverse Chemical and Biological Applications
Ak, Gunes; Tüfekci, Enis Fuat; Mustafa, Ahmed M.; Caprioli, Giovanni; Altunoglu, Yasemin Celik; Baloglu, Mehmet Cengiz; Cakılcıoglu, Ugur; Polat, Rıdvan; Darendelioglu, Ekrem; Zengin, Gokhan
Sorbus torminalis (L.) Crantz has a rich history of versatile applications spanning the fields of medicine and nutrition. It is noteworthy that the decoction obtained from S. torminalis leaves is a traditional treatment method against both diabetes and stomach disorders. Phytochemical profiling determined by HPLC/MS-MS. The effects of the extracts on cell viability were investigated using the MTT (3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide) method against MDA-MB-231 cell line (human breast adenocarcinoma).The ethanol/water extract contained more concentration of total phenolic (91.41 mg gallic acid (GAE) equivalent /gr) and flavanoid (29.10 mg rutin (RE) equivalent/gr) in the tested extract (p<0.05). Resulting of HPLC analysis, the chemical constituents varied depending on the solvents and chlorogenic acid, hyperoside, isoquercetin, delphindin-3,5-diglucoside, procyanidin B2, epicatechin, neochlorogenic acid, 3,5-dicaffeoylquinic acid were identified in all extracts. Overall, ethanol, n-hexane and ethyl acetate extracts showed the highest inhibition for the tyrosinase enzyme. The effect of leaf extracts of S. torminalis on antimicrobial, biofilm inhibitory, and anticancer activities was examined. Based on outcomes of our study recognize this plant as a critical source of medically active chemicals for feasible phytopharmaceutical and nutraceutical applications, providing the first scientific insight into the detailed biological and chemical profiles of S. torminalis.
AtıfScopus7OpenAlex5İncele - MakaleAçık Erişim2024Scopus SJRQ2Leachate treatment via electrocoagulation–coal-based powdered activated carbon process: Efficiencies, mechanisms, kinetics, and costs
Ogedey, Aysenur; Oguz, Ensar
This study aims to improve COD, NH3-N, and turbidity removal from Bingöl's leachate using a single-reactor integrated electrocoagulation (EC)–coal-based powdered activated carbon (CBPAC) process under various experimental conditions. In the EC-CBPAC process, three stainless-steel cathodes and three aluminum electrodes were connected to the negative and positive terminals of the power supply, respectively. The initial concentrations in the leachate were 1044 mg O2/L for COD, 204 mg/L for NH3-N, and 57 NTU (or 71.25-mg (NH2)2H2SO4/L) for turbidity, respectively. After a 40-min EC-CBPAC process, with a CBPAC dosage of 5 g/L and pH of 5 for COD and turbidity, and 9.5 for NH3-N, the optimum removal efficiencies for COD, NH3-N, and turbidity were achieved at 92%, 40%, and 91%, respectively. When the EC process was applied without CBPAC under the same experimental conditions, the removal efficiencies of COD, NH3-N, and turbidity were 87%, 28%, and 54%, respectively. Before and after the EC-CBPAC process, the Brunauer–Emmett–Teller (BET) surface area, pore volume, and mean pore diameter of the CBPAC were found to be (888 m2/g, 0.498 cm3/g, and 22.28 Å) and (173 m2/g, 0.18 cm3/g, and 42.8 Å), respectively. The optimum pseudo-first-order (PFO) rate constants for COD, turbidity, and NH3-N were determined to be 3.15 × 10−2, 4.77 × 10−2, and 8.8 × 10−3 min−1, respectively. With the current density increasing from 15 to 25 mA/cm2, energy consumption, unit energy consumption, and total cost increased from 68.7 to 122.4 kWh/m3, 6.948 to 15.226 kWh/kg COD, and 0.85 to 1.838 $/kg COD, respectively. Practitioner points: EC-CBPAC process has greater COD, NH3-N, and turbidity removal efficiency than EC process. COD and turbidity achieved their optimum disposal efficiencies at 92% and 91%, respectively, at pH 5 The most efficient disposal efficiency for NH3-N was observed to be 40% at pH 9.5. EC-CBPAC process increased removal efficiencies for COD, NH3-N, and turbidity by 20%, 19%, and 38%, respectively, compared with EC alone. The turbidity, NH3-N, and COD disposal fitted PSO model due to high correlation values (R2 0.94–0.99).
AtıfScopus3WoS3OpenAlex3İncele - MakaleYalnız künye2024Scopus SJRQ2Evaluation of effect of boric acid on thermoplastic starch: Morphological, mechanical, barrier, and optical properties
Yoğurtçu, Hakan; Gürler, Nedim
In this study, starch was modified with different amounts of boric acid, and the degree of substitution of the synthesized compounds at different temperatures and times was determined by Fourier transform infrared (FTIR) and titration methods. The degrees of substitution in both methods showed similar tendency. Optimum conditions were determined, and thermoplastic starch (TPS) and boric acid (B) films were prepared by casting method using glycerol as plasticizer. The morphological properties of the films were studied by scanning electron microscope-energy dispersive spectrometry (SEM-EDS). According to the FTIR results, it was observed that the B-O and B-O-C stretching vibrations increased when the amount of boric acid increased. The tensile strength, water barrier (swelling capacity, solubility, and water vapor permeability), and optical properties of samples were investigated. The swelling capacity, solubility, and water vapor permeability of the films decreased with the addition of 0.5% boric acid to the starch, but the highest tensile strength was achieved. The tensile strength for TPSB0.5% increased compared to control group TPS. In addition, the film showed the highest transparency. Thermoplastic film containing 0.5% boric acid can be used as a packaging material due to its improved mechanical and water barrier. Highlights: The thermoplastic starch and boric acid composite were successfully produced. The presence of boric acid was confirmed by energy dispersive spectrometry (EDS). The degree of substitution was determined by two different methods. Transparency increased with the addition of boric acid. Tensile strength improved with boric acid content.
AtıfScopus26WoS25OpenAlex27İncele - MakaleYalnız künye2024Scopus SJRQ3Assessing the Chemical Composition, Antioxidant and enzyme Inhibitory Effects of Pentapleura subulifera and Cyclotrichium glabrescens Extracts
Nilofar, Nilofar; Zengin, Gokhan; Acar, Mikail; Bouyayha, Abdelhakim; Youssra, Aalilou; Eldahshan, Omayma; Fayez, Shaimaa; Fahmy, Nouran
The Lamiaceae family, encompassing diverse plant species, holds significant value in food, medicine, and cosmetics. Within this family, Pentapleura subulifera and Cyclotrichium glabrescens, relatively unexplored species, were investigated for their chemical composition, antioxidant capacity, and enzyme-inhibiting effects. The chemical composition of hexane, methanolic, and aqueous extracts from P. subulifera and C. glabrescens were analyzed using LC-ESI-MS/MS and the non-polar hexane fraction was investigated via GC-MS. The antioxidant potential of the extracts was determined through radical scavenging, reducing power and metal chelating assays. Additionally, inhibitory activity against six enzymes – acetylcholinesterase (AChE), butyrylcholinesterase (BChE), tyrosinase, amylase, and glucosidase – was examined. The aqueous extract of P. subulifera and the methanolic extract of C. glabrescens exhibited elevated phenolic content at 129.47 mg gallic acid equivalent (GAE)/g and 55.97 mg GAE/g, respectively. Chemical profiling of the constituents of the two plant species resulted in the identification of a total of twenty compounds. The majority of which belonged to flavonoids and quinic acid derivatives, primarily concentrated in the methanol and aqueous extracts. Among all antioxidant assays, the aqueous extracts of P. subulifera demonstrated superior antioxidant activity, with the highest recorded activity of 404.93 mg trolox equivalent (TE)/g in the cupric reducing antioxidant capacity (CUPRAC) test. Meanwhile, the hexane extract of C. glabrescens exhibited the highest AChE inhibitory activity at 2.71 mg galanthamine equivalent (GALAE)/g, followed by the methanol extract of P. subulifera at 2.41 mg GALAE/g. These findings unequivocally establish the notable antioxidant and enzyme inhibitory activity of P. subulifera and C. glabrescens extracts, underscoring their potential as a source of valuable natural antioxidants.
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